Volume 129
Main Index

Issue 01

Regioselective Arene Hydroxylation Mediated by a (μ-Peroxo)diiron(III) Complex:  A Functional Model for Toluene Monooxygenase Mai Yamashita, Hideki Furutachi, Takehiko Tosha, Shuhei Fujinami, Wataru Saito, Yonezo Maeda, Kenji Takahashi, Koji Tanaka, Teizo Kitagawa, and Masatatsu Suzuki pp 2–3 DOI: 10.1021/ja063987z Supporting Info

Fe(I)-Mediated Reductive Cleavage and Coupling of CO2:  An FeII(μ-O,μ-CO)FeII Core Connie C. Lu, Caroline T. Saouma, Michael W. Day, and Jonas C. Peters pp 4–5 DOI: 10.1021/ja065524z Supporting Info

Self-Repair of Thymine Dimer in Duplex DNA Matthew Ray Holman, Takeo Ito, and Steven E. Rokita pp 6–7 DOI: 10.1021/ja0668365 Supporting Info

A Single-Molecule Magnet with a “Twist” Constantinos J. Milios, Alina Vinslava, Peter A. Wood, Simon Parsons, Wolfgang Wernsdorfer, George Christou, Spyros P. Perlepes, and Euan K. Brechin pp 8–9 DOI: 10.1021/ja0666755 Supporting Info

Kinase-Catalyzed Biotinylation for Phosphoprotein Detection Keith D. Green and Mary Kay H. Pflum pp 10–11 DOI: 10.1021/ja066828o Supporting Info

Immobilizing Au Nanoparticles with Polymer Single Crystals, Patterning and Asymmetric Functionalization Bing Li and Christopher Y. Li pp 12–13 DOI: 10.1021/ja0668318 Supporting Info

Mammalian Cell Surface Imaging with Nitrile-Functionalized Nanoprobes:  Biophysical Characterization of Aggregation and Polarization Anisotropy in SERS Imaging Qingyan Hu, Li-Lin Tay, Matthew Noestheden, and John Paul Pezacki pp 14–15 DOI: 10.1021/ja0670005 Supporting Info

A Dynamic Zn Site in Helicobacter pylori HypA:  A Potential Mechanism for Metal-Specific Protein Activity David C. Kennedy, Robert W. Herbst, Jeffrey S. Iwig, Peter T. Chivers, and Michael J. Maroney pp 16–17 DOI: 10.1021/ja066958x Supporting Info

Role of C,C‘-Linkage in the Formation and Stabilization of Supercarboranes. Synthesis and Structure of Carbon-Atoms-Apart 13-Vertex Carborane and 14-Vertex Metallacarborane Jian Zhang, Liang Deng, Hoi-Shan Chan, and Zuowei Xie pp 18–19 DOI: 10.1021/ja067129e Supporting Info

Nanowindow-Regulated Specific Capacitance of Supercapacitor Electrodes of Single-Wall Carbon Nanohorns Cheol-Min Yang, Yong-Jung Kim, Morinobu Endo, Hirofumi Kanoh, Masako Yudasaka, Sumio Iijima, and Katsumi Kaneko pp 20–21 DOI: 10.1021/ja065501k Supporting Info

Rh-Catalyzed Intermolecular Reactions of Alkynes with α-Diazoesters That Possess β-Hydrogens:  Ligand-Based Control over Divergent Pathways Patricia Panne and Joseph M. Fox pp 22–23 DOI: 10.1021/ja0660195 Supporting Info

Two-Step Potentially Prebiotic Synthesis of α-d-Cytidine-5‘-phosphate from d-Glyceraldehyde-3-phosphate Carole Anastasi, Michael A. Crowe, and John D. Sutherland pp 24–25 DOI: 10.1021/ja066495v Supporting Info

An Isolable Disilyne Anion Radical and a New Route to the Disilenide Ion upon Reduction of a Disilyne Rei Kinjo, Masaaki Ichinohe, and Akira Sekiguchi pp 26–27 DOI: 10.1021/ja066762x Supporting Info

Regio- and Chemoselective Silylmetalation of Functionalized Terminal Alkenes Shinji Nakamura and Masanobu Uchiyama pp 28–29 DOI: 10.1021/ja066864n Supporting Info

Why Excess Cyanide Can Be Detrimental to Pd-Catalyzed Cyanation of Haloarenes. Facile Formation and Characterization of [Pd(CN)3(H)]2- and [Pd(CN)3(Ph)]2- Kerwin D. Dobbs, William J. Marshall, and Vladimir V. Grushin pp 30–31 DOI: 10.1021/ja066931d Supporting Info

Preparation and Reactivity of Nanocrystalline Cocrystals Formed via Sonocrystallization Dejan-Krešimir Buar and Leonard R. MacGillivray pp 32–33 DOI: 10.1021/ja0671161 Supporting Info

Synthesis and Phase Transformation of In2Se3 and CuInSe2 Nanowires Hailin Peng, David T. Schoen, Stefan Meister, Xiao Feng Zhang, and Yi Cui pp 34–35 DOI: 10.1021/ja067436k Supporting Info

Production of Dihydroisocoumarins in Fusarium verticillioides by Swapping Ketosynthase Domain of the Fungal Iterative Polyketide Synthase Fum1p with That of Lovastatin Diketide Synthase Xiangcheng Zhu, Fengan Yu, Xing-Cong Li, and Liangcheng Du pp 36–37 DOI: 10.1021/ja0672122 Supporting Info

Mild Reductive Opening of Aryl Pyranosides Promoted by Scandium(III) Triflate Hua-Li Qin, Jason T. Lowe, and James S. Panek pp 38–39 DOI: 10.1021/ja067234o Supporting Info

Shape Selectivity in the Assembly of Lithographically Designed Colloidal Particles Stéphane Badaire, Cécile Cottin-Bizonne, Joseph W. Woody, Allen Yang, and Abraham D. Stroock pp 40–41 DOI: 10.1021/ja067527h Supporting Info

Low Temperature CO Oxidation over Unsupported Nanoporous Gold Caixia Xu, Jixin Su, Xiaohong Xu, Pengpeng Liu, Hongjuan Zhao, Fang Tian, and Yi Ding pp 42–43 DOI: 10.1021/ja0675503 Supporting Info

Direct N-Cyclopropylation of Cyclic Amides and Azoles Employing a Cyclopropylbismuth Reagent Alexandre Gagnon, Miguel St-Onge, Kelly Little, Martin Duplessis, and Francis Barabé pp 44–45 DOI: 10.1021/ja0676758 Supporting Info

Methods to Explore Cellular Uptake of Ruthenium Complexes Cindy A. Puckett and Jacqueline K. Barton pp 46–47 DOI: 10.1021/ja0677564 Supporting Info

Structural Criteria for the Design of Anion Receptors:  The Interaction of Halides with Electron-Deficient Arenes Orion B. Berryman, Vyacheslav S. Bryantsev, David P. Stay, Darren W. Johnson, and Benjamin P. Hay pp 48–58 DOI: 10.1021/ja063460m Supporting Info

High Fidelity Functional Patterns of an Extracellular Matrix Protein by Electron Beam-Based Inactivation Jonas Rundqvist, Beatriz Mendoza, Jeffrey L. Werbin, William F. Heinz, Christopher Lemmon, Lewis H. Romer, David B. Haviland, and Jan H. Hoh pp 59–67 DOI: 10.1021/ja063698a

Highly Diastereoselective Synthesis of Nucleoside Adducts from the Carcinogenic Benzo[a]pyrene Diol Epoxide and a Computational Analysis Mahesh K. Lakshman, John C. Keeler, Felix N. Ngassa, John H. Hilmer, Padmanava Pradhan, Barbara Zajc, and Kathryn A. Thomasson pp 68–76 DOI: 10.1021/ja063902u Supporting Info

Brilliant Sm, Eu, Tb, and Dy Chiral Lanthanide Complexes with Strong Circularly Polarized Luminescence Stéphane Petoud, Gilles Muller, Evan G. Moore, Jide Xu, Jurek Sokolnicki, James P. Riehl, Uyen N. Le, Seth M. Cohen, and Kenneth N. Raymond pp 77–83 DOI: 10.1021/ja064902x Supporting Info

Silica-Stabilized Gold Island Films for Transmission Localized Surface Plasmon Sensing Irit Ruach-Nir, Tatyana A. Bendikov, Ilanit Doron-Mor, Zahava Barkay, Alexander Vaskevich, and Israel Rubinstein pp 84–92 DOI: 10.1021/ja064919f

High-Yield Activation of Scaffold Polymer Surfaces To Attach Cell Adhesion Molecules T. Joseph Dennes, Geoffrey C. Hunt, Jean E. Schwarzbauer, and Jeffrey Schwartz pp 93–97 DOI: 10.1021/ja065217t Supporting Info

Composite Particles of Polyethylene @ Silica Hanan Sertchook, Hila Elimelech, Carina Makarov, Rafail Khalfin, Yachin Cohen, Michael Shuster, Florence Babonneau, and David Avnir pp 98–108 DOI: 10.1021/ja0653167

Supramolecular Control of Unwinding and Rewinding of a Double Helix of Oligoresorcinol Using Cyclodextrin/Adamantane System Hidetoshi Goto, Yoshio Furusho, and Eiji Yashima pp 109–112 DOI: 10.1021/ja065477a Supporting Info

Fe L-Edge X-ray Absorption Spectroscopy of Low-Spin Heme Relative to Non-heme Fe Complexes:  Delocalization of Fe d-Electrons into the Porphyrin Ligand Rosalie K. Hocking, Erik C. Wasinger, Yi-Long Yan, Frank M. F. deGroot, F. Ann Walker, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 113–125 DOI: 10.1021/ja065627h Supporting Info

Formation of the Early Photoproduct Lumi-R of Cyanobacterial Phytochrome Cph1 Observed by Ultrafast Mid-Infrared Spectroscopy Jasper J. van Thor, Kate L. Ronayne, and Michael Towrie pp 126–132 DOI: 10.1021/ja0660709 Supporting Info

Catalyst-Assisted Solution−Liquid−Solid Synthesis of CdS/CdSe Nanorod Heterostructures Lian Ouyang, Kristin N. Maher, Chun Liang Yu, Justin McCarty, and Hongkun Park pp 133–138 DOI: 10.1021/ja066243u Supporting Info

(α/β+α)-Peptide Antagonists of BH3 Domain/Bcl-xL Recognition:  Toward General Strategies for Foldamer-Based Inhibition of Protein−Protein Interactions Jack D. Sadowsky, W. Douglas Fairlie, Erik B. Hadley, Hee-Seung Lee, Naoki Umezawa, Zaneta Nikolovska-Coleska, Shaomeng Wang, David C. S. Huang, York Tomita, and Samuel H. Gellman pp 139–154 DOI: 10.1021/ja0662523 Supporting Info

Charge Recombination versus Charge Separation in Donor−Bridge−Acceptor Systems Joanna Wiberg, Lijun Guo, Karin Pettersson, Daniel Nilsson, Thomas Ljungdahl, Jerker Mårtensson, and Bo Albinsson pp 155–163 DOI: 10.1021/ja066346c Supporting Info

Tunneling in the 1,5-Hydrogen Shift Reactions of 1,3-Cyclopentadiene and 5-Methyl-1,3-Cyclopentadiene G. Robert Shelton, David A. Hrovat, and Weston Thatcher Borden pp 164–168 DOI: 10.1021/ja0664279 Supporting Info

Characterization of Folding Intermediates of a Domain-Swapped Protein by Solid-State NMR Spectroscopy Manuel Etzkorn, Anja Böckmann, François Penin, Dietmar Riedel, and Marc Baldus pp 169–175 DOI: 10.1021/ja066469x Supporting Info

Well-Defined Surface Imido Amido Tantalum(V) Species from Ammonia and Silica-Supported Tantalum Hydrides Priscilla Avenier, Anne Lesage, Mostafa Taoufik, Anne Baudouin, Aimery De Mallmann, Steven Fiddy, Manon Vautier, Laurent Veyre, Jean-Marie Basset, Lyndon Emsley, and Elsje Alessandra Quadrelli pp 176–186 DOI: 10.1021/ja0666809

Proton-Coupled Electron Transfer in Soybean Lipoxygenase:  Dynamical Behavior and Temperature Dependence of Kinetic Isotope Effects Elizabeth Hatcher, Alexander V. Soudackov, and Sharon Hammes-Schiffer pp 187–196 DOI: 10.1021/ja0667211 Supporting Info

Synthetic Control over Magnetic Moment and Exchange Bias in All-Oxide Materials Encapsulated within a Spherical Protein Cage Michael T. Klem, Damon A. Resnick, Keith Gilmore, Mark Young, Yves U. Idzerda, and Trevor Douglas pp 197–201 DOI: 10.1021/ja0667561

Unusual Crystallization Behaviors of Anatase Nanocrystallites from a Molecularly Thin Titania Nanosheet and Its Stacked Forms:  Increase in Nucleation Temperature and Oriented Growth Katsutoshi Fukuda, Yasuo Ebina, Tatsuo Shibata, Takashi Aizawa, Izumi Nakai, and Takayoshi Sasaki pp 202–209 DOI: 10.1021/ja0668116 Supporting Info

Controlling the Helicity of 2,2‘-Bipyridyl Ruthenium(II) and Zinc(II) Hemicage Complexes Karl D. Oyler, Frederick J. Coughlin, and Stefan Bernhard pp 210–217 DOI: 10.1021/ja067016v Supporting Info

Preferential Solvation within Hydrophilic Nanocavities and Its Effect on the Folding of Cholate Foldamers Yan Zhao, Zhenqi Zhong, and Eui-Hyun Ryu pp 218–225 DOI: 10.1021/ja0671159 Supporting Info

Redox-State-Dependent Complex Formation between Pseudoazurin and Nitrite Reductase Antonietta Impagliazzo, Anneloes J. Blok, Matthew J. Cliff, John E. Ladbury, and Marcellus Ubbink pp 226–233 DOI: 10.1021/ja0659830 Supporting Info

Kinetics of Hydrogen Atom Transfer from (η5-C5H5)Cr(CO)3H to Various Olefins:  Influence of Olefin Structure Jongwook Choi, Lihao Tang, and Jack R. Norton pp 234–240 DOI: 10.1021/ja066325i Supporting Info

Direct Palladium-Catalyzed C-2 and C-3 Arylation of Indoles:  A Mechanistic Rationale for Regioselectivity [J. Am. Chem. Soc. 2005, 127, 8050−8057]. Benjamin S. Lane, Meghann A. Brown, and Dalibor Sames* p 241 DOI: 10.1021/ja0699790 Supporting Info

Elements of Molecular and Biomolecular Electrochemistry:  An Electrochemical Approach to Electron Transfer Chemistry By Jean-Michel Savéant (Université de Paris 7, Denis Diderot). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xviii + 486 pp. $135. ISBN 0-471-44573-8. Allen J. Bard p 242 DOI: 10.1021/ja069754p

Issue 02

15N−15N J-Coupling Across HgII:  Direct Observation of HgII-Mediated T−T Base Pairs in a DNA Duplex Yoshiyuki Tanaka, Shuji Oda, Hiroshi Yamaguchi, Yoshinori Kondo, Chojiro Kojima, and Akira Ono pp 244–245 DOI: 10.1021/ja065552h Supporting Info

Transmembrane Helices Have Rough Energy Surfaces Harald Janovjak, Helene Knaus, and Daniel J. Muller pp 246–247 DOI: 10.1021/ja065684a Supporting Info

Chiral Cyanide-Bridged MnIIMnIII Ferrimagnets, [MnII(HL)(H2O)][MnIII(CN)6]·2H2O (L = S- or R-1,2-diaminopropane):  Syntheses, Structures, and Magnetic Behaviors Wakako Kaneko, Susumu Kitagawa, and Masaaki Ohba pp 248–249 DOI: 10.1021/ja066140b Supporting Info

Superexpanded Prussian-Blue Analogue with [Fe(CN)6]4-, [Nb6Cl12(CN)6]4-, and [Mn(salen)]+ as Building Units Jianjun Zhang and Abdessadek Lachgar pp 250–251 DOI: 10.1021/ja066104c Supporting Info

Measurement of Chiral-Dependent Magnetic Anisotropy in Carbon Nanotubes Omar N. Torrens, Daniel E. Milkie, Han Y. Ban, Ming Zheng, G. Bibiana Onoa, Timothy D. Gierke, and James M. Kikkawa pp 252–253 DOI: 10.1021/ja066719+ Supporting Info

Dynamic Assembly by Electrokinetic Microfluidics Shengnian Wang, Xin Hu, and L. James Lee pp 254–255 DOI: 10.1021/ja0666295 Supporting Info

Enantioselective Rauhut−Currier Reactions Promoted by Protected Cysteine Carrie E. Aroyan and Scott J. Miller pp 256–257 DOI: 10.1021/ja067139f Supporting Info

Examination of the New α-(2‘Z-Fluoro)vinyl Trigger with Lysine Decarboxylase:  The Absolute Stereochemistry Dictates the Reaction Course Kannan R. Karukurichi, Roberto de la Salud-Bea, Wan Jin Jahng, and David B. Berkowitz pp 258–259 DOI: 10.1021/ja067240k Supporting Info

Reversibly Caged Glutamate:  A Photochromic Agonist of Ionotropic Glutamate Receptors Matthew Volgraf, Pau Gorostiza, Stephanie Szobota, Max R. Helix, Ehud Y. Isacoff, and Dirk Trauner pp 260–261 DOI: 10.1021/ja067269o Supporting Info

Electrochemical Detection of Parts-Per-Billion Lead via an Electrode-Bound DNAzyme Assembly Yi Xiao, Aaron A. Rowe, and Kevin W. Plaxco pp 262–263 DOI: 10.1021/ja067278x Supporting Info

A 1:1 Copper−Dioxygen Adduct is an End-on Bound Superoxo Copper(II) Complex which Undergoes Oxygenation Reactions with Phenols Debabrata Maiti, H. Christopher Fry, Julia S. Woertink, Michael A. Vance, Edward I. Solomon, and Kenneth D. Karlin pp 264–265 DOI: 10.1021/ja067411l Supporting Info

Using β-Lactamase to Trigger Supramolecular Hydrogelation Zhimou Yang, Pak-Leung Ho, Gaolin Liang, Kin Hung Chow, Qigang Wang, Yang Cao, Zhihong Guo, and Bing Xu pp 266–267 DOI: 10.1021/ja0675604 Supporting Info

Endocytic Delivery of Vancomycin Mediated by a Synthetic Cell Surface Receptor:  Rescue of Bacterially Infected Mammalian Cells and Tissue Targeting In Vivo Siwarutt Boonyarattanakalin, Jianfang Hu, Sheryl A. Dykstra-Rummel, Avery August, and Blake R. Peterson pp 268–269 DOI: 10.1021/ja067674f Supporting Info

A Double-Stranded Helix by Complexation of Two Polymer Chains with a Helical Supramolecular Assembly Takahiro Sugimoto, Takayuki Suzuki, Seiji Shinkai, and Kazuki Sada pp 270–271 DOI: 10.1021/ja067613h

A-B-A-B-A Block Amphiphiles. Balance between Hydrophilic and Hydrophobic Segmentation Fredric M. Menger, Hao Lu, and Dan Lundberg pp 272–273 DOI: 10.1021/ja067841b Supporting Info

Configuration Change in [14]Annulene Requires Möbius Antiaromatic Bond Shifting Joseph F. Moll, Ryan P. Pemberton, M. Gertrude Gutierrez, Claire Castro, and William L. Karney pp 274–275 DOI: 10.1021/ja0678469 Supporting Info

Cu(I) Tol-BINAP-Catalyzed Enantioselective Michael Reactions of Grignard Reagents and Unsaturated Esters Shun-Yi Wang, Shun-Jun Ji, and Teck-Peng Loh pp 276–277 DOI: 10.1021/ja0666046 Supporting Info

Reactivity of Reduced Nitroprusside, [Fe(CN)5NO•]3-, toward Oxygen Mariela Videla, Federico Roncaroli, Leonardo D. Slep, and José A. Olabe pp 278–279 DOI: 10.1021/ja066900i Supporting Info

Iridium-Catalyzed C−C Bond Forming Hydrogenation:  Direct Regioselective Reductive Coupling of Alkyl-Substituted Alkynes to Activated Ketones Ming-Yu Ngai, Andriy Barchuk, and Michael J. Krische pp 280–281 DOI: 10.1021/ja0670815 Supporting Info

Enantioselective Synthesis of α-Tertiary Hydroxyaldehydes by Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates Barry M. Trost, Jiayi Xu, and Markus Reichle pp 282–283 DOI: 10.1021/ja067342a Supporting Info

Ionic Liquids:  First Direct Determination of their Cohesive Energy Luís M. N. B. F. Santos, José N. Canongia Lopes, João A. P. Coutinho, José M. S. S. Esperança, Lígia R. Gomes, Isabel M. Marrucho, and Luís P. N. Rebelo pp 284–285 DOI: 10.1021/ja067427b Supporting Info

Vanadium-Catalyzed Asymmetric Epoxidation of Homoallylic Alcohols Wei Zhang and Hisashi Yamamoto pp 286–287 DOI: 10.1021/ja067495y Supporting Info

Direct Catalytic Asymmetric Synthesis of anti-1,2-Amino Alcohols and syn-1,2-Diols through Organocatalytic anti-Mannich and syn-Aldol Reactions S. S. V. Ramasastry, Haile Zhang, Fujie Tanaka, and Carlos F. Barbas, III pp 288–289 DOI: 10.1021/ja0677012 Supporting Info

Chemoselective Hydrogenation of Imides Catalyzed by Cp*Ru(PN) Complexes and Its Application to the Asymmetric Synthesis of Paroxetine Masato Ito, Ayaka Sakaguchi, Chika Kobayashi, and Takao Ikariya pp 290–291 DOI: 10.1021/ja067777y Supporting Info

Enantioselective Friedel−Crafts Reaction of Electron-Rich Alkenes Catalyzed by Chiral Brønsted Acid Masahiro Terada and Keiichi Sorimachi pp 292–293 DOI: 10.1021/ja0678166 Supporting Info

The Multiple Amidation Reactions Catalyzed by Cobyric Acid Synthetase from Salmonella typhimurium Are Sequential and Dissociative LaKenya Williams, Vicente Fresquet, Patricio J. Santander, and Frank M. Raushel pp 294–295 DOI: 10.1021/ja067962b

1H/2H NMR Studies of Geometric H/D Isotope Effects on the Coupled Hydrogen Bonds in Porphycene Derivatives Mariusz Pietrzak, Mohamed F. Shibl, Martin Bröring, Oliver Kühn, and Hans-Heinrich Limbach pp 296–304 DOI: 10.1021/ja065170b

Mechanistic Study of Precursor Evolution in Colloidal Group II−VI Semiconductor Nanocrystal Synthesis Haitao Liu, Jonathan S. Owen, and A. Paul Alivisatos pp 305–312 DOI: 10.1021/ja0656696 Supporting Info

High Energy and Quantum Efficiency in Photoinduced Charge Separation John M. Weber, Matthew T. Rawls, Valerie J. MacKenzie, Bradford R. Limoges, and C. Michael Elliott pp 313–320 DOI: 10.1021/ja0665500 Supporting Info

Modulation of Fluorescence through Coassembly of Molecules in Organic Nanostructures Heather A. Behanna, Kanya Rajangam, and Samuel I. Stupp pp 321–327 DOI: 10.1021/ja062415b Supporting Info

Singlet-State Exchange NMR Spectroscopy for the Study of Very Slow Dynamic Processes Riddhiman Sarkar, Paul R. Vasos, and Geoffrey Bodenhausen pp 328–334 DOI: 10.1021/ja0647396 Supporting Info

17O Magic Angle Spinning NMR Studies of Brønsted Acid Sites in Zeolites HY and HZSM-5 Luming Peng, Hua Huo, Yun Liu, and Clare P. Grey pp 335–346 DOI: 10.1021/ja064922z Supporting Info

A Molecular Keypad Lock:  A Photochemical Device Capable of Authorizing Password Entries David Margulies, Clifford E. Felder, Galina Melman, and Abraham Shanzer pp 347–354 DOI: 10.1021/ja065317z Supporting Info

Direct Demonstration of Enhanced Diffusion in Mesoporous ZSM-5 Zeolite Obtained via Controlled Desilication Johan C. Groen, Weidong Zhu, Sander Brouwer, Steven J. Huynink, Freek Kapteijn, Jacob A. Moulijn, and Javier Pérez-Ramírez pp 355–360 DOI: 10.1021/ja065737o

Rotational-Echo Double-Resonance NMR Distance Measurements for the Tubulin-Bound Paclitaxel Conformation Younkee Paik, Chao Yang, Belhu Metaferia, Shoubin Tang, Susan Bane, Rudravajhala Ravindra, Natasha Shanker, Ana A. Alcaraz, Scott A. Johnson, Jacob Schaefer, Robert D. O'Connor, Lynette Cegelski, James P. Snyder, and David G. I. Kingston pp 361–370 DOI: 10.1021/ja0656604 Supporting Info

Organometallics Meet Colloid Chemistry:  A Case Study in Three Phases Based on Molecular Carbonyl Precursors Containing Zinc and Manganese A. Orlov, A. Roy, M. Lehmann, M. Driess, and S. Polarz pp 371–375 DOI: 10.1021/ja0659626 Supporting Info

Progress toward a Rationally Designed, Chemically Powered Rotary Molecular Motor T. Ross Kelly, Xiaolu Cai, Fehmi Damkaci, Sreeletha B. Panicker, Bin Tu, Simon M. Bushell, Ivan Cornella, Matthew J. Piggott, Richard Salives, Marta Cavero, Yajun Zhao, and Serge Jasmin pp 376–386 DOI: 10.1021/ja066044a Supporting Info

Proton Shuttles and Phosphatase Activity in Soluble Epoxide Hydrolase Marco De Vivo, Bernd Ensing, Matteo Dal Peraro, German A. Gomez, David W. Christianson, and Michael L. Klein pp 387–394 DOI: 10.1021/ja066150c Supporting Info

The Role of Achiral Pyrazolidinone Templates in Enantioselective Diels−Alder Reactions:  Scope, Limitations, and Conformational Insights Mukund P. Sibi, Levi M. Stanley, Xiaoping Nie, Lakshmanan Venkatraman, Mei Liu, and Craig P. Jasperse pp 395–405 DOI: 10.1021/ja066425o Supporting Info

Isomerization Dynamics and Control of the η2/N Equilibrium for Pyridine Complexes David A. Delafuente, George W. Kosturko, Peter M. Graham, W. Hill Harman, William H. Myers, Yogesh Surendranath, Rachel C. Klet, Kevin D. Welch, Carl O. Trindle, Michal Sabat, and W. Dean Harman pp 406–416 DOI: 10.1021/ja066623f Supporting Info

Interplay among Folding, Sequence, and Lipophilicity in the Antibacterial and Hemolytic Activities of α/β-Peptides Margaret A. Schmitt, Bernard Weisblum, and Samuel H. Gellman pp 417–428 DOI: 10.1021/ja0666553 Supporting Info

Total Synthesis of Abyssomicin C, Atrop-abyssomicin C, and Abyssomicin D:  Implications for Natural Origins of Atrop-abyssomicin C K. C. Nicolaou and Scott T. Harrison pp 429–440 DOI: 10.1021/ja067083p Supporting Info

Organocatalytic Asymmetric Direct α-Alkynylation of Cyclic β-Ketoesters Thomas B. Poulsen, Luca Bernardi, José Alemán, Jacob Overgaard, and Karl Anker Jørgensen pp 441–449 DOI: 10.1021/ja067289q Supporting Info

Modern Terpyridine Chemistry By Ulrich S. Schubert (Eindhoven University of Technology, Eindhoven, the Netherlands), Harald Hofmeier (Eindhoven University of Technology), and George R. Newkome (University of Akron, USA). Wiley-VCH Verlag GmbH & Co. KgaA:  Weinheim. 2006. VIII + 230 pp. $110.00. ISBN 3-527-31475-X. Randolph Thummel p 450 DOI: 10.1021/ja069800l

Name Reactions:  A Collection of Detailed Reaction Mechanisms, 3rd ed By Jack Li (Pfizer Global Research and Development, Ann Arbor, MI). Springer:  Berlin, Heidelberg, New York. 2006. xx + 652 pp. $89.95. ISBN 3-540-30030-9. p 450 DOI: 10.1021/ja0698275

The Chemistry of Peroxides, Volume 2, Parts 1−2. From the Patai Series:  The Chemistry of Functional Groups Edited by Zvi Rappoport (The Hebrew University, Jerusalem). John Wiley & Sons, Ltd.:  Chichester. 2006. xx + xx + 1498 pp. $990. ISBN 0-470-86274-2. A. L. Baumstark pp 450–451 DOI: 10.1021/ja069786c

Crystal Structure Refinement:  A Crystallographer's Guide to SHELXL. IUCr Texts on Crystallography, 8 By Peter Müller (Massachusetts Institute of Technology, Cambridge, USA), Regine Herbst-Irmer (University of Göttingen, Germany), Anthony L. Spek (Utrecht University, The Netherlands), Thomas R. Schneider (The FIRC Institute of Molecular Oncology, Biocrystallography, and Structural Bioinformatics, Italy), and Michael R. Sawaya (University of California, Los Angeles, USA). Oxford University Press:  Oxford, New York. 2006. XVIII + 214 pp. $98.50. ISBN 0-19-857076-7. p 451 DOI: 10.1021/ja0698026

Structure and Chemistry of Crystalline Solids By Bodie E. Douglas and Shih-Ming Ho (University of Pittsburgh). Springer Science + Business Media, Inc.:  New York. 2006. x + 346 pp. $129.00. ISBN 0-387-26147-8. Raymond E. Schaak pp 451–452 DOI: 10.1021/ja069778w

Issue 03

A Complete Microfluidic Screening Platform for Rational Protein Crystallization Billy T. C. Lau, Chris A. Baitz, Xiao P. Dong, and Carl L. Hansen pp 454–455 DOI: 10.1021/ja065855b Supporting Info

A Pentanuclear Manganese Single-Molecule Magnet with a Large Anisotropy Chen-I Yang, Wolfgang Wernsdorfer, Gene-Hsiang Lee, and Hui-Lien Tsai pp 456–457 DOI: 10.1021/ja066533a Supporting Info

Enzyme-Responsive Molecular Assembly System with Amylose-Primer Surfactants Nobuyuki Morimoto, Naruhito Ogino, Tadashi Narita, Shinichi Kitamura, and Kazunari Akiyoshi pp 458–459 DOI: 10.1021/ja065966a Supporting Info

Bifunctional Catalysis of Proton Transfer at an Antibody Active Site Roger Müller, Erik W. Debler, Michael Steinmann, Florian P. Seebeck, Ian A. Wilson, and Donald Hilvert pp 460–461 DOI: 10.1021/ja066578b Supporting Info

NMR Detection of Protein 15N Spins near Paramagnetic Lanthanide Ions Michael John, Ah Young Park, Nicholas E. Dixon, and Gottfried Otting pp 462–463 DOI: 10.1021/ja066995o Supporting Info

Cross-Bridging Reaction of 5,20-Diethynyl Substituted Hexaphyrins to Vinylene-Bridged Hexaphyrins Masaaki Suzuki and Atsuhiro Osuka pp 464–465 DOI: 10.1021/ja067102v Supporting Info

Azidoproline Containing Helices:  Stabilization of the Polyproline II Structure by a Functionalizable Group Michael Kümin, Louis-Sebastian Sonntag, and Helma Wennemers pp 466–467 DOI: 10.1021/ja067148o Supporting Info

Reversible Cell Deformation by a Polymeric Actuator Avishay Pelah, Ralf Seemann, and Thomas M. Jovin pp 468–469 DOI: 10.1021/ja067171+ Supporting Info

Simultaneous Supralinear Line-Narrowing and Sensitivity Enhancement at High Fields in Magic Angle Spinning NMR of Spin-1/2 Nuclei in Solids Riqiang Fu, Ozge Gunaydin-Sen, and Naresh S. Dalal pp 470–471 DOI: 10.1021/ja067179j Supporting Info

High-Accuracy Distance Measurement between Remote Methyls in Specifically Protonated Proteins Remy Sounier, Laurence Blanchard, Zhengrong Wu, and Jérôme Boisbouvier pp 472–473 DOI: 10.1021/ja067260m Supporting Info

Conformational Dynamics of Substrate in the Active Site of Cytochrome P450 BM-3/NPG Complex:  Insights from NMR Order Parameters Krishna Pratap Ravindranathan, Emilio Gallicchio, Ann E. McDermott, and Ronald M. Levy pp 474–475 DOI: 10.1021/ja0672371

Extremely Strong and Readily Accessible AAA−DDD Triple Hydrogen Bond Complexes Smilja Djurdjevic, David A. Leigh, Hamish McNab, Simon Parsons, Gilberto Teobaldi, and Francesco Zerbetto pp 476–477 DOI: 10.1021/ja067410t Supporting Info

Boron Binding by a Siderophore Isolated from Marine Bacteria Associated with the Toxic Dinoflagellate Gymnodinium catenatum Shady A. Amin, Frithjof C. Küpper, David H. Green, Wesley R. Harris, and Carl J. Carrano pp 478–479 DOI: 10.1021/ja067369u Supporting Info

Photodelivery of Nitric Oxide from Water-Soluble Platinum Nanoparticles Elisa B. Caruso, Salvatore Petralia, Sabrina Conoci, Salvatore Giuffrida, and Salvatore Sortino pp 480–481 DOI: 10.1021/ja067568d Supporting Info

A Versatile Strategy for Quantum Dot Ligand Exchange Fabien Dubois, Benoît Mahler, Benoît Dubertret, Eric Doris, and Charles Mioskowski pp 482–483 DOI: 10.1021/ja067742y Supporting Info

Pentaindenocorannulene and Tetraindenocorannulene:  New Aromatic Hydrocarbon π Systems with Curvatures Surpassing That of C60 Edward A. Jackson, Brian D. Steinberg, Mihail Bancu, Atsushi Wakamiya, and Lawrence T. Scott pp 484–485 DOI: 10.1021/ja067487h Supporting Info

Intramolecular Cyclobutadiene Cycloaddition/Cyclopropanation/Thermal Rearrangement:  An Effective Strategy for the Asymmetric Syntheses of Pleocarpenene and Pleocarpenone Michael J. Williams, Holly L. Deak, and Marc L. Snapper pp 486–487 DOI: 10.1021/ja0674340 Supporting Info

Ultralarge and Thermally Stable Electro-Optic Activities from Supramolecular Self-Assembled Molecular Glasses Tae-Dong Kim, Jae-Wook Kang, Jingdong Luo, Sei-Hum Jang, Jae-Won Ka, Neil Tucker, Jason B. Benedict, Larry R. Dalton, Tomoko Gray, René M. Overney, Dong Hun Park, Warren N. Herman, and Alex K.-Y. Jen pp 488–489 DOI: 10.1021/ja067970s Supporting Info

Synthesis of Potent Bicyclic Bisarylimidazole c-Jun N-Terminal Kinase Inhibitors by Catalytic C−H Bond Activation Jason C. Rech, Michihisa Yato, Derek Duckett, Brian Ember, Philip V. LoGrasso, Robert G. Bergman, and Jonathan A. Ellman pp 490–491 DOI: 10.1021/ja0676004 Supporting Info

Lewis Acid-Promoted Intermolecular Acetal-Initiated Cationic Polyene Cyclizations Yu-Jun Zhao, Shu-Sin Chng, and Teck-Peng Loh pp 492–493 DOI: 10.1021/ja067660+ Supporting Info

Low-Temperature Heck Reactions of Axially Chiral o-Iodoacrylanilides Occur with Chirality Transfer:  Implications for Catalytic Asymmetric Heck Reactions Andre J. B. Lapierre, Steven J. Geib, and Dennis P. Curran pp 494–495 DOI: 10.1021/ja067790i Supporting Info

Catalytic Enantioselective Allenylation Reactions of Aldehydes with Tethered Bis(8-quinolinolato) (TBOx) Chromium Complex Guoyao Xia and Hisashi Yamamoto pp 496–497 DOI: 10.1021/ja0679578 Supporting Info

Total Synthesis of (±)-Merrilactone A via Catalytic Nazarov Cyclization Wei He, Jie Huang, Xiufeng Sun, and Alison J. Frontier pp 498–499 DOI: 10.1021/ja068150i Supporting Info

Catalytic Enantioselective Mannich-type Reactions of Ketoimines Yutaka Suto, Motomu Kanai, and Masakatsu Shibasaki pp 500–501 DOI: 10.1021/ja068226a Supporting Info

Intermolecular Chirality Transfer from Silicon to Carbon:  Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover Sebastian Rendler, Martin Oestreich, Craig P. Butts, and Guy C. Lloyd-Jones pp 502–503 DOI: 10.1021/ja067780h Supporting Info

A Conformational Switch to β-Sheet Structure in Cytochrome c Leads to Heme Exposure. Implications for Cardiolipin Peroxidation and Apoptosis Gurusamy Balakrishnan, Ying Hu, Oyeyemi F. Oyerinde, Jia Su, John T. Groves, and Thomas G. Spiro pp 504–505 DOI: 10.1021/ja0678727 Supporting Info

Unusual Mechanical Performance of Amphiphilic Crosslinked Polymer Networks Jinqi Xu, David A. Bohnsack, Michael E. Mackay, and Karen L. Wooley pp 506–507 DOI: 10.1021/ja067986i Supporting Info

Spirastrellolide B Reveals the Absolute Configuration of the Spirastrellolide Macrolide Core Kaoru Warabi, David E. Williams, Brian O. Patrick, Michel Roberge, and Raymond J. Andersen pp 508–509 DOI: 10.1021/ja068271i Supporting Info

Enantioselective Synthesis and Structure Revision of Solandelactone E Jennifer E. Davoren and Stephen F. Martin pp 510–511 DOI: 10.1021/ja068270q Supporting Info

Design of a Functional Membrane Protein by Engineering a Heme-Binding Site in Glycophorin A Jeanine M. Cordova, Pamela L. Noack, Simon A. Hilcove, James D. Lear, and Giovanna Ghirlanda pp 512–518 DOI: 10.1021/ja057495i Supporting Info

Effect of the Methionine Ligand on the Reorganization Energy of the Type-1 Copper Site of Nitrite Reductase Hein J. Wijma, Iain MacPherson, Ole Farver, Elitza I. Tocheva, Israel Pecht, Martin Ph. Verbeet, Michael E. P. Murphy, and Gerard W. Canters pp 519–525 DOI: 10.1021/ja064763j Supporting Info

Interactions of 1-Methylimidazole with UO2(CH3CO2)2 and UO2(NO3)2:  Structural, Spectroscopic, and Theoretical Evidence for Imidazole Binding to the Uranyl Ion Keith E. Gutowski, Violina A. Cocalia, Scott T. Griffin, Nicholas J. Bridges, David A. Dixon, and Robin D. Rogers pp 526–536 DOI: 10.1021/ja064592i Supporting Info

Following Photoinduced Dynamics in Bacteriorhodopsin with 7-fs Impulsive Vibrational Spectroscopy Anat Kahan, Omer Nahmias, Noga Friedman, Mordechai Sheves, and Sanford Ruhman pp 537–546 DOI: 10.1021/ja064910d

Electrostatics and Color:  Massive Electrostatic Perturbation of Chromophores by Ion Cluster Ligands Robert Weiss and Frank G. Pühlhofer pp 547–553 DOI: 10.1021/ja064907u

A Fluorescence-Based Synthetic LPS Sensor Söhnke Voss, Rainer Fischer, Günther Jung, Karl-Heinz Wiesmüller, and Roland Brock pp 554–561 DOI: 10.1021/ja065016p

Catalytic Intermolecular Amination of C−H Bonds: Method Development and Mechanistic Insights Kristin Williams Fiori and J. Du Bois pp 562–568 DOI: 10.1021/ja0650450 Supporting Info

Investigation of Proton Transport Tautomerism in Clusters of Protonated Nucleic Acid Bases (Cytosine, Uracil, Thymine, and Adenine) and Ammonia by High-Pressure Mass Spectrometry and Ab Initio Calculations Ronghu Wu and Terry B. McMahon pp 569–580 DOI: 10.1021/ja065088g Supporting Info

Control of Mesoporous Silica Nanostructures and Pore-Architectures Using a Thickener and a Gelator Yonggang Yang, Masahiro Suzuki, Sanae Owa, Hirofusa Shirai, and Kenji Hanabusa pp 581–587 DOI: 10.1021/ja064240b Supporting Info

Ultrafast and Ultraslow Oxygen Atom Transfer Reactions between Late Metal Centers Kevin C. Fortner, David S. Laitar, John Muldoon, Lihung Pu, Sonja B. Braun-Sand, Olaf Wiest, and Seth N. Brown pp 588–600 DOI: 10.1021/ja065713h Supporting Info

Investigating the Molecular Mechanisms of In-Plane Mechanochemistry on Cantilever Arrays Moyu Watari, Jane Galbraith, Hans-Peter Lang, Marilyne Sousa, Martin Hegner, Christoph Gerber, Mike A. Horton, and Rachel A. McKendry pp 601–609 DOI: 10.1021/ja065222x Supporting Info

CT−CT Annihilation in Rigid Perylene End-Capped Pentaphenylenes Eduard Fron, Toby D. M. Bell, Antoine Van Vooren, Gerd Schweitzer, Jérôme Cornil, David Beljonne, Paul Toele, Josemon Jacob, Klaus Müllen, Johan Hofkens, Mark Van der Auweraer, and Frans C. De Schryver pp 610–619 DOI: 10.1021/ja064794e Supporting Info

Near-Infrared (NIR) to Red and Green Up-Conversion Emission from Silica Sol−Gel Thin Films Made with La0.45Yb0.50Er0.05F3 Nanoparticles, Hetero-Looping-Enhanced Energy Transfer (Hetero-LEET):  A New Up-Conversion Process Sri Sivakumar, Frank C. J. M van Veggel, and P. Stanley May pp 620–625 DOI: 10.1021/ja065378x

Design and Optimization of Molecular Nanovalves Based on Redox-Switchable Bistable Rotaxanes Thoi D. Nguyen, Yi Liu, Sourav Saha, Ken C.-F. Leung, J. Fraser Stoddart, and Jeffrey I. Zink pp 626–634 DOI: 10.1021/ja065485r Supporting Info

Analysis of PUGNAc and NAG-thiazoline as Transition State Analogues for Human O-GlcNAcase:  Mechanistic and Structural Insights into Inhibitor Selectivity and Transition State Poise Garrett E. Whitworth, Matthew S. Macauley, Keith A. Stubbs, Rebecca J. Dennis, Edward J. Taylor, Gideon J. Davies, Ian R. Greig, and David J. Vocadlo pp 635–644 DOI: 10.1021/ja065697o Supporting Info

Highly Selective Diels-Alder Reactions of Directly Connected Enyne Dienophiles Mingji Dai, David Sarlah, Maolin Yu, Samuel J. Danishefsky, Gavin O. Jones, and K. N. Houk pp 645–657 DOI: 10.1021/ja065762u Supporting Info

Design of Sandwichlike Complexes Based on the Planar Tetracoordinate Carbon Unit CAl42- Li-ming Yang, Yi-hong Ding, and Chia-chung Sun pp 658–665 DOI: 10.1021/ja066217w Supporting Info

Photon-Induced Selective Interaction between Small-Diameter Metallic Carbon Nanotubes and Triton X-100 Zhi-Bin Zhang and Shi-Li Zhang pp 666–671 DOI: 10.1021/ja066419s Supporting Info

End-to-End vs Interior Loop Formation Kinetics in Unfolded Polypeptide Chains Beat Fierz and Thomas Kiefhaber pp 672–679 DOI: 10.1021/ja0666396

J-GFT NMR for Precise Measurement of Mutually Correlated Nuclear Spin−Spin Couplings Hanudatta S. Atreya, Erwin Garcia, Yang Shen, and Thomas Szyperski pp 680–692 DOI: 10.1021/ja066586s Supporting Info

Zinc−Zinc Bonded Zincocene Structures. Synthesis and Characterization of Zn2(η5-C5Me5)2 and Zn2(η5-C5Me4Et)2 Abdessamad Grirrane, Irene Resa, Amor Rodriguez, Ernesto Carmona, Eleuterio Alvarez, Enrique Gutierrez-Puebla, Angeles Monge, Agustín Galindo, Diego del Río, and Richard A. Andersen pp 693–703 DOI: 10.1021/ja0668217 Supporting Info

Supramolecular PEG−co-Oligo(p-benzamide)s Prepared on a Peptide Synthesizer Hannah M. König, Tatiana Gorelik, Ute Kolb, and Andreas F. M. Kilbinger pp 704–708 DOI: 10.1021/ja0672831 Supporting Info

Engineering Copper Sites in Proteins:  Loops Confer Native Structures and Properties to Chimeric Cupredoxins Chan Li, Mark J. Banfield, and Christopher Dennison pp 709–718 DOI: 10.1021/ja0661562 Supporting Info

Formation of Water-Dispersible Nanotubular Graphitic Assembly Decorated with Isothiouronium Ion Groups and Its Supramolecular Functionalization Guanxin Zhang, Wusong Jin, Takanori Fukushima, Atsuko Kosaka, Noriyuki Ishii, and Takuzo Aida pp 719–722 DOI: 10.1021/ja0671518 Supporting Info

Characterization of Manganese(V)−Oxo Polyoxometalate Intermediates and Their Properties in Oxygen-Transfer Reactions [J. Am. Chem. Soc. 2006, 128,15451−15460]. p 723 DOI: 10.1021/ja068770j

A Modular Approach toward Regulating the Secondary Coordination Sphere of Metal Ions:  Differential Dioxygen Activation Assisted by Intramolecular Hydrogen Bonds [J. Am. Chem. Soc. 2006, 128, 15476−15489]. p 723 DOI: 10.1021/ja069983b

Natural Fullerenes and Related Structures of Elemental Carbon. From the Series:  Developments in Fullerene Science, Volume 6 Edited by Frans J. M. Rietmeijer (University of New Mexico, Albuquerque, NM). Springer:  Dordrecht. 2006. xxiii + 296 pp. $169.00. ISBN 1-4020-4134-9. Susanna L. Widicus Weaver and Benjamin J. McCall p 724 DOI: 10.1021/ja069789p

CRC Handbook of Chemistry and Physics, 87th ed Editor-in-Chief:  David R. Lide (National Institute of Standards and Technology). CRC Press/Taylor and Francis Group:  Boca Raton, FL. 2006. 2608 pp. $139.95. ISBN 0-8493-0487-3. p 724 DOI: 10.1021/ja069813z

Issue 04

Identification of the Peroxy Adduct in Multicopper Oxidases by a Combination of Computational Chemistry and Extended X-ray Absorption Fine-Structure Measurements Ulf Ryde, Ya-Wen Hsiao, Lubomír Rulíšek, and Edward I. Solomon pp 726–727 DOI: 10.1021/ja062954g Supporting Info

Proton Assisted Insensitive Nuclei Cross Polarization Józef R. Lewandowski, Gaël De Paëpe, and Robert G. Griffin pp 728–729 DOI: 10.1021/ja0650394 Supporting Info

Effects of Macromolecular Crowding on the Intrinsic Catalytic Efficiency and Structure of Enterobactin-Specific Isochorismate Synthase Ming Jiang and Zhihong Guo pp 730–731 DOI: 10.1021/ja065064+ Supporting Info

Label-Free Optical Detection of Anthrax-Causing Spores Ghanashyam Acharya, Derek D. Doorneweerd, Chun-Li Chang, Walter A. Henne, Philip S. Low, and Cagri A. Savran pp 732–733 DOI: 10.1021/ja0656649 Supporting Info

Effect of Chemical Bond Type on Electron Transport in GaAs−Chemical Bond−Alkyl/Hg Junctions Guy Nesher, Hagay Shpaisman, and David Cahen pp 734–735 DOI: 10.1021/ja065399r Supporting Info

Transnitrosation of Thiols from Aliphatic N-Nitrosamines:  S-Nitrosation and Indirect Generation of Nitric Oxide Takahiro Yanagimoto, Takeshi Toyota, Norio Matsuki, Yumi Makino, Seiichi Uchiyama, and Tomohiko Ohwada pp 736–737 DOI: 10.1021/ja0658259 Supporting Info

Fly-Casting in Protein−DNA Binding:  Frustration between Protein Folding and Electrostatics Facilitates Target Recognition Yaakov Levy, José N. Onuchic, and Peter G. Wolynes pp 738–739 DOI: 10.1021/ja065531n Supporting Info

Anisotropic Free-Electron-Like Dispersions and Standing Waves Realized in Self-Assembled Monolayers of Glycine on Cu(100) Ken Kanazawa, Yasuyuki Sainoo, Yasuaki Konishi, Shoji Yoshida, Atsushi Taninaka, Arifumi Okada, Maxime Berthe, Nobuhiko Kobayashi, Osamu Takeuchi, and Hidemi Shigekawa pp 740–741 DOI: 10.1021/ja066318u Supporting Info

Asymmetric Conjugate Addition of Silyl Enol Ethers Catalyzed by Tethered Bis(8-quinolinolato) Aluminum Complexes Norito Takenaka, Joshua P. Abell, and Hisashi Yamamoto pp 742–743 DOI: 10.1021/ja0668320 Supporting Info

An Electrochemical Avenue to Blue Luminescent Nanocrystals from Multiwalled Carbon Nanotubes (MWCNTs) Jigang Zhou, Christina Booker, Ruying Li, Xingtai Zhou, Tsun-Kong Sham, Xueliang Sun, and Zhifeng Ding pp 744–745 DOI: 10.1021/ja0669070 Supporting Info

Low-Pressure Molecular Hydrogen Storage in Semi-clathrate Hydrates of Quaternary Ammonium Compounds Antonin Chapoy, Ross Anderson, and Bahman Tohidi pp 746–747 DOI: 10.1021/ja066883x

Biomimetic Catalysis of Intermodular Aminoacyl Transfer Keith M. Wilcoxen, Luke J. Leman, Dana A. Weinberger, Zheng-Zheng Huang, and M. Reza Ghadiri pp 748–749 DOI: 10.1021/ja067124h Supporting Info

Hydrogen-Bonding Directed Reversal of Enantioselectivity Wei Zeng, Guo-Ying Chen, Yong-Gui Zhou, and Yu-Xue Li pp 750–751 DOI: 10.1021/ja067346f Supporting Info

Layered Organic Structure at the Carbon Tetrachloride−Water Interface Dennis K. Hore, Dave S. Walker, and Geraldine L. Richmond pp 752–753 DOI: 10.1021/ja067473b

Direct Observation of Dipolar Couplings and Hydrogen Bonds across a β-Hairpin in 8 M Urea Sebastian Meier, Mark Strohmeier, Martin Blackledge, and Stephan Grzesiek pp 754–755 DOI: 10.1021/ja067522k Supporting Info

Isolated Fluid Polyhedral Vesicles Alfredo González-Pérez, Marc Schmutz, Gilles Waton, María J. Romero, and Marie Pierre Krafft pp 756–757 DOI: 10.1021/ja067228s Supporting Info

Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki−Miyaura Coupling Hiroyoshi Noguchi, Kosho Hojo, and Michinori Suginome pp 758–759 DOI: 10.1021/ja067975p Supporting Info

Importance of the Anisotropic Exchange Interaction for the Magnetic Anisotropy of Polymetallic Systems Stergios Piligkos, Eckhard Bill, David Collison, Eric J. L. McInnes, Grigore A. Timco, Høgni Weihe, Richard E. P. Winpenny, and Frank Neese pp 760–761 DOI: 10.1021/ja068017q Supporting Info

A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes Haifeng Du, Baoguo Zhao, and Yian Shi pp 762–763 DOI: 10.1021/ja0680562 Supporting Info

Bio-mimic Multichannel Microtubes by a Facile Method Yong Zhao, Xinyu Cao, and Lei Jiang pp 764–765 DOI: 10.1021/ja068165g Supporting Info

Supported Metallocene Catalysis for In Situ Synthesis of High Energy Density Metal Oxide Nanocomposites Neng Guo, Sara A. DiBenedetto, Do-Kyun Kwon, Lian Wang, Matthew T. Russell, Michael T. Lanagan, Antonio Facchetti, and Tobin J. Marks pp 766–767 DOI: 10.1021/ja066965l Supporting Info

Control of Diastereoselectivity in Tandem Asymmetric Reactions Generating Nonadjacent Stereocenters with Bifunctional Catalysis by Cinchona Alkaloids Baomin Wang, Fanghui Wu, Yi Wang, Xiaofeng Liu, and Li Deng pp 768–769 DOI: 10.1021/ja0670409 Supporting Info

Tin-Free and Catalytic Radical Cyclizations Deborah M. Smith, Mary E. Pulling, and Jack R. Norton pp 770–771 DOI: 10.1021/ja0673276 Supporting Info

Hole Migration is the Major Pathway Involved in Alkali-Labile Lesion Formation in DNA by the Direct Effect of Ionizing Radiation Hui Ding and Marc M. Greenberg pp 772–773 DOI: 10.1021/ja0678931 Supporting Info

Iridium(I)-Catalyzed Regio- and Enantioselective Decarboxylative Allylic Amidation of Substituted Allyl Benzyl Imidodicarbonates Om V. Singh and Hyunsoo Han pp 774–775 DOI: 10.1021/ja067966g Supporting Info

Unexpected C−C Bond Cleavage and C−C Bond Formation Observed in the Reaction of a Cationic Iridium Complex with Heteroatom-Substituted Cyclopropanes Mitchell R. Anstey, Cathleen M. Yung, Juana Du, and Robert G. Bergman pp 776–777 DOI: 10.1021/ja068312a Supporting Info

Butenolide Synthesis by Molybdenum-Mediated Hetero-Pauson−Khand Reaction of Alkynyl Aldehydes Javier Adrio and Juan C. Carretero pp 778–779 DOI: 10.1021/ja0684186 Supporting Info

Three-Component Coupling Reactions of Thioformamides with Organolithium and Grignard Reagents Leading to Formation of Tertiary Amines and a Thiolating Agent Toshiaki Murai and Fumio Asai pp 780–781 DOI: 10.1021/ja068523f Supporting Info

O6-(Benzotriazol-1-yl)inosine Derivatives:  Easily Synthesized, Reactive Nucleosides Suyeal Bae and Mahesh K. Lakshman pp 782–789 DOI: 10.1021/ja064682n Supporting Info

Stereospecific Cross-Coupling of α-(Thiocarbamoyl)organostannanes with Alkenyl, Aryl, and Heteroaryl Iodides J. R. Falck, Paresh K. Patel, and Anish Bandyopadhyay pp 790–793 DOI: 10.1021/ja064948q Supporting Info

High-Resolution 2D NMR Spectroscopy of Bicelles To Measure the Membrane Interaction of Ligands Sergey V. Dvinskikh, Ulrich H. N. Dürr, Kazutoshi Yamamoto, and Ayyalusamy Ramamoorthy pp 794–802 DOI: 10.1021/ja065536k

Facile N···N Coupling of Manganese(V) Imido Species Shek-Man Yiu, William W. Y. Lam, Chi-Ming Ho, and Tai-Chu Lau pp 803–809 DOI: 10.1021/ja066440t Supporting Info

1,4-Shifts in a Dinuclear Ni(I) Biarylyl Complex:  A Mechanistic Study of C−H Bond Activation by Monovalent Nickel Alana L. Keen, Meghan Doster, and Samuel A. Johnson pp 810–819 DOI: 10.1021/ja067112w Supporting Info

Strengths of Hydrogen Bonds Involving Phosphorylated Amino Acid Side Chains Daniel J. Mandell, Ilya Chorny, Eli S. Groban, Sergio E. Wong, Elisheva Levine, Chaya S. Rapp, and Matthew P. Jacobson pp 820–827 DOI: 10.1021/ja063019w Supporting Info

Molecular and Electronic Structures of the Long-Bonded π-Dimers of Tetrathiafulvalene Cation-Radical in Intermolecular Electron Transfer and in (Solid-State) Conductivity Sergiy V. Rosokha and Jay K. Kochi pp 828–838 DOI: 10.1021/ja064166x Supporting Info

Rotational Dynamics in a Crystalline Molecular Gyroscope by Variable-Temperature 13C NMR, 2H NMR, X-Ray Diffraction, and Force Field Calculations Tinh-Alfredo V. Khuong, Hung Dang, Peter D. Jarowski, Emily F. Maverick, and Miguel A. Garcia-Garibay pp 839–845 DOI: 10.1021/ja064325c Supporting Info

Bonding and Electronic Structure of XeF3- Ian H. Krouse, Changtong Hao, Catherine E. Check, Kim C. Lobring, Lee S. Sunderlin, and Paul G. Wenthold pp 846–852 DOI: 10.1021/ja065038b Supporting Info

Dimerization of Alkynes Promoted by a Pincer-Ligated Iridium Complex. C−C Reductive Elimination Inhibited by Steric Crowding Rajshekhar Ghosh, Xiawei Zhang, Patrick Achord, Thomas J. Emge, Karsten Krogh-Jespersen, and Alan S. Goldman pp 853–866 DOI: 10.1021/ja0647194 Supporting Info

Solid-State NMR Evidence for a Protonation Switch in the Binding Pocket of the H1 Receptor upon Binding of the Agonist Histamine Venkata R. P. Ratnala, Suzanne R. Kiihne, Francesco Buda, Rob Leurs, Huub J. M. de Groot, and Willem J. DeGrip pp 867–872 DOI: 10.1021/ja0652262 Supporting Info

Polyproline-Rod Approach to Isolating Protein Targets of Bioactive Small Molecules:  Isolation of a New Target of Indomethacin Shin-ichi Sato, Youngjoo Kwon, Shinji Kamisuki, Neeta Srivastava, Qian Mao, Yoshinori Kawazoe, and Motonari Uesugi pp 873–880 DOI: 10.1021/ja0655643 Supporting Info

Thallium(I) Sandwich, Multidecker, and Ether Complexes Stabilized by Weakly-Coordinating Anions:  A Spectroscopic, Structural, and Theoretical Investigation Yann Sarazin, David L. Hughes, Nikolas Kaltsoyannis, Joseph A. Wright, and Manfred Bochmann pp 881–894 DOI: 10.1021/ja0657105 Supporting Info

Stabilization and Structure of Telomeric and c-myc Region Intramolecular G-Quadruplexes:  The Role of Central Cations and Small Planar Ligands Valérie Gabelica, Erin Shammel Baker, Marie-Paule Teulade-Fichou, Edwin De Pauw, and Michael T. Bowers pp 895–904 DOI: 10.1021/ja065989p Supporting Info

A DFT Study on the Mechanism of Phosphodiester Cleavage Mediated by Monozinc Complexes Yubo Fan and Yi Qin Gao pp 905–913 DOI: 10.1021/ja0660251 Supporting Info

Preparation of Chiral α-Oxy-[2H1]methyllithiums of 99% ee and Determination of Their Configurational Stability Dagmar Kapeller, Roland Barth, Kurt Mereiter, and Friedrich Hammerschmidt pp 914–923 DOI: 10.1021/ja066183s Supporting Info

Hydrogenation of Simple Aromatic Molecules: A Computational Study of the Mechanism George Zhong, Bun Chan, and Leo Radom pp 924–933 DOI: 10.1021/ja066251a Supporting Info

Does the A·T or G·C Base-Pair Possess Enhanced Stability? Quantifying the Effects of CH···O Interactions and Secondary Interactions on Base-Pair Stability Using a Phenomenological Analysis and ab Initio Calculations Jordan R. Quinn, Steven C. Zimmerman, Janet E. Del Bene, and Isaiah Shavitt pp 934–941 DOI: 10.1021/ja066341f Supporting Info

From Insulator to Electride:  A Theoretical Model of Nanoporous Oxide 12CaO·7Al2O3 Peter V. Sushko, Alexander L. Shluger, Masahiro Hirano, and Hideo Hosono pp 942–951 DOI: 10.1021/ja066177w Supporting Info

Synthesis, Structure, and Magnetic Properties of an Antiferromagnetic Spin-Ladder Complex:  Bis(2,3-dimethylpyridinium) Tetrabromocuprate Alexander Shapiro, Christopher P. Landee, Mark M. Turnbull, Joaquim Jornet, Mercè Deumal, Juan J. Novoa, Michael A. Robb, and William Lewis pp 952–959 DOI: 10.1021/ja066330m Supporting Info

Functionally Rigid Bistable [2]Rotaxanes Sune Nygaard, Ken C.-F. Leung, Ivan Aprahamian, Taichi Ikeda, Sourav Saha, Bo W. Laursen, Soo-Young Kim, Stinne W. Hansen, Paul C. Stein, Amar H. Flood, J. Fraser Stoddart, and Jan O. Jeppesen pp 960–970 DOI: 10.1021/ja0663529 Supporting Info

Origin of the Monoclinic-to-Monoclinic Phase Transition and Evidence for the Centrosymmetric Crystal Structure of BiMnO3 Alexei A. Belik, Satoshi Iikubo, Tadahiro Yokosawa, Katsuaki Kodama, Naoki Igawa, Shinichi Shamoto, Masaki Azuma, Mikio Takano, Koji Kimoto, Yoshio Matsui, and Eiji Takayama-Muromachi pp 971–977 DOI: 10.1021/ja0664032 Supporting Info

Transient Palladadiphosphanylcarbenes:  Singlet Carbenes with an “Inverse” Electronic Configuration (pπ2 instead of σ2) and Unusual Transannular Metal−Carbene Interactions (πC→Pd Donation and σPd→C Back-donation) Joan Vignolle, Heinz Gornitzka, Laurent Maron, Wolfgang W. Schoeller, Didier Bourissou, and Guy Bertrand pp 978–985 DOI: 10.1021/ja066738j Supporting Info

Photoreversible Multiple Additions of Hydrogen to a Highly Unsaturated Platinum−Rhenium Cluster Complex Richard D. Adams, Burjor Captain, Chad Beddie, and Michael B. Hall pp 986–1000 DOI: 10.1021/ja067028g Supporting Info

Diels−Alder Ribozyme Catalysis:  A Computational Approach Xiaohua Zhang and Thomas C. Bruice pp 1001–1007 DOI: 10.1021/ja067416i

An Organic White Light-Emitting Fluorophore [J. Am. Chem. Soc. 2006, 128, 14081−14092]. p 1008 DOI: 10.1021/ja068506q Supporting Info

Self-Assembly of Coordination Polymers:  Evidence for Dynamic Exchange between Oligomers in Solution and the Isolation of a Homochiral Decagold(I) Oligomer [J. Am. Chem. Soc. 2006, 128, 15370−15371]. p 1008 DOI: 10.1021/ja069985w

Progress in Colloid and Polymer Science, Volume 133, 2006:  Smart Colloidal Materials Edited by Walter Richtering (RWTH Aachen University, Germany). Series edited by F. Kremer and W. Richtering. Springer:  Berlin, Heidelberg, New York. 2006. viii + 184 pp. $199.00. ISBN 3-540-32701-0. p 1009 DOI: 10.1021/ja069828x

Greene's Protective Groups in Organic Synthesis, 4th ed By Peter G. M. Wuts (Pfizer) and Theodora W. Greene (The Rowland Institute for Science). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xxviii + 1082 pp. $94.95. ISBN 0-471-68754-0. p 1009 DOI: 10.1021/ja069836d

Supramolecular Polymers, Polymeric Betains, Oligomers. Advances in Polymer Science, 201 Springer:  Berlin, Heidelberg, New York. 2006. x + 302 pp. $259.00. ISBN 3-540-31923-9. Rigoberto C. Advincula pp 1009–1010 DOI: 10.1021/ja069804q

Electrokinetic Chromatography:  Theory, Instrumentation and Applications Edited by Ute Pyell (University of Marburg, Germany). John Wiley & Sons, Ltd:  Chichester. 2006. xii + 540 pp. $235.00. ISBN 0-470-87102-4. Shahab A. Shamsi pp 1010–1011 DOI: 10.1021/ja069790o

Inorganic Chemistry in Focus III Edited by Gerd Meyer, Dieter Naumann (Universität Köln, Germany), and Lars Wesemann (Universität Tübingen, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xlvi + 330 pp. $125. ISBN 3-527-31510-1. R. Bruce King p 1011 DOI: 10.1021/ja069826c

Peptide Hybrid Polymers. Advances in Polymer Science, 202 Edited by Harm-Anton Klok (Ecole Polytechnique Fédérale de Lausanne, Lausanne, Switzerland) and Helmut Schlaad (Max Planck Institute of Colloids and Interfaces, Potsdam-Golm, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xii + 160 pp. $179. ISBN 3-540-32567-0. Stuart J Rowan pp 1011–1012 DOI: 10.1021/ja069805i

Potential Health Benefits of Citrus. ACS Symposium Series 936 Edited by Bhimanagouda S. Patil (Texas A&M University), Nancy D. Turner (Texas A&M University), Edward G. Miller (Baylor University), and Jennifer S. Brodbelt (University of Texas at Austin). American Chemical Society:  Washington, DC (Distributed by Oxford University Press). 2006. xiv + 282 pp. $174.50. ISBN 0-8412-3957-6. p 1012 DOI: 10.1021/ja0698432

Issue 05

Giant Heterometallic Cu17Mn28 Cluster with Td Symmetry and High-Spin Ground State Wen-Guo Wang, Ai-Ju Zhou, Wei-Xiong Zhang, Ming-Liang Tong, Xiao-Ming Chen, Motohiro Nakano, Christopher C. Beedle, and David N. Hendrickson pp 1014–1015 DOI: 10.1021/ja065707l Supporting Info

Solid-State NMR Studies of Two Backbone Conformations at Tyr185 as a Function of Retinal Configurations in the Dark, Light, and Pressure Adapted Bacteriorhodopsins Izuru Kawamura, Naoki Kihara, Masato Ohmine, Katsuyuki Nishimura, Satoru Tuzi, Hazime Saitô, and Akira Naito pp 1016–1017 DOI: 10.1021/ja0664887

Separations Using Carbon Dioxide Vaclav Stastny and Dmitry M. Rudkevich pp 1018–1019 DOI: 10.1021/ja0672369 Supporting Info

Synthesis and Cellular Profiling of Diverse Organosilicon Small Molecules Annaliese K. Franz, Philip D. Dreyfuss, and Stuart L. Schreiber pp 1020–1021 DOI: 10.1021/ja067552n Supporting Info

The Acyl Group as the Central Element of the Structural Organization of Antimicrobial Lipopeptide Boštjan Japelj, Mateja Zorko, Andreja Majerle, Primož Pristovšek, Susana Sanchez-Gomez, Guillermo Martinez de Tejada, Ignacio Moriyon, Sylvie E. Blondelle, Klaus Brandenburg, Jörg Andrä, Karl Lohner, and Roman Jerala pp 1022–1023 DOI: 10.1021/ja067419v Supporting Info

Oligomers as Intermediates in Ring-Closing Metathesis Jay C. Conrad, Melanie D. Eelman, João A. Duarte Silva, Sebastien Monfette, Henrietta H. Parnas, Jennifer L. Snelgrove, and Deryn E. Fogg pp 1024–1025 DOI: 10.1021/ja067531t Supporting Info

Highly Selective Recognition of Cytosine over Uracil and Adenine by a Guanine Analogue, 2-N-Acetyl-3-deazaguanine, in 2‘-O-Methyl-RNA/RNA and DNA Duplexes Kohji Seio, Takeshi Sasami, Akihiro Ohkubo, Kaori Ando, and Mitsuo Sekine pp 1026–1027 DOI: 10.1021/ja064612g Supporting Info

Sluggish σ-Bond Formation between sp-Hybridized Carbons:  Acetylide Coupling on Ag(111) Hsuan Kung, Long-Cheng Lee, Shin-Mou Wu, Hsiu-Yao Cheng, and Chao-Ming Chiang pp 1028–1029 DOI: 10.1021/ja066066x Supporting Info

Ruthenium-Catalyzed Carboxylative Cyclization of 1,6-Diynes Hahn Kim, Stephen D. Goble, and Chulbom Lee pp 1030–1031 DOI: 10.1021/ja067336e Supporting Info

Stereoelectronic Effects Dictate Mechanistic Dichotomy between Cu(II)-Catalyzed and Enzyme-Catalyzed Reactions of Malonic Acid Half Thioesters Kevin C. Fortner and Matthew D. Shair pp 1032–1033 DOI: 10.1021/ja0673682 Supporting Info

Enantioselective Pd-Catalyzed Allylation Reaction of Fluorinated Silyl Enol Ethers Étienne Bélanger, Katy Cantin, Olivier Messe, Mélanie Tremblay, and Jean-François Paquin pp 1034–1035 DOI: 10.1021/ja067501q Supporting Info

Cascade Michael−Aldol Reactions Promoted by Hydrogen Bonding Mediated Catalysis Liansuo Zu, Jian Wang, Hao Li, Hexin Xie, Wei Jiang, and Wei Wang pp 1036–1037 DOI: 10.1021/ja067781+ Supporting Info

New, Chiral Phase Transfer Catalysts for Effecting Asymmetric Conjugate Additions of α-Alkyl-α-cyanoacetates to Acetylenic Esters Xisheng Wang, Masanori Kitamura, and Keiji Maruoka pp 1038–1039 DOI: 10.1021/ja068119g Supporting Info

Microtubule Formation Using Two-Component Gel System Ho Yong Lee, Seong Ryong Nam, and Jong-In Hong pp 1040–1041 DOI: 10.1021/ja0676197 Supporting Info

A Target-Responsive Electrochemical Aptamer Switch (TREAS) for Reagentless Detection of Nanomolar ATP Xiaolei Zuo, Shiping Song, Jiong Zhang, Dun Pan, Lihua Wang, and Chunhai Fan pp 1042–1043 DOI: 10.1021/ja067024b Supporting Info

Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Catalysts Frédéric Blanc, Jean Thivolle-Cazat, Jean-Marie Basset, Christophe Copéret, Adam S. Hock, Zachary J. Tonzetich, and Richard. R. Schrock pp 1044–1045 DOI: 10.1021/ja068249p Supporting Info

Copper-Catalyzed Asymmetric [4+1] Cycloadditions of Enones with Diazo Compounds To Form Dihydrofurans Sunghee Son and Gregory C. Fu pp 1046–1047 DOI: 10.1021/ja068344y Supporting Info

Total Synthesis of (+)-Galbulimima Alkaloid 13 and (+)-Himgaline David A. Evans and Drew J. Adams pp 1048–1049 DOI: 10.1021/ja0684996 Supporting Info

Total Syntheses of Durgamone, Nakorone, and Abudinol B via Biomimetic Oxa- and Carbacyclizations Rongbiao Tong, Jason C. Valentine, Frank E. McDonald, Rui Cao, Xikui Fang, and Kenneth I. Hardcastle pp 1050–1051 DOI: 10.1021/ja068826+ Supporting Info

Protein Assistance in the Photoisomerization of Rhodopsin and 9-cis-RhodopsinInsights from Experiment and Theory Sivakumar Sekharan, Minoru Sugihara, Oliver Weingart, Tetsuji Okada, and Volker Buss pp 1052–1054 DOI: 10.1021/ja066970p Supporting Info

Collective Relaxation of Protein Protons at Very Low Magnetic Field:  A New Window on Protein Dynamics and Aggregation Claudio Luchinat and Giacomo Parigi pp 1055–1064 DOI: 10.1021/ja0633417 Supporting Info

X-ray Absorption and EPR Spectroscopic Studies of the Biotransformations of Chromium(VI) in Mammalian Cells. Is Chromodulin an Artifact of Isolation Methods? Aviva Levina, Hugh H. Harris, and Peter A. Lay pp 1065–1075 DOI: 10.1021/ja063792r Supporting Info

The Mechanistically Significant Coordination Chemistry of Dinitrogen at FeMo-co, the Catalytic Site of Nitrogenase Ian Dance pp 1076–1088 DOI: 10.1021/ja0644428 Supporting Info

Controlled Formation of Ag Nanoparticles by Means of Long-Chain Sodium Polyacrylates in Dilute Solution Klaus Huber, Thomas Witte, Jutta Hollmann, and Susanne Keuker-Baumann pp 1089–1094 DOI: 10.1021/ja063368q Supporting Info

Electrospray Mass Spectrometry Study of Tiopronin Monolayer-Protected Gold Nanoclusters Anthony P. Gies, David M. Hercules, Aren E. Gerdon, and David E. Cliffel pp 1095–1104 DOI: 10.1021/ja0639057 Supporting Info

Ring-Expanding Olefin Metathesis:  A Route to Highly Active Unsymmetrical Macrocyclic Oligomeric Co-Salen Catalysts for the Hydrolytic Kinetic Resolution of Epoxides Xiaolai Zheng, Christopher W. Jones, and Marcus Weck pp 1105–1112 DOI: 10.1021/ja0641406 Supporting Info

Temperature-Induced Reversible Morphological Changes of Polystyrene-block-Poly(ethylene Oxide) Micelles in Solution Prachur Bhargava, Yingfeng Tu, Joseph X. Zheng, Huiming Xiong, Roderic P. Quirk, and Stephen Z. D. Cheng pp 1113–1121 DOI: 10.1021/ja0653019 Supporting Info

Structural Assessment and Catalytic Consequences of the Oxygen Coordination Environment in Grafted Ti−Calixarenes Justin M. Notestein, Leandro R. Andrini, Vitaly I. Kalchenko, Felix G. Requejo, Alexander Katz, and Enrique Iglesia pp 1122–1131 DOI: 10.1021/ja065830c Supporting Info

Ambient Temperature Synthesis of High Enantiopurity N-Protected Peptidyl Ketones by Peptidyl Thiol Ester−Boronic Acid Cross-Coupling Hao Yang, Hao Li, Rüdiger Wittenberg, Masahiro Egi, Wenwei Huang, and Lanny S. Liebeskind pp 1132–1140 DOI: 10.1021/ja0658719 Supporting Info

Homoleptic Isocyanidemetalates of 4d- and 5d-Transition Metals:  [Nb(CNXyl)6]-, [Ta(CNXyl)6]-, and Derivatives Thereof1 Mikhail V. Barybin, William W. Brennessel, Benjamin E. Kucera, Mikhail E. Minyaev, Victor J. Sussman, Victor G. Young, Jr., and John E. Ellis pp 1141–1150 DOI: 10.1021/ja065964q Supporting Info

New Members of a Class of Iron−Thiolate−Nitrosyl Compounds:  Trinuclear Iron−Thiolate−Nitrosyl Complexes Containing Fe3S6 Core I-Jui Hsu, Chung-Hung Hsieh, Shyue-Chu Ke, Kuo-An Chiang, Jenn-Min Lee, Jin-Ming Chen, Ling-Yun Jang, Gene-Hsiang Lee, Yu Wang, and Wen-Feng Liaw pp 1151–1159 DOI: 10.1021/ja065401e Supporting Info

Site-Specific Incorporation of a 19F-Amino Acid into Proteins as an NMR Probe for Characterizing Protein Structure and Reactivity Jennifer C. Jackson, Jared T. Hammill, and Ryan A. Mehl pp 1160–1166 DOI: 10.1021/ja064661t Supporting Info

Synthesis of Cationic Rhenium(VII) Oxo Imido Complexes and Their Tunability Towards Oxygen Atom Transfer Elon A. Ison, Jeanette E. Cessarich, Nicholas E. Travia, Phillip E. Fanwick, and Mahdi M. Abu-Omar pp 1167–1178 DOI: 10.1021/ja065551p Supporting Info

Structure and Dynamics of the Homologous Series of Alanine Peptides:  A Joint Molecular Dynamics/NMR Study Jürgen Graf, Phuong H. Nguyen, Gerhard Stock, and Harald Schwalbe pp 1179–1189 DOI: 10.1021/ja0660406 Supporting Info

Diastereo- and Enantioselective Synthesis of Nitroso Diels−Alder-Type Bicycloketones Using Dienamine:  Mechanistic Insight into Sequential Nitroso Aldol/Michael Reaction and Application for Optically Pure 1-Amino-3,4-diol Synthesis Norie Momiyama, Yuhei Yamamoto, and Hisashi Yamamoto pp 1190–1195 DOI: 10.1021/ja066037m Supporting Info

Effect of Disorder on the Optically Amplified Photocatalytic Efficiency of Titania Inverse Opals Jennifer I. L. Chen, Georg von Freymann, Vladimir Kitaev, and Geoffrey A. Ozin pp 1196–1202 DOI: 10.1021/ja066102s Supporting Info

High-Capacity Hydrogen and Nitric Oxide Adsorption and Storage in a Metal−Organic Framework Bo Xiao, Paul S. Wheatley, Xuebo Zhao, Ashleigh J. Fletcher, Sarah Fox, Adriano G. Rossi, Ian L. Megson, S. Bordiga, L. Regli, K. Mark Thomas, and Russell E. Morris pp 1203–1209 DOI: 10.1021/ja066098k Supporting Info

Protonation States of Ammonia/Ammonium in the Hydrophobic Pore of Ammonia Transporter Protein AmtB Hiroshi Ishikita and Ernst-Walter Knapp pp 1210–1215 DOI: 10.1021/ja066208n Supporting Info

Valence Anions in Complexes of Adenine and 9-Methyladenine with Formic Acid:  Stabilization by Intermolecular Proton Transfer Kamil Mazurkiewicz, Maciej Harańczyk, Maciej Gutowski, Janusz Rak, Dunja Radisic, Soren N. Eustis, Di Wang, and Kit H. Bowen pp 1216–1224 DOI: 10.1021/ja066229h Supporting Info

Dual Binding Modes of Congo Red to Amyloid Protofibril Surface Observed in Molecular Dynamics Simulations Chun Wu, Zhixiang Wang, Hongxing Lei, Wei Zhang, and Yong Duan pp 1225–1232 DOI: 10.1021/ja0662772 Supporting Info

Photochemical and Thermal Reactions of Intermediates in the Phenylnitrene Rearrangement Inside a Hemicarcerand Ralf Warmuth and Slawomir Makowiec pp 1233–1241 DOI: 10.1021/ja066130a Supporting Info

Regioselective Cycloaddition Reaction of Alkene Molecules with the Asymmetric Dimer on Si(100)c(4×2) Kazuhiro Oguchi, Masashi Nagao, Hirobumi Umeyama, Tetsuo Katayama, Yoshiyuki Yamashita, Kozo Mukai, Jun Yoshinobu, Kazuto Akagi, and Shinji Tsuneyuki pp 1242–1245 DOI: 10.1021/ja066285i

Rhenium(VII) Oxide Catalyzed Heteroacylative Ring-Opening Dimerization of Tetrahydrofuran H. Christine Lo, Hongna Han, Lawrence J. D'Souza, Subhash C. Sinha, and Ehud Keinan pp 1246–1253 DOI: 10.1021/ja0668668

9-Donor-Substituted Acridizinium Salts:  Versatile Environment-Sensitive Fluorophores for the Detection of Biomacromolecules Anton Granzhan, Heiko Ihmels, and Giampietro Viola pp 1254–1267 DOI: 10.1021/ja0668872 Supporting Info

Synthesis, Characterization, and Reactivities of Manganese(V)−Oxo Porphyrin Complexes Woon Ju Song, Mi Sook Seo, Serena DeBeer George, Takehiro Ohta, Rita Song, Min-Jung Kang, Takehiko Tosha, Teizo Kitagawa, Edward I. Solomon, and Wonwoo Nam pp 1268–1277 DOI: 10.1021/ja066460v Supporting Info

Boronic Acid-Based Bipyridinium Salts as Tunable Receptors for Monosaccharides and α-Hydroxycarboxylates Soya Gamsey, Aaron Miller, Marilyn M. Olmstead, Christine M. Beavers, Lacie C. Hirayama, Sulolit Pradhan, Ritchie A. Wessling, and Bakthan Singaram pp 1278–1286 DOI: 10.1021/ja066567i Supporting Info

The Ion Sensitivity of Surface Conductive Single Crystalline Diamond Andreas Härtl, Jose A. Garrido, Stefan Nowy, Ralf Zimmermann, Carsten Werner, Dominik Horinek, Roland Netz, and Martin Stutzmann pp 1287–1292 DOI: 10.1021/ja066543b Supporting Info

Structure of Molecular Tweezer Complexes in the Solid State:  NMR Experiments, X-ray Investigations, and Quantum Chemical Calculations Torsten Schaller, Uta P. Büchele, Frank-Gerrit Klärner, Dieter Bläser, Roland Boese, Steven P. Brown, Hans Wolfgang Spiess, Felix Koziol, Jörg Kussmann, and Christian Ochsenfeld pp 1293–1303 DOI: 10.1021/ja0666351 Supporting Info

Structural Characterization of a Rigidified Threading Bisintercalator Yongjun Chu, Steven Sorey, David W. Hoffman, and Brent L. Iverson pp 1304–1311 DOI: 10.1021/ja066480x Supporting Info

Dependence of Effective Molarity on Linker Length for an Intramolecular Protein−Ligand System Vijay M. Krishnamurthy, Vincent Semetey, Paul J. Bracher, Nan Shen, and George M. Whitesides pp 1312–1320 DOI: 10.1021/ja066780e Supporting Info

Residue-Specific 13C‘ CSA Tensor Principal Components for Ubiquitin:  Correlation between Tensor Components and Hydrogen Bonding Robert A. Burton and Nico Tjandra pp 1321–1326 DOI: 10.1021/ja066835c

Six-fold Oxygen-Coordinated Triplet (S = 1) Palladium(II) Moieties Templated by Tris(bipyridine)ruthenium(II) Ions Fabrice Pointillart, Cyrille Train, Françoise Villain, Christophe Cartier dit Moulin, Patrick Gredin, Lise-Marie Chamoreau, Michel Gruselle, Gabriel Aullon, Santiago Alvarez, and Michel Verdaguer pp 1327–1334 DOI: 10.1021/ja066817v Supporting Info

Vibrational Gating of Double Hydrogen Tunneling in Porphycene Michał Gil and Jacek Waluk pp 1335–1341 DOI: 10.1021/ja066976e Supporting Info

Aryl-Fluoride Reductive Elimination from Pd(II):  Feasibility Assessment from Theory and Experiment Dmitry V. Yandulov and Ngon T. Tran pp 1342–1358 DOI: 10.1021/ja066930l Supporting Info

Mechanism of Titanocene-Mediated Epoxide Opening through Homolytic Substitution Andreas Gansäuer, Andriy Barchuk, Florian Keller, Martin Schmitt, Stefan Grimme, Mareike Gerenkamp, Christian Mück-Lichtenfeld, Kim Daasbjerg, and Heidi Svith pp 1359–1371 DOI: 10.1021/ja067054e Supporting Info

UltraSOFAST HMQC NMR and the Repetitive Acquisition of 2D Protein Spectra at Hz Rates Maayan Gal, Paul Schanda, Bernhard Brutscher, and Lucio Frydman pp 1372–1377 DOI: 10.1021/ja066915g

The Carboxylate Shift in Zinc Enzymes: A Computational Study Sérgio F. Sousa, Pedro A. Fernandes, and Maria João Ramos pp 1378–1385 DOI: 10.1021/ja067103n Supporting Info

Structures of Alkali Metals in Silica Gel Nanopores:  New Materials for Chemical Reductions and Hydrogen Production Mouath Shatnawi, Gianluca Paglia, James L. Dye, Kevin C. Cram, Michael Lefenfeld, and Simon J. L. Billinge pp 1386–1392 DOI: 10.1021/ja067140e

A Fractional Bond Order of 1/2 in Pd25+−Formamidinate Species; The Value of Very High-Field EPR Spectra John F. Berry, Eckhard Bill, Eberhard Bothe, F. Albert Cotton, Naresh S. Dalal, Sergey A. Ibragimov, Narpinder Kaur, Chun Y. Liu, Carlos A. Murillo, Saritha Nellutla, J. Micah North, and Dino Villagrán pp 1393–1401 DOI: 10.1021/ja067328y Supporting Info

Distinct Reaction Pathways Followed upon Reduction of Oxy-Heme Oxygenase and Oxy-Myoglobin as Characterized by Mössbauer Spectroscopy Ricardo Garcia-Serres, Roman M. Davydov, Toshitaka Matsui, Masao Ikeda-Saito, Brian M. Hoffman, and Boi Hanh Huynh pp 1402–1412 DOI: 10.1021/ja067209i Supporting Info

Discovery of Chemical Reactions through Multidimensional Screening Aaron B. Beeler, Shun Su, Chris A. Singleton, and John A. Porco, Jr. pp 1413–1419 DOI: 10.1021/ja0674744 Supporting Info

Multiple Orientation of Melittin inside a Single Lipid Bilayer Determined by Combined Vibrational Spectroscopic Studies Xiaoyun Chen, Jie Wang, Andrew P. Boughton, Cornelius B. Kristalyn, and Zhan Chen pp 1420–1427 DOI: 10.1021/ja067446l Supporting Info

FePt@CoS2 Yolk−Shell Nanocrystals as a Potent Agent to Kill HeLa Cells Jinhao Gao, Gaolin Liang, Bei Zhang, Yi Kuang, Xixiang Zhang, and Bing Xu pp 1428–1433 DOI: 10.1021/ja067785e Supporting Info

Electronic and Magnetic Communication in Mixed-Valent and Homovalent Ruthenium Complexes Containing Phenylcyanamide Type Bridging Ligands Muriel Fabre and Jacques Bonvoisin pp 1434–1444 DOI: 10.1021/ja067255i Supporting Info

About Long-Lived Nuclear Spin States Involved in Para-Hydrogenated Molecules Daniel Canet, Sabine Bouguet-Bonnet, Christie Aroulanda, and Francesca Reineri pp 1445–1449 DOI: 10.1021/ja066313x

Origin of Structural Diversity in Natural Triterpenes: Direct Synthesis of seco-Triterpene Skeletons by Oxidosqualene Cyclase Masaaki Shibuya, Ting Xiang, Yuji Katsube, Miyuki Otsuka, Hong Zhang, and Yutaka Ebizuka pp 1450–1455 DOI: 10.1021/ja066873w Supporting Info

Modified DNA Aptamer That Binds the (R)-Isomer of a Thalidomide Derivative with High Enantioselectivity Atsushi Shoji, Masayasu Kuwahara, Hiroaki Ozaki, and Hiroaki Sawai pp 1456–1464 DOI: 10.1021/ja067098n Supporting Info

Total Synthesis of (+)-Nakadomarin A Ian S. Young and Michael A. Kerr pp 1465–1469 DOI: 10.1021/ja068047t Supporting Info

8-Hydroxyquinoline Derivatives as Fluorescent Sensors for Magnesium in Living Cells [J. Am. Chem. Soc. 2006, 128, 344−350]. Giovanna Farruggia, Stefano Iotti, Luca Prodi, Marco Montalti, Nelsi Zaccheroni, Paul B. Savage, Valentina Trapani, Patrizio Sale, and Federica I. Wolf p 1470 DOI: 10.1021/ja069973a

A Cyclic Triphenylamine Dimer for Organic Field-Effect Transistors with High Performance  [J. Am. Chem. Soc. 2006, 128, 15940−15941].  Yabin Song, Chong'an Di, Xiaodi Yang, Shouping Li, Wei Xu, Yunqi Liu, Lianming Yang, Zhigang Shuai, Deqing Zhang, and Daoben Zhu p 1470 DOI: 10.1021/ja069986o

Properties of Single Organic Molecules on Crystal Surfaces Edited by Peter Grütter (McGill University, Canada), Werner Hofer (University of Liverpool, UK), and Federico Rosei (Université du Québec, Canada). Imperial College Press:  London. 2006. xii + 430 pp. $108.00. ISBN 1-86094-628-3. David A. Vanden Bout p 1471 DOI: 10.1021/ja069788x

N4-Macrocyclic Metal Complexes Edited by José H. Zagal (Universidad de Santiago de Chile), Fethi Bedioui (Ecole Nationale Supérieure de Chimie de Paris, France), and Jean-Pol Dodelet (INRS-Énergie, Matériaux et Télécommunications, Varennes, Québec, Canada). Springer Science + Business Media, LLC:  New York. 2006. xvii + 814 pp. $179.00. ISBN 0-387-28429-X. Martin Stillman pp 1471–1472 DOI: 10.1021/ja069795l

Organic Synthesis:  State of the Art 2003−2005 By Douglass F. Taber (University of Delaware, Newark). John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. x + 216 pp. $99.95. ISBN 0-470-05331-3. p 1472 DOI: 10.1021/ja069830o

Metal-Catalysis in Industrial Organic Processes Edited by Gian Paolo Chiusoli (University of Parma, Italy) and Peter M. Maitlis (The University of Sheffield, UK). Royal Society of Chemistry:  Cambridge, 2006. xx + 290 pp. $189.00. ISBN 0-85404-862-6. p 1472 DOI: 10.1021/ja0698376

Issue 06

Bacterial Spore Detection by [Tb3+(macrocycle)(dipicolinate)] Luminescence Morgan L. Cable, James P. Kirby, Karn Sorasaenee, Harry B. Gray, and Adrian Ponce pp 1474–1475 DOI: 10.1021/ja061831t Supporting Info

X-ray Excited Optical Luminescence from Diamond Thin Films:  The Contribution of sp2- and H-Bonded Carbon to the Luminescence Xingtai Zhou, Tsun-Kong Sham, Yu Wu, Yat-Ming Chong, Igor Bello, Shuit-Tong Lee, Franziskus Heigl, Tom Regier, and Robert I. R. Blyth pp 1476–1477 DOI: 10.1021/ja064555r

Application of Superhydrophobic Surface with High Adhesive Force in No Lost Transport of Superparamagnetic Microdroplet Xia Hong, Xuefeng Gao, and Lei Jiang pp 1478–1479 DOI: 10.1021/ja065537c Supporting Info

Catalytic Asymmetric Inverse-Electron-Demand Diels−Alder Reaction of N-Sulfonyl-1-Aza-1,3-Dienes Jorge Esquivias, Ramón Gómez Arrayás, and Juan C. Carretero pp 1480–1481 DOI: 10.1021/ja0658766 Supporting Info

A Highly Efficient and Selective Route to Isomeric Cyclic Diazadienes Mark E. Scott, Yann Bethuel, and Mark Lautens pp 1482–1483 DOI: 10.1021/ja067304r Supporting Info

Highly Enantioselective Friedel−Crafts Reaction of Indoles with Imines by a Chiral Phosphoric Acid Qiang Kang, Zhuo-An Zhao, and Shu-Li You pp 1484–1485 DOI: 10.1021/ja067417a Supporting Info

A New Class of Macrocyclic Receptors from iota-Peptides Sang-Woo Kang, Chris M. Gothard, Santanu Maitra, Atia-tul-Wahab, and James S. Nowick pp 1486–1487 DOI: 10.1021/ja0677970 Supporting Info

Photochemical Single-Molecule Affinity Switch Christian Schäfer, Rainer Eckel, Robert Ros, Jochen Mattay, and Dario Anselmetti pp 1488–1489 DOI: 10.1021/ja067734h Supporting Info

Electroformation of Giant Vesicles on a Non-Electroconductive Substrate Yukihisa Okumura, Hao Zhang, Takuya Sugiyama, and Yuuichi Iwata pp 1490–1491 DOI: 10.1021/ja068127x Supporting Info

Rhodium-Catalyzed Asymmetric Cyclodimerization of Oxa- and Azabicyclic Alkenes Takahiro Nishimura, Takahiro Kawamoto, Keigo Sasaki, Eiji Tsurumaki, and Tamio Hayashi pp 1492–1493 DOI: 10.1021/ja068488c Supporting Info

Iron Porphyrin-Catalyzed Olefination of Ketenes with Diazoacetate for the Enantioselective Synthesis of Allenes Chuan-Ying Li, Xiao-Bing Wang, Xiu-Li Sun, Yong Tang, Jun-Cheng Zheng, Zheng-Hu Xu, Yong-Gui Zhou, and Li-Xin Dai pp 1494–1495 DOI: 10.1021/ja068642v Supporting Info

Stereospecific Interaction between Immune Cells and Chiral Surfaces Taolei Sun, Dong Han, Kristina Rhemann, Lifeng Chi, and Harald Fuchs pp 1496–1497 DOI: 10.1021/ja0686155 Supporting Info

Chiral Oxazaborolidine−Aluminum Bromide Complexes Are Unusually Powerful and Effective Catalysts for Enantioselective Diels−Alder Reactions Duan Liu, Eda Canales, and E. J. Corey pp 1498–1499 DOI: 10.1021/ja068637r Supporting Info

A Selective Fluorescent Sensor for Imaging Cd2+ in Living Cells Xiaojun Peng, Jianjun Du, Jiangli Fan, Jingyun Wang, Yunkou Wu, Jianzhang Zhao, Shiguo Sun, and Tao Xu pp 1500–1501 DOI: 10.1021/ja0643319 Supporting Info

A G-Quadruplex Ligand with 10000-Fold Selectivity over Duplex DNA Isabelle M. Dixon, Frédéric Lopez, Agueda M. Tejera, Jean-Pierre Estève, Maria A. Blasco, Geneviève Pratviel, and Bernard Meunier pp 1502–1503 DOI: 10.1021/ja065591t Supporting Info

Probing Secondary, Tertiary, and Quaternary Structure along with Protein−Cofactor Interactions for a Helical Transmembrane Protein Complex through 1H Spin Diffusion with MAS NMR Spectroscopy Swapna Ganapathy, Adriaan J. van Gammeren, Frans B. Hulsbergen, and Huub J. M. de Groot pp 1504–1505 DOI: 10.1021/ja0664436 Supporting Info

Chelation-Enhanced Circular Dichroism of Tripodal Bisporphyrin Ligands Andrea E. Holmes, Debasis Das, and James W. Canary pp 1506–1507 DOI: 10.1021/ja0666147 Supporting Info

Quantitative Evaluation of the Relative Cell Permeability of Peptoids and Peptides Yong-Uk Kwon and Thomas Kodadek pp 1508–1509 DOI: 10.1021/ja0668623 Supporting Info

Myriad Planar Hexacoordinate Carbon Molecules Inviting Synthesis Keigo Ito, Zhongfang Chen, Clémence Corminboeuf, Chaitannya S. Wannere, Xiu Hui Zhang, Qian Shu Li, and Paul v. R. Schleyer pp 1510–1511 DOI: 10.1021/ja067292+ Supporting Info

Understanding the Selectivity of a Moderate Oxidation Catalyst:  Hydrogen Abstraction by a Fully Characterized, Activated Catalyst, the Robust Dihydroxo Manganese(IV) Complex of a Bridged Cyclam Guochuan Yin, Andrew M. Danby, David Kitko, John D. Carter, William M. Scheper, and Daryle H. Busch pp 1512–1513 DOI: 10.1021/ja0673229 Supporting Info

[Cu(C24H22N4O3)]·CH2Cl2:  A Discrete Breathing Metallamacrocycle Showing Selective and Reversible Guest Adsorption with Retention of Single Crystallinity Yu-Bin Dong, Qiang Zhang, Li-Li Liu, Jian-Ping Ma, Bo Tang, and Ru-Qi Huang pp 1514–1515 DOI: 10.1021/ja067384z Supporting Info

CVD Synthesis of Single-Walled Carbon Nanotubes from Gold Nanoparticle Catalysts Sreekar Bhaviripudi, Ervin Mile, Stephen A. Steiner III, Aurea T. Zare, Mildred S. Dresselhaus, Angela M. Belcher, and Jing Kong pp 1516–1517 DOI: 10.1021/ja0673332 Supporting Info

Bioinspired Chemical Inversion of l-Amino Acids to d-Amino Acids Hyunjung Park, Kwan Mook Kim, Areum Lee, Sihyun Ham, Wonwoo Nam, and Jik Chin pp 1518–1519 DOI: 10.1021/ja067724g Supporting Info

Material Design for Piezochromic Luminescence:  Hydrogen-Bond-Directed Assemblies of a Pyrene Derivative Yoshimitsu Sagara, Toshiki Mutai, Isao Yoshikawa, and Koji Araki pp 1520–1521 DOI: 10.1021/ja0677362 Supporting Info

Enantioselective Synthesis of Planar-Chiral Metacyclophanes through Rhodium-Catalyzed Alkyne Cyclotrimerization Ken Tanaka, Hiromi Sagae, Kazuki Toyoda, Keiichi Noguchi, and Masao Hirano pp 1522–1523 DOI: 10.1021/ja0679127 Supporting Info

Fluorescent Core−Shell Ag@SiO2 Nanocomposites for Metal-Enhanced Fluorescence and Single Nanoparticle Sensing Platforms Kadir Aslan, Meng Wu, Joseph R. Lakowicz, and Chris D. Geddes pp 1524–1525 DOI: 10.1021/ja0680820 Supporting Info

Direct Identification of the Minority and Majority Species in the Single-Molecule Magnet Mn12-Acetate by Inelastic Neutron Scattering Oliver Waldmann, Graham Carver, Chris Dobe, Andreas Sieber, Hans U. Güdel, and Hannu Mutka pp 1526–1527 DOI: 10.1021/ja068375t

Soft-Landing Isolation of Multidecker V2(benzene)3 Complexes in an Organic Monolayer Matrix:  An Infrared Spectroscopy and Thermal Desorption Study Shuhei Nagaoka, Takeshi Matsumoto, Kaori Ikemoto, Masaaki Mitsui, and Atsushi Nakajima pp 1528–1529 DOI: 10.1021/ja068442j Supporting Info

Observation of the Solvent Shell Reorganization around Photoexcited Atomic Solutes by Picosecond X-ray Absorption Spectroscopy Van-Thai Pham, Wojciech Gawelda, Yuri Zaushitsyn, Maik Kaiser, Daniel Grolimund, Steven L. Johnson, Rafael Abela, Christian Bressler, and Majed Chergui pp 1530–1531 DOI: 10.1021/ja068466q

High-Resolution Structure of a β-Peptide Bundle Douglas S. Daniels, E. James Petersson, Jade X. Qiu, and Alanna Schepartz pp 1532–1533 DOI: 10.1021/ja068678n Supporting Info

Synthesis of Silica Hollow Nanoparticles Templated by Polymeric Micelle with Core−Shell−Corona Structure Anil Khanal, Yuko Inoue, Mitsunori Yada, and Kenichi Nakashima pp 1534–1535 DOI: 10.1021/ja0684904 Supporting Info

Asymmetric Organocatalytic β-Hydroxylation of α,β-Unsaturated Aldehydes Søren Bertelsen, Peter Dinér, Rasmus Lyng Johansen, and Karl Anker Jørgensen pp 1536–1537 DOI: 10.1021/ja068908y Supporting Info

Chemical Transformation from FePt to Fe1-xPtMx (M = Ru, Ni, Sn) Nanocrystals by a Cation Redox Reaction:  X-ray Absorption Spectroscopic Studies Di-Yan Wang, Ching-Hsiang Chen, Hung-Chi Yen, You-Liang Lin, Pei-Yu Huang, Bing-Joe Hwang, and Chia-Chun Chen pp 1538–1540 DOI: 10.1021/ja067567l Supporting Info

Positive and Negative TiO2 Micropatterns on Organic Polymer Substrates Peng Yang, Min Yang, Shengli Zou, Jingyi Xie, and Wantai Yang pp 1541–1552 DOI: 10.1021/ja063716o Supporting Info

A Simple Class of Photorheological Fluids:  Surfactant Solutions with Viscosity Tunable by Light Aimee M. Ketner, Rakesh Kumar, Tanner S. Davies, Patrick W. Elder, and Srinivasa R. Raghavan pp 1553–1559 DOI: 10.1021/ja065053g Supporting Info

An Apparent Violation of Microscopic Reversibility:  Mechanisms for Ligand Substitution Reactions of Oxorhenium(V) Dithiolate Complexes Xinzheng Yang and Michael B. Hall pp 1560–1567 DOI: 10.1021/ja065428y Supporting Info

Secondary Structures of Peptides and Proteins via NMR Chemical-Shielding Anisotropy (CSA) Parameters Eszter Czinki, Attila G. Császár, Gábor Magyarfalvi, Peter R. Schreiner, and Wesley D. Allen pp 1568–1577 DOI: 10.1021/ja065461k Supporting Info

Solution-Phase Structural Characterization of Supramolecular Assemblies by Molecular Diffraction Jodi L. O'Donnell, Xiaobing Zuo, Andrew J. Goshe, Lev Sarkisov, Randall Q. Snurr, Joseph T. Hupp, and David M. Tiede pp 1578–1585 DOI: 10.1021/ja0659065 Supporting Info

The Crystal Structures of the Calcium-Bound con-G and con-T[K7γ] Dimeric Peptides Demonstrate a Metal-Dependent Helix-Forming Motif Sara E. Cnudde, Mary Prorok, Qiuyun Dai, Francis J. Castellino, and James H. Geiger pp 1586–1593 DOI: 10.1021/ja065722q

A Mechanism for Non-stoichiometry in the Lithium Amide/Lithium Imide Hydrogen Storage Reaction William I. F. David, Martin O. Jones, Duncan H. Gregory, Catherine M. Jewell, Simon R. Johnson, Allan Walton, and Peter P. Edwards pp 1594–1601 DOI: 10.1021/ja066016s Supporting Info

Structural Dynamics of the Cooperative Binding of Organic Molecules in the Human Cytochrome P450 3A4 Dan Fishelovitch, Carina Hazan, Sason Shaik, Haim J. Wolfson, and Ruth Nussinov pp 1602–1611 DOI: 10.1021/ja066007j Supporting Info

Infrared Spectroscopy of Cationized Arginine in the Gas Phase:  Direct Evidence for the Transition from Nonzwitterionic to Zwitterionic Structure Matthew F. Bush, Jeremy T. O'Brien, James S. Prell, Richard J. Saykally, and Evan R. Williams pp 1612–1622 DOI: 10.1021/ja066335j Supporting Info

Toward an Improved Understanding of the Glutamate Mutase System Gregory M. Sandala, David M. Smith, E. Neil G. Marsh, and Leo Radom pp 1623–1633 DOI: 10.1021/ja066432c Supporting Info

Intermolecular Covalent π−π Bonding Interaction Indicated by Bond Distances, Energy Bands, and Magnetism in Biphenalenyl Biradicaloid Molecular Crystal Jingsong Huang and Miklos Kertesz pp 1634–1643 DOI: 10.1021/ja066426g Supporting Info

Quantifying the Sequence-Dependent Species Barrier between Hamster and Mouse Prions Lily Y.-L. Lee and Rita P.-Y. Chen pp 1644–1652 DOI: 10.1021/ja0667413 Supporting Info

Controlling Multiple Fluorescent Signal Output in Cyclic Peptide-Based Supramolecular Systems Roberto J. Brea, M. Eugenio Vázquez, Manuel Mosquera, Luis Castedo, and Juan R. Granja pp 1653–1657 DOI: 10.1021/ja066885h Supporting Info

Observation of a Small Number of Molecules at a Metal Nanogap Arrayed on a Solid Surface Using Surface-Enhanced Raman Scattering Yoshitaka Sawai, Baku Takimoto, Hideki Nabika, Katsuhiro Ajito, and Kei Murakoshi pp 1658–1662 DOI: 10.1021/ja067034c

Radical Energies and the Regiochemistry of Addition to Heme Groups. Methylperoxy and Nitrite Radical Additions to the Heme of Horseradish Peroxidase Grzegorz Wojciechowski and Paul R. Ortiz de Montellano pp 1663–1672 DOI: 10.1021/ja067067s Supporting Info

Enhanced Hydrogen Storage Capacity of High Surface Area Zeolite-like Carbon Materials Zhuxian Yang, Yongde Xia, and Robert Mokaya pp 1673–1679 DOI: 10.1021/ja067149g Supporting Info

Screening of 5-HT1A Receptor Antagonists using Molecularly Imprinted Polymers Naphtali A. O'Connor, David A. Paisner, Donna Huryn, and Kenneth J. Shea pp 1680–1689 DOI: 10.1021/ja067276c Supporting Info

Ordered Mesoporous Silicas and Carbons with Large Accessible Pores Templated from Amphiphilic Diblock Copolymer Poly(ethylene oxide)-b-polystyrene Yonghui Deng, Ting Yu, Ying Wan, Yifeng Shi, Yan Meng, Dong Gu, Lijuan Zhang, Yan Huang, Chong Liu, Xiaojing Wu, and Dongyuan Zhao pp 1690–1697 DOI: 10.1021/ja067379v Supporting Info

Mechanistic Studies on 14-Electron Ruthenacyclobutanes:  Degenerate Exchange with Free Ethylene Patricio E. Romero and Warren E. Piers pp 1698–1704 DOI: 10.1021/ja0675245 Supporting Info

X-ray Photoelectron Spectroscopy and First Principles Calculation of BCN Nanotubes Shin Young Kim, Jeunghee Park, Hyun Chul Choi, Jae Pyung Ahn, Jin Qiang Hou, and Hong Seok Kang pp 1705–1716 DOI: 10.1021/ja067592r Supporting Info

Cross-Linking of Cationic Block Copolymer Micelles by Silica Deposition Jian-Jun Yuan, Oleksandr O. Mykhaylyk, Anthony J. Ryan, and Steven P. Armes pp 1717–1723 DOI: 10.1021/ja0674946 Supporting Info

Formation of 4H-1,2-Benzoxazines by Intramolecular Cyclization of Nitroalkanes. Scope of Aromatic Oxygen-Functionalization Reaction Involving a Nitro Oxygen Atom and Mechanistic Insights Satoshi Nakamura, Hiromichi Sugimoto, and Tomohiko Ohwada pp 1724–1732 DOI: 10.1021/ja067682w Supporting Info

Mechanistic Studies on the Galvanic Replacement Reaction between Multiply Twinned Particles of Ag and HAuCl4 in an Organic Medium Xianmao Lu, Hsing-Yu Tuan, Jingyi Chen, Zhi-Yuan Li, Brian A. Korgel, and Younan Xia pp 1733–1742 DOI: 10.1021/ja067800f Supporting Info

Probing Side-Chain Dynamics in the Proteasome by Relaxation Violated Coherence Transfer NMR Spectroscopy Vitali Tugarinov, Remco Sprangers, and Lewis E. Kay pp 1743–1750 DOI: 10.1021/ja067827z Supporting Info

An Unexpected Pathway for the Catalytic Oxidation of Methylidyne on Rh{111} as a Route to Syngas Oliver R. Inderwildi, Stephen J. Jenkins, and David A. King pp 1751–1759 DOI: 10.1021/ja067722w

Total Synthesis of Marinomycins A−C and of Their Monomeric Counterparts Monomarinomycin A and iso-Monomarinomycin A K. C. Nicolaou, Andrea L. Nold, Robert R. Milburn, Corinna S. Schindler, Kevin P. Cole, and Junichiro Yamaguchi pp 1760–1768 DOI: 10.1021/ja068053p Supporting Info

Symmetry Control of Radiative Decay in Linear Polyenes:  Low Barriers for Isomerization in the S1 State of Hexadecaheptaene Ronald L. Christensen, Mary Grace I. Galinato, Emily F. Chu, Ritsuko Fujii, Hideki Hashimoto, and Harry A. Frank pp 1769–1775 DOI: 10.1021/ja0609607 Supporting Info

TiIV-Mediated Reactions between Primary Amines and Secondary Carboxamides:  Amidine Formation Versus Transamidation Denis A. Kissounko, Justin M. Hoerter, Ilia A. Guzei, Qiang Cui, Samuel H. Gellman, and Shannon S. Stahl pp 1776–1783 DOI: 10.1021/ja0650293 Supporting Info

Hyperpolarized 83Kr and 129Xe NMR Relaxation Measurements of Hydrated Surfaces:  Implications for Materials Science and Pulmonary Diagnostics Zackary I. Cleveland, Karl F. Stupic, Galina E. Pavlovskaya, John E. Repine, Jan B. Wooten, and Thomas Meersmann pp 1784–1792 DOI: 10.1021/ja065994t

Sequential Reduction of High Hydride Count Octahedral Rhodium Clusters [Rh6(PR3)6H12][BArF4]2:  Redox-Switchable Hydrogen Storage Simon K. Brayshaw, Andrew Harrison, J. Scott McIndoe, Frank Marken, Paul R. Raithby, John E. Warren, and Andrew S. Weller pp 1793–1804 DOI: 10.1021/ja066940m Supporting Info

Nitrogen-Rich Oligoacenes:  Candidates for n-Channel Organic Semiconductors Michael Winkler and K. N. Houk pp 1805–1815 DOI: 10.1021/ja067087u Supporting Info

The Enantiomeric Scaffold Approach to Highly Functionalized 1-Oxadecalines:  Enantio- and Regiocontrolled [4 + 2] Cycloadditions of 5-Alkenyl-η3-Pyranylmolybdenum Complexes Ramón Gómez Arrayás, Jingjun Yin, and Lanny S. Liebeskind pp 1816–1825 DOI: 10.1021/ja067104f Supporting Info

Oxygen as a Paramagnetic Probe of Clustering and Solvent Exposure in Folded and Unfolded States of an SH3 Domain Irina Bezsonova, Ferenc Evanics, Joseph A. Marsh, Julie D. Forman-Kay, and R. Scott Prosser pp 1826–1835 DOI: 10.1021/ja065173o Supporting Info

Biomimetic Synthesis of Antimalarial Naphthoquinones [J. Am. Chem. Soc. 2005, 127, 6276 6283] (Additions/Corrections) Jeremiah P. Malerich, Thomas J. Maimone, Gregory I. Elliott, and Dirk Trauner p 1836 DOI: 10.1021/ja069018l

Issue 07

Direct Electrochemistry of Tetraheme Cytochrome c554 from Nitrosomonas europaea:  Redox Cooperativity and Gating Gökçe Su Pulcu, Bradley L. Elmore, David M. Arciero, Alan B. Hooper, and Sean J. Elliott pp 1838–1839 DOI: 10.1021/ja065657k Supporting Info

Highly Luminescent Quantum-Dot Monoliths Indika U. Arachchige and Stephanie L. Brock pp 1840–1841 DOI: 10.1021/ja066749c Supporting Info

Design and Synthesis of a BODIPY-α-Tocopherol Adduct for Use as an Off/On Fluorescent Antioxidant Indicator Paul Oleynik, Yoshihiro Ishihara, and Gonzalo Cosa pp 1842–1843 DOI: 10.1021/ja066789g Supporting Info

Base Metal Catalyzed Dehydrogenation of Ammonia−Borane for Chemical Hydrogen Storage Richard J. Keaton, Johanna M. Blacquiere, and R. Tom Baker pp 1844–1845 DOI: 10.1021/ja066860i Supporting Info

Multiple Alignment of Membrane Proteins for Measuring Residual Dipolar Couplings Using Lanthanide Ions Bound to a Small Metal Chelator Douglas E. Kamen, Sean M. Cahill, and Mark E. Girvin pp 1846–1847 DOI: 10.1021/ja067089e Supporting Info

Interparticle Electromagnetic Coupling in Assembled Gold-Necklace Nanoparticles Guda Ramakrishna, Qiu Dai, Jianhua Zou, Qun Huo, and Theodore Goodson III pp 1848–1849 DOI: 10.1021/ja067123p Supporting Info

Photoswitchable Molecular Lock. One-Way Catenation of a Pt(II)-Linked Coordination Ring via the Photolabilization of a Pt(II)−Pyridine Bond Ken-ichi Yamashita, Masaki Kawano, and Makoto Fujita pp 1850–1851 DOI: 10.1021/ja067132y Supporting Info

Interstrand Cross-Links Generated by Abasic Sites in Duplex DNA Sanjay Dutta, Goutam Chowdhury, and Kent S. Gates pp 1852–1853 DOI: 10.1021/ja067294u Supporting Info

Indirect Electrochemical Sensing of DNA Hybridization Based on the Catalytic Oxidation of Cobalt (II) Di Xue, C. Michael Elliott, Ping Gong, David W. Grainger, Carlo A. Bignozzi, and Stefano Caramori pp 1854–1855 DOI: 10.1021/ja067339r Supporting Info

Highly Efficient G-Quadruplex Recognition by Bisquinolinium Compounds Anne De Cian, Elsa DeLemos, Jean-Louis Mergny, Marie-Paule Teulade-Fichou, and David Monchaud pp 1856–1857 DOI: 10.1021/ja067352b Supporting Info

Framework-Catenation Isomerism in Metal−Organic Frameworks and Its Impact on Hydrogen Uptake Shengqian Ma, Daofeng Sun, Michael Ambrogio, Jacqueline A. Fillinger, Sean Parkin, and Hong-Cai Zhou pp 1858–1859 DOI: 10.1021/ja067435s Supporting Info

Titanium-Catalyzed Dehydrocoupling of Silanes:  Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Si-H···Ti Interactions Michael D. Spencer, Quinetta D. Shelby, and Gregory S. Girolami pp 1860–1861 DOI: 10.1021/ja067503a Supporting Info

A Simple and Efficient Approach to a Printable Silver Conductor for Printed Electronics Yiliang Wu, Yuning Li, and Beng S. Ong pp 1862–1863 DOI: 10.1021/ja067596w Supporting Info

Synthesis of 2-Quinuclidonium by Eliminating Water:  Experimental Quantification of the High Basicity of Extremely Twisted Amides Tony Ly, Michael Krout, Don K. Pham, Kousuke Tani, Brian M. Stoltz, and Ryan R. Julian pp 1864–1865 DOI: 10.1021/ja067703m Supporting Info

Copper(II)-Catalyzed Aminohydroxylation of Olefins David J. Michaelis, Christopher J. Shaffer, and Tehshik P. Yoon pp 1866–1867 DOI: 10.1021/ja067894t Supporting Info

Ru-Catalyzed Asymmetric Hydrogenation of Racemic Aldehydes via Dynamic Kinetic Resolution:  Efficient Synthesis of Optically Active Primary Alcohols Jian-Hua Xie, Zhang-Tao Zhou, Wei-Ling Kong, and Qi-Lin Zhou pp 1868–1869 DOI: 10.1021/ja0680109 Supporting Info

Highly Soluble Tris-hydroxypyridonate Gd(III) Complexes with Increased Hydration Number, Fast Water Exchange, Slow Electronic Relaxation, and High Relaxivity1 Eric J. Werner, Stefano Avedano, Mauro Botta, Benjamin P. Hay, Evan G. Moore, Silvio Aime, and Kenneth N. Raymond pp 1870–1871 DOI: 10.1021/ja068026z Supporting Info

Chlorine Promotion of Styrene Epoxidation on Au(111) Dilini S. Pinnaduwage, Ling Zhou, Weiwei Gao, and Cynthia M. Friend pp 1872–1873 DOI: 10.1021/ja068245k Supporting Info

Pd-Catalyzed Borylative Cyclization of 1,6-Enynes Juan Marco-Martínez, Verónica López-Carrillo, Elena Buñuel, Raquel Simancas, and Diego J. Cárdenas pp 1874–1875 DOI: 10.1021/ja0685598 Supporting Info

Directly Observed Transmetalation from Boron to Rhodium. β-Aryl Elimination from Rh(I) Arylboronates and Diarylborinates Pinjing Zhao, Christopher D. Incarvito, and John F. Hartwig pp 1876–1877 DOI: 10.1021/ja068587q Supporting Info

Organocatalytic and Highly Stereoselective Direct Vinylogous Mannich Reaction Tian-Yu Liu, Hai-Lei Cui, Jun Long, Bang-Jing Li, Yong Wu, Li-Sheng Ding, and Ying-Chun Chen pp 1878–1879 DOI: 10.1021/ja068703p Supporting Info

Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes Gregory C. Welch and Douglas W. Stephan pp 1880–1881 DOI: 10.1021/ja067961j Supporting Info

High-Performance Transistor Based on Individual Single-Crystalline Micrometer Wire of Perylo[1,12-b,c,d]thiophene Yanming Sun, Lin Tan, Shidong Jiang, Hualei Qian, Zhaohui Wang, Dongwei Yan, Chongan Di, Ying Wang, Weiping Wu, Gui Yu, Shouke Yan, Chunru Wang, Wenping Hu, Yunqi Liu, and Daoben Zhu pp 1882–1883 DOI: 10.1021/ja068079g Supporting Info

Coupled Conformational Equilibria in β-Sheet Peptide−Dendron Conjugates Hui Shao, Jeffrey W. Lockman, and Jon R. Parquette pp 1884–1885 DOI: 10.1021/ja068154n Supporting Info

Conformational Control of Transmembrane Cl- Transport Paul V. Santacroce, Jeffery T. Davis, Mark E. Light, Philip A. Gale, José Carlos Iglesias-Sánchez, Pilar Prados, and Roberto Quesada pp 1886–1887 DOI: 10.1021/ja068067v Supporting Info

Electrochemical Approach for Constructing a Monolayer of Thiophenolates from Grafted Multilayers of Diaryl Disulfides Lasse T. Nielsen, Karina H. Vase, Mingdong Dong, Flemming Besenbacher, Steen U. Pedersen, and Kim Daasbjerg pp 1888–1889 DOI: 10.1021/ja0682430 Supporting Info

Tunable Electrochemical Switches Based on Ultrathin Organic Films Claire Fave, Yann Leroux, Gaelle Trippé, Hyacinte Randriamahazaka, Vincent Noel, and Jean-Christophe Lacroix pp 1890–1891 DOI: 10.1021/ja068143u Supporting Info

Acid-Induced Molecular Folding and Unfolding of N-Methyl Aromatic Amide Bearing 2,6-Disubstituted Pyridines Iwao Okamoto, Mayumi Nabeta, Yasuko Hayakawa, Nobuyoshi Morita, Tetsuya Takeya, Hyuma Masu, Isao Azumaya, and Osamu Tamura pp 1892–1893 DOI: 10.1021/ja0682879 Supporting Info

Biomarkers for Phenol Carcinogen Exposure Act as pH-Sensing Fluorescent Probes Kewen M. Sun, Christopher K. McLaughlin, Dean R. Lantero, and Richard A. Manderville pp 1894–1895 DOI: 10.1021/ja068416l Supporting Info

Converting Metals into Phosphides:  A General Strategy for the Synthesis of Metal Phosphide Nanocrystals Amanda E. Henkes, Yolanda Vasquez, and Raymond E. Schaak pp 1896–1897 DOI: 10.1021/ja068502l Supporting Info

Selective Aggregation of Single-Walled Carbon Nanotubes via Salt Addition Sandip Niyogi, Sofiane Boukhalfa, Satishkumar B. Chikkannanavar, Timothy J. McDonald, Michael J. Heben, and Stephen K. Doorn pp 1898–1899 DOI: 10.1021/ja068321j Supporting Info

Assembly and Stabilization of a Planar Tetracoordinated Carbon Radical CAl3Si:  A Way To Design Spin-Based Molecular Materials Li-ming Yang, Yi-hong Ding, and Chia-chung Sun pp 1900–1901 DOI: 10.1021/ja068334x Supporting Info

Reactions of a N-Acyliminium Ion Pool with Benzylsilanes. Implication of a Radical/Cation/Radical Cation Chain Mechanism Involving Oxidative C−Si Bond Cleavage Tomokazu Maruyama, Yusuke Mizuno, Ikuo Shimizu, Seiji Suga, and Jun-ichi Yoshida pp 1902–1903 DOI: 10.1021/ja068589a Supporting Info

Mask-Directed Multiphoton Lithography Bryan Kaehr and Jason B. Shear pp 1904–1905 DOI: 10.1021/ja068390y Supporting Info

Total Syntheses of Ipomoeassin B and E Alois Fürstner and Takashi Nagano pp 1906–1907 DOI: 10.1021/ja068901g Supporting Info

A Room Temperature Negishi Cross-Coupling Approach to C-Alkyl Glycosides Hegui Gong, Riccardo Sinisi, and Michel R. Gagné pp 1908–1909 DOI: 10.1021/ja068950t Supporting Info

Modular Polyketide Synthases and cis Double Bond Formation:  Establishment of Activated cis-3-Cyclohexylpropenoic Acid as the Diketide Intermediate in Phoslactomycin Biosynthesis Mamoun M. Alhamadsheh, Nadaraj Palaniappan, Suparna DasChouduri, and Kevin A. Reynolds pp 1910–1911 DOI: 10.1021/ja068818t Supporting Info

Crystal Chemistry and Electronic Structure of the Metallic Lithium Ion Conductor, LiNiN Zlatka Stoeva, Bernd Jäger, Ruben Gomez, Sabri Messaoudi, Mouna Ben Yahia, Xavier Rocquefelte, Gary B. Hix, Walter Wolf, Jeremy J. Titman, Régis Gautier, Peter Herzig, and Duncan H. Gregory pp 1912–1920 DOI: 10.1021/ja063208e Supporting Info

An Aluminum Ate Base:  Its Design, Structure, Function, and Reaction Mechanism Hiroshi Naka, Masanobu Uchiyama, Yotaro Matsumoto, Andrew E. H. Wheatley, Mary McPartlin, James V. Morey, and Yoshinori Kondo pp 1921–1930 DOI: 10.1021/ja064601n Supporting Info

Redox-Switched Complexation/Decomplexation of K+ and Cs+ by Molecular Cyanometalate Boxes Julie L. Boyer, Maya Ramesh, Haijun Yao, Thomas B. Rauchfuss, and Scott R. Wilson pp 1931–1936 DOI: 10.1021/ja0646545 Supporting Info

Donor−Acceptor Biradicals as Ground State Analogues of Photoinduced Charge Separated States Martin L. Kirk, David A. Shultz, Ezra C. Depperman, and Candice L. Brannen pp 1937–1943 DOI: 10.1021/ja065384t

Spectroscopic and Electronic Structure Study of the Enzyme−Substrate Complex of Intradiol Dioxygenases:  Substrate Activation by a High-Spin Ferric Non-heme Iron Site Monita Y. M. Pau, Mindy I. Davis, Allen M. Orville, John D. Lipscomb, and Edward I. Solomon pp 1944–1958 DOI: 10.1021/ja065671x Supporting Info

DNA-Encoded Antibody Libraries:  A Unified Platform for Multiplexed Cell Sorting and Detection of Genes and Proteins Ryan C. Bailey, Gabriel A. Kwong, Caius G. Radu, Owen N. Witte, and James R. Heath pp 1959–1967 DOI: 10.1021/ja065930i Supporting Info

Structure and Dynamics of Surfactin Studied by NMR in Micellar Media Pascale Tsan, Laurent Volpon, Françoise Besson, and Jean-Marc Lancelin pp 1968–1977 DOI: 10.1021/ja066117q Supporting Info

Synthesis of an Optically Active Al(salalen) Complex and Its Application to Catalytic Hydrophosphonylation of Aldehydes and Aldimines Bunnai Saito, Hiromichi Egami, and Tsutomu Katsuki pp 1978–1986 DOI: 10.1021/ja0651005 Supporting Info

CH Activation Reactions of Ruthenium N-Heterocyclic Carbene Complexes:  Application in a Catalytic Tandem Reaction Involving CC Bond Formation from Alcohols Suzanne Burling, Belinda M. Paine, Devendrababu Nama, Victoria S. Brown, Mary F. Mahon, Timothy J. Prior, Paul S. Pregosin, Michael K. Whittlesey, and Jonathan M. J. Williams pp 1987–1995 DOI: 10.1021/ja065790c Supporting Info

Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Pyrrolidines from 2,3-Aziridin-1-ols Using a Sulfoxonium Ylide:  A One-Carbon Homologative Relay Ring Expansion Jennifer M. Schomaker, Somnath Bhattacharjee, Jun Yan, and Babak Borhan pp 1996–2003 DOI: 10.1021/ja065833p Supporting Info

Four-Stranded DNA Structures Can Be Stabilized by Two Different Types of Minor Groove G:C:G:C Tetrads Núria Escaja, Irene Gómez-Pinto, Enrique Pedroso, and Carlos González pp 2004–2014 DOI: 10.1021/ja066172z Supporting Info

Dissecting the Thermodynamics and Cooperativity of Ligand Binding in Cytochrome P450eryF B. K. Muralidhara, Surendra S. Negi, and James R. Halpert pp 2015–2024 DOI: 10.1021/ja066303w Supporting Info

Fluorescent DNA Nanotags:  Supramolecular Fluorescent Labels Based on Intercalating Dye Arrays Assembled on Nanostructured DNA Templates Andrea L. Benvin, Yehuda Creeger, Gregory W. Fisher, Byron Ballou, Alan S. Waggoner, and Bruce A. Armitage pp 2025–2034 DOI: 10.1021/ja066354t Supporting Info

Isolation and Structural Characterization of a Family of Endohedral Fullerenes Including the Large, Chiral Cage Fullerenes Tb3N@C88 and Tb3N@C86 as well as the Ih and D5h Isomers of Tb3N@C80 Tianming Zuo, Christine M. Beavers, James C. Duchamp, Anne Campbell, Harry C. Dorn, Marilyn M. Olmstead, and Alan L. Balch pp 2035–2043 DOI: 10.1021/ja066437+ Supporting Info

Fluorescent Pyrimidine Ribonucleotide:  Synthesis, Enzymatic Incorporation, and Utilization Seergazhi G. Srivatsan and Yitzhak Tor pp 2044–2053 DOI: 10.1021/ja066455r Supporting Info

Radiationless Decay of Red Fluorescent Protein Chromophore Models via Twisted Intramolecular Charge-Transfer States Seth Olsen and Sean C. Smith pp 2054–2065 DOI: 10.1021/ja066430s Supporting Info

Preparation of Metal−TCNQ Charge-Transfer Complexes on Conducting and Insulating Surfaces by Photocrystallization Anthony P. O'Mullane, Nigel Fay, Ayman Nafady, and Alan M. Bond pp 2066–2073 DOI: 10.1021/ja066874o Supporting Info

Chemical and Electrochemical Oxidation of C8-Arylamine Adducts of 2‘-Deoxyguanosine James S. Stover, Madalina Ciobanu, David E. Cliffel, and Carmelo J. Rizzo pp 2074–2081 DOI: 10.1021/ja066404u Supporting Info

Scope and Mechanism of the Intermolecular Addition of Aromatic Aldehydes to Olefins Catalyzed by Rh(I) Olefin Complexes Amy H. Roy, Christian P. Lenges, and Maurice Brookhart pp 2082–2093 DOI: 10.1021/ja066509x Supporting Info

Characterization and Control of Lipid Layer Fluidity in Hybrid Bilayer Membranes Neil A. Anderson, Lee J. Richter, John C. Stephenson, and Kimberly A. Briggman pp 2094–2100 DOI: 10.1021/ja066588c

Depurinating Acylfulvene−DNA Adducts:  Characterizing Cellular Chemical Reactions of a Selective Antitumor Agent Jiachang Gong, V. G. Vaidyanathan, Xiang Yu, Thomas W. Kensler, Lisa A. Peterson, and Shana J. Sturla pp 2101–2111 DOI: 10.1021/ja0665951 Supporting Info

Origin of Diastereoselectivity in the Tandem Oxy-Cope/Claisen/Ene Reaction:  Experimental and Theoretical Studies of the Ring Inversion Mechanism Effiette L. O. Sauer, James Hooper, Tom Woo, and Louis Barriault pp 2112–2119 DOI: 10.1021/ja066830f Supporting Info

Coordination-Driven Self-Assembly of Metallodendrimers Possessing Well-Defined and Controllable Cavities as Cores Hai-Bo Yang, Adam M. Hawkridge, Songping D. Huang, Neeladri Das, Scott D. Bunge, David C. Muddiman, and Peter J. Stang pp 2120–2129 DOI: 10.1021/ja066804h Supporting Info

Chiral Phosphine−Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions Wei-Liang Duan, Hiroshi Iwamura, Ryo Shintani, and Tamio Hayashi pp 2130–2138 DOI: 10.1021/ja0671013 Supporting Info

Nanoshell Magnetic Resonance Imaging Contrast Agents Chia-Hao Su, Hwo-Shuenn Sheu, Chia-Yun Lin, Chih-Chia Huang, Yi-Wei Lo, Ying-Chih Pu, Jun-Cheng Weng, Dar-Bin Shieh, Jyh-Horng Chen, and Chen-Sheng Yeh pp 2139–2146 DOI: 10.1021/ja0672066 Supporting Info

Ultrafast Structural Rearrangements in the MLCT Excited State for Copper(I) bis-Phenanthrolines in Solution George B. Shaw, Christian D. Grant, Hideaki Shirota, Edward W. CastnerJr., Gerald J. Meyer, and Lin X. Chen pp 2147–2160 DOI: 10.1021/ja067271f

Array of Molecularly Mediated Thin Film Assemblies of Nanoparticles:  Correlation of Vapor Sensing with Interparticle Spatial Properties Lingyan Wang,Lingyan Wang, Xiajing Shi, Nancy N. Kariuki, Mark Schadt, Guannan Roger Wang, Qiang Rendeng, Jeongku Choi, Jin Luo, Susan Lu, and Chuan-Jian Zhong pp 2161–2170 DOI: 10.1021/ja0673074 Supporting Info

Dimetalloendofullerene U2@C60 Has a U−U Multiple Bond Consisting of Sixfold One-Electron-Two-Center Bonds Xin Wu and Xin Lu pp 2171–2177 DOI: 10.1021/ja067281g Supporting Info

Synchronous Photoinitiation of Endothelial NO Synthase Activity by a Nanotrigger Targeted at Its NADPH Site Edward Beaumont, Jean-Christophe Lambry, Clément Gautier, Anne-Claire Robin, Said Gmouh, Vladimir Berka, Ah-Lim Tsai, Mireille Blanchard-Desce, and Anny Slama-Schwok pp 2178–2186 DOI: 10.1021/ja067543e Supporting Info

Fluorescent Biomembrane Probe for Ratiometric Detection of Apoptosis Vasyl V. Shynkar, Andrey S. Klymchenko, Corinne Kunzelmann, Guy Duportail, Christian D. Muller, Alexander P. Demchenko, Jean-Marie Freyssinet, and Yves Mely pp 2187–2193 DOI: 10.1021/ja068008h

First Catalytic Reductive Coupling of 1,3-Diynes to Carbonyl Partners:  A New Regio- and Enantioselective C−C Bond Forming Hydrogenation [J. Am. Chem. Soc. 2003, 125, 11488−11489]. Ryan R. Huddleston, Hye-Young Jang, and Michael J. Krische p 2194 DOI: 10.1021/ja070167t

Encyclopedia of Electrochemistry, Volume 7b:  Inorganic Electrochemistry Edited by Fritz Scholz (Universität Greifswald, Germany) and Christopher J. Pickett (John Innes Centre, Norwich, UK). Series Edited by Alan J. Bard (University of Texas) and Martin Stratmann (Max-Planck-Institut, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. x + 527 pp. $440.00. ISBN 3-527-31700-7. Karen J. Brewer p 2195 DOI: 10.1021/ja069798y

Esterification of Polysaccharides By Thomas Heinze, Tim Liebert, and Andreas Koschella (Friedrich-Schiller-Universität Jena, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xvi + 232 pp. $64.95. ISBN 3-540-32103-9. T. Bruce Grindley pp 2195–2196 DOI: 10.1021/ja069801d

HPLC Made to Measure:  A Practical Handbook for Optimization Edited by Stavros Kromidas (Saarbrucken, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, 2006. xxxiv + 754 pp. $150.00. ISBN 3-527-31377-X. David K. Ryan p 2196 DOI: 10.1021/ja0698073

Metal Catalyzed Cascade Reactions. Topics in Organometallic Chemistry, 19 Edited by T. J. J. Müller (Universität Heidelberg). Springer:  Berlin, Heidelberg, New York. 2006. x + 340 pp. $199.00. ISBN 3-540-32958-7. Michael A. Tarselli and Michel R. Gagné pp 2196–2197 DOI: 10.1021/ja069819o

The Merck Index:  An Encyclopedia of Chemicals, Drugs, and Biologicals, 14th ed. Edited by Maryadele J. O'Neil (Editor), Patricia E. Heckelman (Senior Associate Editor), Cherie B. Koch (Associate Editor), and Kristin J. Roman (Assistant Editor). Merck and Co., Inc.:  Whitehouse Station, NJ. 2006. 2564 pp. $125.00. ISBN 0-911910-00-X. p 2197 DOI: 10.1021/ja069838y

Recent Advances in Actinide Science Edited by Rebeca Alvarez, Nicholas D. Bryan, and Iain May (The University of Manchester, UK). Royal Society of Chemistry:  Cambridge. 2006. XXVI + 810 pp. $249.00. ISBN 0-85404-678-X. p 2197 DOI: 10.1021/ja069839q

Surface-Enhanced Raman Scattering:  Physics and Applications Edited by Katrin Kneipp (Harvard University Medical School, Boston), Martin Moskovits (University of California, Santa Barbara), and Harald Kneipp (Harvard University Medical School). Springer:  Berlin, Heidelberg, New York. 2006. xviii + 464 pp. $219.00. ISBN 3-540-33566-8. Christy L. Haynes pp 2197–2198 DOI: 10.1021/ja069825k

Issue 08

Interplay of Structure and Vibrational Dynamics in Six-Coordinate Heme Nitrosyls Nathan J. Silvernail, Alexander Barabanschikov, Jeffrey W. Pavlik, Bruce C. Noll, Jiyong Zhao, E. Ercan Alp, Wolfgang Sturhahn, J. Timothy Sage, and W. Robert Scheidt pp 2200–2201 DOI: 10.1021/ja066869k Supporting Info

Collagen-Related Peptides:  Self-Assembly of Short, Single Strands into a Functional Biomaterial of Micrometer Scale Mabel A. Cejas, William A. Kinney, Cailin Chen, Gregory C. Leo, Brett A. Tounge, Jeremy G. Vinter, Pratik P. Joshi, and Bruce E. Maryanoff pp 2202–2203 DOI: 10.1021/ja066986f Supporting Info

Reversible, Erasable, and Rewritable Nanorecording on an H2 Rotaxane Thin Film Min Feng, Li Gao, Zhitao Deng, Wei Ji, Xuefeng Guo, Shixuan Du, Dongxia Shi, Deqing Zhang, Daoben Zhu, and Hongjun Gao pp 2204–2205 DOI: 10.1021/ja067037p

Synthesis of a Ring-Expanded Bryostatin Analogue Barry M. Trost, Hanbiao Yang, Oliver R. Thiel, Alison J. Frontier, and Cheyenne S. Brindle pp 2206–2207 DOI: 10.1021/ja067305j Supporting Info

Discrete Thermal Patterns of Hydrogen and Deuterium Molecules Enclathrated in Confined Hydrate Cages Yong Nam Choi, Sun-Hwa Yeon, Youngjune Park, Sukjeong Choi, and Huen Lee pp 2208–2209 DOI: 10.1021/ja0674441 Supporting Info

Assignment of Individual Metal Redox States in a Metalloprotein by Crystallographic Refinement at Multiple X-ray Wavelengths Oliver Einsle, Susana L. A. Andrade, Holger Dobbek, Jacques Meyer, and Douglas C. Rees pp 2210–2211 DOI: 10.1021/ja067562o Supporting Info

On the Substrate Specificity of Dehydration by Lacticin 481 Synthetase Xingang Zhang and Wilfred A. van der Donk pp 2212–2213 DOI: 10.1021/ja067672v Supporting Info

Catalytic Conjugate Addition of Allyl Groups to Styryl-Activated Enones Joshua D. Sieber, Shubin Liu, and James P. Morken pp 2214–2215 DOI: 10.1021/ja067878w Supporting Info

Fluorescent Sequence-Specific dsDNA Binding Oligomers David M. Chenoweth, Anne Viger, and Peter B. Dervan pp 2216–2217 DOI: 10.1021/ja0682576 Supporting Info

Paramagnetic Ions Provide Structural Restraints in Solid-State NMR of Proteins Stéphane Balayssac, Ivano Bertini, Moreno Lelli, Claudio Luchinat, and Massimiliano Maletta pp 2218–2219 DOI: 10.1021/ja068105a Supporting Info

Evidence for Water Rings in the Hexahydrated Sulfate Dianion from IR Spectroscopy Matthew F. Bush, Richard J. Saykally, and Evan R. Williams pp 2220–2221 DOI: 10.1021/ja068357b Supporting Info

Ab Initio Calculation of Isotopic Fractionation in B(OH)3(aq) and BOH4-(aq) James R. Rustad and Eric J. Bylaska pp 2222–2223 DOI: 10.1021/ja0683335 Supporting Info

Facile Synthesis of Highly π-Extended Heteroarenes, Dinaphtho[2,3-b:2‘,3‘-f]chalcogenopheno[3,2-b]chalcogenophenes, and Their Application to Field-Effect Transistors Tatsuya Yamamoto and Kazuo Takimiya pp 2224–2225 DOI: 10.1021/ja068429z Supporting Info

Forward and Reverse Electron Transfer with the Y356DOPA-β2 Heterodimer of E. coli Ribonucleotide Reductase Mohammad R. Seyedsayamdost and JoAnne Stubbe pp 2226–2227 DOI: 10.1021/ja0685607 Supporting Info

Predicted Oxidation of CO Catalyzed by Au Nanoclusters on a Thin Defect-Free MgO Film Supported on a Mo(100) Surface Chun Zhang, Bokwon Yoon, and Uzi Landman pp 2228–2229 DOI: 10.1021/ja0684545 Supporting Info

Synthesis of Acyclic α,β-Unsaturated Ketones via Pd(II)-Catalyzed Intermolecular Reaction of Alkynamides and Alkenes Norie Momiyama, Matthew W. Kanan, and David R. Liu pp 2230–2231 DOI: 10.1021/ja068886f Supporting Info

Balance of Structure−Building Forces in Selenium-Based Self-Assembled Monolayers Andrey Shaporenko, Jan Müller, Tobias Weidner, Andreas Terfort, and Michael Zharnikov pp 2232–2233 DOI: 10.1021/ja068916e Supporting Info

Snapshots of an Alkylidyne for Nitride Triple-Bond Metathesis Brad C. Bailey, Alison R. Fout, Hongjun Fan, John Tomaszewski, John C. Huffman, J. Brannon Gary, Marc J. A. Johnson, and Daniel J. Mindiola pp 2234–2235 DOI: 10.1021/ja0689684 Supporting Info

Highly Active Half-Metallocene Chromium(III) Catalysts for Ethylene Polymerization Activated by Trialkylaluminum Tieqi Xu, Ying Mu, Wei Gao, Jianguo Ni, Ling Ye, and Yanchun Tao pp 2236–2237 DOI: 10.1021/ja0671363 Supporting Info

4,5-Dicyano-1H-[1,2,3]-Triazole as a Proton Transport Facilitator for Polymer Electrolyte Membrane Fuel Cells Ram Subbaraman, Hossein Ghassemi, and Thomas A. Zawodzinski Jr. pp 2238–2239 DOI: 10.1021/ja067332+ Supporting Info

Activation of Oxygen by Metallic Gold in Au/TiO2 Catalysts Norbert Weiher, Angela M. Beesley, Nikolaos Tsapatsaris, Laurent Delannoy, Catherine Louis, Jeroen A. van Bokhoven, and Sven L. M. Schroeder pp 2240–2241 DOI: 10.1021/ja067316c Supporting Info

Sonochemical Synthesis of Nanosized Hollow Hematite Jin Ho Bang and Kenneth S. Suslick pp 2242–2243 DOI: 10.1021/ja0676657 Supporting Info

Probing the Reversibility of Sidewall Functionalization Using Carbon Nanotube Transistors Janie Cabana and Richard Martel pp 2244–2245 DOI: 10.1021/ja068320r Supporting Info

Electrochemical Generation of Cationic Pd Catalysts and Application to Pd/TEMPO Double-Mediatory Electrooxidative Wacker-Type Reactions Koichi Mitsudo, Takashi Kaide, Eriko Nakamoto, Kenta Yoshida, and Hideo Tanaka pp 2246–2247 DOI: 10.1021/ja069043r Supporting Info

Asymmetric Reductive Coupling of Dienes and Aldehydes Catalyzed by Nickel Complexes of Spiro Phosphoramidites:  Highly Enantioselective Synthesis of Chiral Bishomoallylic Alcohols Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, and Qi-Lin Zhou pp 2248–2249 DOI: 10.1021/ja0693183 Supporting Info

Acoustic Emission Spectra from 515 kHz Cavitation in Aqueous Solutions Containing Surface-Active Solutes Muthupandian Ashokkumar, Mark Hodnett, Bajram Zeqiri, Franz Grieser, and Gareth J. Price pp 2250–2258 DOI: 10.1021/ja067960r

n-Butyllithium/N,N,N‘,N‘-Tetramethylethylenediamine-Mediated Ortholithiations of Aryl Oxazolines:  Substrate-Dependent Mechanisms Scott T. Chadwick, Antonio Ramirez, Lekha Gupta, and David B. Collum pp 2259–2268 DOI: 10.1021/ja068057u Supporting Info

Asymmetric Total Syntheses of (+)-3-(Z)-Laureatin and (+)-3-(Z)-Isolaureatin by “Lone Pair−Lone Pair Interaction-Controlled” Isomerization Hyoungsu Kim, Hyunjoo Lee, Dongjoo Lee, Sanghee Kim, and Deukjoon Kim pp 2269–2274 DOI: 10.1021/ja068346i Supporting Info

Modeling the 2-His-1-Carboxylate Facial Triad:  Iron−Catecholato Complexes as Structural and Functional Models of the Extradiol Cleaving Dioxygenases Pieter C. A. Bruijnincx, Martin Lutz, Anthony L. Spek, Wilfred R. Hagen, Bert M. Weckhuysen, Gerard van Koten, and Robertus J. M. Klein Gebbink pp 2275–2286 DOI: 10.1021/ja064816x Supporting Info

Conductivity in Alkylamine/Gold and Alkanethiol/Gold Molecular Junctions Measured in Molecule/Nanoparticle/Molecule Bridges and Conducting Probe Structures Changwoong Chu, Jeong-Seok Na, and Gregory N. Parsons pp 2287–2296 DOI: 10.1021/ja064968s

IR Spectroscopy of Nb+(N2)n Complexes:  Coordination, Structures, and Spin States E. Dinesh Pillai, Todd D. Jaeger, and Michael A. Duncan pp 2297–2307 DOI: 10.1021/ja0661008 Supporting Info

Triplet 1,3-Diphenylpropynylidene (Ph−C−C−C−Ph) Jeffrey T. DePinto, Wendy A. deProphetis, Jessica L. Menke, and Robert J. McMahon pp 2308–2315 DOI: 10.1021/ja066300j Supporting Info

Sulfur K-Edge X-ray Absorption Spectroscopy as a Probe of Ligand−Metal Bond Covalency:  Metal vs Ligand Oxidation in Copper and Nickel Dithiolene Complexes Ritimukta Sarangi, Serena DeBeer George, Deanne Jackson Rudd, Robert K. Szilagyi, Xavi Ribas, Concepció Rovira, Manuel Almeida, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 2316–2326 DOI: 10.1021/ja0665949 Supporting Info

Self-Assembled Architectures from Biohybrid Triblock Copolymers Irene C. Reynhout, Jeroen J. L. M. Cornelissen, and Roeland J. M. Nolte pp 2327–2332 DOI: 10.1021/ja066790f Supporting Info

Top-Down Solid-Phase Fabrication of Nanoporous Cadmium Oxide Architectures Haidong Yu, Deshen Wang, and Ming-Yong Han pp 2333–2337 DOI: 10.1021/ja066884p Supporting Info

Filamentous Phage Studied by Magic-Angle Spinning NMR:  Resonance Assignment and Secondary Structure of the Coat Protein in Pf1 Amir Goldbourt, Benjamin J. Gross, Loren A. Day, and Ann E. McDermott pp 2338–2344 DOI: 10.1021/ja066928u Supporting Info

Glycosidase Inhibition:  An Assessment of the Binding of 18 Putative Transition-State Mimics Tracey M. Gloster, Peter Meloncelli, Robert V. Stick, David Zechel, Andrea Vasella, and Gideon J. Davies pp 2345–2354 DOI: 10.1021/ja066961g Supporting Info

Effects of Gas Molecules on Nanofluidic Behaviors Yu Qiao, Guoxin Cao, and Xi Chen pp 2355–2359 DOI: 10.1021/ja067185f

Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2−) and the Significantly Stronger Coupling Chloranilate(•3−) Radical Trianion Kil Sik Min, Antonio G. DiPasquale, James A. Golen, Arnold L. Rheingold, and Joel S. Miller pp 2360–2368 DOI: 10.1021/ja067208q Supporting Info

Tuning the Electrocrystallization Parameters of Semiconducting Co[TCNQ]2-Based Materials To Yield either Single Nanowires or Crystalline Thin Films Ayman Nafady, Alan M. Bond, Alexander Bilyk, Alexander R. Harris, Anand I. Bhatt, Anthony P. O'Mullane, and Roland De Marco pp 2369–2382 DOI: 10.1021/ja067219j Supporting Info

Structure Determination of Triplet Diphenylcarbenes by in Situ X-ray Crystallographic Analysis Masaki Kawano, Katsuyuki Hirai, Hideo Tomioka, and Yuji Ohashi pp 2383–2391 DOI: 10.1021/ja067306b Supporting Info

Reversible Switching of the Sol−Gel Transition with Ultrasound in Rhodium(I) and Iridium(I) Coordination Networks Jos M. J. Paulusse, D. J. M. van Beek, and Rint P. Sijbesma pp 2392–2397 DOI: 10.1021/ja067523c Supporting Info

Probing Hydrogen Bonding and Ion−Carbonyl Interactions by Solid-State 17O NMR Spectroscopy:  G-Ribbon and G-Quartet Irene C. M. Kwan, Xin Mo, and Gang Wu pp 2398–2407 DOI: 10.1021/ja067991m Supporting Info

Wheel-Shaped Polyoxotungstate [Cu20Cl(OH)24(H2O)12-(P8W48O184)]25- Macroanions Form Supramolecular “Blackberry” Structure in Aqueous Solution [J. Am. Chem. Soc. 2006, 128, 10103−10110]. Guang Liu, Tianbo Liu, Sib Sankar Mal, and Ulrich Kortz p 2408 DOI: 10.1021/ja069317a

Issue 09

Catalytic Asymmetric Rearrangement of α,α-Disubstituted α-Siloxy Aldehydes to Optically Active Acyloins Using Axially Chiral Organoaluminum Lewis Acids Takashi Ooi, Kohsuke Ohmatsu, and Keiji Maruoka pp 2410–2411 DOI: 10.1021/ja063051q Supporting Info

Etching Colloidal Gold Nanocrystals with Hyperbranched and Multivalent Polymers:  A New Route to Fluorescent and Water-Soluble Atomic Clusters Hongwei Duan and Shuming Nie pp 2412–2413 DOI: 10.1021/ja067727t Supporting Info

Slow Conformational Dynamics and Unfolding of the Calmodulin C-Terminal Domain Yng-Gwei Chen and Gerhard Hummer pp 2414–2415 DOI: 10.1021/ja067791a Supporting Info

Transition of Ionic Liquid [bmim][PF6] from Liquid to High-Melting-Point Crystal When Confined in Multiwalled Carbon Nanotubes Shimou Chen, Guozhong Wu, Maolin Sha, and Shirong Huang pp 2416–2417 DOI: 10.1021/ja067972c Supporting Info

Enhanced Sensitized NIR Luminescence from Gold Nanoparticles via Energy Transfer from Surface-Bound Fluorophores Marco Montalti, Nelsi Zaccheroni, Luca Prodi, Niamh O'Reilly, and Stuart L. James pp 2418–2419 DOI: 10.1021/ja068095d Supporting Info

Heterogeneously Catalyzed Living Cationic Polymerization of Isobutyl Vinyl Ether Using Iron(III) Oxide Arihiro Kanazawa, Shokyoku Kanaoka, and Sadahito Aoshima pp 2420–2421 DOI: 10.1021/ja068124k Supporting Info

Dynamic Recompartmentalization of Supported Lipid Bilayers Using Focused Femtosecond Laser Pulses Andreia M. Smith, Thomas Huser, and Atul N. Parikh pp 2422–2423 DOI: 10.1021/ja065626p Supporting Info

Formation of a Cobalt(III) Imido from a Cobalt(II) Amido Complex. Evidence for Proton-Coupled Electron Transfer Ryan E. Cowley, Ranko P. Bontchev, John Sorrell, Orcino Sarracino, Yanhua Feng, Haobin Wang, and Jeremy M. Smith pp 2424–2425 DOI: 10.1021/ja066899n Supporting Info

Design, Synthesis, and Characterization of Binuclear Ni(II) Complexes with Inherent Helical Chirality Vadim A. Soloshonok and Hisanori Ueki pp 2426–2427 DOI: 10.1021/ja0671215 Supporting Info

A Dramatic Effect of Lewis-Acid Catalysts on Nickel-Catalyzed Carbocyanation of Alkynes Yoshiaki Nakao, Akira Yada, Shiro Ebata, and Tamejiro Hiyama pp 2428–2429 DOI: 10.1021/ja067364x Supporting Info

Gd-Loaded Liposomes as T1, Susceptibility, and CEST Agents, All in One Silvio Aime, Daniela Delli Castelli, Dale Lawson, and Enzo Terreno pp 2430–2431 DOI: 10.1021/ja0677867

Isotropic Bicelles Stabilize the Functional Form of a Small Multidrug-Resistance Pump for NMR Structural Studies Sébastien F. Poget, Sean M. Cahill, and Mark E. Girvin pp 2432–2433 DOI: 10.1021/ja0679836 Supporting Info

Synthetic Macrolides that Inhibit Breast Cancer Cell Migration in Vitro Belhu B. Metaferia, Lin Chen, Heather L. Baker, Xin-Yun Huang, and Carole A. Bewley pp 2434–2435 DOI: 10.1021/ja068538d Supporting Info

Interplay of EnE‘3-nC Valence Isomers (E, E‘ = Si, Ge):  Bicyclo[1.1.0]butanes with Very Short Bridging Bonds and Their Isomerization to Alkyl-Substituted Cyclopropenes Vladimir Ya. Lee, Hiroyuki Yasuda, and Akira Sekiguchi pp 2436–2437 DOI: 10.1021/ja068229n Supporting Info

Spirodiepoxide Reaction with Cuprates Partha Ghosh, Stephen D. Lotesta, and Lawrence J. Williams pp 2438–2439 DOI: 10.1021/ja068813w Supporting Info

Self-Assembly and Self-Metallization of Porphyrin Nanosheets Zhongchun Wang, Zhiyong Li, Craig J. Medforth, and John A. Shelnutt pp 2440–2441 DOI: 10.1021/ja068250o Supporting Info

Luminescence from Neptunyl(VI) Species in Solution Catherine Talbot-Eeckelaers, Simon J. A. Pope, Amanda J. Hynes, Roy Copping, Chris J. Jones, Robin J. Taylor, Stephen Faulkner, Daniel Sykes, Francis R. Livens, and Iain May pp 2442–2443 DOI: 10.1021/ja068522n Supporting Info

Critical Importance of Length-Scale Dependence in Implicit Modeling of Hydrophobic Interactions Jianhan Chen and Charles L. Brooks III pp 2444–2445 DOI: 10.1021/ja068383+ Supporting Info

Electrochemical Oxidation of Water by an Adsorbed μ-Oxo-Bridged Ru Complex Feng Liu, Thomas Cardolaccia, Brooks J. Hornstein, Jon R. Schoonover, and Thomas J. Meyer pp 2446–2447 DOI: 10.1021/ja068630+ Supporting Info

Noncovalent Functionalization of Carbon Nanotubes by Fluorescein−Polyethylene Glycol:  Supramolecular Conjugates with pH-Dependent Absorbance and Fluorescence Nozomi Nakayama-Ratchford, Sarunya Bangsaruntip, Xiaoming Sun, Kevin Welsher, and Hongjie Dai pp 2448–2449 DOI: 10.1021/ja068684j Supporting Info

Rectangular Nanostructuring of Au(111) Surfaces by Self-Assembly of Size-Selected Thiacrown Ether Macrocycles Aymeric Nion, Peng Jiang, Alexandre Popoff, and Denis Fichou pp 2450–2451 DOI: 10.1021/ja068709e Supporting Info

Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes Rebecca L. LaLonde, Benjamin D. Sherry, Eun Joo Kang, and F. Dean Toste pp 2452–2453 DOI: 10.1021/ja068819l Supporting Info

Facile Activation of Hydrogen by an Unsaturated Platinum−Osmium Cluster Complex Richard D. Adams, Burjor Captain, and Lei Zhu pp 2454–2455 DOI: 10.1021/ja0688272 Supporting Info

Reactivation of the p53 Tumor Suppressor Pathway by a Stapled p53 Peptide Federico Bernal, Andrew F. Tyler, Stanley J. Korsmeyer, Loren D. Walensky, and Gregory L. Verdine pp 2456–2457 DOI: 10.1021/ja0693587 Supporting Info

Thermodynamic Stability of Boron:  The Role of Defects and Zero Point Motion Michiel J. van Setten, Matthé A. Uijttewaal, Gilles A. de Wijs, and Robert A. de Groot pp 2458–2465 DOI: 10.1021/ja0631246 Supporting Info

Exploring the Subtleties of Drug−Receptor Interactions:  The Case of Matrix Metalloproteinases Ivano Bertini, Vito Calderone, Marco Fragai, Andrea Giachetti, Mauro Loconte, Claudio Luchinat, Massimiliano Maletta, Cristina Nativi, and Kwon Joo Yeo pp 2466–2475 DOI: 10.1021/ja065156z Supporting Info

Energy-Resolved Collision-Induced Dissociation Cross Sections of 2:1 Bis-oxazoline Copper Complexes. Nonbonded Interactions and Nonlinear Effects Eva Zocher, Rolf Dietiker, and Peter Chen pp 2476–2481 DOI: 10.1021/ja065390p Supporting Info

Reactive Nature of Dopamine as a Surface Functionalization Agent in Iron Oxide Nanoparticles Michael D. Shultz, J. Ulises Reveles, Shiv N. Khanna, and Everett E. Carpenter pp 2482–2487 DOI: 10.1021/ja0651963 Supporting Info

Effect of Deuterium on the Kinetics of 1,5-Hydrogen Shifts:  5-Dideuteriomethylene-2,4,6,7,9-pentamethyl-11,11a- dihydro-12H-naphthacene William von E. Doering and Edmund J. Keliher pp 2488–2495 DOI: 10.1021/ja066018c Supporting Info

Surface Chemistry of Aerosolized Silicon Nanoparticles:  Evolution and Desorption of Hydrogen from 6-nm Diameter Particles Jason Holm and Jeffrey T. Roberts pp 2496–2503 DOI: 10.1021/ja0658970

Effect of Field Direction on Electrowetting in a Nanopore Dusan Bratko, Christopher D. Daub, Kevin Leung, and Alenka Luzar pp 2504–2510 DOI: 10.1021/ja0659370 Supporting Info

Hierarchical Chiral Framework Based on a Rigid Adamantane Tripod on Au(111) Satoshi Katano, Yousoo Kim, Hiroaki Matsubara, Toshikazu Kitagawa, and Maki Kawai pp 2511–2515 DOI: 10.1021/ja065893v

Hydrogen-Induced Transition from Dissociative to Molecular Chemisorption of CO on Vanadium Clusters Ingmar Swart, André Fielicke, Britta Redlich, Gerard Meijer, Bert M. Weckhuysen, and Frank M. F. de Groot pp 2516–2520 DOI: 10.1021/ja066261b Supporting Info

“Amide Resonance” Correlates with a Breadth of C−N Rotation Barriers Carl R. Kemnitz and Mark J. Loewen pp 2521–2528 DOI: 10.1021/ja0663024 Supporting Info

Reactions of Monomeric [1,2,4-(Me3C)3C5H2]2CeH and CO with or without H2:  An Experimental and Computational Study Evan L. Werkema, Laurent Maron, Odile Eisenstein, and Richard A. Andersen pp 2529–2541 DOI: 10.1021/ja066482h Supporting Info

Concerted Molecular Displacements in a Thermally-Induced Solid-State Transformation in Crystals of DL-Norleucine Jamshed Anwar, Sigrid C. Tuble, and John Kendrick pp 2542–2547 DOI: 10.1021/ja066686y Supporting Info

Cyclic Modular β-Sheets R. Jeremy Woods, Justin O. Brower, Elena Castellanos, Mehrnoosh Hashemzadeh, Omid Khakshoor, Wade A. Russu, and James S. Nowick pp 2548–2558 DOI: 10.1021/ja0667965 Supporting Info

Syntheses and Electronic Structures of One-Electron-Oxidized Group 10 Metal(II)−(Disalicylidene)diamine Complexes (Metal = Ni, Pd, Pt) Yuichi Shimazaki, Tatsuo Yajima, Fumito Tani, Satoru Karasawa, Koichi Fukui, Yoshinori Naruta, and Osamu Yamauchi pp 2559–2568 DOI: 10.1021/ja067022r Supporting Info

Methyl Chloride Production from Methane over Lanthanum-Based Catalysts Simon G. Podkolzin, Eric E. Stangland, Mark E. Jones, Elvira Peringer, and Johannes A. Lercher pp 2569–2576 DOI: 10.1021/ja066913w

Classification of Water Molecules in Protein Binding Sites Caterina Barillari, Justine Taylor, Russell Viner, and Jonathan W. Essex pp 2577–2587 DOI: 10.1021/ja066980q Supporting Info

Spectroscopic Observation of Conformation-Dependent Charge Distribution in a Molecular Cation Kang Taek Lee, Hyung Min Kim, Kyu Young Han, Jiha Sung, Kwang Jun Lee, and Seong Keun Kim pp 2588–2592 DOI: 10.1021/ja0670308 Supporting Info

Layer-Engineering of High-Tc Superconductors:  (Cu,Mo)Sr2(Ce,Y)4Cu2O13+δ with a Quadruple-Fluorite-Layer Block Between CuO2 Planes Inga Grigoraviciute, Hisao Yamauchi, and Maarit Karppinen pp 2593–2596 DOI: 10.1021/ja0671316 Supporting Info

Ultrafast Study of p-Biphenylyldiazoethane. The Chemistry of the Diazo Excited State and the Relaxed Carbene Jin Wang, Gotard Burdzinski, Terry L. Gustafson, and Matthew S. Platz pp 2597–2606 DOI: 10.1021/ja067213u Supporting Info

Three-Dimensional Porous Coordination Polymer Functionalized with Amide Groups Based on Tridentate Ligand:  Selective Sorption and Catalysis Shinpei Hasegawa, Satoshi Horike, Ryotaro Matsuda, Shuhei Furukawa, Katsunori Mochizuki, Yoshinori Kinoshita, and Susumu Kitagawa pp 2607–2614 DOI: 10.1021/ja067374y Supporting Info

Crystal Nucleation, Growth, and Morphology of the Synthetic Malaria Pigment β-Hematin and the Effect Thereon by Quinoline Additives:  The Malaria Pigment as a Target of Various Antimalarial Drugs Inna Solomonov, Maria Osipova, Yishay Feldman, Carsten Baehtz, Kristian Kjaer, Ian K. Robinson, Grant T. Webster, Don McNaughton, Bayden R. Wood, Isabelle Weissbuch, and Leslie Leiserowitz pp 2615–2627 DOI: 10.1021/ja0674183 Supporting Info

Size-Sorted Anionic Iron Oxide Nanomagnets as Colloidal Mediators for Magnetic Hyperthermia Jean-Paul Fortin, Claire Wilhelm, Jacques Servais, Christine Ménager, Jean-Claude Bacri, and Florence Gazeau pp 2628–2635 DOI: 10.1021/ja067457e

Mechanical Stabilization Effect of Water on a Membrane-like System Matteo Castronovo, Fouzia Bano, Simone Raugei, Denis Scaini, Martina Dell'Angela, Robert Hudej, Loredana Casalis, and Giacinto Scoles pp 2636–2641 DOI: 10.1021/ja067462i Supporting Info

Origin of Oxide Sensitivity in Gold-Based Catalysts:  A First Principle Study of CO Oxidation over Au Supported on Monoclinic and Tetragonal ZrO2 Chuan-Ming Wang, Kang-Nian Fan, and Zhi-Pan Liu pp 2642–2647 DOI: 10.1021/ja067510z

Total Syntheses, Fragmentation Studies, and Antitumor/Antiproliferative Activities of FR901464 and Its Low Picomolar Analogue Brian J. Albert, Ananthapadmanabhan Sivaramakrishnan, Tadaatsu Naka, Nancy L. Czaicki, and Kazunori Koide pp 2648–2659 DOI: 10.1021/ja067870m Supporting Info

Minimization of a Protein−DNA Dimerizer Ryan L. Stafford, Hans-Dieter Arndt, Mary L. Brezinski, Aseem Z. Ansari, and Peter B. Dervan pp 2660–2668 DOI: 10.1021/ja067971k

Organically Modified Silica Nanoparticles Co-encapsulating Photosensitizing Drug and Aggregation-Enhanced Two-Photon Absorbing Fluorescent Dye Aggregates for Two-Photon Photodynamic Therapy Sehoon Kim, Tymish Y. Ohulchanskyy, Haridas E. Pudavar, Ravindra K. Pandey, and Paras N. Prasad pp 2669–2675 DOI: 10.1021/ja0680257 Supporting Info

Charge Density of Divalent Metal Cations Determines RNA Stability Eda Koculi, Changbong Hyeon, D. Thirumalai, and Sarah A. Woodson pp 2676–2682 DOI: 10.1021/ja068027r

Self-Assembled Heterotrimeric Collagen Triple Helices Directed through Electrostatic Interactions Varun Gauba and Jeffrey D. Hartgerink pp 2683–2690 DOI: 10.1021/ja0683640 Supporting Info

The Participation of Alkynylboronates in Inverse Electron Demand [4 + 2] Cycloadditions:  A Mechanistic Study Enrique Gomez-Bengoa, Matthew D. Helm, Andrew Plant, and Joseph P. A. Harrity pp 2691–2699 DOI: 10.1021/ja068527k Supporting Info

Shapes and Noncovalent Interactions of Oligomers:  The Rotational Spectrum of the Difluoromethane Trimer Susana Blanco, Sonia Melandri, Paolo Ottaviani, and Walther Caminati pp 2700–2703 DOI: 10.1021/ja068599b Supporting Info

Does Aromaticity in a Reaction Product Increase or Decrease the Intrinsic Barrier? Kinetics of the Reversible Deprotonation of Benzofuran-3(2H)-one and Benzothiophene-3(2H)-one Claude F. Bernasconi and Moisés Pérez-Lorenzo pp 2704–2712 DOI: 10.1021/ja067118l Supporting Info

Carbocyclization by Radical Closure onto O-Trityl Oximes:  Dramatic Effect of Diphenyl Diselenide Derrick L. J. Clive, Mai P. Pham, and Rajendra Subedi pp 2713–2717 DOI: 10.1021/ja067117t Supporting Info

Ligand-Dependent Catalytic Cycle and Role of Styrene in Nickel-Catalyzed Anhydride Cross-Coupling:  Evidence for Turnover-Limiting Reductive Elimination Jeffrey B. Johnson, Eric A. Bercot, John M. Rowley, Geoffrey W. Coates, and Tomislav Rovis pp 2718–2725 DOI: 10.1021/ja067845g Supporting Info

Heterocyclic Antitumor Antibiotics. Topics in Heterocyclic Chemistry, 02 Edited by Moses Lee (Hope College, Holland, MI). Series Edited by R. R. Gupta. Springer:  Berlin, Heidelberg, New York. 2006. xiv + 252 pp. $149.00. ISBN 3-540-30982-9. Gary I. Dmitrienko p 2726 DOI: 10.1021/ja0697830

Issue 10

Synthesis and Liposome Insertion of a New Poly(carboranylalkylthio)porphyrazine to Improve Potentiality in Multiple-Approach Cancer Therapy Sandra Ristori, Anna Salvati, Giacomo Martini, Olivier Spalla, Daniela Pietrangeli, Angela Rosa, and Giampaolo Ricciardi pp 2728–2729 DOI: 10.1021/ja0661459 Supporting Info

Energy Optimum Chiralities of Multiwalled Carbon Nanotubes Wanlin Guo and Yufeng Guo pp 2730–2731 DOI: 10.1021/ja0662063 Supporting Info

Facial Control of Nanoparticle Binding to Cytochrome c Halil Bayraktar, Chang-Cheng You, Vincent M. Rotello, and Michael J. Knapp pp 2732–2733 DOI: 10.1021/ja067497i Supporting Info

Enzymatic Redox 3‘-End-Labeling of DNA Oligonucleotide Monolayers on Gold Surfaces Using Terminal Deoxynucleotidyl Transferase (TdT)-Mediated Single Base Extension Agnès Anne, Christelle Bonnaudat, Christophe Demaille, and Kang Wang pp 2734–2735 DOI: 10.1021/ja067954v

Interparticle Influence on Size/Size Distribution Evolution of Nanocrystals Jason Thessing, Jianghong Qian, Haiyan Chen, Narayan Pradhan, and Xiaogang Peng pp 2736–2737 DOI: 10.1021/ja068072z Supporting Info

Mode-Selective Excited-State Proton Transfer in 2-(2‘-Pyridyl)pyrrole Isolated in a Supersonic Jet Michał Kijak, Yevgeniy Nosenko, Ajay Singh, Randolph P. Thummel, and Jacek Waluk pp 2738–2739 DOI: 10.1021/ja068109f Supporting Info

A New Octanuclear Copper(II)−Nucleoside Wheel Donatella Armentano, Teresa F. Mastropietro, Miguel Julve, Rachele Rossi, Patrizia Rossi, and Giovanni De Munno pp 2740–2741 DOI: 10.1021/ja068201b Supporting Info

Deep Quench:  An Expanded Dynamic Range for Protein Kinase Sensors Vyas Sharma, Richard S. Agnes, and David S. Lawrence pp 2742–2743 DOI: 10.1021/ja068280r Supporting Info

Chemical Probes for the Rapid Detection of Fatty-Acylated Proteins in Mammalian Cells Howard C. Hang, Ernst-Jan Geutjes, Gijsbert Grotenbreg, Annette M. Pollington, Marie Jose Bijlmakers, and Hidde L. Ploegh pp 2744–2745 DOI: 10.1021/ja0685001 Supporting Info

Highly Selective Supramolecular Catalyzed Allylic Alcohol Isomerization Dennis H. Leung, Robert G. Bergman, and Kenneth N. Raymond pp 2746–2747 DOI: 10.1021/ja068688o Supporting Info

Water Permeation through a Subnanometer Boron Nitride Nanotube Chang Y. Won and N. R. Aluru pp 2748–2749 DOI: 10.1021/ja0687318 Supporting Info

Stable, Solution-Processed, High-Mobility ZnO Thin-Film Transistors Beng S. Ong, Chensha Li, Yuning Li, Yiliang Wu, and Rafik Loutfy pp 2750–2751 DOI: 10.1021/ja068876e Supporting Info

Design and Synthesis of Modular Oxazoline Ligands for the Enantioselective Chromium-Catalyzed Addition of Allyl Bromide to Ketones Jeremie J. Miller and Matthew S. Sigman pp 2752–2753 DOI: 10.1021/ja068915m Supporting Info

A Record Anisotropy Barrier for a Single-Molecule Magnet Constantinos J. Milios, Alina Vinslava, Wolfgang Wernsdorfer, Stephen Moggach, Simon Parsons, Spyros P. Perlepes, George Christou, and Euan K. Brechin pp 2754–2755 DOI: 10.1021/ja068961m Supporting Info

Automated Spectral Compression for Fast Multidimensional NMR and Increased Time Resolution in Real-Time NMR Spectroscopy Ewen Lescop, Paul Schanda, Rodolfo Rasia, and Bernhard Brutscher pp 2756–2757 DOI: 10.1021/ja068949u Supporting Info

Targeted Labeling of DNA by Methyltransferase-Directed Transfer of Activated Groups (mTAG) Gražvydas Lukinaviius, Vidmantas Lapienė, Zdislav Staševskij, Christian Dalhoff, Elmar Weinhold, and Saulius Klimašauskas pp 2758–2759 DOI: 10.1021/ja0691876 Supporting Info

Synthesis, Structure, and Magnetism of Np2O5 Tori Z. Forbes, Peter C. Burns, S. Skanthakumar, and L. Soderholm pp 2760–2761 DOI: 10.1021/ja069250r Supporting Info

“Super Silyl” Group for Diastereoselective Sequential Reactions:  Access to Complex Chiral Architecture in One Pot Matthew B. Boxer and Hisashi Yamamoto pp 2762–2763 DOI: 10.1021/ja0693542 Supporting Info

Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes Britton K. Corkey and F. Dean Toste pp 2764–2765 DOI: 10.1021/ja068723r Supporting Info

Cation−π Control of Regiochemistry of Intramolecular Schmidt Reactions en Route to Bridged Bicyclic Lactams Lei Yao and Jeffrey Aubé pp 2766–2767 DOI: 10.1021/ja068919r Supporting Info

Highly Selective Copper-Catalyzed Ring Expansion of Vinyl Thiiranes:  Application to Synthesis of Biotin and the Heterocyclic Core of Plavix Erik Rogers, Hiroshi Araki, Lindsay A. Batory, Christine E. McInnis, and Jon T. Njardarson pp 2768–2769 DOI: 10.1021/ja069059h Supporting Info

Automated Synthesis of the Tumor-Associated Carbohydrate Antigens Gb-3 and Globo-H:  Incorporation of α-Galactosidic Linkages Daniel B. Werz, Bastien Castagner, and Peter H. Seeberger pp 2770–2771 DOI: 10.1021/ja069218x Supporting Info

Activated Iodosylbenzene Monomer as an Ozone Equivalent:  Oxidative Cleavage of Carbon−Carbon Double Bonds in the Presence of Water Kazunori Miyamoto, Norihiro Tada, and Masahito Ochiai pp 2772–2773 DOI: 10.1021/ja070179e Supporting Info

Total Synthesis of Papulacandin D Scott E. Denmark, Christopher S. Regens, and Tetsuya Kobayashi pp 2774–2776 DOI: 10.1021/ja070071z Supporting Info

Electric Field Induced Orientation of Polymer Chains in Macroscopically Aligned Electrospun Polymer Nanofibers Meghana V. Kakade, Steven Givens, Kenncorwin Gardner, Keun Hyung Lee, D. Bruce Chase, and John F. Rabolt pp 2777–2782 DOI: 10.1021/ja065043f Supporting Info

Transition-State Analysis of S. pneumoniae 5‘-Methylthioadenosine Nucleosidase Vipender Singh and Vern L. Schramm pp 2783–2795 DOI: 10.1021/ja065082r Supporting Info

Fourier Transform Ion Mobility Measurement of Chain Branching in Mass-Selected, Chemically Trapped Oligomers from Methylalumoxane-Activated, Metallocene-Catalyzed Polymerization of Ethylene Rolf Dietiker, Fabio di Lena, and Peter Chen pp 2796–2802 DOI: 10.1021/ja065482e Supporting Info

Alkanephosphonates on Hafnium-Modified Gold:  A New Class of Self-Assembled Organic Monolayers Michael L. Jespersen, Christina E. Inman, Gregory J. Kearns, Evan W. Foster, and James E. Hutchison pp 2803–2807 DOI: 10.1021/ja065598a Supporting Info

Role of Zinc Content on the Catalytic Efficiency of B1 Metallo β-Lactamases Matteo Dal Peraro, Alejandro J. Vila, Paolo Carloni, and Michael L. Klein pp 2808–2816 DOI: 10.1021/ja0657556 Supporting Info

Inductive vs Solvation Effects in Primary Alkyl Amines:  Determination of the Standard Potentials José Luis Bourdelande, Iluminada Gallardo, and Gonzalo Guirado pp 2817–2821 DOI: 10.1021/ja0656245 Supporting Info

(I2)n Encapsulation inside TiO2:  A Way To Tune Photoactivity in the Visible Region Sandro Usseglio, Alessandro Damin, Domenica Scarano, Silvia Bordiga, Adriano Zecchina, and Carlo Lamberti pp 2822–2828 DOI: 10.1021/ja066083m Supporting Info

Fingerprint Vibrational Spectra of Protonated Methyl Esters of Amino Acids in the Gas Phase Aude Simon, Luke MacAleese, Philippe Maître, Joël Lemaire, and Terrance B. McMahon pp 2829–2840 DOI: 10.1021/ja0662321 Supporting Info

From Cd-Rich to Se-Rich − the Manipulation of CdSe Nanocrystal Surface Stoichiometry Jacek Jasieniak and Paul Mulvaney pp 2841–2848 DOI: 10.1021/ja066205a Supporting Info

The Pattern of Distribution of Amino Groups Modulates the Structure and Dynamics of Natural Aminoglycosides:  Implications for RNA Recognition Francisco Corzana, Igor Cuesta, Felix Freire, Julia Revuelta, Mario Torrado, Agatha Bastida, Jesús Jiménez-Barbero, and Juan Luis Asensio pp 2849–2865 DOI: 10.1021/ja066348x Supporting Info

Nonstatistical Behavior of Reactive Scattering in the 18O+32O2 Isotope Exchange Reaction Annalise L. Van Wyngarden, Kathleen A. Mar, Kristie A. Boering, Jim J. Lin, Yuan T. Lee, Shi-Ying Lin, Hua Guo, and Gyorgy Lendvay pp 2866–2870 DOI: 10.1021/ja0668163

Forming Biocompatible and Nonaggregated Nanocrystals in Water Using Amphiphilic Polymers William W. Yu, Emmanuel Chang, Joshua C. Falkner, Junyan Zhang, Ali M. Al-Somali, Christie M. Sayes, Judah Johns, Rebekah Drezek, and Vicki L. Colvin pp 2871–2879 DOI: 10.1021/ja067184n Supporting Info

The Reactivity with CO of AHb1 and AHb2 from Arabidopsis thaliana is Controlled by the Distal HisE7 and Internal Hydrophobic Cavities Stefano Bruno, Serena Faggiano, Francesca Spyrakis, Andrea Mozzarelli, Stefania Abbruzzetti, Elena Grandi, Cristiano Viappiani, Alessandro Feis, Stephan Mackowiak, Giulietta Smulevich, Elena Cacciatori, and Paola Dominici pp 2880–2889 DOI: 10.1021/ja066638d

A Simple Model System for the Study of Carbohydrate−Aromatic Interactions Giancarlo Terraneo, Donatella Potenza, Angeles Canales, Jesus Jiménez-Barbero, Kim K. Baldridge, and Anna Bernardi pp 2890–2900 DOI: 10.1021/ja066633g Supporting Info

Solvent Effect on Conical Intersections in Excited-State 9H-Adenine:  Radiationless Decay Mechanism in Polar Solvent Shohei Yamazaki and Shigeki Kato pp 2901–2909 DOI: 10.1021/ja0669169 Supporting Info

Storage of an Excess Proton in the Hydrogen-Bonded Network of the D-Pathway of Cytochrome c Oxidase:  Identification of a Protonated Water Cluster Jiancong Xu, Martyn A. Sharpe, Ling Qin, Shelagh Ferguson-Miller, and Gregory A. Voth pp 2910–2913 DOI: 10.1021/ja067360s Supporting Info

Biosynthesis of Thiamin Thiazole in Eukaryotes:  Conversion of NAD to an Advanced Intermediate Abhishek Chatterjee, Christopher T. Jurgenson, Frank C. Schroeder, Steven E. Ealick, and Tadhg P. Begley pp 2914–2922 DOI: 10.1021/ja067606t Supporting Info

An IR Study of Protonation Changes Associated with Heme−Heme Electron Transfer in Bovine Cytochrome c Oxidase Masayo Iwaki and Peter R. Rich pp 2923–2929 DOI: 10.1021/ja067779i Supporting Info

Binding Induced Folding in p53−MDM2 Complex Hai-Feng Chen and Ray Luo pp 2930–2937 DOI: 10.1021/ja0678774 Supporting Info

Alkenylsilane Structure Effects on Mononuclear and Binuclear Organotitanium-Mediated Ethylene Polymerization:  Scope and Mechanism of Simultaneous Polyolefin Branch and Functional Group Introduction Smruti B. Amin and Tobin J. Marks pp 2938–2953 DOI: 10.1021/ja0675292 Supporting Info

Biomimetic and Aggregation-Driven Crystallization Route for Room-Temperature Material Synthesis:  Growth of β-Ga2O3 Nanoparticles on Peptide Assemblies as Nanoreactors Sang-Yup Lee, Xueyun Gao, and Hiroshi Matsui pp 2954–2958 DOI: 10.1021/ja0677057 Supporting Info

Functional and Mechanistic Analyses of Biomimetic Aminoacyl Transfer Reactions in de Novo Designed Coiled Coil Peptides via Rational Active Site Engineering Luke J. Leman, Dana A. Weinberger, Zheng-Zheng Huang, Keith M. Wilcoxen, and M. Reza Ghadiri pp 2959–2966 DOI: 10.1021/ja068052x Supporting Info

Structures and Large NLO Responses of New Electrides:  Li-Doped Fluorocarbon Chain Hong-Liang Xu, Zhi-Ru Li, Di Wu, Bing-Qiang Wang, Ying Li, Feng Long Gu, and Yuriko Aoki pp 2967–2970 DOI: 10.1021/ja068038k Supporting Info

Heteronuclear NMR Spectroscopy for Lysine NH3 Groups in Proteins:  Unique Effect of Water Exchange on 15N Transverse Relaxation Junji Iwahara, Young-Sang Jung, and G. Marius Clore pp 2971–2980 DOI: 10.1021/ja0683436

Effects of As(III) Binding on β-Hairpin Structure Danny Ramadan, Daniel J. Cline, Shi Bai, Colin Thorpe, and Joel P. Schneider pp 2981–2988 DOI: 10.1021/ja067068k Supporting Info

Electrostatic Properties of Adsorbed Polar Molecules:  Opposite Behavior of a Single Molecule and a Molecular Monolayer Dudi Deutsch, Amir Natan, Yoram Shapira, and Leeor Kronik pp 2989–2997 DOI: 10.1021/ja068417d Supporting Info

Ammonia Production at the FeMo Cofactor of Nitrogenase:  Results from Density Functional Theory Johannes Kästner and Peter E. Blöchl pp 2998–3006 DOI: 10.1021/ja068618h Supporting Info

Molecular Insights into Azumamide E Histone Deacetylases Inhibitory Activity Nakia Maulucci, Maria Giovanna Chini, Simone Di Micco, Irene Izzo, Emiddio Cafaro, Adele Russo, Paola Gallinari, Chantal Paolini, Maria Chiara Nardi, Agostino Casapullo, Raffaele Riccio, Giuseppe Bifulco, and Francesco De Riccardis pp 3007–3012 DOI: 10.1021/ja0686256 Supporting Info

Covalent Catalysis by Pyridoxal:  Evaluation of the Effect of the Cofactor on the Carbon Acidity of Glycine Krisztina Toth and John P. Richard pp 3013–3021 DOI: 10.1021/ja0679228

Probing the Electronic Structure and Band Gap Evolution of Titanium Oxide Clusters (TiO2)n- (n = 1−10) Using Photoelectron Spectroscopy Hua-Jin Zhai and Lai-Sheng Wang pp 3022–3026 DOI: 10.1021/ja068601z

Proton-Induced Lewis Acidity of Unsaturated Iridium Amides [J. Am. Chem. Soc. 2006, 128, 13048−13049]. Zachariah M. Heiden and Thomas B. Rauchfuss p 3027 DOI: 10.1021/ja0699844

FEP-Guided Selection of Bicyclic Heterocycles in Lead Optimization for Non-Nucleoside Inhibitors of HIV-1 Reverse Transcriptase [J. Am. Chem. Soc. 2006, 128, 15372−15373]. Joseph T. Kim, Andrew D. Hamilton, Christopher M. Bailey, Robert A. Domaoal, Ligong Wang, Karen S. Anderson, and William L. Jorgensen p 3027 DOI: 10.1021/ja076881s

Handbook of Applied Solid State Spectroscopy Edited by D. R. Vij (Kurukshetra University, India). Springer Science + Business Media, LLC:  New York. 2006. xx + 742 pp. $299.00. ISBN 0-387-32497-6. Janice L. Musfeldt p 3028 DOI: 10.1021/ja069810m

Handbook of Reagents for Organic Synthesis:  Reagents for Direct Functionalization of C−H Bonds Edited by Philip L. Fuchs (Purdue University, West Lafayette, IN, USA). J. Wiley & Sons, Ltd.:  Chichester. 2007. x + 412 pp. $135.00. ISBN 0-470-01022-3. p 3028 DOI: 10.1021/ja0698477

HPLC:  A Practical User's Guide, 2nd ed By Marvin C. McMaster (University of Missouri-St. Louis, USA). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xiv + 238 pp. $74.95. ISBN 0-471-75401-3. pp 3028–3029 DOI: 10.1021/ja069846e

Solid State NMR Spectroscopy for Biopolymers:  Principles and Applications By Hazime Saitô (Himeji Institute of Technology and Hiroshima University, Japan), Isao Ando (Tokyo Institute of Technology, Japan), and Akira Naito (Yokohama National University, Japan). Springer:  Dordrecht. 2006. xiv + 464 pp. $129.00. ISBN 1-4020-4302-3. Michèle Auger p 3029 DOI: 10.1021/ja0698230

Modelling Molecular Structure and Reactivity in Bio-logical Systems Edited by Kevin J. Naidoo (Uni-versity of Cape Town, South Africa), John Brady (Cor-nell University, USA), Martin J. Field (Institut de Biologie Structurale, Grenoble, France), Jiali Gao (University of Minnesota, USA), and Michael Hann (GlaxoSmithKline Medicines Research Centre, Stevenage, UK). Royal Society of Chemistry:  Cambridge. 2006. x + 294 pp. $219.00. ISBN 0-85404-668-2. p 3029 DOI: 10.1021/ja069845m

Single Molecule Chemistry and Physics:  An Introduction By Chen Wang and Chunli Bai (National Center for Nanoscience and Technology, Beijing, China). From the Series:  Nanoscience and Technology. Edited by P. Avouris, B. Bhushan, D. Bimberg, K. von Klitzing, H. Sakaki, and R. Wiesendanger. Springer:  Berlin, Heidelberg, New York. 2006. xii + 304 pp. $119.00. ISBN 3-540-25369-6. Naresh Dalal pp 3029–3030 DOI: 10.1021/ja069818w

Issue 11

Amino Acid Bulkiness Defines the Local Conformations and Dynamics of Natively Unfolded α-Synuclein and Tau Min-Kyu Cho, Hai-Young Kim, Pau Bernado, Claudio O. Fernandez, Martin Blackledge, and Markus Zweckstetter pp 3032–3033 DOI: 10.1021/ja067482k Supporting Info

Sulfur K-Edge XAS as a Probe of Sulfur-Centered Radical Intermediates Vlad Martin-Diaconescu and Pierre Kennepohl pp 3034–3035 DOI: 10.1021/ja0676760 Supporting Info

A New Anticoagulant−Antidote Pair:  Control of Thrombin Activity by Aptamers and Porphyrins Astrid Joachimi, Günter Mayer, and Jörg S. Hartig pp 3036–3037 DOI: 10.1021/ja0677822 Supporting Info

Colorimetric Sensors for Volatile Organic Compounds (VOCs) Based on Conjugated Polymer-Embedded Electrospun Fibers Jaewon Yoon, Sang Kyun Chae, and Jong-Man Kim pp 3038–3039 DOI: 10.1021/ja067856+ Supporting Info

Growth Factor Mediated Assembly of Cell Receptor-Responsive Hydrogels Nori Yamaguchi, Le Zhang, Byeong-Seok Chae, Chandra S. Palla, Eric M. Furst, and Kristi L. Kiick pp 3040–3041 DOI: 10.1021/ja0680358 Supporting Info

Reverse-Keggin Ions:  Polycondensation of Antimonate Ligands Give Inorganic Cryptand Viswanathan Baskar, Maheswaran Shanmugam, Madeleine Helliwell, Simon J. Teat, and Richard E. P. Winpenny pp 3042–3043 DOI: 10.1021/ja068214p Supporting Info

Thermally Driven Unidirectional Crystallization of Charged Colloidal Silica Akiko Toyotama, Junpei Yamanaka, Masakatsu Yonese, Tsutomu Sawada, and Fumio Uchida pp 3044–3045 DOI: 10.1021/ja0682327 Supporting Info

Generation and Reactions of o-Bromophenyllithium without Benzyne Formation Using a Microreactor Hirotsugu Usutani, Yutaka Tomida, Aiichiro Nagaki, Hideho Okamoto, Toshiki Nokami, and Jun-ichi Yoshida pp 3046–3047 DOI: 10.1021/ja068330s Supporting Info

DNA Hybridization Detection with Blue Luminescent Quantum Dots and Dye-Labeled Single-Stranded DNA Hui Peng, Lijuan Zhang, Tanja H. M. Kjällman, Christian Soeller, and Jadranka Travas-Sejdic pp 3048–3049 DOI: 10.1021/ja0685452 Supporting Info

Analog Parallel Processing of Molecular Sensory Information A. Prasanna de Silva, S. Sisira K. de Silva, Nalin C. W. Goonesekera, H. Q. Nimal Gunaratne, P. L. Mark Lynch, Kemuel R. Nesbitt, Suram T. Patuwathavithana, and N. L. D. Sydney Ramyalal pp 3050–3051 DOI: 10.1021/ja0686514 Supporting Info

Lamellar Assembly of Conical Molecules Possessing a Fullerene Apex in Crystals and Liquid Crystals Yu-Wu Zhong, Yutaka Matsuo, and Eiichi Nakamura pp 3052–3053 DOI: 10.1021/ja068780k Supporting Info

Coexistence of Conducting and Magnetic Electrons Based on Molecular π-Electrons in the Supramolecular Conductor (Me-3,5-DIP)[Ni(dmit)2]2 Yosuke Kosaka, Hiroshi M. Yamamoto, Akiko Nakao, Masafumi Tamura, and Reizo Kato pp 3054–3055 DOI: 10.1021/ja0687825 Supporting Info

Folding Intermediate in the Villin Headpiece Domain Arises from Disruption of a N-Terminal Hydrogen-Bonded Network Jana Khandogin, Daniel P. Raleigh, and Charles L. Brooks, III pp 3056–3057 DOI: 10.1021/ja0688880 Supporting Info

Intermolecular Ene Reactions Utilizing Oxazolones and Enol Ethers Jason S. Fisk and Jetze J. Tepe pp 3058–3059 DOI: 10.1021/ja0627904 Supporting Info

Identification of a Mo−Fe−S Cluster on NifEN by Mo K-Edge Extended X-ray Absorption Fine Structure Simon J. George, Robert Y. Igarashi, Cinthia Piamonteze, Basem Soboh, Stephen P. Cramer, and Luis M. Rubio pp 3060–3061 DOI: 10.1021/ja0663428 Supporting Info

Defect-Site Promoted Surface Reorganization in Nanocrystalline Ceria for the Low-Temperature Activation of Ethylbenzene B. Murugan and A. V. Ramaswamy pp 3062–3063 DOI: 10.1021/ja066834k Supporting Info

Intercalation of Well-Dispersed Gold Nanoparticles into Layered Oxide Nanosheets through Intercalation of a Polyamine Hideo Hata, Shoichi Kubo, Yoji Kobayashi, and Thomas E. Mallouk pp 3064–3065 DOI: 10.1021/ja068272a Supporting Info

High-Performance Solid-Oxide Fuel Cell Cathodes Based on Cobaltite Nanotubes Martín G. Bellino, Joaquín G. Sacanell, Diego G. Lamas, Ana G. Leyva, and Noemí E. Walsöe de Reca pp 3066–3067 DOI: 10.1021/ja068115b Supporting Info

Iterative Stereospecific Reagent-Controlled Homologation of Pinacol Boronates by Enantioenriched α-Chloroalkyllithium Reagents Paul R. Blakemore and Matthew S. Burge pp 3068–3069 DOI: 10.1021/ja068808s Supporting Info

Simple, Stable, and Versatile Double-Allylation Reagents for the Stereoselective Preparation of Skeletally Diverse Compounds Feng Peng and Dennis G. Hall pp 3070–3071 DOI: 10.1021/ja068985t Supporting Info

Hexagonally Ordered Nanostructures Comprised of a Flexible Disk-like Molecule with High Self-Assembling Properties at Neutral and Cationic States Masashi Hasegawa, Hideo Enozawa, Youhei Kawabata, and Masahiko Iyoda pp 3072–3073 DOI: 10.1021/ja069025+ Supporting Info

A Simple Primary−Tertiary Diamine−Brønsted Acid Catalyst for Asymmetric Direct Aldol Reactions of Linear Aliphatic Ketones Sanzhong Luo, Hui Xu, Jiuyuan Li, Long Zhang, and Jin-Pei Cheng pp 3074–3075 DOI: 10.1021/ja069372j Supporting Info

Palladium(II)-Catalyzed Enantioselective Aerobic Dialkoxylation of 2-Propenyl Phenols:  A Pronounced Effect of Copper Additives on Enantioselectivity Yang Zhang and Matthew S. Sigman pp 3076–3077 DOI: 10.1021/ja070263u Supporting Info

The Intramolecular Photometathesis of Pyrroles Luke D. Elliott, Malcolm Berry, Andrew J. Orr-Ewing, and Kevin I. Booker-Milburn pp 3078–3079 DOI: 10.1021/ja070254l Supporting Info

Synthesis of Heptaprenyl−Lipid IV to Analyze Peptidoglycan Glycosyltransferases Yi Zhang, Eric J. Fechter, Tsung-Shing Andrew Wang, Dianah Barrett, Suzanne Walker, and Daniel E. Kahne pp 3080–3081 DOI: 10.1021/ja069060g Supporting Info

GdCo1-xGa3Ge:  Charge Density Wave in a Ga Square Net Marina A. Zhuravleva, Michel Evain, Vaclav Petricek, and Mercouri G. Kanatzidis pp 3082–3083 DOI: 10.1021/ja069195m Supporting Info

Synthesis and Alcohol Vapor Sensitivity of a Ferromagnetic Copper−Tungsten Bimetallic Assembly Shin-ichi Ohkoshi, Yoshihide Tsunobuchi, Hitomi Takahashi, Toshiya Hozumi, Motoo Shiro, and Kazuhito Hashimoto pp 3084–3085 DOI: 10.1021/ja069353+ Supporting Info

Concise Total Synthesis of (±)-Marcfortine B Barry M. Trost, Nicolai Cramer, and Heiko Bernsmann pp 3086–3087 DOI: 10.1021/ja070142u Supporting Info

Carbocyclic Carbene Ligands Derived from Aromatic Nitrones:  Formation and Catalytic Activity of Their Pd(II) Complexes Qingwei Yao, Mark Zabawa, Joyce Woo, and Chong Zheng pp 3088–3089 DOI: 10.1021/ja0701659 Supporting Info

A Controlled Approach to Well-Defined Oligothiophenes via Oxidatively Induced Reductive Elimination of Stable Pt(II) Oligothienyl Complexes Fan Zhang and Peter Bäuerle pp 3090–3091 DOI: 10.1021/ja070083k Supporting Info

Intramolecular C−H Activation Directed Self-Assembly of an Organoplatinum(II) Molecular Square Shu-Bin Zhao, Rui-Yao Wang, and Suning Wang pp 3092–3093 DOI: 10.1021/ja0702770 Supporting Info

Lithio Siloles:  Facile Synthesis and Applications Chao Wang, Qian Luo, Hui Sun, Xiangyu Guo, and Zhenfeng Xi pp 3094–3095 DOI: 10.1021/ja070404s Supporting Info

From Discrete Linear ZntBu2 Molecules to 1D Coordination Polymers and 2D Fabrics Janusz Lewiński, Maciej Dranka, Wojciech Bury, Witold Śliwiński, Iwona Justyniak, and Janusz Lipkowski pp 3096–3098 DOI: 10.1021/ja067229k Supporting Info

Realistic Modeling of Ruthenium-Catalyzed Transfer Hydrogenation Jan-Willem Handgraaf and Evert Jan Meijer pp 3099–3103 DOI: 10.1021/ja062359e Supporting Info

Self-Assembling Light-Harvesting Systems from Synthetically Modified Tobacco Mosaic Virus Coat Proteins Rebekah A. Miller, Andrew D. Presley, and Matthew B. Francis pp 3104–3109 DOI: 10.1021/ja063887t Supporting Info

Importance of Correlated Motions on the Low Barrier Rotational Potentials of Crystalline Molecular Gyroscopes Peter D. Jarowski, K. N. Houk, and Miguel A. Garcia-Garibay pp 3110–3117 DOI: 10.1021/ja0637907 Supporting Info

The Case of the Missing Ring:  Radical Cleavage of a Carbon−Carbon Bond and Implications for GFP Chromophore Biosynthesis David P. Barondeau, Carey J. Kassmann, John A. Tainer, and Elizabeth D. Getzoff pp 3118–3126 DOI: 10.1021/ja063983u

Relationship Among Ligand Conformations in Solution, in the Solid State, and at the Hsp90 Binding Site:  Geldanamycin and Radicicol Pahk Thepchatri, Tomasso Eliseo, Daniel O. Cicero, David Myles, and James P. Snyder pp 3127–3134 DOI: 10.1021/ja064863p Supporting Info

Intermediates in Dioxygen Activation by Methane Monooxygenase:  A QM/MM Study David Rinaldo, Dean M. Philipp, Stephen J. Lippard, and Richard A. Friesner pp 3135–3147 DOI: 10.1021/ja0654074 Supporting Info

Growth and Characterization of Films Containing Fullerenes and Water Soluble Porphyrins for Solar Energy Conversion Applications Vito Sgobba, Gabriele Giancane, Sabrina Conoci, Serena Casilli, Giampaolo Ricciardi, Dirk M. Guldi, Maurizio Prato, and Ludovico Valli pp 3148–3156 DOI: 10.1021/ja0655789 Supporting Info

From Single to Multiple Atomic Layers:  A Unique Approach to the Systematic Tuning of Structures and Properties of Inorganic−Organic Hybrid Nanostructured Semiconductors Xiaoying Huang and Jing Li pp 3157–3162 DOI: 10.1021/ja065799e Supporting Info

Molecular Wiring of Insulators:  Charging and Discharging Electrode Materials for High-Energy Lithium-Ion Batteries by Molecular Charge Transport Layers Qing Wang, Nick Evans, Shaik M. Zakeeruddin, Ivan Exnar, and Michael Grätzel pp 3163–3167 DOI: 10.1021/ja066260j Supporting Info

The Dynamics of Water−Protein Interaction Studied by Ultrafast Optical Kerr-Effect Spectroscopy Neil T. Hunt, Lisa Kattner, Richard P. Shanks, and Klaas Wynne pp 3168–3172 DOI: 10.1021/ja066289n

Photoinitiated Charge Transport in Supramolecular Assemblies of a 1,7,N,N‘-Tetrakis(zinc porphyrin)-perylene-3,4:9,10-bis(dicarboximide) Richard F. Kelley, Won Suk Shin, Boris Rybtchinski, Louise E. Sinks, and Michael R. Wasielewski pp 3173–3181 DOI: 10.1021/ja0664741 Supporting Info

Compound I of Nitric Oxide Synthase:  The Active Site Protonation State Kyung-Bin Cho, Etienne Derat, and Sason Shaik pp 3182–3188 DOI: 10.1021/ja066662r Supporting Info

Atomic XAFS as a Tool To Probe the Reactivity of Metal Oxide Catalysts:  Quantifying Metal Oxide Support Effects Daphne E. Keller, Sanna M. K. Airaksinen, A. Outi Krause, Bert M. Weckhuysen, and Diederik C. Koningsberger pp 3189–3197 DOI: 10.1021/ja0667007 Supporting Info

Cyclohexenylphenyldiazene:  A Simple Surrogate of the Azobenzene Photochromic Unit Irene Conti, Filippo Marchioni, Alberto Credi, Giorgio Orlandi, Goffredo Rosini, and Marco Garavelli pp 3198–3210 DOI: 10.1021/ja0668466 Supporting Info

Mechanistic Aspects of the Oxidative and Reductive Fragmentation of N-Nitrosoamines:  A New Method for Generating Nitrenium Cations, Amide Anions, and Aminyl Radicals Krzysztof Piech, Thomas Bally, Adam Sikora, and Andrzej Marcinek pp 3211–3217 DOI: 10.1021/ja066855e Supporting Info

Cyclic Peptoids Sung Bin Y. Shin, Barney Yoo, Louis J. Todaro, and Kent Kirshenbaum pp 3218–3225 DOI: 10.1021/ja066960o Supporting Info

X-ray Scattering Study of Thin Films of Poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene) Michael L. Chabinyc,, Michael F. Toney, R. Joseph Kline, Iain McCulloch, and Martin Heeney pp 3226–3237 DOI: 10.1021/ja0670714 Supporting Info

Reactions of Large Water Cluster Anions with Hydrogen Chloride:  Formation of Atomic Hydrogen and Phase Separation in the Gas Phase Chi-Kit Siu, O. Petru Balaj, Vladimir E. Bondybey, and Martin K. Beyer pp 3238–3246 DOI: 10.1021/ja067355o Supporting Info

Competing Electron-Transfer Pathways in Hydrocarbon Frameworks:  Short-Circuiting Through-Bond Coupling by Nonbonded Contacts in Rigid U-Shaped Norbornylogous Systems Containing a Cavity-Bound Aromatic Pendant Group Subhasis Chakrabarti, Min Liu, David H. Waldeck, Anna M. Oliver, and Michael N. Paddon-Row pp 3247–3256 DOI: 10.1021/ja067266b Supporting Info

Fluorescent HIV-1 Dimerization Initiation Site:  Design, Properties, and Use for Ligand Discovery Victor K. Tam, Denise Kwong, and Yitzhak Tor pp 3257–3266 DOI: 10.1021/ja0675797 Supporting Info

Ultralarge Hyperpolarizability Twisted π-Electron System Electro-Optic Chromophores:  Synthesis, Solid-State and Solution-Phase Structural Characteristics, Electronic Structures, Linear and Nonlinear Optical Properties, and Computational Studies Hu Kang, Antonio Facchetti, Hua Jiang, Elena Cariati, Stefania Righetto, Renato Ugo, Cristiano Zuccaccia, Alceo Macchioni, Charlotte L. Stern, Zhifu Liu, Seng-Tiong Ho, Eric C. Brown, Mark A. Ratner, and Tobin J. Marks pp 3267–3286 DOI: 10.1021/ja0674690 Supporting Info

Preparation, Self-Assembly, and Mechanistic Study of Highly Monodispersed Nanocubes Jintian Ren and Richard D. Tilley pp 3287–3291 DOI: 10.1021/ja067636w

Controlled MegaDalton Assembly with Locally Stiff but Globally Flexible Polyphenylene Dendrimers Christopher G. Clark, Jr., Ryan J. Wenzel, Ekaterina V. Andreitchenko, Werner Steffen, Renato Zenobi, and Klaus Müllen pp 3292–3301 DOI: 10.1021/ja067662u Supporting Info

The Conformations of 13-Vertex ML2C2B10 Metallacarboranes:  Experimental and Computational Studies Kelly J. Dalby, David Ellis, Stefan Erhardt, Ruaraidh D. McIntosh, Stuart A. Macgregor, Karen Rae, Georgina M. Rosair, Volker Settels, Alan J. Welch, Bruce E. Hodson, Thomas D. McGrath, and F. Gordon A. Stone pp 3302–3314 DOI: 10.1021/ja067698m Supporting Info

A Model of Interdomain Mobility in a Multidomain Protein Yaroslav E. Ryabov and David Fushman pp 3315–3327 DOI: 10.1021/ja067667r Supporting Info

Competing Forward and Reversed Chain Reactions in One-Dimensional Molecular Line Growth on the Si(100)−(2 × 1)−H Surface Md. Zakir Hossain, Hiroyuki S. Kato, and Maki Kawai pp 3328–3332 DOI: 10.1021/ja0678626

Cell-Penetrating Quantum Dots Based on Multivalent and Endosome-Disrupting Surface Coatings Hongwei Duan and Shuming Nie pp 3333–3338 DOI: 10.1021/ja068158s

Efficient and Color-Tunable Mn-Doped ZnSe Nanocrystal Emitters:  Control of Optical Performance via Greener Synthetic Chemistry Narayan Pradhan and Xiaogang Peng pp 3339–3347 DOI: 10.1021/ja068360v Supporting Info

Tuning the Hydrolytic Aqueous Chemistry of Osmium Arene Complexes with N,O-Chelating Ligands to Achieve Cancer Cell Cytotoxicity Anna F. A. Peacock, Simon Parsons, and Peter J. Sadler pp 3348–3357 DOI: 10.1021/ja068335p Supporting Info

Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki−Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters Kelvin Billingsley and Stephen L. Buchwald pp 3358–3366 DOI: 10.1021/ja068577p Supporting Info

DNA−Protein Interactions as the Source of Large-Length-Scale Chirality Evident in the Liquid Crystal Behavior of Filamentous Bacteriophages Sonit Tomar, Mark M. Green, and Loren A. Day pp 3367–3375 DOI: 10.1021/ja068498d

Hydration Dynamics and Time Scales of Coupled Water−Protein Fluctuations Tanping Li, Ali A. Hassanali, Ya-Ting Kao, Dongping Zhong, and Sherwin J. Singer pp 3376–3382 DOI: 10.1021/ja0685957 Supporting Info

Autoassembly of Nanofibrous Zeolite Crystals via Silicon Carbide Substrate Self-Transformation Svetlana Ivanova, Benoit Louis, Marc-Jacques Ledoux, and Cuong Pham-Huu pp 3383–3391 DOI: 10.1021/ja0686209

Metallaborane Reactivity. A Stoichiometric Mechanism for the Insertion of Two Alkynes into an Iridaborane Framework via a Disposable Molybdenum Chaperone Frédéric de Montigny, Ramón Macias, Bruce C. Noll, Thomas P. Fehlner, Karine Costuas, Jean-Yves Saillard, and Jean-François Halet pp 3392–3401 DOI: 10.1021/ja068999z Supporting Info

Reduction of Activated Olefins by SmI2. Detouring the Classical Birch Mechanism and a Negative Order in SmI2 Alexander Tarnopolsky and Shmaryahu Hoz pp 3402–3407 DOI: 10.1021/ja0686662 Supporting Info

Mild and Selective Hydrozirconation of Amides to Aldehydes Using Cp2Zr(H)Cl:  Scope and Mechanistic Insight Jared T. Spletstoser, Jonathan M. White, Ashok Rao Tunoori, and Gunda I. Georg pp 3408–3419 DOI: 10.1021/ja066362+ Supporting Info

Oxidation of H2 and CO over Ion-Exchanged X and Y Zeolites Daniel G. Lahr, Junhui Li, and Robert J. Davis pp 3420–3425 DOI: 10.1021/ja0671520

8-Azaguanine Reporter of Purine Ionization States in Structured RNAs Carla P. Da Costa, Martha J. Fedor, and Lincoln G. Scott pp 3426–3432 DOI: 10.1021/ja067699e

Interplay between Two-Electron and Four-Electron Donor Carbonyl Groups in Oxophilic Metal Systems:  Highly Unsaturated Divanadocene Carbonyls Qian-shu Li, Xiuhui Zhang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III pp 3433–3443 DOI: 10.1021/ja068058m Supporting Info

Calorimetric, Spectroscopic, and Model Studies Provide Insight into the Transport of Ti(IV) by Human Serum Transferrin Arthur D. Tinoco, Christopher D. Incarvito, and Ann M. Valentine pp 3444–3454 DOI: 10.1021/ja068149j Supporting Info

Energetic Determinants of Oligomeric State Specificity in Coiled Coils [J. Am. Chem. Soc. 2006, 128, 15499−15510]. Jorge Ramos and Themis Lazaridis pp 3455–3456 DOI: 10.1021/ja076882k

Issue 12

A Fluorescent Sensor for Imaging Reversible Redox Cycles in Living Cells Evan W. Miller, Shelly X. Bian, and Christopher J. Chang pp 3458–3459 DOI: 10.1021/ja0668973 Supporting Info

Competitive C−H Bond Activation and β-Hydride Elimination at Platinum(II) Susan M. Kloek and Karen I. Goldberg pp 3460–3461 DOI: 10.1021/ja0669629 Supporting Info

Anaerobic Sulfatase-Maturating Enzymes:  Radical SAM Enzymes Able To Catalyze in Vitro Sulfatase Post-translational Modification Alhosna Benjdia, Jérôme Leprince, Alain Guillot, Hubert Vaudry, Sylvie Rabot, and Olivier Berteau pp 3462–3463 DOI: 10.1021/ja067175e Supporting Info

Reversible Single Crystal to Single Crystal Transformation through Fe−O(H)Me/Fe−OH2 Bond Formation/Bond Breaking in a Gas−Solid Reaction at an Ambient Condition Sabbani Supriya and Samar K. Das pp 3464–3465 DOI: 10.1021/ja067572p Supporting Info

Chiral Proton Catalysis:  Enantioselective Brønsted Acid Catalyzed Additions of Nitroacetic Acid Derivatives as Glycine Equivalents Anand Singh, Ryan A. Yoder, Bo Shen, and Jeffrey N. Johnston pp 3466–3467 DOI: 10.1021/ja068073r Supporting Info

Control of ansa-Zirconocene Stereochemistry by Reversible Exchange of Cyclopentadienyl and Chloride Ligands Richard M. Buck, Nawaporn Vinayavekhin, and Richard F. Jordan pp 3468–3469 DOI: 10.1021/ja0681523 Supporting Info

An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine-Catalyzed (3 + 2) Cycloaddition of Allenoates and Alkenes Yuanzhi Xia, Yong Liang, Yuanyuan Chen, Ming Wang, Lei Jiao, Feng Huang, Song Liu, Yahong Li, and Zhi-Xiang Yu pp 3470–3471 DOI: 10.1021/ja068215h Supporting Info

Field-Effect Transistors Based on a Benzothiadiazole−Cyclopentadithiophene Copolymer Ming Zhang, Hoi Nok Tsao, Wojciech Pisula, Changduk Yang, Ashok K. Mishra, and Klaus Müllen pp 3472–3473 DOI: 10.1021/ja0683537 Supporting Info

Design of an Emission Ratiometric Biosensor from MerR Family Proteins:  A Sensitive and Selective Sensor for Hg2+ Seraphine V. Wegner, Ayse Okesli, Peng Chen, and Chuan He pp 3474–3475 DOI: 10.1021/ja068342d Supporting Info

Geometry of Hydrogen Bonds Formed by Lipid Bilayer Nitroxide Probes:  A High-Frequency Pulsed ENDOR/EPR Study Tatyana I. Smirnova, Alex I. Smirnov, Serguei V. Paschenko, and Oleg G. Poluektov pp 3476–3477 DOI: 10.1021/ja068395v Supporting Info

Highly Enantiomeric Supramolecular [4 + 4] Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Human Serum Albumin Masaki Nishijima, Takehiko Wada, Tadashi Mori, Tamara C. S. Pace, Cornelia Bohne, and Yoshihisa Inoue pp 3478–3479 DOI: 10.1021/ja068475z Supporting Info

EPR Study of the Low-Spin [d3; S =1/2], Jahn−Teller-Active, Dinitrogen Complex of a Molybdenum Trisamidoamine Rebecca L. McNaughton, Jia Min Chin, Walter W. Weare, Richard R. Schrock, and Brian M. Hoffman pp 3480–3481 DOI: 10.1021/ja068546u

Photoelectron Spectroscopic Characterization of the Niobium−Benzene Anion Produced by Reaction of Niobium with Ethylene Stephen R. Miller, Timothy P. Marcy, Evan L. Millam, and D. Geller Leopold pp 3482–3483 DOI: 10.1021/ja068568g

Titanocene-Catalyzed Regiodivergent Epoxide Openings Andreas Gansäuer, Chun-An Fan, Florian Keller, and Jutta Keil pp 3484–3485 DOI: 10.1021/ja0686211 Supporting Info

A Memory Effect Controlled by a Pulsed Voltage in Photoinduced Conductivity Switching in an Organic Charge-Transfer Salt Toshifumi Iimori, Toshio Naito, and Nobuhiro Ohta pp 3486–3487 DOI: 10.1021/ja068791d Supporting Info

Patterned Deposition of a Mixed-Coordination Adenine−Silver Helicate, Containing a π-Stacked Metallacycle, on a Graphite Surface Chandra Shekhar Purohit and Sandeep Verma pp 3488–3489 DOI: 10.1021/ja068892b Supporting Info

N- versus O-Arylation of Aminoalcohols:  Orthogonal Selectivity in Copper-Based Catalysts Alexandr Shafir, Phillip A. Lichtor, and Stephen L. Buchwald pp 3490–3491 DOI: 10.1021/ja068926f Supporting Info

Reactivity of Individual Organolithium Aggregates:  A RINMR Study of n-Butyllithium and 2-Methoxy-6-(methoxymethyl)phenyllithium Amanda C. Jones, Aaron W. Sanders, Martin J. Bevan, and Hans J. Reich pp 3492–3493 DOI: 10.1021/ja0689334 Supporting Info

Variation of Linker Length in Ratiometric Fluorescent Sensor Proteins Allows Rational Tuning of Zn(II) Affinity in the Picomolar to Femtomolar Range Elisabeth M. W. M. van Dongen, Toon H. Evers, Linda M. Dekkers, E. W. Meijer, Leo W. J. Klomp, and Maarten Merkx pp 3494–3495 DOI: 10.1021/ja069105d Supporting Info

Reversible Water-Induced Magnetic and Structural Conversion of a Flexible Microporous Ni(II)Fe(III) Ferromagnet Nobuhiro Yanai, Wakako Kaneko, Ko Yoneda, Masaaki Ohba, and Susumu Kitagawa pp 3496–3497 DOI: 10.1021/ja069166b Supporting Info

The Total Synthesis of Spirotenuipesines A and B Mingji Dai and Samuel J. Danishefsky pp 3498–3499 DOI: 10.1021/ja069164r Supporting Info

“Threading-Followed-by-Swelling”:  A New Protocol for Rotaxane Synthesis Ching-Wei Chiu, Chien-Chen Lai, and Sheng-Hsien Chiu pp 3500–3501 DOI: 10.1021/ja069362i Supporting Info

Color Change of N-Isopropylacrylamide Copolymer Bearing Reichardts Dye as Optical Sensor for Lower Critical Solution Temperature and for Host−Guest Interaction with β-Cyclodextrin Carsten Koopmans and Helmut Ritter pp 3502–3503 DOI: 10.1021/ja068959v Supporting Info

Bis(phenyl)dirhodium(III) Caprolactamate:  A Dinuclear Paddlewheel Complex with No Metal−Metal Bond Jason M. Nichols, Joffrey Wolf, Peter Zavalij, Bindhu Varughese, and Michael P. Doyle pp 3504–3505 DOI: 10.1021/ja070122s Supporting Info

Generating Patterns for Sensing Using a Single Receptor Scaffold Britto S. Sandanaraj, Robert Demont, and S. Thayumanavan pp 3506–3507 DOI: 10.1021/ja070229f Supporting Info

Insights into the Mechanism of the Negishi Reaction:  ZnRX versus ZnR2 Reagents Juan A. Casares, Pablo Espinet, Beatriz Fuentes, and Gorka Salas pp 3508–3509 DOI: 10.1021/ja070235b Supporting Info

Palladium-Catalyzed Methylation and Arylation of sp2 and sp3 C−H Bonds in Simple Carboxylic Acids Ramesh Giri, Nathan Maugel, Jiao-Jie Li, Dong-Hui Wang, Steven P. Breazzano, Lindsey B. Saunders, and Jin-Quan Yu pp 3510–3511 DOI: 10.1021/ja0701614 Supporting Info

Design and Synthesis of Molecules with Switchable Chirality via Formation and Cleavage of Metal−Ligand Coordination Bonds Vadim A. Soloshonok, Hisanori Ueki, Jason L. Moore, and Trevor K. Ellis pp 3512–3513 DOI: 10.1021/ja067995r Supporting Info

Radical Intermediates in Monooxygenase Reactions of Rieske Dioxygenases Sarmistha Chakrabarty, Rachel N. Austin, Dayi Deng, John T. Groves, and John D. Lipscomb pp 3514–3515 DOI: 10.1021/ja068188v Supporting Info

Total Synthesis of Jerangolid D Jiří Pospíšil and István E. Markó pp 3516–3517 DOI: 10.1021/ja0691728 Supporting Info

Palladium-Catalyzed Asymmetric Silaborative C−C Cleavage of meso-Methylenecyclopropanes Toshimichi Ohmura, Hiroki Taniguchi, Yoshiyuki Kondo, and Michinori Suginome pp 3518–3519 DOI: 10.1021/ja0703170 Supporting Info

Enantioselective, Cyclopentene-Forming Annulations via NHC-Catalyzed Benzoin−Oxy-Cope Reactions Pei-Chen Chiang, Juthanat Kaeobamrung, and Jeffrey W. Bode pp 3520–3521 DOI: 10.1021/ja0705543 Supporting Info

Selective Layer Reaction of Layer-by-Layer Assembled Layered Double-Hydroxide Nanocrystals Jong Hyeon Lee, Seog Woo Rhee, and Duk-Young Jung pp 3522–3523 DOI: 10.1021/ja070512e Supporting Info

Reversibly Photoswitchable Dual-Color Fluorescent Nanoparticles as New Tools for Live-Cell Imaging Linyong Zhu, Wuwei Wu, Ming-Qiang Zhu, Jason J. Han, James K. Hurst, and Alexander D. Q. Li pp 3524–3526 DOI: 10.1021/ja068452k Supporting Info

Single-Crystal Nanoribbons, Nanotubes, and Nanowires from Intramolecular Charge-Transfer Organic Molecules Xiujuan Zhang, Xiaohong Zhang, Kai Zou, Chun-Sing Lee, and Shuit-Tong Lee pp 3527–3532 DOI: 10.1021/ja0642109 Supporting Info

Ethynylbenzene Monolayers on Gold:  A Metal-Molecule Binding Motif Derived from a Hydrocarbon Andrew M. McDonagh, Hadi M. Zareie, Michael J. Ford, Christopher S. Barton, Milena Ginic-Markovic, and Janis G. Matisons pp 3533–3538 DOI: 10.1021/ja064297y Supporting Info

Single-Molecule Spectroscopic Investigation of Energy Migration Processes in Cyclic Porphyrin Arrays Mira Park, Min-Chul Yoon, Zin Seok Yoon, Takaaki Hori, Xiaobin Peng, Naoki Aratani, Jun-ichi Hotta, Hiroshi Uji-i, Michel Sliwa, Johan Hofkens, Atsuhiro Osuka, and Dongho Kim pp 3539–3544 DOI: 10.1021/ja065813n Supporting Info

Chiral Separation:  Mechanism Modeling in Two-Dimensional Systems Irina Paci, Igal Szleifer, and Mark A. Ratner pp 3545–3555 DOI: 10.1021/ja066422b Supporting Info

Ultraviolet Resonance Raman Evidence for Utilization of the Heme 6-Propionate Hydrogen-Bond Network in Signal Transmission from Heme to Protein in Ec DOS Protein Samir F. El-Mashtoly, Hiroto Takahashi, Toru Shimizu, and Teizo Kitagawa pp 3556–3563 DOI: 10.1021/ja0669777 Supporting Info

Optimizing the Photocatalytic Properties of Hydrothermal TiO2 by the Control of Phase Composition and Particle Morphology. A Systematic Approach Andrea Testino, Ignazio Renato Bellobono, Vincenzo Buscaglia, Carmen Canevali, Massimiliano D'Arienzo, Stefano Polizzi, Roberto Scotti, and Franca Morazzoni pp 3564–3575 DOI: 10.1021/ja067050+ Supporting Info

Reactions of Nitrogen Oxides with the Five-Coordinate FeIII(porphyrin) Nitrito Intermediate Fe(Por)(ONO) in Sublimed Solids Tigran S. Kurtikyan, Astghik A. Hovhannisyan, Manya E. Hakobyan, James C. Patterson, Alexei Iretskii, and Peter C. Ford pp 3576–3585 DOI: 10.1021/ja067245h Supporting Info

Site-Specific Incorporation of Glycosylated Serine and Tyrosine Derivatives into Proteins Nour Eddine Fahmi, Larisa Dedkova, Bixun Wang, Serguei Golovine, and Sidney M. Hecht pp 3586–3597 DOI: 10.1021/ja067466n Supporting Info

XeOF2, F2OXeN≡CCH3, and XeOF2·nHF:  Rare Examples of Xe(IV) Oxide Fluorides David S. Brock, Vural Bilir, Hélène P. A. Mercier, and Gary J. Schrobilgen pp 3598–3611 DOI: 10.1021/ja0673480 Supporting Info

The Inconsistency in Adsorption Properties and Powder XRD Data of MOF-5 Is Rationalized by Framework Interpenetration and the Presence of Organic and Inorganic Species in the Nanocavities Jasmina Hafizovic, Morten Bjørgen, Unni Olsbye, Pascal D. C. Dietzel, Silvia Bordiga, Carmelo Prestipino, Carlo Lamberti, and Karl Petter Lillerud pp 3612–3620 DOI: 10.1021/ja0675447 Supporting Info

A Theoretical Study of Cohesion, Structural Deformation, Inclusion, and Dynamics in Porous Hydrogen-Bonded Molecular Networks Cédric Trolliet, Guillaume Poulet, Alain Tuel, James D. Wuest, and Philippe Sautet pp 3621–3626 DOI: 10.1021/ja067844o Supporting Info

Effect of Elemental Composition of PtPd Bimetallic Nanoparticles Containing an Average of 180 Atoms on the Kinetics of the Electrochemical Oxygen Reduction Reaction Heechang Ye and Richard M. Crooks pp 3627–3633 DOI: 10.1021/ja068078o Supporting Info

Protein Flexibility and Species Specificity in Structure-Based Drug Discovery:  Dihydrofolate Reductase as a Test System Anna L. Bowman, Michael G. Lerner, and Heather A. Carlson pp 3634–3640 DOI: 10.1021/ja068256d Supporting Info

Ion Pair Recognition of Quaternary Ammonium and Iminium Salts by Uranyl−Salophen Compounds in Solution and in the Solid State Massimo Cametti, Maija Nissinen, Antonella Dalla Cort, Luigi Mandolini, and Kari Rissanen pp 3641–3648 DOI: 10.1021/ja068561z Supporting Info

Search for a Predicted Hydrogen Bonding Motif − A Multidisciplinary Investigation into the Polymorphism of 3-Azabicyclo[3.3.1]nonane-2,4-dione Ashley T. Hulme, Andrea Johnston, Alastair J. Florence, Phillipe Fernandes, Kenneth Shankland, Colin T. Bedford, Gareth W. A. Welch, Ghazala Sadiq, Delia A. Haynes, W. D. Samuel Motherwell, Derek A. Tocher, and Sarah L. Price pp 3649–3657 DOI: 10.1021/ja0687466 Supporting Info

Shear Instabilities in Metallic Nanoparticles:  Hydrogen-Stabilized Structure of Pt37 on Carbon Lin-Lin Wang and D. D. Johnson pp 3658–3664 DOI: 10.1021/ja068750h

Synthesis and Mechanistic Study of Palladium Nanobars and Nanorods Yujie Xiong, Honggang Cai, Benjamin J. Wiley, Jinguo Wang, Moon J. Kim, and Younan Xia pp 3665–3675 DOI: 10.1021/ja0688023 Supporting Info

Supramolecular Helical Assembly of an Achiral Cyanine Dye in an Induced Helical Amphiphilic Poly(phenylacetylene) Interior in Water Toyoharu Miyagawa, Miho Yamamoto, Reiko Muraki, Hisanari Onouchi, and Eiji Yashima pp 3676–3682 DOI: 10.1021/ja068951l Supporting Info

Continuum of Outer- and Inner-Sphere Mechanisms for Organic Electron Transfer. Steric Modulation of the Precursor Complex in Paramagnetic (Ion-Radical) Self-Exchanges Sergiy V. Rosokha and Jay K. Kochi pp 3683–3697 DOI: 10.1021/ja069149m Supporting Info

Antibody-Catalyzed Oxidation of Δ9-Tetrahydrocannabinol Andrew P. Brogan, Lisa M. Eubanks, George F. Koob, Tobin J. Dickerson, and Kim D. Janda pp 3698–3702 DOI: 10.1021/ja070022m Supporting Info

Photostability versus Photodegradation in the Excited-State Intramolecular Proton Transfer of Nitro Enamines:  Competing Reaction Paths and Conical Intersections Annapaola Migani, Michael J. Bearpark, Massimo Olivucci, and Michael A. Robb pp 3703–3713 DOI: 10.1021/ja066592o Supporting Info

Cluster Core Controlled Reactions of Substitution of Terminal Bromide Ligands by Triphenylphosphine in Octahedral Rhenium Chalcobromide Complexes Michael A. Shestopalov, Yuri V. Mironov, Konstantin A. Brylev, Svetlana G. Kozlova, Vladimir E. Fedorov, Hartmut Spies, Hans-Jürgen Pietzsch, Holger Stephan, Gerhard Geipel, and Gerd Bernhard pp 3714–3721 DOI: 10.1021/ja0668062 Supporting Info

A Synthetic Trivalent Hapten that Aggregates anti-2,4-DNP IgG into Bicyclic Trimers Başar Bilgiçer, Demetri T. Moustakas, and George M. Whitesides pp 3722–3728 DOI: 10.1021/ja067159h Supporting Info

Continuous Structural Evolution of Calcium Carbonate Particles:  A Unifying Model of Copolymer-Mediated Crystallization Alex N. Kulak, Peter Iddon, Yuting Li, Steven P. Armes, Helmut Cölfen, Oskar Paris, Rory M. Wilson, and Fiona C. Meldrum pp 3729–3736 DOI: 10.1021/ja067422e Supporting Info

Sequential Silylcarbocyclization/Silicon-Based Cross-Coupling Reactions Scott E. Denmark and Jack Hung-Chang Liu pp 3737–3744 DOI: 10.1021/ja067854p Supporting Info

Stable exo-nido-Metallacarboranes (M = OsIV) that Incorporate meta-Carborane-Based Dicarbollide Ligands Elena V. Balagurova, Dmitri N. Cheredilin, Galina D. Kolomnikova, Oleg L. Tok, Fedor M. Dolgushin, Alexander I. Yanovsky, and Igor T. Chizhevsky pp 3745–3753 DOI: 10.1021/ja067838s Supporting Info

Counterion, Temperature, and Time Modulation of Nanometric Chiral Ribbons from Gemini-Tartrate Amphiphiles Aurélie Brizard, Carole Aimé, Thomas Labrot, Ivan Huc, Damien Berthier, Franck Artzner, Bernard Desbat, and Reiko Oda pp 3754–3762 DOI: 10.1021/ja0682172

Carbene Stabilization by Aryl Substituents. Is Bigger Better? H. Lee Woodcock, Damian Moran, Bernard R. Brooks, Paul v. R. Schleyer, and Henry F. Schaefer, III pp 3763–3770 DOI: 10.1021/ja068899t Supporting Info

Oxidative Palladium(II) Catalysis:  A Highly Efficient and Chemoselective Cross-Coupling Method for Carbon−Carbon Bond Formation under Base-Free and Nitrogenous-Ligand Conditions [J. Am. Chem. Soc. 2006, 128, 16384−16393]. Kyung Soo Yoo, Cheol Hwan Yoon, Rajesh K. Mishra, Young Chun Jung, Sung Wook Yi, and Kyung Woon Jung p 3771 DOI: 10.1021/ja070517b

Two-Step FRET as a Structural Tool [J. Am. Chem. Soc. 2003, 125, 7336−7343]. Heather M. Watrob, Chia-Pin Pan, and Mary D. Barkley p 3771 DOI: 10.1021/ja070915e

Single-Molecule Magnets and Related Phenomena. Structure and Bonding, 122 Edited by R. Winpenny (The University of Manchester, UK). Series Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2006. xiv + 262 pp. $239.00. ISBN 3-540-33239-1. Matthew P. Shores p 3772 DOI: 10.1021/ja069806a

Surface and Interfacial Organometallic Chemistry and Catalysis. Topics in Organometallic Chemistry, 16 Edited by Christophe Copéret (Laboratoire de Chimie Organometallique de Surface, Villeurbanne, France) and Bruno Chaudret (Laboratoire de Chimie de Coordination du CNRS, Toulouse, France). Springer:  Berlin, Heidelberg, New York. 2005. x + 291 pp. $259.00. ISBN 3-540-26496-5. Bradley J. Holliday pp 3772–3773 DOI: 10.1021/ja0697065

Heterogeneous Enantioselective Hydrogenation:  Theory and Practice By Evgenii Klabunovskii (Russian Academy of Sciences, Moscow, Russia), Gerard V. Smith (Southern Illinois University, Carbondale, USA), and Ágnes Zsigmond (University of Szeged, Szeged, Hungary). From the Series:  Catalysis by Metal Complexes, Volume 31. Series Edited by Brian James and Piet W. N. M. van Leeuwen. Springer:  Dordrecht. 2006. xiv + 302 pp. $175. ISBN 1-4020-4294-9. Hans-Ulrich Blaser pp 3773–3774 DOI: 10.1021/ja069831g

Issue 13

Structure−Activity Correlation in Titanium Single-Site Olefin Polymerization Catalysts Containing Mixed Cyclopentadienyl/Aryloxide Ligation Thomas A. Manz, Khamphee Phomphrai, Grigori Medvedev, Balachandra B. Krishnamurthy, Shalini Sharma, Jesmin Haq, Krista A. Novstrup, Kendall T. Thomson, W. Nicholas Delgass, James M. Caruthers, and Mahdi M. Abu-Omar pp 3776–3777 DOI: 10.1021/ja0640849 Supporting Info

Photoinduced Superparamagnetism in Trimetallic Coordination Nanoparticles Daniela Brinzei, Laure Catala, Corine Mathonière, Wolfgang Wernsdorfer, Alexandre Gloter, Odile Stephan, and Talal Mallah pp 3778–3779 DOI: 10.1021/ja068451s Supporting Info

Multi-oxygenase Complexes of the Gilvocarcin and Jadomycin Biosyntheses Madan K. Kharel, Lili Zhu, Tao Liu, and Jürgen Rohr pp 3780–3781 DOI: 10.1021/ja0680515 Supporting Info

Assembly of Metallic Carbon Nanodots Aligned on a Vicinal Si(111)-7×7 Surface Jiajun Mao, Xiang Yang Kong, Dan Wang, and Zhiqiang Zou pp 3782–3783 DOI: 10.1021/ja068410w Supporting Info

A Direct Observation of a Concerted Two-Bond Breaking Reaction Jr-Wei Ho, Wei-Kan Chen, and Po-Yuan Cheng pp 3784–3785 DOI: 10.1021/ja0684747 Supporting Info

Nitric Oxide-Releasing Fabrics and Other Acrylonitrile-Based Diazeniumdiolates Frank DeRosa, Melina R. Kibbe, Samer F. Najjar, Michael L. Citro, Larry K. Keefer, and Joseph A. Hrabie pp 3786–3787 DOI: 10.1021/ja0686864 Supporting Info

Formation of Helical Mesopores in Organic Polymer Matrices François-Xavier Simon, Nawel S. Khelfallah, Marc Schmutz, Nancy Díaz, and Philippe J. Mésini pp 3788–3789 DOI: 10.1021/ja067261e Supporting Info

Chiral Brønsted Acid-Catalyzed Direct Asymmetric Mannich Reaction Qi-Xiang Guo, Hua Liu, Chang Guo, Shi-Wei Luo, Yi Gu, and Liu-Zhu Gong pp 3790–3791 DOI: 10.1021/ja068236b Supporting Info

Triggering of the Bergman Cyclization by Photochemical Ring Contraction. Facile Cycloaromatization of Benzannulated Cyclodeca-3,7-diene-1,5-diynes Grigori V. Karpov and Vladimir V. Popik pp 3792–3793 DOI: 10.1021/ja064470q Supporting Info

Tetrasubstituted Pyrrolidines via a Tandem Aza-Payne/Hydroamination Reaction Jennifer M. Schomaker, Andrea R. Geiser, Rui Huang, and Babak Borhan pp 3794–3795 DOI: 10.1021/ja068077w Supporting Info

Role of Aspartate-1 in Cu(II) Binding to the Amyloid-β Peptide of Alzheimer's Disease Jesse W. Karr and Veronika A. Szalai pp 3796–3797 DOI: 10.1021/ja068952d Supporting Info

Gold-Catalyzed Deoxygenated Cyclization of cis-2,4-Dien-1-als with Regioselective Addition of Two Nucleophiles. One-Pot Synthesis of Highly Functionalized Cyclopentene Framework Chung-Chang Lin, Tse-Min Teng, Arjan Odedra, and Rai-Shung Liu pp 3798–3799 DOI: 10.1021/ja069171f Supporting Info

Catalytic Nitrile-Alkyne Cross-Metathesis Andrea M. Geyer, Robyn L. Gdula, Eric S. Wiedner, and Marc J. A. Johnson pp 3800–3801 DOI: 10.1021/ja0693439 Supporting Info

Palladium-Catalyzed Formal [4+2] Cycloaddtion of o-Xylylenes with Olefins Ryoichi Kuwano and Takenori Shige pp 3802–3803 DOI: 10.1021/ja070012l Supporting Info

Ionic Liquids Are Useful Contact Angle Probe Fluids Lichao Gao and Thomas J. McCarthy pp 3804–3805 DOI: 10.1021/ja070169d

Intermolecular Chain-to-Chain Tunneling in Metal−Alkanethiol−Metal Junctions Hyunwook Song, Hyoyoung Lee, and Takhee Lee pp 3806–3807 DOI: 10.1021/ja068875m Supporting Info

Modified-RNA Aptamer-Based Sensor for Competitive Impedimetric Assay of Neomycin B Noemí de-los-Santos-Álvarez, María Jesús Lobo-Castañón, Arturo J. Miranda-Ordieres, and Paulino Tuñón-Blanco pp 3808–3809 DOI: 10.1021/ja0689482 Supporting Info

A New Route for the Synthesis of Uniform Nanozeolites with Hydrophobic External Surface in Organic Solvent Medium Gia-Thanh Vuong and Trong-On Do pp 3810–3811 DOI: 10.1021/ja069058p Supporting Info

Site-Specific Incorporation of Allosteric-Inhibition Sites in a Protein Tyrosine Phosphatase Xin-Yu Zhang and Anthony C. Bishop pp 3812–3813 DOI: 10.1021/ja069098t Supporting Info

Spotlighting of Cocaine by an Autonomous Aptamer-Based Machine Bella Shlyahovsky, Di Li, Yossi Weizmann, Roni Nowarski, Moshe Kotler, and Itamar Willner pp 3814–3815 DOI: 10.1021/ja069291n Supporting Info

Saccharide-Coated M12L24 Molecular Spheres That Form Aggregates by Multi-interaction with Proteins Nozomi Kamiya, Masahide Tominaga, Sota Sato, and Makoto Fujita pp 3816–3817 DOI: 10.1021/ja0693082 Supporting Info

Assembly and Exchange of Resorcinarene Capsules Monitored by Fluorescence Resonance Energy Transfer Elizabeth S. Barrett, Trevor J. Dale, and Julius Rebek, Jr. pp 3818–3819 DOI: 10.1021/ja0700956 Supporting Info

Solid-State Self-Assembly of a Calix[4]pyrrole−Resorcinarene Hybrid into a Hexameric Cage Guzmán Gil-Ramírez, Jordi Benet-Buchholz, Eduardo C. Escudero-Adán, and Pablo Ballester pp 3820–3821 DOI: 10.1021/ja070037k Supporting Info

Circumventing Anti-Androgen Resistance by Molecular Design Paula L. McGinley and John T. Koh pp 3822–3823 DOI: 10.1021/ja0701154 Supporting Info

Directed Catalytic Asymmetric Olefin Metathesis. Selectivity Control by Enoate and Ynoate Groups in Ru-Catalyzed Asymmetric Ring-Opening/Cross-Metathesis Russell E. Giudici and Amir H. Hoveyda pp 3824–3825 DOI: 10.1021/ja070187v Supporting Info

Total Synthesis of 2‘-O-Methylmyxalamide D and (6E)-2‘-O-Methylmyxalamide D Robert S. Coleman, Xiaoling Lu, and Isabelle Modolo pp 3826–3827 DOI: 10.1021/ja070265e Supporting Info

Pyrophosphate-Selective Fluorescent Chemosensor at Physiological pH:  Formation of a Unique Excimer upon Addition of Pyrophosphate Ha Na Lee, Zhaochao Xu, Sook Kyung Kim, K. M. K. Swamy, Youngmee Kim, Sung-Jin Kim, and Juyoung Yoon pp 3828–3829 DOI: 10.1021/ja0700294 Supporting Info

Catalytic Enantioselective Synthesis of Flavanones and Chromanones Margaret M. Biddle, Michael Lin, and Karl A. Scheidt pp 3830–3831 DOI: 10.1021/ja070394v Supporting Info

Aggregation of Rod−Coil Block Copolymers Containing Rigid Polyampholyte Blocks in Aqueous Solution Min Mao and S. Richard Turner pp 3832–3833 DOI: 10.1021/ja070422+ Supporting Info

Lysine Nζ-Decarboxylation in the BlaR1 Protein from Staphylococcus aureus at the Root of Its Function As an Antibiotic Sensor Jooyoung Cha and Shahriar Mobashery pp 3834–3835 DOI: 10.1021/ja070472e Supporting Info

Kinetic Resolution of Hydroperoxides with Enantiopure Phosphines:  Preparation of Enantioenriched Tertiary Hydroperoxides Tom G. Driver, Jason R. Harris, and K. A. Woerpel pp 3836–3837 DOI: 10.1021/ja070482f Supporting Info

Evidence for a Plasma Core during Multibubble Sonoluminescence in Sulfuric Acid Nathan C. Eddingsaas and Kenneth S. Suslick pp 3838–3839 DOI: 10.1021/ja070192z

A Rapid Flow Mixer with 11-μs Mixing Time Microfabricated by a Pulsed-Laser Ablation Technique:  Observation of a Barrier-Limited Collapse in Cytochrome c Folding Shuzo Matsumoto, Akira Yane, Satoru Nakashima, Masaki Hashida, Masayuki Fujita, Yuji Goto, and Satoshi Takahashi pp 3840–3841 DOI: 10.1021/ja0660958 Supporting Info

A Double Concave Hydrocarbon Buckycatcher Andrzej Sygula, Frank R. Fronczek, Renata Sygula, Peter W. Rabideau, and Marilyn M. Olmstead pp 3842–3843 DOI: 10.1021/ja070616p Supporting Info

Pd-Catalyzed Kumada−Corriu Cross-Coupling Reactions at Low Temperatures Allow the Use of Knochel-type Grignard Reagents Ruben Martin and Stephen L. Buchwald pp 3844–3845 DOI: 10.1021/ja070830d Supporting Info

Readily Accessible, Modular, and Tuneable BINOL 3,3‘-Perfluoroalkylsulfones:  Highly Efficient Catalysts for Enantioselective In-Mediated Imine Allylation Robert Kargbo, Yoko Takahashi, Santosh Bhor, Gregory R. Cook, Guy C. Lloyd-Jones, and Ian R. Shepperson pp 3846–3847 DOI: 10.1021/ja070742t Supporting Info

Core/Shell Quantum Dots with High Relaxivity and Photoluminescence for Multimodality Imaging Shizhong Wang, Benjamin R. Jarrett, Susan M. Kauzlarich, and Angelique Y. Louie pp 3848–3856 DOI: 10.1021/ja065996d

Quasi Chiral Phase Separation in a Two-Dimensional Orientationally Disordered System:  6-Nitrospiropyran on Au(111) Tian Huang, Zhenpeng Hu, Aidi Zhao, Haiqian Wang, Bing Wang, Jinlong Yang, and J. G. Hou pp 3857–3862 DOI: 10.1021/ja066521p Supporting Info

Atomic Layer Deposition of TiO2 from TiI4 and H2O onto SiO2 Surfaces:  Ab Initio Calculations of the Initial Reaction Mechanisms Zheng Hu and C. Heath Turner pp 3863–3878 DOI: 10.1021/ja066529z Supporting Info

Tuned Polymer Electrolyte Membranes Based on Aromatic Polyethers for Fuel Cell Applications Kenji Miyatake, Yohei Chikashige, Eiji Higuchi, and Masahiro Watanabe pp 3879–3887 DOI: 10.1021/ja0672526 Supporting Info

Functional Polythiophene Nanoparticles:  Size-Controlled Electropolymerization and Ion Selective Response Pengchao Si, Qijin Chi, Zheshen Li, Jens Ulstrup, Preben Juul Møller, and John Mortensen pp 3888–3896 DOI: 10.1021/ja067193w Supporting Info

Nephila clavipes Spider Dragline Silk Microstructure Studied by Scanning Transmission X-ray Microscopy Marie-Eve Rousseau, Daniel Hernández Cruz, M. Marcia West, Adam P. Hitchcock, and Michel Pézolet pp 3897–3905 DOI: 10.1021/ja067471r

Dynamic Docking of Cytochrome b5 with Myoglobin and α-Hemoglobin:  Heme-Neutralization “Squares” and the Binding of Electron-Transfer-Reactive Configurations Korin E. Wheeler, Judith M. Nocek, Deborah A. Cull, Liliya A. Yatsunyk, Amy C. Rosenzweig, and Brian M. Hoffman pp 3906–3917 DOI: 10.1021/ja067598g Supporting Info

An Enzymatically Activated Fluorescence Probe for Targeted Tumor Imaging Mako Kamiya, Hisataka Kobayashi, Yukihiro Hama, Yoshinori Koyama, Marcelino Bernardo, Tetsuo Nagano, Peter L. Choyke, and Yasuteru Urano pp 3918–3929 DOI: 10.1021/ja067710a Supporting Info

The Gaseous Enthalpy of Formation of the Ionic Liquid 1-Butyl-3-methylimidazolium Dicyanamide from Combustion Calorimetry, Vapor Pressure Measurements, and Ab Initio Calculations Vladimir N. Emel'yanenko, Sergey P. Verevkin, and Andreas Heintz pp 3930–3937 DOI: 10.1021/ja0679174 Supporting Info

Synthesis, Characterization, and Photoinduced Electron Transfer in Functionalized Single Wall Carbon Nanohorns Carla Cioffi, Stéphane Campidelli, Chloé Sooambar, Massimo Marcaccio, Gabriele Marcolongo, Moreno Meneghetti, Demis Paolucci, Francesco Paolucci, Christian Ehli, G. M. Aminur Rahman, Vito Sgobba, Dirk M. Guldi, and Maurizio Prato pp 3938–3945 DOI: 10.1021/ja068007p Supporting Info

A Structure−Reactivity Relationship for Single Walled Carbon Nanotubes Reacting with 4-Hydroxybenzene Diazonium Salt Nitish Nair, Woo-Jae Kim, Monica L. Usrey, and Michael S. Strano pp 3946–3954 DOI: 10.1021/ja068018i Supporting Info

Spectroscopic, Computational, and Kinetic Studies of the μ4-Sulfide-Bridged Tetranuclear CuZ Cluster in N2O Reductase:  pH Effect on the Edge Ligand and Its Contribution to Reactivity Somdatta Ghosh, Serge I. Gorelsky, Serena DeBeer George, Jeannine M. Chan, Inês Cabrito, David M. Dooley, José J. G. Moura, Isabel Moura, and Edward I. Solomon pp 3955–3965 DOI: 10.1021/ja068059e Supporting Info

Benzil-Tethered Precipitons for Controlling Solubility:  A Round-Trip Energy-Transfer Mechanism in the Isomerization of Extended Stilbene Analogues Mark R. Ams and Craig S. Wilcox pp 3966–3972 DOI: 10.1021/ja068211c Supporting Info

Bimodal Bond-Length Distributions in Cobalt-Doped CdSe, ZnSe, and Cd1-xZnxSe Quantum Dots Steven A. Santangelo, Eric A. Hinds, Vladimir A. Vlaskin, Paul I. Archer, and Daniel R. Gamelin pp 3973–3978 DOI: 10.1021/ja068260p Supporting Info

Instantaneous Inclusion of a Polynucleotide and Hydrophobic Guest Molecules into a Helical Core of Cationic β-1,3-Glucan Polysaccharide Masato Ikeda, Teruaki Hasegawa, Munenori Numata, Kouta Sugikawa, Kazuo Sakurai, Michiya Fujiki, and Seiji Shinkai pp 3979–3988 DOI: 10.1021/ja0684343 Supporting Info

Ester versus Polyketone Formation in the Palladium−Diphosphine Catalyzed Carbonylation of Ethene Erik Zuidema, Carles Bo, and Piet W. N. M. van Leeuwen pp 3989–4000 DOI: 10.1021/ja0684500 Supporting Info

Total Syntheses of 2,2‘-epi-Cytoskyrin A, Rugulosin, and the Alleged Structure of Rugulin K. C. Nicolaou, Yee Hwee Lim, Jared L. Piper, and Charles D. Papageorgiou pp 4001–4013 DOI: 10.1021/ja0685708 Supporting Info

Structural and Photophysical Properties of Adducts of [Ru(bipy)(CN)4]2- with Different Metal Cations:  Metallochromism and Its Use in Switching Photoinduced Energy Transfer Theodore Lazarides, Timothy L. Easun, Claire Veyne-Marti, Wassim Z. Alsindi, Michael W. George, Nina Deppermann, Christopher A. Hunter, Harry Adams, and Michael D. Ward pp 4014–4027 DOI: 10.1021/ja068436n Supporting Info

Infrared and Ultraviolet Spectral Signatures and Conformational Preferences of Jet-Cooled Serotonin Tracy A. LeGreve, Esteban E. Baquero, and Timothy S. Zwier pp 4028–4038 DOI: 10.1021/ja068881i Supporting Info

Hybrid Peptide Design. Hydrogen Bonded Conformations in Peptides Containing the Stereochemically Constrained γ-Amino Acid Residue, Gabapentin Prema G. Vasudev, Kuppanna Ananda, Sunanda Chatterjee, Subrayashastry Aravinda, Narayanaswamy Shamala, and Padmanabhan Balaram pp 4039–4048 DOI: 10.1021/ja068910p Supporting Info

Cation−Anion Interactions as Structure Directing Factors:  Structure and Bonding of Ca2CdSb2 and Yb2CdSb2 Sheng-qing Xia and Svilen Bobev pp 4049–4057 DOI: 10.1021/ja069261k Supporting Info

Mechanistic Studies of Platinum(II)-Catalyzed Ethylene Dimerization:  Determination of Barriers to Migratory Insertion in Diimine Pt(II) Hydrido Ethylene and Ethyl Ethylene Intermediates Masashi Shiotsuki, Peter S. White, Maurice Brookhart, and Joseph L. Templeton pp 4058–4067 DOI: 10.1021/ja068118o Supporting Info

On the Photophysics of Artificial Blue-Light Photoreceptors:  An Ab Initio Study on a Flavin-Based Dye Dyad at the Level of Coupled-Cluster Response Theory Keyarash Sadeghian and Martin Schütz pp 4068–4074 DOI: 10.1021/ja068536t Supporting Info

Ionic Electrets:  Electrostatic Charging of Surfaces by Transferring Mobile Ions upon Contact Logan S. McCarty, Adam Winkleman, and George M. Whitesides pp 4075–4088 DOI: 10.1021/ja067301e Supporting Info

Characterization and Mechanism of Formation of Tandem Lesions in DNA by a Nucleobase Peroxyl Radical In Seok Hong, K. Nolan Carter, Kousuke Sato, and Marc M. Greenberg pp 4089–4098 DOI: 10.1021/ja0692276 Supporting Info

Copper-Catalyzed anti-Hydrophosphination Reaction of 1-Alkynylphosphines with Diphenylphosphine Providing (Z)-1,2-Diphosphino-1-alkenes Azusa Kondoh, Hideki Yorimitsu, and Koichiro Oshima pp 4099–4104 DOI: 10.1021/ja070048d Supporting Info

Supramolecular Chirality. Topics in Current Chemistry, 265 Edited by Mercedes Crego-Calama and David N. Reinhoudt (University of Twente, Enschede, The Netherland). Springer:  Berlin, Heidelberg, New York. 2006. xii + 312 pp. $299.00. ISBN 3-540-32151-9. Danith H. Ly p 4105 DOI: 10.1021/ja069781f

Principles of Mass Spectrometry Applied to Biomolecules Edited by Julia Laskin (Pacific Northwest National Lab, Richland, Washington) and Chava Lifshitz (The Hebrew University, Jerusalem, Israel). From the Wiley-Interscience Series on Mass Spectrometry. Series Edited by Dominic Desiderio and Nico Nibbering. John Wiley & Sons, Inc.:  Hoboken, NJ. 2006. xviii + 688 pp. $150.00. ISBN 0-471-72184-0. Jennifer S. Brodbelt pp 4105–4106 DOI: 10.1021/ja0698331

Colloidal Particles at Liquid Interfaces Edited by Bernard P. Binks and Tommy S. Horozov (University of Hull, U.K.). Cambridge University Press:  Cambridge. 2006. XIV + 504 pp. $145.00. ISBN 0-521-84846-6. John Y. Walz pp 4106–4107 DOI: 10.1021/ja069814r

Catalysis by Gold By Geoffrey C. Bond (Brunel University, U.K.), Catherine Louis (Université Pierre et Marie Curie, France), and David T. Thompson (Consultant, World Gold Council, UK). From the Series:  Catalytic Science Series, Volume 6. Series Edited by Graham J. Hutchings. Imperial College Press:  London. 2006. xvi + 366 pp. $88.00. ISBN 1-86094-658-5. John P. Fackler, Jr. p 4107 DOI: 10.1021/ja069835l

Trace Chemical Sensing of Explosives Edited by Ronald L. Woodfin (Sandia National Laboratories, New Mexico). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xxvi + 364 pp. $99.95. ISBN 0-471-73839-5. p 4107 DOI: 10.1021/ja0769088

Applied Thin-Layer Chromatography:  Best Practice and Avoidance of Mistakes, 2nd ed. (Revised and Enlarged) By Elke Hahn-Deinstrop (Eckental, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xvi + 314 pp. $165.00. ISBN 978-3-527-31553-5. pp 4107–4108 DOI: 10.1021/ja076907f

Nanoscopic Materials:  Size-Dependent Phenomena By Emil Roduner (University of Stuttgart, Germany). Royal Society of Chemistry:  Cambridge. 2006. xii + 286 pp. $69.95. ISBN 0-85404.857-X. Thomas P. Russell p 4108 DOI: 10.1021/ja069840p

Fieser's Reagents for Organic Synthesis, Volume 23 By Tse-Lok Ho (National Chiao Tung University and Shanghai Institute of Organic Chemistry, China). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xvi + 534 pp. $125.00. ISBN 0-471-68243-8. p 4108 DOI: 10.1021/ja076901q

Issue 14

Gold-Coated Transition-Metal Anion [Mn13@Au20]- with Ultrahigh Magnetic Moment Jinlan Wang, Jaeil Bai, Julius Jellinek, and Xiao Cheng Zeng pp 4110–4111 DOI: 10.1021/ja0664234 Supporting Info

Low-Temperature, Solution-Processed, High-Mobility Polymer Semiconductors for Thin-Film Transistors Hualong Pan, Yuning Li, Yiliang Wu, Ping Liu, Beng S. Ong, Shiping Zhu, and Gu Xu pp 4112–4113 DOI: 10.1021/ja067879o Supporting Info

Solution-Phase Structure of an Artificial Foldamer:  X-ray Scattering Study Richard F. Kelley, Boris Rybtchinski, Matthew T. Stone, Jeffrey S. Moore, and Michael R. Wasielewski pp 4114–4115 DOI: 10.1021/ja068213x Supporting Info

Electrical Switching and Phase Transformation in Silver Selenide Nanowires David T. Schoen, Chong Xie, and Yi Cui pp 4116–4117 DOI: 10.1021/ja068365s Supporting Info

Direct Revelation of Multiple Conformations in RNA by Femtosecond Dynamics Liang Zhao and Tianbing Xia pp 4118–4119 DOI: 10.1021/ja068391q Supporting Info

Mechanism-Based Inactivation of Benzoylformate Decarboxylase, A Thiamin Diphosphate-Dependent Enzyme Asim K. Bera, Lena S. Polovnikova, Juliatek Roestamadji, Theodore S. Widlanski, George L. Kenyon, Michael J. McLeish, and Miriam S. Hasson pp 4120–4121 DOI: 10.1021/ja068636z Supporting Info

Pd(0)-Catalyzed Amphiphilic Allylation of Aldehydes with Vinyl Epoxide Masanari Kimura, Ryutaro Mukai, Takato Tamaki, Yoshikazu Horino, and Yoshinao Tamaru pp 4122–4123 DOI: 10.1021/ja0687320 Supporting Info

Organocatalysis in Radical Chemistry. Enantioselective α-Oxyamination of Aldehydes Mukund P. Sibi and Masayuki Hasegawa pp 4124–4125 DOI: 10.1021/ja069245n Supporting Info

Configurational and Conformational Effects on Tin−Lithium Exchange in α-Aminoorganostannanes by Rapid-Injection NMR Rosalyn Klein and Robert E. Gawley pp 4126–4127 DOI: 10.1021/ja0692377 Supporting Info

UV-Driven Reversible Switching of a Roselike Vanadium Oxide Film between Superhydrophobicity and Superhydrophilicity Ho Sun Lim, Donghoon Kwak, Dong Yun Lee, Seung Goo Lee, and Kilwon Cho pp 4128–4129 DOI: 10.1021/ja0692579

Dynamic DNA Templates for Discrete Gold Nanoparticle Assemblies:  Control of Geometry, Modularity, Write/Erase and Structural Switching Faisal A. Aldaye and Hanadi F. Sleiman pp 4130–4131 DOI: 10.1021/ja070017i Supporting Info

Controlling Photoreactions with Restricted Spaces and Weak Intermolecular Forces:  Exquisite Selectivity during Oxidation of Olefins by Singlet Oxygen Arunkumar Natarajan, Lakshmi S. Kaanumalle, Steffen Jockusch, Corinne L. D. Gibb, Bruce C. Gibb, Nicholas J. Turro, and V. Ramamurthy pp 4132–4133 DOI: 10.1021/ja070086x Supporting Info

Polydiacetylene Nanofibers Created in Low-Molecular-Weight Gels by Post Modification:  Control of Blue and Red Phases by the Odd−Even Effect in Alkyl Chains Norifumi Fujita, Yoshimine Sakamoto, Michihiro Shirakawa, Masayoshi Ojima, Akihiko Fujii, Masanori Ozaki, and Seiji Shinkai pp 4134–4135 DOI: 10.1021/ja069307+ Supporting Info

Size-Dependent Electron Injection from Excited CdSe Quantum Dots into TiO2 Nanoparticles István Robel, Masaru Kuno, and Prashant V. Kamat pp 4136–4137 DOI: 10.1021/ja070099a Supporting Info

Regio- and Diastereoselective Decarboxylative Coupling of Heteroaromatic Alkanes Shelli R. Waetzig and Jon A. Tunge pp 4138–4139 DOI: 10.1021/ja070116w Supporting Info

An Extremely Effective DNA Photocleavage Utilizing Functionalized Liposomes with a Fullerene-Enriched Lipid Bilayer Atsushi Ikeda, Yuki Doi, Mineo Hashizume, Jun-ichi Kikuchi, and Toshifumi Konishi pp 4140–4141 DOI: 10.1021/ja070243s Supporting Info

The Mechanism of Polymerization of Butadiene by “Ligand-Free” Nickel(II) Complexes Abby R. O'Connor, Peter S. White, and Maurice Brookhart pp 4142–4143 DOI: 10.1021/ja070364s Supporting Info

A Fast-Acting Reagent for Accurate Analysis of RNA Secondary and Tertiary Structure by SHAPE Chemistry Stefanie A. Mortimer and Kevin M. Weeks pp 4144–4145 DOI: 10.1021/ja0704028 Supporting Info

Photosensitized NO Release from Water-Soluble Nanoparticle Assemblies Daniel Neuman, Alexis D. Ostrowski, Ryan O. Absalonson, Geoffrey F. Strouse, and Peter C. Ford pp 4146–4147 DOI: 10.1021/ja070490w Supporting Info

Total Syntheses of (+)-Lyconadin A and (−)-Lyconadin B Douglas C. Beshore and Amos B. Smith, III pp 4148–4149 DOI: 10.1021/ja070336+ Supporting Info

Chlorocyclopropane Macrolides from the Marine Sponge Phorbas sp. Assignment of the Configurations of Phorbasides A and B by Quantitative CD Colin K. Skepper, John B. MacMillan, Guang-Xiong Zhou, Makoto N. Masuno, and Tadeusz F. Molinski pp 4150–4151 DOI: 10.1021/ja0703978 Supporting Info

Layered Copper Metagermanate Nanobelts:  Hydrothermal Synthesis, Structure, and Magnetic Properties Rui-Qi Song, An-Wu Xu, and Shu-Hong Yu pp 4152–4153 DOI: 10.1021/ja070536l Supporting Info

A Sensitive and Homogeneous SNP Detection Using Cationic Conjugated Polymers Xinrui Duan, Zhengping Li, Fang He, and Shu Wang pp 4154–4155 DOI: 10.1021/ja070452c Supporting Info

Protease-Triggered Dispersion of Nanoparticle Assemblies Anna Laromaine, Liling Koh, Muthu Murugesan, Rein V. Ulijn, and Molly M. Stevens pp 4156–4157 DOI: 10.1021/ja0706504 Supporting Info

Quantitative Molecular Ensemble Interpretation of NMR Dipolar Couplings without Restraints Scott A. Showalter and Rafael Brüschweiler pp 4158–4159 DOI: 10.1021/ja070658d Supporting Info

Rearrangement of Alkynyl Sulfoxides Catalyzed by Gold(I) Complexes Nathan D. Shapiro and F. Dean Toste pp 4160–4161 DOI: 10.1021/ja070789e Supporting Info

Zinc Stannate (Zn2SnO4) Dye-Sensitized Solar Cells Bing Tan, Elizabeth Toman, Yanguang Li, and Yiying Wu pp 4162–4163 DOI: 10.1021/ja070804f Supporting Info

Structure Elucidation and Enantioselective Total Synthesis of the Potent HMG-CoA Reductase Inhibitor FR901512 via Catalytic Asymmetric Nozaki−Hiyama Reactions Masahiro Inoue and Masahisa Nakada pp 4164–4165 DOI: 10.1021/ja070812w Supporting Info

Cobalt-Catalyzed Diastereoselective Reductive [3 + 2] Cycloaddition of Allenes and Enones Hong-Tai Chang, Thiruvellore Thatai Jayanth, and Chien-Hong Cheng pp 4166–4167 DOI: 10.1021/ja0710196 Supporting Info

Tandem ROMP−Hydrogenation with a Third-Generation Grubbs Catalyst Kenneth D. Camm, Nemesio Martinez Castro, Yuwen Liu, Pawel Czechura, Jennifer L. Snelgrove, and Deryn E. Fogg pp 4168–4169 DOI: 10.1021/ja071047o Supporting Info

Noncovalent Immobilization of Proteins on a Solid Surface by Cucurbit[7]uril-Ferrocenemethylammonium Pair, a Potential Replacement of Biotin−Avidin Pair Ilha Hwang, Kangkyun Baek, Minseon Jung, Youngkook Kim, Kyeng Min Park, Don-Wook Lee, Narayanan Selvapalam, and Kimoon Kim pp 4170–4171 DOI: 10.1021/ja071130b Supporting Info

Aromatic Substitution with Hypercloso C(BCH3)11:  A New Mechanism Kamesh Vyakaranam, Zdenek Havlas, and Josef Michl pp 4172–4174 DOI: 10.1021/ja066520x Supporting Info

Total Synthesis of Plusbacin A3:  A Depsipeptide Antibiotic Active Against Vancomycin-Resistant Bacteria Aaron Wohlrab, Ryan Lamer, and Michael S. VanNieuwenhze pp 4175–4177 DOI: 10.1021/ja068455x Supporting Info

Helix Bundle Quaternary Structure from α/β-Peptide Foldamers W. Seth Horne, Joshua L. Price, James L. Keck, and Samuel H. Gellman pp 4178–4180 DOI: 10.1021/ja070396f Supporting Info

Cyclopropyl Conjugation and Ketyl Anions:  When Do Things Begin to Fall Apart? J. M. Tanko, Xiangzhong Li, M'hamed Chahma, Woodward F. Jackson, and Jared N. Spencer pp 4181–4192 DOI: 10.1021/ja063857q Supporting Info

The Structures and Electronic Configuration of Compound I Intermediates of Helicobacter pylori and Penicillium vitale Catalases Determined by X-ray Crystallography and QM/MM Density Functional Theory Calculations Mercedes Alfonso-Prieto, Anton Borovik, Xavier Carpena, Garib Murshudov, William Melik-Adamyan, Ignacio Fita, Carme Rovira, and Peter C. Loewen pp 4193–4205 DOI: 10.1021/ja063660y Supporting Info

Protein Phosphorylation and Intermolecular Electron Transfer:  A Joint Experimental and Computational Study of a Hormone Biosynthesis Pathway Andy Zöllner, Melissa A. Pasquinelli, Rita Bernhardt, and David N. Beratan pp 4206–4216 DOI: 10.1021/ja064803j Supporting Info

Iron(III) Complex of a Crown Ether−Porphyrin Conjugate and Reversible Binding of Superoxide to Its Iron(II) Form Katharina Dürr, Brendan P. Macpherson, Ralf Warratz, Frank Hampel, Felix Tuczek, Matthias Helmreich, Norbert Jux, and Ivana Ivanović-Burmazović pp 4217–4228 DOI: 10.1021/ja064984p Supporting Info

Gas-Phase Chemistry of Actinides Ions:  New Insights into the Reaction of UO+ and UO2+ with Water Maria del Carmen Michelini, Nino Russo, and Emilia Sicilia pp 4229–4239 DOI: 10.1021/ja065683i Supporting Info

The Catalytic Mn2+ Sites in the Enolase−Inhibitor Complex:  Crystallography, Single-Crystal EPR, and DFT Calculations Raanan Carmieli, Todd M. Larsen, George H. Reed, Samir Zein, Frank Neese, and Daniella Goldfarb pp 4240–4252 DOI: 10.1021/ja066124e Supporting Info

Constrained Geometry Organoactinides as Versatile Catalysts for the Intramolecular Hydroamination/Cyclization of Primary and Secondary Amines Having Diverse Tethered C−C Unsaturation Bryan D. Stubbert and Tobin J. Marks pp 4253–4271 DOI: 10.1021/ja0665444 Supporting Info

Statistical Mechanics of Helix Bundles Using a Dynamic Programming Approach Adam Lucas, Liang Huang, Aravind Joshi, and Ken A. Dill pp 4272–4281 DOI: 10.1021/ja067153s Supporting Info

Understanding the Molecular Basis for the Inhibition of the Alzheimer's Aβ-Peptide Oligomerization by Human Serum Albumin Using Saturation Transfer Difference and Off-Resonance Relaxation NMR Spectroscopy Julijana Milojevic, Veronica Esposito, Rahul Das, and Giuseppe Melacini pp 4282–4290 DOI: 10.1021/ja067367+ Supporting Info

Probing the Efficiency of Electron Transfer through Porphyrin-Based Molecular Wires Mikael U. Winters, Emma Dahlstedt, Holly E. Blades, Craig J. Wilson, Michael J. Frampton, Harry L. Anderson, and Bo Albinsson pp 4291–4297 DOI: 10.1021/ja067447d Supporting Info

Dehydrogenation of Aromatic Molecules under a Scanning Tunneling Microscope:  Pathways and Inelastic Spectroscopy Simulations Hervé Lesnard, Marie-Laure Bocquet, and Nicolás Lorente pp 4298–4305 DOI: 10.1021/ja067442g Supporting Info

Engineering Hydrogen-Bonded Molecular Crystals Built from Derivatives of Hexaphenylbenzene and Related Compounds Kenneth E. Maly, Eric Gagnon, Thierry Maris, and James D. Wuest pp 4306–4322 DOI: 10.1021/ja067571x Supporting Info

Large Impact of Particle Size on Insertion Reactions. A Case for Anatase LixTiO2 Marnix Wagemaker, Wouter J. H. Borghols, and Fokko M. Mulder pp 4323–4327 DOI: 10.1021/ja067733p

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy Junrong Zheng and Michael D. Fayer pp 4328–4335 DOI: 10.1021/ja067760f Supporting Info

Influence of Defects on the Electrical Characteristics of Mercury-Drop Junctions:  Self-Assembled Monolayers of n-Alkanethiolates on Rough and Smooth Silver Emily A. Weiss, Ryan C. Chiechi, George K. Kaufman, Jennah K. Kriebel, Zhefeng Li, Marco Duati, Maria A. Rampi, and George M. Whitesides pp 4336–4349 DOI: 10.1021/ja0677261 Supporting Info

A Class of Luminescent Cyclometalated Alkynylgold(III) Complexes:  Synthesis, Characterization, and Electrochemical, Photophysical, and Computational Studies of [Au(CNC)(CCR)] (CNC = κ3C,N,C Bis-cyclometalated 2,6-Diphenylpyridyl) Keith Man-Chung Wong, Ling-Ling Hung, Wai Han Lam, Nianyong Zhu, and Vivian Wing-Wah Yam pp 4350–4365 DOI: 10.1021/ja068264u Supporting Info

Epitaxial Supramolecular Assembly of Fullerenes Formed by Using a Coronene Template on a Au(111) Surface in Solution Soichiro Yoshimoto, Eishi Tsutsumi, Ryuji Narita, Yasujiro Murata, Michihisa Murata, Koichi Fujiwara, Koichi Komatsu, Osamu Ito, and Kingo Itaya pp 4366–4376 DOI: 10.1021/ja0684848 Supporting Info

Pyrrolic Tripodal Receptors Effectively Recognizing Monosaccharides. Affinity Assessment through a Generalized Binding Descriptor Cristina Nativi, Martina Cacciarini, Oscar Francesconi, Alberto Vacca, Gloriano Moneti, Andrea Ienco, and Stefano Roelens pp 4377–4385 DOI: 10.1021/ja068754m Supporting Info

Structure of an Unprecedented G-Quadruplex Scaffold in the Human c-kit Promoter Anh Tuân Phan, Vitaly Kuryavyi, Sarah Burge, Stephen Neidle, and Dinshaw J. Patel pp 4386–4392 DOI: 10.1021/ja068739h Supporting Info

Proton-Coupled Electron Transfer in a Biomimetic Peptide as a Model of Enzyme Regulatory Mechanisms Robin Sibert, Mira Josowicz, Fernando Porcelli, Gianluigi Veglia, Kevin Range, and Bridgette A. Barry pp 4393–4400 DOI: 10.1021/ja068805f Supporting Info

Tuning the Bergman Cyclization by Introduction of Metal Fragments at Various Positions of the Enediyne. Metalla-Bergman Cyclizations Edyta M. Brzostowska, Roald Hoffmann, and Carol A. Parish pp 4401–4409 DOI: 10.1021/ja068884v Supporting Info

Insertion of Molecular Oxygen into a Palladium−Hydride Bond:  Computational Evidence for Two Nearly Isoenergetic Pathways Brian V. Popp and Shannon S. Stahl pp 4410–4422 DOI: 10.1021/ja069037v Supporting Info

Protonation of a Histidine Copper Ligand in Fern Plastocyanin Rinske Hulsker, Annabelle Mery, Ellen A. Thomassen, Antonio Ranieri, Marco Sola, Martin Ph. Verbeet, Takamitsu Kohzuma, and Marcellus Ubbink pp 4423–4429 DOI: 10.1021/ja0690464 Supporting Info

A Density Functional Study of the 13C NMR Chemical Shifts in Functionalized Single-Walled Carbon Nanotubes Eva Zurek, Chris J. Pickard, and Jochen Autschbach pp 4430–4439 DOI: 10.1021/ja069110h Supporting Info

Coupling of Functional Hydrogen Bonds in Pyridoxal-5‘-phosphate−Enzyme Model Systems Observed by Solid-State NMR Spectroscopy Shasad Sharif, David Schagen, Michael D. Toney, and Hans-Heinrich Limbach pp 4440–4455 DOI: 10.1021/ja066240h Supporting Info

Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides and Chlorohydrins David M. Hodgson, Ying Kit Chung, Irene Nuzzo, Glòria Freixas, Krystyna K. Kulikiewicz, Ed Cleator, and Jean-Marc Paris pp 4456–4462 DOI: 10.1021/ja0672932 Supporting Info

Pd(OAc)2/P(cC6H11)3-Catalyzed Allylation of Aryl Halides with Homoallyl Alcohols via Retro-Allylation Masayuki Iwasaki, Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima pp 4463–4469 DOI: 10.1021/ja067372d Supporting Info

Growth Kinetics of ZnO Nanocrystals:  A Few Surprises Ranjani Viswanatha, Heinz Amenitsch, and D. D. Sarma pp 4470–4475 DOI: 10.1021/ja068161b Supporting Info

Structure and Interaction in Aqueous Urea−Trimethylamine-N-oxide Solutions Sandip Paul and Grenfell N. Patey pp 4476–4482 DOI: 10.1021/ja0685506

Controlled Electrochemical Synthesis of Conductive Polymer Nanotube Structures Rui Xiao, Seung Il Cho, Ran Liu, and Sang Bok Lee pp 4483–4489 DOI: 10.1021/ja068924v Supporting Info

Secondary Deuterium Isotope Effects on the Acidity of Carboxylic Acids and Phenols Charles L. Perrin and Yanmei Dong pp 4490–4497 DOI: 10.1021/ja069103t Supporting Info

Radical Transfer Hydroamination with Aminated Cyclohexadienes Using Polarity Reversal Catalysis:  Scope and Limitations Joyram Guin, Christian Mück-Lichtenfeld, Stefan Grimme, and Armido Studer pp 4498–4503 DOI: 10.1021/ja0692581 Supporting Info

Carbocyclic Carbene Ligands Derived from Aromatic Nitrones:  Formation and Catalytic Activity of Their Pd(II) Complexes  [J. Am. Chem. Soc. 2007, 129, 3088−3089]. Qingwei Yao, Mark Zabawa, Joyce Woo, and Chong Zheng p 4504 DOI: 10.1021/ja071283z

Toward the Syntheses of Universal Ligands for Metal Oxide Surfaces:  Controlling Surface Functionality through Click Chemistry  [J. Am. Chem. Soc. 2006, 128, 11356−11357]. Meghann A. White, Jeremiah A. Johnson, Jeffrey T. Koberstein, and Nicholas J. Turro p 4504 DOI: 10.1021/ja071422c

Issue 15

An Experimental and Computational Study of Stereoselectivity and Reactivity in Lewis Acid Promoted Lithiation-Substitution of Tertiary Amines Satinder V. Kessar, Paramjit Singh, Kamal Nain Singh, P. Venugopalan, Amarjit Kaur, Prasad V. Bharatam, and Arvind K. Sharma pp 4506–4507 DOI: 10.1021/ja0675144 Supporting Info

Nucleophilic Acylation of o-Quinone Methides:  An Umpolung Strategy for the Synthesis of α-Aryl Ketones and Benzofurans Anita E. Mattson and Karl A. Scheidt pp 4508–4509 DOI: 10.1021/ja068189n Supporting Info

Combinatorial Rosamine Library and Application to in Vivo Glutathione Probe Young-Hoon Ahn, Jun-Seok Lee, and Young-Tae Chang pp 4510–4511 DOI: 10.1021/ja068230m Supporting Info

Covalent Assembly of Molecular Ladders C. Scott Hartley, Erin L. Elliott, and Jeffrey S. Moore pp 4512–4513 DOI: 10.1021/ja0690013 Supporting Info

α-Helical Peptide Containing N,N-Dimethyl Lysine Residues Displays Low-Nanomolar and Highly Specific Binding to RRE RNA Soonsil Hyun, Hyun Jin Kim, Nam Ju Lee, Kyung Hyun Lee, Yeongran Lee, Dae Ro Ahn, Keysun Kim, Sunjoo Jeong, and Jaehoon Yu pp 4514–4515 DOI: 10.1021/ja068265m Supporting Info

anti-[2.2](1,4)Phthalocyaninophane:  Spectroscopic Evidence for Transannular Interaction in the Excited States Yoshiaki Asano, Atsuya Muranaka, Akira Fukasawa, Terutaka Hatano, Masanobu Uchiyama, and Nagao Kobayashi pp 4516–4517 DOI: 10.1021/ja068528c Supporting Info

Noninvasive Probing of the Spatial Organization of Polymer Chains in Hydrogels Using Fluorescence Resonance Energy Transfer (FRET) Hyun Joon Kong, Chan Joong Kim, Nathaniel Huebsch, David Weitz, and David J. Mooney pp 4518–4519 DOI: 10.1021/ja0690058 Supporting Info

Temperature-Dependent Synthesis of Metal-Organic Frameworks Based on a Flexible Tetradentate Ligand with Bidirectional Coordination Donors Yu-Bin Dong, You-Yun Jiang, Jie Li, Jian-Ping Ma, Feng-Ling Liu, Bo Tang, Ru-Qi Huang, and Stuart R. Batten pp 4520–4521 DOI: 10.1021/ja0701917 Supporting Info

Enantioselective Conjugate Addition of Hydrazines to α,β-Unsaturated Imides. Synthesis of Chiral Pyrazolidinones Mukund P. Sibi and Takahiro Soeta pp 4522–4523 DOI: 10.1021/ja069312d Supporting Info

Selective Fluorescent Detection of Flavin Adenine Dinucleotide in Human Eosinophils by Using Bis(Zn2+-Dipicolylamine) Complex Hyun-Woo Rhee, Ha-Young Choi, Kyungja Han, and Jong-In Hong pp 4524–4525 DOI: 10.1021/ja070026r Supporting Info

Versatile Photosensitizers for Photodynamic Therapy at Infrared Excitation Peng Zhang, Wim Steelant, Manoj Kumar, and Matthew Scholfield pp 4526–4527 DOI: 10.1021/ja0700707 Supporting Info

Lewis Acid Catalysis Alters the Shapes and Products of Bis-Pericyclic Diels−Alder Transition States Nihan Çelebi-Ölçüm, Daniel H. Ess, Viktorya Aviyente, and K. N. Houk pp 4528–4529 DOI: 10.1021/ja070686w Supporting Info

Transition-State Mimicry by Glycosidase Inhibitors:  A Critical Kinetic Analysis Jacqueline Wicki, Spencer J. Williams, and Stephen G. Withers pp 4530–4531 DOI: 10.1021/ja0707254 Supporting Info

Ion Gel Gated Polymer Thin-Film Transistors Jiyoul Lee, Matthew J. Panzer, Yiyong He, Timothy P. Lodge, and C. Daniel Frisbie pp 4532–4533 DOI: 10.1021/ja070875e

Ortho Green Fluorescence Protein Synthetic Chromophore; Excited-State Intramolecular Proton Transfer via a Seven-Membered-Ring Hydrogen-Bonding System Kew-Yu Chen, Yi-Ming Cheng, Cheng-Hsuan Lai, Cheng-Chih Hsu, Mei-Lin Ho, Gene-Hsiang Lee, and Pi-Tai Chou pp 4534–4535 DOI: 10.1021/ja070880i Supporting Info

Iridium-Catalyzed Asymmetric Hydrogenation of Fluorinated Olefins Using N,P-Ligands:  A Struggle with Hydrogenolysis and Selectivity Mattias Engman, Jarle S. Diesen, Alexander Paptchikhine, and Pher G. Andersson pp 4536–4537 DOI: 10.1021/ja0686763 Supporting Info

Mesoporous Au/TiO2 Nanocomposites with Enhanced Photocatalytic Activity Hexing Li, Zhenfeng Bian, Jian Zhu, Yuning Huo, Hui Li, and Yunfeng Lu pp 4538–4539 DOI: 10.1021/ja069113u Supporting Info

A Diosphenol-Based Strategy for the Total Synthesis of (−)-Terpestacin Barry M. Trost, Guangbin Dong, and Jennifer A. Vance pp 4540–4541 DOI: 10.1021/ja070571s Supporting Info

On the Mechanism of Reaction of Radicals with Tirapazamine Xiaofeng Shi, Sarah M. Mandel, and Matthew S. Platz pp 4542–4550 DOI: 10.1021/ja0647405 Supporting Info

Alkylthio Bridged 44 cve Triangular Platinum Clusters:  Synthesis, Oxidation, Degradation, Ligand Substitution, and Quantum Chemical Calculations Christian Albrecht, Sebastian Schwieger, Clemens Bruhn, Christoph Wagner, Ralph Kluge, Harry Schmidt, and Dirk Steinborn pp 4551–4566 DOI: 10.1021/ja068476r Supporting Info

Cluster Growth and Fragmentation in the Highly Fluxional Platinum Derivatives of Sn94-:  Synthesis, Characterization, and Solution Dynamics of Pt2@Sn174- and Pt@Sn9H3- Banu Kesanli, Jordan E. Halsig, Peter Zavalij, James C. Fettinger, Yiu-Fai Lam, and Bryan W. Eichhorn pp 4567–4574 DOI: 10.1021/ja065764e Supporting Info

Binding of a Single Zinc Ion to One Subunit of Copper−Zinc Superoxide Dismutase Apoprotein Substantially Influences the Structure and Stability of the Entire Homodimeric Protein Soshanna Zittin Potter, Haining Zhu, Bryan Francis Shaw, Jorge A. Rodriguez, Peter A. Doucette, Se Hui Sohn, Armando Durazo, Kym F. Faull, Edith Butler Gralla, Aram M. Nersissian, and Joan Selverstone Valentine pp 4575–4583 DOI: 10.1021/ja066690+ Supporting Info

Anharmonic Vibrational Calculations Modeling the Raman Spectra of Intermediates in the Photoactive Yellow Protein (PYP) Photocycle Adeyemi A. Adesokan, Duohai Pan, Erick Fredj, Richard A. Mathies, and R. Benny Gerber pp 4584–4594 DOI: 10.1021/ja066903v Supporting Info

Multichromophoric Polyphenylene Dendrimers:  Toward Brilliant Light Emitters with an Increased Number of Fluorophores Ingo Oesterling and Klaus Müllen pp 4595–4605 DOI: 10.1021/ja067174m Supporting Info

Engineering Modular Protein Interaction Switches by Sequence Overlap Nathan A. Sallee, Brian J. Yeh, and Wendell A. Lim pp 4606–4611 DOI: 10.1021/ja0672728 Supporting Info

Synthesis of Nitric Oxide-Releasing Silica Nanoparticles Jae Ho Shin, Sara K. Metzger, and Mark H. Schoenfisch pp 4612–4619 DOI: 10.1021/ja0674338 Supporting Info

Red-, Blue-, or No-Shift in Hydrogen Bonds:  A Unified Explanation Jorly Joseph and Eluvathingal D. Jemmis pp 4620–4632 DOI: 10.1021/ja067545z Supporting Info

A Molecular Plug−Socket Connector Guillaume Rogez, Belén Ferrer Ribera, Alberto Credi, Roberto Ballardini, Maria Teresa Gandolfi, Vincenzo Balzani, Yi Liu, Brian H. Northrop, and J. Fraser Stoddart pp 4633–4642 DOI: 10.1021/ja067739e Supporting Info

Photobleaching Pathways in Single-Molecule FRET Experiments Xiangxu Kong, Eyal Nir, Kambiz Hamadani, and Shimon Weiss pp 4643–4654 DOI: 10.1021/ja068002s Supporting Info

Tetrachelate Porphyrin Chromophores for Metal Oxide Semiconductor Sensitization:  Effect of the Spacer Length and Anchoring Group Position Jonathan Rochford, Dorothy Chu, Anders Hagfeldt, and Elena Galoppini pp 4655–4665 DOI: 10.1021/ja068218u Supporting Info

Cyclopropylmethyl/Cyclobutyl Rearrangements on Surfaces:  Evidence for Transient Cation Formation near O-Covered Mo(110) Sean H. Wiedemann, Dae-Hyuk Kang, Robert G. Bergman, and Cynthia M. Friend pp 4666–4677 DOI: 10.1021/ja0682428 Supporting Info

Effect of Ions on the Hydrophobic Interaction between Two Plates Ronen Zangi, Morten Hagen, and B. J. Berne pp 4678–4686 DOI: 10.1021/ja068305m

Multinuclear Solid-State NMR Spectroscopy of Doped Lanthanum Fluoride Nanoparticles Andy Y. H. Lo, Vasanthakumaran Sudarsan, Sri Sivakumar, Frank van Veggel, and Robert W. Schurko pp 4687–4700 DOI: 10.1021/ja068604b Supporting Info

A Storable Encapsulated Bilayer Chip Containing a Single Protein Nanopore Xiao-feng Kang, Stephen Cheley, Allison C. Rice-Ficht, and Hagan Bayley pp 4701–4705 DOI: 10.1021/ja068654g

Base-Dependent Electron Photodetachment from Negatively Charged DNA Strands upon 260-nm Laser Irradiation Valérie Gabelica, Frédéric Rosu, Thibault Tabarin, Catherine Kinet, Rodolphe Antoine, Michel Broyer, Edwin De Pauw, and Philippe Dugourd pp 4706–4713 DOI: 10.1021/ja068440z Supporting Info

Surface-Mediated Nucleation in the Solid-State Polymorph Transformation of Terephthalic Acid Gregg T. Beckham, Baron Peters, Cindy Starbuck, Narayan Variankaval, and Bernhardt L. Trout pp 4714–4723 DOI: 10.1021/ja0687567 Supporting Info

Exploring Multiple Timescale Motions in Protein GB3 Using Accelerated Molecular Dynamics and NMR Spectroscopy Phineus R. L. Markwick, Guillaume Bouvignies, and Martin Blackledge pp 4724–4730 DOI: 10.1021/ja0687668 Supporting Info

A Water-Mediated and Substrate-Assisted Catalytic Mechanism for Sulfolobus solfataricus DNA Polymerase IV Lihua Wang, Xinyun Yu, Po Hu, Suse Broyde, and Yingkai Zhang pp 4731–4737 DOI: 10.1021/ja068821c Supporting Info

Spontaneous Pattern Formation Due to Modulation Instability of Incoherent White Light in a Photopolymerizable Medium Ian B. Burgess, Whitney E. Shimmell, and Kalaichelvi Saravanamuttu pp 4738–4746 DOI: 10.1021/ja068967b Supporting Info

meso-Aryl-Substituted Subporphyrins:  Synthesis, Structures, and Large Substituent Effects on Their Electronic Properties Yasuhide Inokuma, Zin Seok Yoon, Dongho Kim, and Atsuhiro Osuka pp 4747–4761 DOI: 10.1021/ja069324z Supporting Info

Total Synthesis of Dimeric Pyrrole−Imidazole Alkaloids:  Sceptrin, Ageliferin, Nagelamide E, Oxysceptrin, Nakamuric Acid, and the Axinellamine Carbon Skeleton Daniel P. O'Malley, Ke Li, Michael Maue, Alexandros L. Zografos, and Phil S. Baran pp 4762–4775 DOI: 10.1021/ja069035a Supporting Info

PRODAN-Conjugated DNA:  Synthesis and Photochemical Properties Kazuki Tainaka, Kazuo Tanaka, Shuji Ikeda, Ken-ichiro Nishiza, Tomo Unzai, Yoshimasa Fujiwara, Isao Saito, and Akimitsu Okamoto pp 4776–4784 DOI: 10.1021/ja069156a Supporting Info

Fluorescent Sensors for Specific RNA:  A General Paradigm Using Chemistry and Combinatorial Biology Brian A. Sparano and Kazunori Koide pp 4785–4794 DOI: 10.1021/ja070111z

Nucleophilic Addition to a p-Benzyne Derived from an Enediyne:  A New Mechanism for Halide Incorporation into Biomolecules Charles L. Perrin, Betsy L. Rodgers, and Joseph M. O'Connor pp 4795–4799 DOI: 10.1021/ja070023e Supporting Info

Molecular Mimicry Enables Competitive Recruitment by a Natively Disordered Protein Daniel A. Bonsor, Irina Grishkovskaya, Eleanor J. Dodson, and Colin Kleanthous pp 4800–4807 DOI: 10.1021/ja070153n

Carbohydrate-Coated Supramolecular Structures:  Transformation of Nanofibers into Spherical Micelles Triggered by Guest Encapsulation Ja-Hyoung Ryu, Eunji Lee, Yong-beom Lim, and Myongsoo Lee pp 4808–4814 DOI: 10.1021/ja070173p Supporting Info

Surface Chemistry of Five-Membered Aromatic Ring Molecules Containing Two Different Heteroatoms on Si(111)-7 × 7 Feng Tao and Steven L. Bernasek pp 4815–4823 DOI: 10.1021/ja070182y Supporting Info

Biaryl Synthesis via Pd-Catalyzed Decarboxylative Coupling of Aromatic Carboxylates with Aryl Halides Lukas J. Goossen, Nuria Rodríguez, Bettina Melzer, Christophe Linder, Guojun Deng, and Laura M. Levy pp 4824–4833 DOI: 10.1021/ja068993+

Bound-State Residual Dipolar Couplings for Rapidly Exchanging Ligands of His-Tagged Proteins Ronald D. Seidel III, Tiandi Zhuang, and James H. Prestegard pp 4834–4839 DOI: 10.1021/ja069145h

Dilithiation of Bis(benzene)molybdenum and Subsequent Isolation of a Molybdenum-Containing Paracyclophane Holger Braunschweig, Nele Buggisch, Ulli Englert, Melanie Homberger, Thomas Kupfer, Dirk Leusser, Matthias Lutz, and Krzysztof Radacki pp 4840–4846 DOI: 10.1021/ja0692130 Supporting Info

The Dewetting Transition and The Hydrophobic Effect Niharendu Choudhury and B. Montgomery Pettitt pp 4847–4852 DOI: 10.1021/ja069242a

Stereospecific Interaction between Immune Cells and Chiral Surfaces [J. Am. Chem. Soc. 2007, 129, 1496−1497]. Taolei Sun, Dong Han, Kristina Riehemann, Lifeng Chi, and Harald Fuchs p 4853 DOI: 10.1021/ja0768845

Bioactive Heterocycles I. Topics in Heterocyclic Chemistry, 06 Edited by Shoji Eguchi (Nagoya University, Japan). Series Edited by R. R. Gupta. Springer:  Berlin, Heidelberg, New York. 2006. xiv + 220 pp. $149.00. ISBN 3-540-33350-9. Gary Sulikowski p 4854 DOI: 10.1021/ja069821f

Marine Natural Products. Topics in Heterocyclic Chemistry, 05 Edited by Hiromasa Kiyota (Tohoku University, Sendai, Japan). Series Edited by R. R. Gupta. Springer:  Berlin, Heidelberg, New York. 2006. xiv + 288 pp. $169.00. ISBN 3-540-33728-8. José-Luis Giner pp 4854–4855 DOI: 10.1021/ja0698228

Fundamentals of Metallic Corrosion:  Atmospheric and Media Corrosion of Metals. Corrosion Engineering Handbook, 2nd ed By Philip A. Schweitzer (Consultant, York, PA). CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2007. xx + 728 pp. $99.95. ISBN 0-8493-8243-2. p 4855 DOI: 10.1021/ja076915w Supporting Info

Asymmetric Synthesis:  The Essentials Edited by Mathias Christmann (RWTH, Aachen, Germany) and Stefan Bräse (Technical University of Karlsruhe, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xl + 346 pp. $115.00. ISBN 978-3-527-31399-0. p 4855 DOI: 10.1021/ja0769301

Degradable Polymers and Materials:  Principles and Practice. ACS Symposium Series 939 Edited by Kishan Khemani (Plantic Technologies, Ltd., Santa Barbara, CA) and Carmen Scholz (University of Alabama, Huntsville). American Chemical Society:  Washingon, DC (distributed by Oxford University Press). 2006. xiv + 442 pp. $199.50. ISBN 0-8412-3972-X. p 4855 DOI: 10.1021/ja076935y

The Potential Distribution Theorem and Models of Molecular Solutions By Thomas L. Beck (University of Cincinnati), Michael E. Paulaitis (The Ohio State University and The Johns Hopkins University), and Lawrence L. Pratt (Los Alamos National Laboratory). Cambridge University Press:  Cambridge. 2006. xiv + 230 pp. $125.00. ISBN 0-521-82215-7. Douglas Henderson pp 4855–4856 DOI: 10.1021/ja069841h

Issue 16

Distinguishing among Structural Ensembles of the GB1 Peptide:  REMD Simulations and NMR Experiments Daniel S. Weinstock, Chitra Narayanan, Anthony K. Felts, Michael Andrec, Ronald M. Levy, Kuen-Phon Wu, and Jean Baum pp 4858–4859 DOI: 10.1021/ja0677517 Supporting Info

Thiamin Phosphate Synthase:  The Rate of Pyrimidine Carbocation Formation Jeremiah W. Hanes, Steven E. Ealick, and Tadhg P. Begley pp 4860–4861 DOI: 10.1021/ja0679634 Supporting Info

Oxygen Replacement with Selenium at the Thymidine 4-Position for the Se Base Pairing and Crystal Structure Studies Jozef Salon, Jia Sheng, Jiansheng Jiang, Guexiong Chen, Julianne Caton-Williams, and Zhen Huang pp 4862–4863 DOI: 10.1021/ja0680919 Supporting Info

Infrared Multiple Photon Dissociation Spectra of Proline and Glycine Proton-Bound Homodimers. Evidence for Zwitterionic Structure Ronghu Wu and Terry B. McMahon pp 4864–4865 DOI: 10.1021/ja068715a Supporting Info

Selective Suppression of Conductance in Metallic Carbon Nanotubes Hye-Mi So, Byoung-Kye Kim, Dong-Won Park, Beom Soo Kim, Ju-Jin Kim, Ki-jeong Kong, Hyunju Chang, and Jeong-O Lee pp 4866–4867 DOI: 10.1021/ja068738p Supporting Info

Pulsed ELDOR Determination of the Intramolecular Distance between the Metal Binding Sites in Dicupric Human Serum Transferrin and Lactoferrin Christopher W. M. Kay, Hassane El Mkami, Richard Cammack, and Robert W. Evans pp 4868–4869 DOI: 10.1021/ja068966j Supporting Info

Ultrafast Excited-State Dynamics of the Photoswitchable Protein Dronpa Eduard Fron, Cristina Flors, Gerd Schweitzer, Satoshi Habuchi, Hideaki Mizuno, Ryoko Ando, Frans C. De Schryver, Atsushi Miyawaki, and Johan Hofkens pp 4870–4871 DOI: 10.1021/ja069365v Supporting Info

Coordination-Driven Nanosized Lanthanide “Molecular Lantern” with Tunable Luminescent Properties Yu-Bin Dong, Peng Wang, Jian-Ping Ma, Xia-Xia Zhao, Hai-Ying Wang, Bo Tang, and Ru-Qi Huang pp 4872–4873 DOI: 10.1021/ja070058e Supporting Info

Lithographic Patterning of Photoreactive Cell-Adhesive Proteins Isaac S. Carrico, Stacey A. Maskarinec, Sarah C. Heilshorn, Marissa L. Mock, Julie C. Liu, Paul J. Nowatzki, Christian Franck, Guruswami Ravichandran, and David A. Tirrell pp 4874–4875 DOI: 10.1021/ja070200b Supporting Info

Self-Assembled Monolayers of Terminal Alkynes on Gold Sheng Zhang, Kusum L. Chandra, and Christopher B. Gorman pp 4876–4877 DOI: 10.1021/ja0704380 Supporting Info

Chemically-Responsive Sol−Gel Transition of Supramolecular Single-Walled Carbon Nanotubes (SWNTs) Hydrogel Made by Hybrids of SWNTs and Cyclodextrins Tomoki Ogoshi, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 4878–4879 DOI: 10.1021/ja070457+ Supporting Info

Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer Zhuojia Lin, Alexandra M. Z. Slawin, and Russell E. Morris pp 4880–4881 DOI: 10.1021/ja070671y Supporting Info

A Synthetic Nucleoside Probe that Discerns a DNA Adduct from Unmodified DNA Jiachang Gong and Shana J. Sturla pp 4882–4883 DOI: 10.1021/ja070688g Supporting Info

Fluorescent ADP Sensing in Physiological Conditions Based on Cooperative Inhibition of a Miniature Esterase Laurent Vial and Pascal Dumy pp 4884–4885 DOI: 10.1021/ja070734c Supporting Info

Morphology Control of Fluorescent Nanoaggregates by Co-Self-Assembly of Wedge- and Dumbbell-Shaped Amphiphilic Perylene Bisimides Xin Zhang, Zhijian Chen, and Frank Würthner pp 4886–4887 DOI: 10.1021/ja070994u Supporting Info

Cation-Dependent Compression Behavior in Low-Silica Zeolite-X Yongjae Lee, Hyun Hwi Lee, Dong Ryeol Lee, Tae Joo Shin, Jae-Young Choi, and Chi-Chang Kao pp 4888–4889 DOI: 10.1021/ja0710961

Langmuir−Blodgett Assembly of Densely Aligned Single-Walled Carbon Nanotubes from Bulk Materials Xiaolin Li, Li Zhang, Xinran Wang, Iwao Shimoyama, Xiaoming Sun, Won-Seok Seo, and Hongjie Dai pp 4890–4891 DOI: 10.1021/ja071114e Supporting Info

Enhancing Cell Adhesion and Confinement by Gradient Nanotopography Karen A. Simon, Erik A. Burton, Yongbin Han, Jun Li, Anny Huang, and Yan-Yeung Luk pp 4892–4893 DOI: 10.1021/ja0653472 Supporting Info

Internal Energy Deposition in Electron Capture Dissociation Measured Using Hydrated Divalent Metal Ions as Nanocalorimeters Ryan D. Leib, William A. Donald, Matthew F. Bush, Jeremy T. O'Brien, and Evan R. Williams pp 4894–4895 DOI: 10.1021/ja0666607

Engineered Biosynthesis of Macrolide Derivatives Bearing the Non-Natural Deoxysugars 4-epi-d-Mycaminose and 3-N-Monomethylamino-3-Deoxy-d-Fucose Charles E. Melançon III and Hung-wen Liu pp 4896–4897 DOI: 10.1021/ja068254t Supporting Info

Evidence for the Rapid Conversion of Stephacidin B into the Electrophilic Monomer Avrainvillamide in Cell Culture Jeremy E. Wulff, Seth B. Herzon, Romain Siegrist, and Andrew G. Myers pp 4898–4899 DOI: 10.1021/ja0690971 Supporting Info

syn-Selective Catalytic Asymmetric Nitro-Mannich Reactions Using a Heterobimetallic Cu−Sm−Schiff Base Complex Shinya Handa, Vijay Gnanadesikan, Shigeki Matsunaga, and Masakatsu Shibasaki pp 4900–4901 DOI: 10.1021/ja0701560 Supporting Info

A Subtype-Selective, Use-Dependent Inhibitor of Native AMPA Receptors Aaron Nilsen and Pamela M. England pp 4902–4903 DOI: 10.1021/ja0705801 Supporting Info

Chemical Modification of Monolayer-Protected Gold Nanoparticles Using Hyperbaric Conditions Jun Zhu, Michael D. Ganton, Michael A. Kerr, and Mark S. Workentin pp 4904–4905 DOI: 10.1021/ja070828m Supporting Info

A Palladium-Catalyzed Cyclization−Oxidation Sequence:  Synthesis of Bicyclo[3.1.0]hexanes and Evidence for SN2 C−O Bond Formation Xiaofeng Tong, Matthias Beller, and Man Kin Tse pp 4906–4907 DOI: 10.1021/ja070919j Supporting Info

Asymmetric Conjugate Alkenylation of Enones Catalyzed by Chiral Diols T. Robert Wu and J. Michael Chong pp 4908–4909 DOI: 10.1021/ja0713734 Supporting Info

A Nearly Isosteric Photosensitive Amide-Backbone Substitution Allows Enzyme Activity Switching in Ribonuclease S Dirk Wildemann, Cordelia Schiene-Fischer, Tobias Aumüller, Annett Bachmann, Thomas Kiefhaber, Christian Lücke, and Gunter Fischer pp 4910–4918 DOI: 10.1021/ja069048o Supporting Info

Specificity of Sites within Eight-Membered Ring Zeolite Channels for Carbonylation of Methyls to Acetyls Aditya Bhan, Ayman D. Allian, Glenn J. Sunley, David J. Law, and Enrique Iglesia pp 4919–4924 DOI: 10.1021/ja070094d Supporting Info

Disorder or Complexity? Understanding a Nanoscale Template Structure on Alumina Sebastian Gritschneder, Conrad Becker, Klaus Wandelt, and Michael Reichling pp 4925–4928 DOI: 10.1021/ja065118f Supporting Info

Molecular Electrodes at the Exposed Edge of Metal/Insulator/Metal Trilayer Structures Pawan Tyagi, Dongfeng Li, Stephen M. Holmes, and Bruce J. Hinds pp 4929–4938 DOI: 10.1021/ja065789d Supporting Info

Intramolecular Anionic Diels−Alder Reactions of 1-Aryl-4-oxahepta-1,6-diyne Systems in DMSO Takayuki Kudoh, Tomoko Mori, Mitsuhito Shirahama, Masashi Yamada, Teruhiko Ishikawa, Seiki Saito, and Hisayoshi Kobayashi pp 4939–4947 DOI: 10.1021/ja066485u Supporting Info

Catalytic Double Carbonylation of Epoxides to Succinic Anhydrides:  Catalyst Discovery, Reaction Scope, and Mechanism John M. Rowley, Emil B. Lobkovsky, and Geoffrey W. Coates pp 4948–4960 DOI: 10.1021/ja066901a Supporting Info

Targeted Drug Delivery Utilizing Protein-Like Molecular Architecture Evonne M. Rezler, David R. Khan, Janelle Lauer-Fields, Mare Cudic, Diane Baronas-Lowell, and Gregg B. Fields pp 4961–4972 DOI: 10.1021/ja066929m Supporting Info

Interfacial Supramolecular Self-Assembled Monolayers of C60 by Thiolated β-Cyclodextrin on Gold Surfaces via Monoanionic C60 Wei Liu, Yi Zhang, and Xiang Gao pp 4973–4980 DOI: 10.1021/ja067056z

BH3-Catalyzed Oligomerization of Ethyl Diazoacetate:  The Role of C-Boron Enolates Jie Bai, Lonnie D. Burke, and Kenneth J. Shea pp 4981–4991 DOI: 10.1021/ja067264r Supporting Info

Photosensitive Function of Encapsulated Dye in Carbon Nanotubes Kazuhiro Yanagi, Konstantin Iakoubovskii, Hiroyuki Matsui, Hiroyuki Matsuzaki, Hiroshi Okamoto, Yasumitsu Miyata, Yutaka Maniwa, Said Kazaoui, Nobutsugu Minami, and Hiromichi Kataura pp 4992–4997 DOI: 10.1021/ja067351j Supporting Info

Networks of Coupled Rotators:  Relationship between Structures and Internal Dynamics in Metal-Binding Proteins. Applications to apo- and holo-Calbindin Anne Dhulesia, Daniel Abergel, and Geoffrey Bodenhausen pp 4998–5006 DOI: 10.1021/ja067429w

Site- and Orientation-Selective Anchoring of a Prototypical Molecular Building Block Pascal Ruffieux, Krisztián Palotás, Oliver Gröning, Daniel Wasserfallen, Klaus Müllen, Werner A. Hofer, Pierangelo Gröning, and Roman Fasel pp 5007–5011 DOI: 10.1021/ja0673231

New Insights into the Mechanism of Triplet Radical-Pair Combinations. The Persistent Radical Effect Masks the Distinction between In-Cage and Out-of-Cage Processes Carlos A. Chesta, Jyotirmayee Mohanty, Werner M. Nau, Urbashi Bhattacharjee, and Richard G. Weiss pp 5012–5022 DOI: 10.1021/ja067461q Supporting Info

Bifunctional Binding of Cisplatin to DNA:  Why Does Cisplatin Form 1,2-Intrastrand Cross-Links with AG But Not with GA? Yogita Mantri, Stephen J. Lippard, and Mu-Hyun Baik pp 5023–5030 DOI: 10.1021/ja067631z Supporting Info

Kinetic and Computational Analysis of the Palladium(II)-Catalyzed Asymmetric Allylic Trichloroacetimidate Rearrangement:  Development of a Model for Enantioselectivity Mary P. Watson, Larry E. Overman, and Robert G. Bergman pp 5031–5044 DOI: 10.1021/ja0676962 Supporting Info

One-Dimensional Supramolecular Organization of Single-Molecule Magnets Lollita Lecren, Wolfgang Wernsdorfer, Yang-Guang Li, Alessandro Vindigni, Hitoshi Miyasaka, and Rodolphe Clérac pp 5045–5051 DOI: 10.1021/ja067744i Supporting Info

Use of p-Toluenesulfonic Acid for the Controlled Grafting of Alkoxysilanes onto Silanol Containing Surfaces:  Preparation of Tunable Hydrophilic, Hydrophobic, and Super-Hydrophobic Silica Nuria García, Esperanza Benito, Julio Guzmán, and Pilar Tiemblo pp 5052–5060 DOI: 10.1021/ja067987a

Single-Wall Carbon Nanotubes Bearing Covalently Linked Phthalocyanines − Photoinduced Electron Transfer Beatriz Ballesteros, Gema de la Torre, Christian Ehli, G. M. Aminur Rahman, F. Agulló-Rueda, Dirk M. Guldi, and Tomás Torres pp 5061–5068 DOI: 10.1021/ja068240n Supporting Info

Proton-Directed Redox Control of O−O Bond Activation by Heme Hydroperoxidase Models Jake D. Soper, Sergey V. Kryatov, Elena V. Rybak-Akimova, and Daniel G. Nocera pp 5069–5075 DOI: 10.1021/ja0683032 Supporting Info

Hybrid Gadolinium Oxide Nanoparticles:  Multimodal Contrast Agents for in Vivo Imaging Jean-Luc Bridot, Anne-Charlotte Faure, Sophie Laurent, Charlotte Rivière, Claire Billotey, Bassem Hiba, Marc Janier, Véronique Josserand, Jean-Luc Coll, Luce Vander Elst, Robert Muller, Stéphane Roux, Pascal Perriat, and Olivier Tillement pp 5076–5084 DOI: 10.1021/ja068356j

Nickel-Specific Response in the Transcriptional Regulator, Escherichia coli NikR Sharon Leitch, Michael J. Bradley, Jessica L. Rowe, Peter T. Chivers, and Michael J. Maroney pp 5085–5095 DOI: 10.1021/ja068505y Supporting Info

Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen Timothy E. Barder and Stephen L. Buchwald pp 5096–5101 DOI: 10.1021/ja0683180 Supporting Info

Substrate Flexibility of Vicenisaminyltransferase VinC Involved in the Biosynthesis of Vicenistatin Atsushi Minami and Tadashi Eguchi pp 5102–5107 DOI: 10.1021/ja0685250 Supporting Info

Ultrahigh-Resolution 1H−13C HSQC Spectra of Metabolite Mixtures Using Nonlinear Sampling and Forward Maximum Entropy Reconstruction Sven G. Hyberts, Gregory J. Heffron, Nestor G. Tarragona, Kirty Solanky, Katherine A. Edmonds, Harry Luithardt, Jasna Fejzo, Michael Chorev, Huseyin Aktas, Kimberly Colson, Kenneth H. Falchuk, Jose A. Halperin, and Gerhard Wagner pp 5108–5116 DOI: 10.1021/ja068541x

Solid-State NMR Study of Amyloid Nanocrystals and Fibrils Formed by the Peptide GNNQQNY from Yeast Prion Protein Sup35p Patrick C. A. van der Wel, Józef R. Lewandowski, and Robert G. Griffin pp 5117–5130 DOI: 10.1021/ja068633m Supporting Info

212Pb@C60 and Its Water-Soluble Derivatives:  Synthesis, Stability, and Suitability for Radioimmunotherapy Michael D. Diener, John M. Alford, Stephen J. Kennel, and Saed Mirzadeh pp 5131–5138 DOI: 10.1021/ja068639b

Systematic Studies of Early Actinide Complexes:  Thorium(IV) Fluoroketimides Eric J. Schelter, Ping Yang, Brian L. Scott, Ryan E. Da Re, Kimberly C. Jantunen, Richard L. Martin, P. Jeffrey Hay, David E. Morris, and Jaqueline L. Kiplinger pp 5139–5152 DOI: 10.1021/ja0686458 Supporting Info

Large Ground-State Entropy Changes for Hydrogen Atom Transfer Reactions of Iron Complexes Elizabeth A. Mader, Ernest R. Davidson, and James M. Mayer pp 5153–5166 DOI: 10.1021/ja0686918 Supporting Info

The Synthesis of Dichlorodiazirine and the Generation of Dichlorocarbene:  Spectroscopy and Structure of Dichlorocarbene Ylides Robert A. Moss, Jingzhi Tian, Ronald R. Sauers, Daniel H. Ess, Kendall N. Houk, and Karsten Krogh-Jespersen pp 5167–5174 DOI: 10.1021/ja068727w Supporting Info

Ruthenium-Catalyzed Reactions of 1-Cyclopropyl-2-propyn-1-ols with Anilines and Water via Allenylidene Intermediates:  Selective Preparation of Tri- and Tetrasubstituted Conjugated Enynes Yoshihiro Yamauchi, Gen Onodera, Ken Sakata, Masahiro Yuki, Yoshihiro Miyake, Sakae Uemura, and Yoshiaki Nishibayashi pp 5175–5179 DOI: 10.1021/ja0687926 Supporting Info

Mechanistic Insight into Hydrosilylation Reactions Catalyzed by High Valent ReX (X = O, NAr, or N) Complexes:  The Silane (SiH) Does Not Add across the Metal−Ligand Multiple Bond Guodong Du, Phillip E. Fanwick, and Mahdi M. Abu-Omar pp 5180–5187 DOI: 10.1021/ja068872+ Supporting Info

Two-Photon Absorption in Tetraphenylporphycenes:  Are Porphycenes Better Candidates than Porphyrins for Providing Optimal Optical Properties for Two-Photon Photodynamic Therapy? Jacob Arnbjerg, Ana Jiménez-Banzo, Martin J. Paterson, Santi Nonell, José I. Borrell, Ove Christiansen, and Peter R. Ogilby pp 5188–5199 DOI: 10.1021/ja0688777 Supporting Info

Modulation of Innate Immune Responses with Synthetic Lipid A Derivatives Yanghui Zhang, Jidnyasa Gaekwad, Margreet A. Wolfert, and Geert-Jan Boons pp 5200–5216 DOI: 10.1021/ja068922a Supporting Info

A Definitive Example of a Geometric “Entatic State” Effect:  Electron-Transfer Kinetics for a Copper(II/I) Complex Involving A Quinquedentate Macrocyclic Trithiaether−Bipyridine Ligand Gezahegn Chaka, Jason L. Sonnenberg, H. Bernhard Schlegel, Mary Jane Heeg, Gregory Jaeger, Timothy J. Nelson, L. A. Ochrymowycz, and D. B. Rorabacher pp 5217–5227 DOI: 10.1021/ja068960u Supporting Info

Mapping the Orientation of Helices in Micelle-Bound Peptides by Paramagnetic Relaxation Waves Michal Respondek, Tobias Madl, Christoph Göbl, Regina Golser, and Klaus Zangger pp 5228–5234 DOI: 10.1021/ja069004f Supporting Info

Highly Populated Turn Conformations in Natively Unfolded Tau Protein Identified from Residual Dipolar Couplings and Molecular Simulation Marco D. Mukrasch, Phineus Markwick, Jacek Biernat, Martin von Bergen, Pau Bernadó, Christian Griesinger, Eckhard Mandelkow, Markus Zweckstetter, and Martin Blackledge pp 5235–5243 DOI: 10.1021/ja0690159 Supporting Info

Self-Duplex Formation of an APy-Substituted Oligodeoxyadenylate and Its Unique Fluorescence Young Jun Seo, Hanju Rhee, Taiha Joo, and Byeang Hyean Kim pp 5244–5247 DOI: 10.1021/ja069069i Supporting Info

Real-Time Observation of the Photoinduced Structural Change of Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) by Femtosecond Fluorescence Spectroscopy:  A Realistic Potential Curve of the Jahn−Teller Distortion Munetaka Iwamura, Satoshi Takeuchi, and Tahei Tahara pp 5248–5256 DOI: 10.1021/ja069300s Supporting Info

Synthesis and Exfoliation of Co2+−Fe3+ Layered Double Hydroxides:  An Innovative Topochemical Approach Renzhi Ma, Zhaoping Liu, Kazunori Takada, Nobuo Iyi, Yoshio Bando, and Takayoshi Sasaki pp 5257–5263 DOI: 10.1021/ja0693035 Supporting Info

Indium-Catalyzed 2-Alkenylation of 1,3-Dicarbonyl Compounds with Unactivated Alkynes Kohei Endo, Takuji Hatakeyama, Masaharu Nakamura, and Eiichi Nakamura pp 5264–5271 DOI: 10.1021/ja0702014 Supporting Info

DNA Metastability and Biological Regulation:  Conformational Dynamics of Metastable Ω-DNA Bulge Loops Jens Völker, Horst H. Klump, and Kenneth J. Breslauer pp 5272–5280 DOI: 10.1021/ja070258q Supporting Info

Hydroxyapatite Surface-Induced Peptide Folding Lisa A. Capriotti, Thomas P. Beebe, Jr., and Joel P. Schneider pp 5281–5287 DOI: 10.1021/ja070356b Supporting Info

An Aryl to Imidoyl Palladium Migration Process Involving Intramolecular C−H Activation Jian Zhao, Dawei Yue, Marino A. Campo, and Richard C. Larock pp 5288–5295 DOI: 10.1021/ja070657l Supporting Info

March's Advanced Organic Chemistry:  Reactions, Mechanisms, and Structure, 6th ed By Michael B. Smith (University of Connecticut, Storrs, CT) and Jerry March (Adelphi University, Garden City, NY, now deceased). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xxii + 2358 pp. $99.95. ISBN 0-471-72091-7. p 5296 DOI: 10.1021/ja076913b

Hawley's Condensed Chemical Dictionary, 15th ed By Richard J. Lewis, Sr. John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 1380 pp. $150.00. ISBN 978-0-471-76865-4. p 5296 DOI: 10.1021/ja0769144

Molecular Organic Materials:  From Molecules to Crystalline Solids By Jordi Fraxedas (Institut de Ciència de Materials de Barcelona, CSIC, Spain). Cambridge University Press:  Cambridge. 2006. xx + 336 pp. $125.00. ISBN 0-521-83446-5. James D. Wuest pp 5296–5297 DOI: 10.1021/ja0697774

Transition State Differences in Hydrolysis Reactions of Alkyl versus Aryl Phosphate Monoester Monoanions [J. Am. Chem. Soc. 2003, 125, 13106−13111]. Piotr K. Grzyska, Przemyslaw G. Czyryca, Jamie Purcell, and Alvan C. Hengge p 5298 DOI: 10.1021/ja071527f

Vanadium-Catalyzed Asymmetric Epoxidation of Homoallylic Alcohols [J. Am. Chem. Soc. 2007, 129, 286−287]. Wei Zhang and Hisashi Yamamoto p 5298 DOI: 10.1021/ja076883c Supporting Info

Rates of Oxygen Exchange between the [HxNb6O19]8-x(aq) Lindqvist Ion and Aqueous Solutions [J. Am. Chem. Soc. 2006, 128, 14712−14720]. Jay R. Black, May Nyman, and William H. Casey p 5298 DOI: 10.1021/ja076885x

Reactivation of the p53 Tumor Suppressor Pathway by a Stapled p53 Peptide [J. Am. Chem. Soc. 2007, 129, 2456−2457]. Federico Bernal, Andrew F. Tyler, Stanley J. Korsmeyer, Loren D. Walensky, and Gregory L. Verdine p 5298 DOI: 10.1021/ja076886p

Issue 17

3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage Koji Harano, Shuichi Hiraoka, and Mitsuhiko Shionoya pp 5300–5301 DOI: 10.1021/ja0659727 Supporting Info

Intermolecular Activation of C−X (X = H, O, F) Bonds by a TiCtBu Linkage Brad C. Bailey, John C. Huffman, and Daniel J. Mindiola pp 5302–5303 DOI: 10.1021/ja0684646 Supporting Info

Uniformly Aligned Full-Length Membrane Proteins in Liquid Crystalline Bilayers for Structural Characterization Conggang Li, Philip Gao, Huajun Qin, Rose Chase, Peter L. Gor'kov, William W. Brey, and Timothy A. Cross pp 5304–5305 DOI: 10.1021/ja068402f Supporting Info

Membrane-Grafted Hyaluronan Films:  A Well-Defined Model System of Glycoconjugate Cell Coats Ralf P. Richter, Kai K. Hock, Jeffrey Burkhartsmeyer, Heike Boehm, Pit Bingen, Guoliang Wang, Nicole F. Steinmetz, David J. Evans, and Joachim P. Spatz pp 5306–5307 DOI: 10.1021/ja068768s Supporting Info

Environmental Modulation of Protein Cation-π Interactions Bruce W. Berry, Margaret M. Elvekrog, and Cecilia Tommos pp 5308–5309 DOI: 10.1021/ja068957a Supporting Info

Polymerase-Directed Synthesis of 2‘-Deoxy-2‘-fluoro-β-D-arabinonucleic Acids Chang G. Peng and Masad J. Damha pp 5310–5311 DOI: 10.1021/ja069100g Supporting Info

Magnetic Bistability and Single-Crystal-to-Single-Crystal Transformation Induced by Guest Desorption Masayuki Nihei, Lingqin Han, and Hiroki Oshio pp 5312–5313 DOI: 10.1021/ja069120i Supporting Info

Hydrogen Storage in a Prototypical Zeolitic Imidazolate Framework-8 Hui Wu, Wei Zhou, and Taner Yildirim pp 5314–5315 DOI: 10.1021/ja0691932 Supporting Info

Photochemical Gating of Intracellular Ca2+ Release Channels Jiahong Ni, Darryl A. Auston, David A. Freilich, Sukumaran Muralidharan, Eric A. Sobie, and Joseph P. Y. Kao pp 5316–5317 DOI: 10.1021/ja069361q Supporting Info

Chemical-Shift Anisotropy Measurements of Amide and Carbonyl Resonances in a Microcrystalline Protein with Slow Magic-Angle Spinning NMR Spectroscopy Benjamin J. Wylie, Lindsay J. Sperling, Heather L. Frericks, Gautam J. Shah, W. Trent Franks, and Chad M. Rienstra pp 5318–5319 DOI: 10.1021/ja0701199 Supporting Info

Redox Regulation of Protein Tyrosine Phosphatase 1B by Peroxymonophosphate (O3POOH) Jason N. LaButti, Goutam Chowdhury, Thomas J. Reilly, and Kent S. Gates pp 5320–5321 DOI: 10.1021/ja070194j Supporting Info

Solid-Phase Synthesis of Oxathiocoraline by a Key Intermolecular Disulfide Dimer Judit Tulla-Puche, Núria Bayó-Puxan, Juan A. Moreno, Andrés M. Francesch, Carmen Cuevas, Mercedes Álvarez, and Fernando Albericio pp 5322–5323 DOI: 10.1021/ja0686312 Supporting Info

Trapping Metal-Organic Framework Nanocrystals:  An in-Situ Time-Resolved Light Scattering Study on the Crystal Growth of MOF-5 in Solution Stephan Hermes, Thomas Witte, Todor Hikov, Denise Zacher, Stefan Bahnmüller, Gerhard Langstein, Klaus Huber, and Roland A. Fischer pp 5324–5325 DOI: 10.1021/ja068835i Supporting Info

A Polyoxometalate-Assisted Electrochemical Method for Silicon Nanostructures Preparation:  From Quantum Dots to Nanowires Zhenhui Kang, Chi Him A. Tsang, Zhendong Zhang, Mingliang Zhang, Ning-bew Wong, J. Antonio Zapien, Yueyue Shan, and Shuit-Tong Lee pp 5326–5327 DOI: 10.1021/ja068894w Supporting Info

Design of Chiral Auxiliaries for the Allene Ether Nazarov Cyclization April R. Banaag and Marcus A. Tius pp 5328–5329 DOI: 10.1021/ja069342g Supporting Info

Direct Measurements of Deuterium Kinetic Isotope Effects in Anionic, Gas-Phase Substitution and Elimination Reactions Scott Gronert, Adelaide E. Fagin, and Lawrence Wong pp 5330–5331 DOI: 10.1021/ja070093l Supporting Info

Rh(I)-Catalyzed Alkylation of Quinolines and Pyridines via C−H Bond Activation Jared C. Lewis, Robert G. Bergman, and Jonathan A. Ellman pp 5332–5333 DOI: 10.1021/ja070388z Supporting Info

Highly Stereoselective Formal [3 + 3] Cycloaddition of Enals and Azomethine Imines Catalyzed by N-Heterocyclic Carbenes Audrey Chan and Karl A. Scheidt pp 5334–5335 DOI: 10.1021/ja0709167 Supporting Info

Design of C2-Symmetric Tetrahydropentalenes as New Chiral Diene Ligands for Highly Enantioselective Rh-Catalyzed Arylation of N-Tosylarylimines with Arylboronic Acids Zhi-Qian Wang, Chen-Guo Feng, Ming-Hua Xu, and Guo-Qiang Lin pp 5336–5337 DOI: 10.1021/ja0710914 Supporting Info

Extraordinarily High Zr4+ Ion Conducting Solid Nobuhito Imanaka, Shinji Tamura, and Tetsushi Itano pp 5338–5339 DOI: 10.1021/ja070293x Supporting Info

Tunable-Alignment Chiral System Based on Gelatin for NMR Spectroscopy Christoph Naumann, William A. Bubb, Bogdan E. Chapman, and Philip W. Kuchel pp 5340–5341 DOI: 10.1021/ja070348v

Photosensitization via Dye Coordination:  A New Strategy to Synthesize Metal Nitrosyls That Release NO under Visible Light Michael J. Rose, Marilyn M. Olmstead, and Pradip K. Mascharak pp 5342–5343 DOI: 10.1021/ja070247x Supporting Info

Biophysical Characterization of a β-Peptide Bundle:  Comparison to Natural Proteins E. James Petersson, Cody J. Craig, Douglas S. Daniels, Jade X. Qiu, and Alanna Schepartz pp 5344–5345 DOI: 10.1021/ja070567g Supporting Info

Dielectric Anisotropy of a Homochiral Trinuclear Nickel(II) Complex Da-Wei Fu, Yu-Mei Song, Guo-Xi Wang, Qiong Ye, Ren-Gen Xiong, Tomoyuki Akutagawa, Takayoshi Nakamura, Philip Wai Hong Chan, and Songping D. Huang pp 5346–5347 DOI: 10.1021/ja0701816 Supporting Info

Oxidation of M4Si4 (M = Na, K) to Clathrates by HCl or H2O Bodo Böhme, Arnold Guloy, Zhongjia Tang, Walter Schnelle, Ulrich Burkhardt, Michael Baitinger, and Yuri Grin pp 5348–5349 DOI: 10.1021/ja0705691 Supporting Info

26-Ring-Channel Structure Constructed from Bimetal Phosphite Helical Chains Yu-Lun Lai, Kwang-Hwa Lii, and Sue-Lein Wang pp 5350–5351 DOI: 10.1021/ja070733k Supporting Info

Synthesis and X-ray Absorption Spectroscopy Structural Studies of Cu(I) Complexes of HistidylHistidine Peptides:  The Predominance of Linear 2-Coordinate Geometry Richard A. Himes, Ga Young Park, Amanda N. Barry, Ninian J. Blackburn, and Kenneth D. Karlin pp 5352–5353 DOI: 10.1021/ja0708013 Supporting Info

Thermal Control over the Topology of Cleavable Polymers:  From Linear to Hyperbranched Structures Chun-Yan Hong, Ye-Zi You, De-Cheng Wu, Ye Liu, and Cai-Yuan Pan pp 5354–5355 DOI: 10.1021/ja070871+ Supporting Info

Versatile Solid Phase Synthesis of Gold Nanoparticle Dimers Using an Asymmetric Functionalization Approach Rajesh Sardar, Tyler B. Heap, and Jennifer S. Shumaker-Parry pp 5356–5357 DOI: 10.1021/ja070933w Supporting Info

Lipid Transmembrane Asymmetry and Intrinsic Membrane Potential:  Two Sides of the Same Coin Andrey A. Gurtovenko and Ilpo Vattulainen pp 5358–5359 DOI: 10.1021/ja070949m

A Lanthanide−Gallium Complex Stabilized by the N-Heterocyclic Carbene Group Polly L. Arnold, Stephen T. Liddle, Jonathan McMaster, Cameron Jones, and David P. Mills pp 5360–5361 DOI: 10.1021/ja0710858 Supporting Info

A Protein Nanocarrier from Charge-Conversion Polymer in Response to Endosomal pH Yan Lee, Shigeto Fukushima, Younsoo Bae, Shigehiro Hiki, Takehiko Ishii, and Kazunori Kataoka pp 5362–5363 DOI: 10.1021/ja071090b Supporting Info

Chiral Calcium Complexes as Brønsted Base Catalysts for Asymmetric Addition of α-Amino Acid Derivatives to α,β-Unsaturated Carbonyl Compounds Susumu Saito, Tetsu Tsubogo, and Shū Kobayashi pp 5364–5365 DOI: 10.1021/ja0709730 Supporting Info

Substrate Profiling of Protein Tyrosine Phosphatase PTP1B by Screening a Combinatorial Peptide Library Mathieu Garaud and Dehua Pei pp 5366–5367 DOI: 10.1021/ja071275i Supporting Info

X-Shaped Rigid Arylethynes to Mediate the Assembly of Nanoparticles I-Im S. Lim, Christopher Vaiana, Zhi-Yang Zhang, Ying-Jun Zhang, De-Lie An, and Chuan-Jian Zhong pp 5368–5369 DOI: 10.1021/ja071280m Supporting Info

Azide-Modified Graphitic Surfaces for Covalent Attachment of Alkyne-Terminated Molecules by “Click” Chemistry Anando Devadoss and Christopher E. D. Chidsey pp 5370–5371 DOI: 10.1021/ja071291f Supporting Info

Selective Activation and Functionalization of Linear Alkanes Initiated under Ambient Conditions by a Tungsten Allyl Nitrosyl Complex Jenkins Y. K. Tsang, Miriam S. A. Buschhaus, and Peter Legzdins pp 5372–5373 DOI: 10.1021/ja0713633 Supporting Info

Unbiased Cold Denaturation:  Low- and High-Temperature Unfolding of Yeast Frataxin under Physiological Conditions Annalisa Pastore, Stephen R. Martin, Anastasia Politou, Kalyan C. Kondapalli, Timothy Stemmler, and Piero A. Temussi pp 5374–5375 DOI: 10.1021/ja0714538

Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents Hongjun Ren, Guillaume Dunet, Peter Mayer, and Paul Knochel pp 5376–5377 DOI: 10.1021/ja071380s Supporting Info

The Acylation Mechanism of CTX-M β-Lactamase at 0.88 Å Resolution Yu Chen, Richard Bonnet, and Brian K. Shoichet pp 5378–5380 DOI: 10.1021/ja0712064

Kedarcidin Chromophore:  Synthesis of Its Proposed Structure and Evidence for a Stereochemical Revision Feng Ren, Philip C. Hogan, Alan J. Anderson, and Andrew G. Myers pp 5381–5383 DOI: 10.1021/ja071205b Supporting Info

DNA Alkylation by Pyrrole−Imidazole seco-CBI Conjugates with an Indole Linker:  Sequence-Specific DNA Alkylation with 10-Base-Pair Recognition through Heterodimer Formation Masafumi Minoshima, Toshikazu Bando, Shunta Sasaki, Ken-ichi Shinohara, Tatsuhiko Shimizu, Jun Fujimoto, and Hiroshi Sugiyama pp 5384–5390 DOI: 10.1021/ja065235a Supporting Info

Single Crystal 55Mn ENDOR of Concanavalin A:  Detection of Two Mn2+ Sites with Different 55Mn Quadrupole Tensors Kuppala V. Narasimhulu, Raanan Carmieli, and Daniella Goldfarb pp 5391–5402 DOI: 10.1021/ja0662826 Supporting Info

Are Carboxyl Groups the Most Acidic Sites in Amino Acids? Gas-Phase Acidity, H/D Exchange Experiments, and Computations on Cysteine and Its Conjugate Base Zhixin Tian, Anna Pawlow, John C. Poutsma, and Steven R. Kass pp 5403–5407 DOI: 10.1021/ja0666194 Supporting Info

Ultrafast Proton Transfer to Solvent:  Molecularity and Intermediates from Solvation- and Diffusion-Controlled Regimes J. L. Pérez-Lustres, F. Rodriguez-Prieto, M. Mosquera, T. A. Senyushkina, N. P. Ernsting, and S. A. Kovalenko pp 5408–5418 DOI: 10.1021/ja0664990 Supporting Info

The Origins of Femtomolar Protein−Ligand Binding:  Hydrogen-Bond Cooperativity and Desolvation Energetics in the Biotin−(Strept)Avidin Binding Site Jason DeChancie and K. N. Houk pp 5419–5429 DOI: 10.1021/ja066950n Supporting Info

Evidence for Sevenfold Coordination in the First Solvation Shell of Hg(II) Aqua Ion Giovanni Chillemi, Giordano Mancini, Nico Sanna, Vincenzo Barone, Stefano Della Longa, Maurizio Benfatto, Nicolae V. Pavel, and Paola D'Angelo pp 5430–5436 DOI: 10.1021/ja066943z Supporting Info

Detection of MicroRNAs Using Target-Guided Formation of Conducting Polymer Nanowires in Nanogaps Yi Fan, Xiantong Chen, Alastair D. Trigg, Chih-hang Tung, Jinming Kong, and Zhiqiang Gao pp 5437–5443 DOI: 10.1021/ja067477g

Foldamers as Reactive Sieves:  Reactivity as a Probe of Conformational Flexibility Ronald A. Smaldone and Jeffrey S. Moore pp 5444–5450 DOI: 10.1021/ja067670a Supporting Info

Secretory Phospholipase A2 Hydrolysis of Phospholipid Analogues Is Dependent on Water Accessibility to the Active Site Günther H. Peters, Martin S. Møller, Kent Jørgensen, Petra Rönnholm, Mette Mikkelsen, and Thomas L. Andresen pp 5451–5461 DOI: 10.1021/ja067755b Supporting Info

Hierarchical Assembly of Model Cell Surfaces:  Synthesis of Mucin Mimetic Polymers and Their Display on Supported Bilayers David Rabuka, Raghuveer Parthasarathy, Goo Soo Lee, Xing Chen, Jay T. Groves, and Carolyn R. Bertozzi pp 5462–5471 DOI: 10.1021/ja067819i Supporting Info

Tetraazachlorin−Fullerene Conjugates:  On−Off Control of Electronic Communication Enabled by Push−Pull Substituents Takamitsu Fukuda, Satoshi Masuda, and Nagao Kobayashi pp 5472–5479 DOI: 10.1021/ja0678323 Supporting Info

Hydrogels Coupled with Self-Assembled Monolayers:  An in Vitro Matrix To Study Calcite Biomineralization Hanying Li and Lara A. Estroff pp 5480–5483 DOI: 10.1021/ja067901d Supporting Info

Spin-State Selective Carbon-Detected HNCO with TROSY Optimization in All Dimensions and Double Echo−Antiecho Sensitivity Enhancement in Both Indirect Dimensions Kaifeng Hu, Beat Vögeli, and G. Marius Clore pp 5484–5491 DOI: 10.1021/ja067981l Supporting Info

On the Theory of Organic Catalysis “on Water” Yousung Jung and R. A. Marcus pp 5492–5502 DOI: 10.1021/ja068120f Supporting Info

4-Aryl-1,3,2-oxathiazolylium-5-olates as pH-Controlled NO-Donors:  The Next Generation of S-Nitrosothiols Dongning Lu, Janos Nadas, Guisheng Zhang, Wesley Johnson, Jay L. Zweier, Arturo J. Cardounel, Frederick A. Villamena, and Peng George Wang pp 5503–5514 DOI: 10.1021/ja0682226 Supporting Info

Neutral Organic Mixed-Valence Compounds:  Synthesis and All-Optical Evaluation of Electron-Transfer Parameters Alexander Heckmann and Christoph Lambert pp 5515–5527 DOI: 10.1021/ja068235j Supporting Info

Structural Analysis of Charge Discrimination in the Binding of Inhibitors to Human Carbonic Anhydrases I and II D. K. Srivastava, Kevin M. Jude, Abir L. Banerjee, Manas Haldar, Sumathra Manokaran, Joel Kooren, Sanku Mallik, and David W. Christianson pp 5528–5537 DOI: 10.1021/ja068359w

Reversible Photoswitching of Ferromagnetic FePt Nanoparticles at Room Temperature Masayuki Suda, Masaru Nakagawa, Tomokazu Iyoda, and Yasuaki Einaga pp 5538–5543 DOI: 10.1021/ja0682374 Supporting Info

Circular DNA and DNA/RNA Hybrid Molecules as Scaffolds for Ricin Inhibitor Design Matthew B. Sturm, Setu Roday, and Vern L. Schramm pp 5544–5550 DOI: 10.1021/ja068054h Supporting Info

Minor Groove Hydrogen Bonds and the Replication of Unnatural Base Pairs Shigeo Matsuda, Aaron M. Leconte, and Floyd E. Romesberg pp 5551–5557 DOI: 10.1021/ja068282b Supporting Info

Macrocyclic β-Sheet Peptides That Mimic Protein Quaternary Structure through Intermolecular β-Sheet Interactions Omid Khakshoor, Borries Demeler, and James S. Nowick pp 5558–5569 DOI: 10.1021/ja068511u Supporting Info

Simultaneous Measurement of Orientational and Spectral Dynamics of Single Molecules in Nanostructured Host−Guest Materials Christophe Jung, Christian Hellriegel, Barbara Platschek, Dieter Wöhrle, Thomas Bein, Jens Michaelis, and Christoph Bräuchle pp 5570–5579 DOI: 10.1021/ja0684850

para-Hydrogen-Induced Polarization in Heterogeneous Hydrogenation Reactions Igor V. Koptyug, Kirill V. Kovtunov, Scott R. Burt, M. Sabieh Anwar, Christian Hilty, Song-I Han, Alexander Pines, and Renad Z. Sagdeev pp 5580–5586 DOI: 10.1021/ja068653o

Heterolytic Activation of H−X (X = H, Si, B, and C) Bonds:  An Experimental and Theoretical Investigation C. M. Nagaraja, Pattiyil Parameswaran, Eluvathingal D. Jemmis, and Balaji R. Jagirdar pp 5587–5596 DOI: 10.1021/ja069044j Supporting Info

Design and Synthesis of a Library of BODIPY-Based Environmental Polarity Sensors Utilizing Photoinduced Electron-Transfer-Controlled Fluorescence ON/OFF Switching Hisato Sunahara, Yasuteru Urano, Hirotatsu Kojima, and Tetsuo Nagano pp 5597–5604 DOI: 10.1021/ja068551y Supporting Info

A Meta Effect in Organic Photochemistry? The Case of SN1 Reactions in Methoxyphenyl Derivatives Valentina Dichiarante, Daniele Dondi, Stefano Protti, Maurizio Fagnoni, and Angelo Albini pp 5605–5611 DOI: 10.1021/ja068647s Supporting Info

Direct Labeling of 5-Methylcytosine and Its Applications Kazuo Tanaka, Kazuki Tainaka, Taku Kamei, and Akimitsu Okamoto pp 5612–5620 DOI: 10.1021/ja068660c

Direct Measurement by Laser Flash Photolysis of Intraprotein Electron Transfer in a Rat Neuronal Nitric Oxide Synthase Changjian Feng, Gordon Tollin, James T. Hazzard, Nickolas J. Nahm, J. Guy Guillemette, John C. Salerno, and Dipak K. Ghosh pp 5621–5629 DOI: 10.1021/ja068685b

Shell-Cross-Linked Cylindrical Polyisoprene-b-Polyferrocenylsilane (PI-b-PFS) Block Copolymer Micelles:  One-Dimensional (1D) Organometallic Nanocylinders Xiaosong Wang, Kun Liu, André C. Arsenault, David A. Rider, Geoffrey A. Ozin, Mitchell A. Winnik, and Ian Manners pp 5630–5639 DOI: 10.1021/ja068730f Supporting Info

Gas Sensing Mechanism in Chemiresistive Cobalt and Metal-Free Phthalocyanine Thin Films Forest I. Bohrer, Amos Sharoni, Corneliu Colesniuc, Jeongwon Park, Ivan K. Schuller, Andrew C. Kummel, and William C. Trogler pp 5640–5646 DOI: 10.1021/ja0689379

Functional Molecules from Single Wall Carbon Nanotubes. Photoinduced Solubility of Short Single Wall Carbon Nanotube Residues by Covalent Anchoring of 2,4,6-Triarylpyrylium Units Mercedes Alvaro, Carmela Aprile, Belen Ferrer, and Hermenegildo Garcia pp 5647–5655 DOI: 10.1021/ja0690520

Structural Characterization of Flexible Proteins Using Small-Angle X-ray Scattering Pau Bernadó, Efstratios Mylonas, Maxim V. Petoukhov, Martin Blackledge, and Dmitri I. Svergun pp 5656–5664 DOI: 10.1021/ja069124n Supporting Info

Polyfluorinated Amino Acids for Sensitive 19F NMR-Based Screening and Kinetic Measurements Gianluca Papeo, Patrizia Giordano, Maria Gabriella Brasca, Ferdinando Buzzo, Dannica Caronni, Franco Ciprandi, Nicola Mongelli, Marina Veronesi, Anna Vulpetti, and Claudio Dalvit pp 5665–5672 DOI: 10.1021/ja069128s Supporting Info

Protein Folding Kinetics:  Barrier Effects in Chemical and Thermal Denaturation Experiments Athi N. Naganathan, Urmi Doshi, and Victor Muñoz pp 5673–5682 DOI: 10.1021/ja0689740

Sapphyrin−Nanotube Assemblies Peter J. Boul, Dong-Gyu Cho, G. M. Aminur Rahman, Manuel Marquez, Zhongping Ou, Karl M. Kadish, Dirk M. Guldi, and Jonathan L. Sessler pp 5683–5687 DOI: 10.1021/ja069266h Supporting Info

Induced Fit Conformational Changes of a “Reversed Amidine” Heterocycle:  Optimized Interactions in a DNA Minor Groove Complex Manoj Munde, Michael Lee, Stephen Neidle, Reem Arafa, David W. Boykin, Yang Liu, Christian Bailly, and W. David Wilson pp 5688–5698 DOI: 10.1021/ja069003n Supporting Info

Processive Rotaxane Systems. Studies on the Mechanism and Control of the Threading Process Pilar Hidalgo Ramos, Ruud G. E. Coumans, Alexander B. C. Deutman, Jan M. M. Smits, Rene de Gelder, Johannes A. A. W. Elemans, Roeland J. M. Nolte, and Alan E. Rowan pp 5699–5702 DOI: 10.1021/ja068714i Supporting Info

Lamellar Structure in Poly(Ala-Gly) Determined by Solid-State NMR and Statistical Mechanical Calculations Tetsuo Asakura, Hirohiko Sato, Fumika Moro, Yasumoto Nakazawa, and Akihiro Aoki pp 5703–5709 DOI: 10.1021/ja070128h Supporting Info

Experimental and Computational Investigation of Unsymmetrical Cyanine Dyes:  Understanding Torsionally Responsive Fluorogenic Dyes Gloria L. Silva, Volkan Ediz, David Yaron, and Bruce A. Armitage pp 5710–5718 DOI: 10.1021/ja070025z Supporting Info

Determining the Orientation of Uniaxially Rotating Membrane Proteins Using Unoriented Samples:  A 2H, 13C, and 15N Solid-State NMR Investigation of the Dynamics and Orientation of a Transmembrane Helical Bundle Sarah D. Cady, Catherine Goodman, Chad D. Tatko, William F. DeGrado, and Mei Hong pp 5719–5729 DOI: 10.1021/ja070305e

Interfacial Bonding of Gold Nanoparticles on a H-terminated Si(100) Substrate Obtained by Electro- and Electroless Deposition Liyan Zhao, Allan Chung-Lung Siu, Joseph Andrew Petrus, Zhenhua He, and Kam Tong Leung pp 5730–5734 DOI: 10.1021/ja070441j

Molecular Basis for Water-Promoted Supramolecular Chirality Inversion in Helical Rosette Nanotubes Ross S. Johnson, Takeshi Yamazaki, Andriy Kovalenko, and Hicham Fenniri pp 5735–5743 DOI: 10.1021/ja0706192 Supporting Info

β-Hydrogen Kinetic Effect Raffaello Romeo, Giuseppina D'Amico, Emilia Sicilia, Nino Russo, and Silvia Rizzato pp 5744–5755 DOI: 10.1021/ja0702162 Supporting Info

Self-Cleaning Resins Vaclav Janout, Sasha B. Myers, Richard A. Register, and Steven L. Regen pp 5756–5759 DOI: 10.1021/ja068679f

Probing the Origin of the Compromised Catalysis of E. coli Alkaline Phosphatase in its Promiscuous Sulfatase Reaction Irina Catrina, Patrick J. O'Brien, Jamie Purcell, Ivana Nikolic-Hughes, Jesse G. Zalatan, Alvan C. Hengge, and Daniel Herschlag pp 5760–5765 DOI: 10.1021/ja069111+

Rh(I)-Catalyzed Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Leading to Indenones Yasuyuki Harada, Jun Nakanishi, Hirokazu Fujihara, Mamoru Tobisu, Yoshiya Fukumoto, and Naoto Chatani pp 5766–5771 DOI: 10.1021/ja070107n Supporting Info

Organocatalytic Asymmetric 1,6-Additions of β-Ketoesters and Glycine Imine Luca Bernardi, Jesús López-Cantarero, Barbara Niess, and Karl Anker Jørgensen pp 5772–5778 DOI: 10.1021/ja0707097 Supporting Info

Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Cata-lysts [J. Am. Chem. Soc. 2007, 129, 1044−1045]. Frédéric Blanc, Jean Thivolle-Cazat, Jean-Marie Basset, Christophe Copéret, Adam S. Hock, Zachary J. Tonzetich, Amritanshu Sinha, and Richard R. Schrock p 5779 DOI: 10.1021/ja071561u

Catalytic Enantioselective Hetero-Diels−Alder Reactions of an Azo Compound  [J. Am. Chem. Soc. 2006, 128, 16482−16483].  Masanori Kawasaki and Hisashi Yamamoto p 5779 DOI: 10.1021/ja076887h Supporting Info

Crystal Nucleation, Growth, and Morphology of the Synthetic Malaria Pigment β-Hematin and the Effect Thereon by Quinoline Additives:  The Malaria Pig-ment as a Target of Various Antimalarial Drugs  [J. Am. Chem. Soc. 2007, 129, 2615−2627]. Inna Solomonov, Maria Osipova, Yishay Feldman, Carsten Baehtz, Kristian Kjaer, Ian K. Robinson, Grant T. Webster, Don McNaughton, Bayden R. Wood, Isabelle Weissbuch, and Leslie Leiserowitz p 5779 DOI: 10.1021/ja076888+

GALAHAD Tripos, Inc., 1699 South Hanley Road, St. Louis, MO 63144-2319. www.tripos.com. Contact company for pricing information. Haizhen Zhong and J. Phillip Bowen p 5780 DOI: 10.1021/ja069815j

Non-Covalent Multi-Porphyrin Assemblies:  Synthesis and Properties. Structure and Bonding, 121 Edited by Enzo Alessio (Università di Trieste, Italy). Series Edited by D. M. P. Mingos. Springer:  Berlin, Heidelberg, New York. 2006. xi + 307 pp. $309.00. ISBN 3-540-32542-5. Alan L. Balch p 5781 DOI: 10.1021/ja069775j

Emissive Materials:  Nanomaterials Advances in Polymer Science, 199 Springer:  Berlin, Heidelberg, New York. 2006. x + 290pp. $279.00. ISBN 3-540-31250-1. D. C. Neckers pp 5781–5782 DOI: 10.1021/ja069780n

A Guide to Chalcogen−Nitrogen Chemistry By Tristram Chivers (University of Calgary, Canada). World Scientific:  New Jersey, London, Singapore. 2005. xx + 318 pp. $86.00. ISBN 981-256-095-5. John F. Corrigan p 5782 DOI: 10.1021/ja069834t

Principles of Protein X-Ray Crystallography, 3rd Edition By Jan Drenth (University of Groningen, The Netherlands). With a major contribution from Jeroen Mester (University of Lübeck, Germany). Springer Science + Business Media LLC:  New York. 2007. xiv + 332 pp. $89.95. ISBN 0-387-33334-7. Jon Robertus pp 5782–5783 DOI: 10.1021/ja076922k

Computer Simulations in Condensed Matter:  From Materials to Chemical Biology - Volume 1 Edited by Mauro Ferrario (Università di Modena e Reggio Emilia, Modena, Italy), Giovanni Ciccotti (Università di Roma La Sapienza, Rome, Italy), and Kurt Binder (Universität Mainz, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xvi + 712 pp. $99.00. ISBN 978-3-540-35270-9. p 5783 DOI: 10.1021/ja0769189

Computer Simulations in Condensed Matter:  From Materials to Chemical Biology - Volume 2 Edited by Mauro Ferrario (Università di Modena e Reggio Emilia, Modena, Italy), Giovanni Ciccotti (Università di Roma La Sapienza, Rome, Italy), and Kurt Binder (Universität Mainz, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xvi + 598 pp. $99.00. ISBN 978-3-540-35283-9. pp 5783–5784 DOI: 10.1021/ja0769191

Film Formation:  Process and Morphology. ACS Symposium Series 941 Edited by Theodore Provder (Eastern Michigan University, Ypsilanti, MI). American Chemical Society:  Washington, DC (distributed by Oxford University Press). 2006. xii + 184 pp. $154.50. ISBN 0-8412-3961-4. p 5784 DOI: 10.1021/ja076931t

Controlled/Living Radical Polymerization:  From Synthesis to Materials, ACS Symposium Series 944 Edited by Krzysztof Matyjaszewski (Carnegie Mellon University, Pittsburgh, PA). American Chemical Society:  Washington, DC (distributed by Oxford University Press). 2006. xvi + 672 pp. $199.50. ISBN 0-8412-3991-6. p 5784 DOI: 10.1021/ja076932l

Issue 18

Understanding a Mechanism of Organic Cosolvent Inactivation in Heme Monooxygenase P450 BM-3 Jochen Kuper, Tuck Seng Wong, Danilo Roccatano, Matthias Wilmanns, and Ulrich Schwaneberg pp 5786–5787 DOI: 10.1021/ja067036x Supporting Info

Heparin/Poly(l-lysine) Nanoparticle-Coated Polymeric Microspheres for Stem-Cell Therapy Kun Na, Sungwon Kim, Kyeongsoon Park, Kwangmeyung Kim, Dae Gyun Woo, Ick Chan Kwon, Hyung-Min Chung, and Keun-Hong Park pp 5788–5789 DOI: 10.1021/ja067707r Supporting Info

Unambiguous Evidence for Efficient Chemical Catalysis of Adenosine Ester Aminolysis by Its 2‘/3‘-OH Stanislav G. Bayryamov, Miroslav A. Rangelov, Aneta P. Mladjova, Vihra Yomtova, and Dimiter D. Petkov pp 5790–5791 DOI: 10.1021/ja068447g Supporting Info

Organoborane Acceptor-Substituted Polythiophene via Side-Group Borylation Haiyan Li, Anand Sundararaman, Krishnan Venkatasubbaiah, and Frieder Jäkle pp 5792–5793 DOI: 10.1021/ja068771b Supporting Info

Intramolecular Single-Turnover Reaction in a Cytochrome c Oxidase Model Bearing a Tyr244 Mimic James P. Collman, Richard A. Decréau, Yilong Yan, Jungjoo Yoon, and Edward I. Solomon pp 5794–5795 DOI: 10.1021/ja0690969 Supporting Info

Transition State Analysis of Model and Enzymatic Prenylation Reactions Stepan Lenevich, Juhua Xu, Ayako Hosokawa, Christopher J. Cramer, and Mark D. Distefano pp 5796–5797 DOI: 10.1021/ja069119j Supporting Info

Ligand Conjugated Low-Density Lipoprotein Nanoparticles for Enhanced Optical Cancer Imaging in Vivo Juan Chen, Ian R. Corbin, Hui Li, Weiguo Cao, Jerry D. Glickson, and Gang Zheng pp 5798–5799 DOI: 10.1021/ja069336k Supporting Info

Valence Tautomerism and Coordinative Lability in Copper(II)−Imidazolyl−Semiquinonate Anion Radical Models for the CuB Center in Cytochrome c Oxidases David G. Lonnon, Sang Tae Lee, and Stephen B. Colbran pp 5800–5801 DOI: 10.1021/ja068972f Supporting Info

Sir2 Deacetylases Exhibit Nucleophilic Participation of Acetyl-Lysine in NAD+ Cleavage Brian C. Smith and John M. Denu pp 5802–5803 DOI: 10.1021/ja070162w Supporting Info

Amplified Analysis of Low-Molecular-Weight Substrates or Proteins by the Self-Assembly of DNAzyme−Aptamer Conjugates Di Li, Bella Shlyahovsky, Johann Elbaz, and Itamar Willner pp 5804–5805 DOI: 10.1021/ja070180d Supporting Info

Counterions Release from Electrostatic Complexes of Polyelectrolytes and Proteins of Opposite Charge:  A Direct Measurement Jérémie Gummel, Fabrice Cousin, and François Boué pp 5806–5807 DOI: 10.1021/ja070414t Supporting Info

Organic−Inorganic Hybrids Based on Pyrene Functionalized Octavinylsilsesquioxane Cores for Application in OLEDs Mee Yoon Lo, Changgua Zhen, Michael Lauters, Ghassan E. Jabbour, and Alan Sellinger pp 5808–5809 DOI: 10.1021/ja070471m

Unexpected CC Bond Formation via Doubly Dehydrogenative Coupling of Two Saturated sp3 C−H Bonds Activated with a Polymolybdate Qiang Li, Yongge Wei, Jian Hao, Yulin Zhu, and Longsheng Wang pp 5810–5811 DOI: 10.1021/ja070600z Supporting Info

Synthesis of Hollow Iron Nanoframes Dokyoon Kim, Jongnam Park, Kwangjin An, Nam-Keun Yang, Je-Geun Park, and Taeghwan Hyeon pp 5812–5813 DOI: 10.1021/ja070667m Supporting Info

Synthesis and Reactions of 20 π-Electron β-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrins Chao Liu, Dong-Mei Shen, and Qing-Yun Chen pp 5814–5815 DOI: 10.1021/ja070855c Supporting Info

An Efficient and Chemoselective Iron Catalyst for the Hydrogenation of Ketones Charles P. Casey and Hairong Guan pp 5816–5817 DOI: 10.1021/ja071159f Supporting Info

Control of the Electrode−Molecule Interface for Molecular Devices Kazumichi Yokota, Masateru Taniguchi, and Tomoji Kawai pp 5818–5819 DOI: 10.1021/ja071365n Supporting Info

Synthesis of Organic Photodimeric Cage Molecules Based on Cycloaddition via Metal−Ligand Directed Assembly Jarrod F. Eubank, Victor Ch. Kravtsov, and Mohamed Eddaoudi pp 5820–5821 DOI: 10.1021/ja070924n Supporting Info

Nigricanosides A and B, Antimitotic Glycolipids Isolated from the Green Alga Avrainvillea nigricans Collected in Dominica David E. Williams, Christopher M. Sturgeon, Michel Roberge, and Raymond J. Andersen pp 5822–5823 DOI: 10.1021/ja0715187 Supporting Info

Mechanistic Evidence for a Ring-Opening Pathway in the Pd-Catalyzed Direct Arylation of Benzoxazoles Rafael S. Sánchez and Fedor A. Zhuravlev pp 5824–5825 DOI: 10.1021/ja0679580 Supporting Info

Chemical Surface Modification via Radical C−C Bond-Forming Reactions Kai Oliver Siegenthaler, Andreas Schäfer, and Armido Studer pp 5826–5827 DOI: 10.1021/ja0686716 Supporting Info

Highly Efficient Au(I)-Catalyzed Intramolecular Addition of β-Ketoamide to Unactivated Alkenes Cong-Ying Zhou and Chi-Ming Che pp 5828–5829 DOI: 10.1021/ja070027j Supporting Info

A Vaulted Biaryl Phosphoric Acid-Catalyzed Reduction of α-Imino Esters:  The Highly Enantioselective Preparation of α-Amino Esters Guilong Li, Yuxue Liang, and Jon C. Antilla pp 5830–5831 DOI: 10.1021/ja070519w Supporting Info

Cyclodimerization of Alkynes with Phosphine-Free Ruthenium Carbene Complexes:  Carbene Consumption by a Shunted Alkyne Oligomerization Steven T. Diver, Amol A. Kulkarni, Daniel A. Clark, and Brian P. Peppers pp 5832–5833 DOI: 10.1021/ja0705689 Supporting Info

Highly Enantioselective Insertion of Carbenoids into N−H Bonds Catalyzed by Copper Complexes of Chiral Spiro Bisoxazolines Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, and Qi-Lin Zhou pp 5834–5835 DOI: 10.1021/ja0711765 Supporting Info

Synthesis of Cyclopropanes via Pd(II/IV)-Catalyzed Reactions of Enynes Leilani L. Welbes, Thomas W. Lyons, Katie A. Cychosz, and Melanie S. Sanford pp 5836–5837 DOI: 10.1021/ja071204j Supporting Info

Gold(I)-Catalyzed Oxidative Rearrangements Cole A. Witham, Pablo Mauleón, Nathan D. Shapiro, Benjamin D. Sherry, and F. Dean Toste pp 5838–5839 DOI: 10.1021/ja071231+ Supporting Info

Deciphering the Structural Transformations during Nickel Oxyhydroxide Electrode Operation Montse Casas-Cabanas, Jesús Canales-Vázquez, Juan Rodríguez-Carvajal, and M. Rosa Palacín pp 5840–5842 DOI: 10.1021/ja068433a Supporting Info

Small-Molecule Inhibitors of Protein Geranylgeranyltransferase Type I Sabrina Castellano, Hannah D. G. Fiji, Sape S. Kinderman, Masaru Watanabe, Pablo de Leon, Fuyuhiko Tamanoi, and Ohyun Kwon pp 5843–5845 DOI: 10.1021/ja070274n Supporting Info

Tunneling in Green Tea:  Understanding the Antioxidant Activity of Catechol-Containing Compounds. A Variational Transition-State Theory Study Ismael Tejero, Núria González-García, Àngels González-Lafont, and José M. Lluch pp 5846–5854 DOI: 10.1021/ja063766t Supporting Info

Reaction of Cytochrome P450BM3 and Peroxynitrite Yields Nitrosyl Complex Rachel K. Behan, Lee M. Hoffart, Kari L. Stone, Carsten Krebs, and Michael T. Green pp 5855–5859 DOI: 10.1021/ja064590y Supporting Info

Pd Catalysis on Dendronized Solid Support:  Generation Effects and the Influence of the Backbone Structure Adi Dahan and Moshe Portnoy pp 5860–5869 DOI: 10.1021/ja065265d Supporting Info

Concerted Proton−Electron Transfer Reactions in Water. Are the Driving Force and Rate Constant Depending on pH When Water Acts as Proton Donor or Acceptor? Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 5870–5879 DOI: 10.1021/ja067950q

Neutral Fragment Mass Spectra via Ambient Thermal Dissociation of Peptide and Protein Ions Hao Chen, Livia S. Eberlin, and R. Graham Cooks pp 5880–5886 DOI: 10.1021/ja067712v Supporting Info

Infrared Spectroscopy and Theoretical Studies on Gas-Phase Protonated Leu-enkephalin and Its Fragments:  Direct Experimental Evidence for the Mobile Proton Nick C. Polfer, Jos Oomens, Sándor Suhai, and Béla Paizs pp 5887–5897 DOI: 10.1021/ja068014d Supporting Info

Correlation of Protein Structure and Dynamics to Scalar Couplings across Hydrogen Bonds Hans-Jürgen Sass, Franziska Fang-Fang Schmid, and Stephan Grzesiek pp 5898–5903 DOI: 10.1021/ja068336h Supporting Info

Design of Liquid-Crystalline Aqueous Suspensions of Rutile Nanorods:  Evidence of Anisotropic Photocatalytic Properties Arnaud Dessombz, David Chiche, Patrick Davidson, Pierre Panine, Corinne Chanéac, and Jean-Pierre Jolivet pp 5904–5909 DOI: 10.1021/ja0684491 Supporting Info

Turn-On and Ratiometric Mercury Sensing in Water with a Red-Emitting Probe Elizabeth M. Nolan and Stephen J. Lippard pp 5910–5918 DOI: 10.1021/ja068879r Supporting Info

Artificial G-Wire Switch with 2,2‘-Bipyridine Units Responsive to Divalent Metal Ions Daisuke Miyoshi, Hisae Karimata, Zhong-Ming Wang, Kazuya Koumoto, and Naoki Sugimoto pp 5919–5925 DOI: 10.1021/ja068707u Supporting Info

Oxoclusters of the Lanthanides Begin to Resemble Solid-State Materials at Very Small Cluster Sizes:  Structure and NIR Emission from Nd(III) Santanu Banerjee, G. Ajith Kumar, Richard. E. Riman, Thomas J. Emge, and John G. Brennan pp 5926–5931 DOI: 10.1021/ja069000a Supporting Info

Photochromism of Diarylethene Single Molecules in Polymer Matrices Tuyoshi Fukaminato, Tohru Umemoto, Yasuhide Iwata, Satoshi Yokojima, Mitsuru Yoneyama, Shinichiro Nakamura, and Masahiro Irie pp 5932–5938 DOI: 10.1021/ja069131b Supporting Info

Biodegradable Nanogels Prepared by Atom Transfer Radical Polymerization as Potential Drug Delivery Carriers:  Synthesis, Biodegradation, in Vitro Release, and Bioconjugation Jung Kwon Oh, Daniel J. Siegwart, Hyung-il Lee, Gizelle Sherwood, Linda Peteanu, Jeffrey O. Hollinger, Kazunori Kataoka, and Krzysztof Matyjaszewski pp 5939–5945 DOI: 10.1021/ja069150l Supporting Info

Protein Tyrosine Phosphatase Oligomerization Studied by a Combination of 15N NMR Relaxation and 129Xe NMR. Effect of Buffer Containing Arginine and Glutamic Acid Jascha Blobel, Sabine Schmidl, David Vidal, Lydia Nisius, Pau Bernadó, Oscar Millet, Eike Brunner, and Miquel Pons pp 5946–5953 DOI: 10.1021/ja069144p Supporting Info

GM1 Clustering Inhibits Cholera Toxin Binding in Supported Phospholipid Membranes Jinjun Shi, Tinglu Yang, Sho Kataoka, Yanjie Zhang, Arnaldo J. Diaz, and Paul S. Cremer pp 5954–5961 DOI: 10.1021/ja069375w Supporting Info

SNAr Displacements with 6-(Fluoro, Chloro, Bromo, Iodo, and Alkylsulfonyl)purine Nucleosides:  Synthesis, Kinetics, and Mechanism1 Jiangqiong Liu and Morris J. Robins pp 5962–5968 DOI: 10.1021/ja070021u Supporting Info

Closo-alanes (Al4H4, AlnHn+2, 4 ≤ n ≤ 8):  A New Chapter in Aluminum Hydride Chemistry A. Grubisic, X. Li, S. T. Stokes, J. Cordes, G. F. Ganteför, K. H. Bowen, B. Kiran, P. Jena, R. Burgert, and H. Schnöckel pp 5969–5975 DOI: 10.1021/ja0700404 Supporting Info

Structure-Based Engineering of a Plant Type III Polyketide Synthase:  Formation of an Unnatural Nonaketide Naphthopyrone Ikuro Abe, Hiroyuki Morita, Satoshi Oguro, Hisashi Noma, Kiyofumi Wanibuchi, Nobuo Kawahara, Yukihiro Goda, Hiroshi Noguchi, and Toshiyuki Kohno pp 5976–5980 DOI: 10.1021/ja070375l Supporting Info

Unsaturated Platinum−Rhenium Cluster Complexes. Synthesis, Structures and Reactivity Richard D. Adams, Burjor Captain, Mark D. Smith, Chad Beddie, and Michael B. Hall pp 5981–5991 DOI: 10.1021/ja070773o Supporting Info

Helical Pores Self-Assembled from Homochiral Dendritic Dipeptides Based on l-Tyr and Nonpolar α-Amino Acids Virgil Percec, Andrés E. Dulcey, Mihai Peterca, Peter Adelman, Ritika Samant, Venkatachalapathy S. K. Balagurusamy, and Paul A. Heiney pp 5992–6002 DOI: 10.1021/ja071088k Supporting Info

Operationally Unsaturated Pincer/Rhenium Complexes Form Metal Carbenes from Cycloalkenes and Metal Carbynes from Alkanes Oleg V. Ozerov, Lori A. Watson, Maren Pink, and Kenneth G. Caulton pp 6003–6016 DOI: 10.1021/ja062327r Supporting Info

Total Synthesis of Lysobactin Aikomari Guzman-Martinez, Ryan Lamer, and Michael S. VanNieuwenhze pp 6017–6021 DOI: 10.1021/ja067648h Supporting Info

Molecular Analysis of the Benastatin Biosynthetic Pathway and Genetic Engineering of Altered Fatty Acid−Polyketide Hybrids Zhongli Xu, Angéla Schenk, and Christian Hertweck pp 6022–6030 DOI: 10.1021/ja069045b Supporting Info

Study of the Coalescence of Acoustic Bubbles as a Function of Frequency, Power, and Water-Soluble Additives Devi Sunartio, Muthupandian Ashokkumar, and Franz Grieser pp 6031–6036 DOI: 10.1021/ja068980w Supporting Info

Selective Ruthenium-Catalyzed Transformations of Enynes with Diazoalkanes into Alkenylbicyclo[3.1.0]hexanes Florian Monnier, Chloé Vovard-Le Bray, Dante Castillo, Vincent Aubert, Sylvie Dérien, Pierre H. Dixneuf, Loic Toupet, Andrea Ienco, and Carlo Mealli pp 6037–6049 DOI: 10.1021/ja0700146 Supporting Info

Practical Synthesis of Enantiomerically Pure β2-Amino Acids via Proline-Catalyzed Diastereoselective Aminomethylation of Aldehydes Yonggui Chi, Emily P. English, William C. Pomerantz, W. Seth Horne, Leo A. Joyce, Lane R. Alexander, William S. Fleming, Elizabeth A. Hopkins, and Samuel H. Gellman pp 6050–6055 DOI: 10.1021/ja070063i Supporting Info

Synthesis, Structure, and Magnetic Properties of Valence Ambiguous Dinuclear Antiferromagnetically Coupled Cobalt and Ferromagnetically Coupled Iron Complexes Containing the Chloranilate(2−) and the Significantly Stronger Coupling Chloranilate(•3−) Radical Trianion [J. Am. Chem. Soc. 2007, 129, 2360−2368]. Kil Sik Min, Antonio G. DiPasqual, James A. Golen, Arnold L. Rheingold, Atta M. Arif, and Joel S. Miller p 6056 DOI: 10.1021/ja0716958

Issue 19

Metal Coordination-Assisted Near-Infrared Photochromic Behavior:  A Large Perturbation on Absorption Wavelength Properties of N,N-Donor Ligands Containing Diarylethene Derivatives by Coordination to the Rhenium(I) Metal Center Penny Ho-Man Lee, Chi-Chiu Ko, Nianyong Zhu, and Vivian Wing-Wah Yam pp 6058–6059 DOI: 10.1021/ja067425r Supporting Info

Inter-DNA Electrostatics from Explicit Solvent Molecular Dynamics Simulations Alexey Savelyev and Garegin A. Papoian pp 6060–6061 DOI: 10.1021/ja070207t Supporting Info

Rapid Screening of Gold Catalysts by Chemiluminescence-Based Array Imaging Xin Wang, Na Na, Sichun Zhang, Yayan Wu, and Xinrong Zhang pp 6062–6063 DOI: 10.1021/ja0702768 Supporting Info

Nanoparticle Self-Assembly Gated by Logical Proteolytic Triggers Geoffrey von Maltzahn, Todd J. Harris, Ji-Ho Park, Dal-Hee Min, Alexander J. Schmidt, Michael J. Sailor, and Sangeeta N. Bhatia pp 6064–6065 DOI: 10.1021/ja070461l Supporting Info

Ortho Arylation of Acetanilides via Pd(II)-Catalyzed C−H Functionalization Shangdong Yang, Bijie Li, Xiaobing Wan, and Zhangjie Shi pp 6066–6067 DOI: 10.1021/ja070767s Supporting Info

Nanoscale Tunable Proton/Hydrogen Sensing:  Evidence for Surface-Adsorbed Hydrogen Atom on Architectured Palladium Nanoparticles Han-Pu Liang, Nathan S. Lawrence, Timothy G. J. Jones, Craig E. Banks, and Caterina Ducati pp 6068–6069 DOI: 10.1021/ja070760a Supporting Info

High-Sensitivity Humidity Sensor Based on a Single SnO2 Nanowire Qin Kuang, Changshi Lao, Zhong Lin Wang, Zhaoxiong Xie, and Lansun Zheng pp 6070–6071 DOI: 10.1021/ja070788m Supporting Info

Rapid Removal of D5h Isomer Using the “Stir and Filter Approach” and Isolation of Large Quantities of Isomerically Pure Sc3N@C80 Metallic Nitride Fullerenes Steven Stevenson, Mary A. Mackey, Curtis E. Coumbe, J. Paige Phillips, Bevan Elliott, and Luis Echegoyen pp 6072–6073 DOI: 10.1021/ja070795a Supporting Info

DNA-Mediated Electrochemistry of Disulfides on Graphite Alon A. Gorodetsky and Jacqueline K. Barton pp 6074–6075 DOI: 10.1021/ja071006s Supporting Info

Monomeric, Two-Coordinate, Univalent Chromium(I) Compounds:  Steric Prevention of Metal−Metal Bond Formation Robert Wolf, Marcin Brynda, Chengbao Ni, Gary J. Long, and Philip P. Power pp 6076–6077 DOI: 10.1021/ja0710860 Supporting Info

ssDNA Templated Self-Assembly of Chromophores Pim G. A. Janssen, Joke Vandenbergh, Joost L. J. van Dongen, E. W. Meijer, and Albertus P. H. J. Schenning pp 6078–6079 DOI: 10.1021/ja0711967 Supporting Info

Stretched Poly(acrylonitrile) as a Scalable Alignment Medium for DMSO Grit Kummerlöwe, Jörg Auernheimer, Andreas Lendlein, and Burkhard Luy pp 6080–6081 DOI: 10.1021/ja071248s Supporting Info

Two-Dimensional Assembly of Rod Amphiphiles into Planar Networks Jung-Keun Kim, Eunji Lee, Young-Hwan Jeong, Jeong-Kyu Lee, Wang-Cheol Zin, and Myongsoo Lee pp 6082–6083 DOI: 10.1021/ja071394y Supporting Info

Enrichment of Single Chirality Carbon Nanotubes Ming Zheng and Ellen D. Semke pp 6084–6085 DOI: 10.1021/ja071577k

A Heterogeneous PNA-Based SERS Method for DNA Detection Laura Fabris, Mark Dante, Gary Braun, Seung Joon Lee, Norbert O. Reich, Martin Moskovits, Thuc-Quyen Nguyen, and Guillermo C. Bazan pp 6086–6087 DOI: 10.1021/ja0705184 Supporting Info

Fe2+ Catalyzes Vitamin E-Induced Fragmentation of Hydroperoxy and Hydroxy Endoperoxides That Generates γ-Hydroxy Alkenals Xiaodong Gu, Wujuan Zhang, and Robert G. Salomon pp 6088–6089 DOI: 10.1021/ja0689785 Supporting Info

Enhancement of Cyclopropanation Chemistry in the Silver-Catalyzed Reactions of Aryldiazoacetates Janelle L. Thompson and Huw M. L. Davies pp 6090–6091 DOI: 10.1021/ja069314y Supporting Info

Transition Metal Migration upon Attempting the Wolff Rearrangement of an Ir(III) Five-Membered Metallacycle Margarita Gómez, Margarita Paneque, Manuel L. Poveda, and Eleuterio Alvarez pp 6092–6093 DOI: 10.1021/ja070360n Supporting Info

Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes with Silacyclobutanes:  Facile Access to Vinylsilanes from Alkenes Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima pp 6094–6095 DOI: 10.1021/ja070938t Supporting Info

Isolable Silylene Anion Radical:  Structural Characteristics in the Solid State and in Solution Shigeyoshi Inoue, Masaaki Ichinohe, and Akira Sekiguchi pp 6096–6097 DOI: 10.1021/ja0711314 Supporting Info

Ruthenium-Catalyzed Carbon−Carbon Bond Formation via the Cleavage of an Unreactive Aryl Carbon−Nitrogen Bond in Aniline Derivatives with Organoboronates Satoshi Ueno, Naoto Chatani, and Fumitoshi Kakiuchi pp 6098–6099 DOI: 10.1021/ja0713431 Supporting Info

Total Synthesis of Archazolid A Dirk Menche, Jorma Hassfeld, Jun Li, and Sven Rudolph pp 6100–6101 DOI: 10.1021/ja071461o Supporting Info

Low-Temperature Formation of Nitrous Oxide from Dinitrogen, Mediated by Supported Tungsten Nanoclusters Wataru Yamaguchi and Junichi Murakami pp 6102–6103 DOI: 10.1021/ja071860j Supporting Info

Properties of Prussian Blue Materials Manifested in Molecular Complexes:  Observation of Cyanide Linkage Isomerism and Spin-Crossover Behavior in Pentanuclear Cyanide Clusters Mikhail Shatruk, Alina Dragulescu-Andrasi, Kristen E. Chambers, Sebastian A. Stoian, Emile L. Bominaar, Catalina Achim, and Kim R. Dunbar pp 6104–6116 DOI: 10.1021/ja066273x Supporting Info

Solvent Tuning from Normal to Inverted Marcus Region of Intramolecular Electron Transfer in Ferrocene-Based Organic Radicals Imma Ratera, Christian Sporer, Daniel Ruiz-Molina, Nora Ventosa, Jacob Baggerman, Albert M. Brouwer, Concepció Rovira, and Jaume Veciana pp 6117–6129 DOI: 10.1021/ja066351g Supporting Info

Directed Evolution of 2-Keto-3-deoxy-6-phosphogalactonate Aldolase To Replace 3-Deoxy-d-arabino-heptulosonic Acid 7-Phosphate Synthase Ningqing Ran and John W. Frost pp 6130–6139 DOI: 10.1021/ja067330p

Protein Design:  Reengineering Cellular Retinoic Acid Binding Protein II into a Rhodopsin Protein Mimic Chrysoula Vasileiou, Soheila Vaezeslami, Rachael M. Crist, Montserrat Rabago-Smith, James H. Geiger, and Babak Borhan pp 6140–6148 DOI: 10.1021/ja067546r Supporting Info

Mechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway Bryan D. Stubbert and Tobin J. Marks pp 6149–6167 DOI: 10.1021/ja0675898 Supporting Info

Spectroscopic and Computational Evaluation of the Structure of the High-Spin Fe(IV)-Oxo Intermediates in Taurine: α-Ketoglutarate Dioxygenase from Escherichia coli and Its His99Ala Ligand Variant Sebastian Sinnecker, Nina Svensen, Eric W. Barr, Shengfa Ye, J. Martin Bollinger, Jr., Frank Neese, and Carsten Krebs pp 6168–6179 DOI: 10.1021/ja067899q Supporting Info

Unexpected Preference of the E. coli Translation System for the Ester Bond during Incorporation of Backbone-Elongated Substrates Shinsuke Sando, Kenji Abe, Nobuhiko Sato, Toshihiro Shibata, Keigo Mizusawa, and Yasuhiro Aoyama pp 6180–6186 DOI: 10.1021/ja068033n Supporting Info

Janus Discs Andreas Walther, Xavier André, Markus Drechsler, Volker Abetz, and Axel H. E. Müller pp 6187–6198 DOI: 10.1021/ja068153v Supporting Info

Lone Pair−π and π−π Interactions Play an Important Role in Proton-Coupled Electron Transfer Reactions Gino A. DiLabio and Erin R. Johnson pp 6199–6203 DOI: 10.1021/ja068090g Supporting Info

Proton Assisted Oxygen−Oxygen Bond Splitting in Cytochrome P450 André R. Groenhof, Andreas W. Ehlers, and Koop Lammertsma pp 6204–6209 DOI: 10.1021/ja0685654 Supporting Info

Observable Azacyclobutenone Ylides with Antiaromatic Character from 2-Diazoacetyl-azaaromatics Nanyan Fu, Annette D. Allen, Shinjiro Kobayashi, Pearl A. Sequeira, Muhong Shang, Thomas T. Tidwell, and Masaaki Mishima pp 6210–6215 DOI: 10.1021/ja0686920 Supporting Info

Sculpting the Bicyclo[3.1.0]hexane Template of Carbocyclic Nucleosides to Improve Recognition by Herpes Thymidine Kinase Maria J. Comin, Riad Agbaria, Tsipi Ben-Kasus, Mahmoud Huleihel, Chenzhong Liao, Guangyu Sun, Marc C. Nicklaus, Jeffrey R. Deschamps, Damon A. Parrish, and Victor E. Marquez pp 6216–6222 DOI: 10.1021/ja0688732 Supporting Info

Ab initio Study of the Excited-State Deactivation Pathways of Protonated Tryptophan and Tyrosine Gilles Grégoire, Christophe Jouvet, Claude Dedonder, and Andrzej L. Sobolewski pp 6223–6231 DOI: 10.1021/ja069050f Supporting Info

Design of a Hybrid Biosensor for Enhanced Phosphopeptide Recognition Based on a Phosphoprotein Binding Domain Coupled with a Fluorescent Chemosensor Takahiro Anai, Eiji Nakata, Yoichiro Koshi, Akio Ojida, and Itaru Hamachi pp 6232–6239 DOI: 10.1021/ja0693284 Supporting Info

2-Aminopurine Flipped into the Active Site of the Adenine-Specific DNA Methyltransferase M.TaqI:  Crystal Structures and Time-Resolved Fluorescence Thomas Lenz, Eleanor Y. M. Bonnist, Goran Pljevaljić, Robert K. Neely, David T. F. Dryden, Axel J. Scheidig, Anita C. Jones, and Elmar Weinhold pp 6240–6248 DOI: 10.1021/ja069366n Supporting Info

Electronic Structure of a Metal−Organic Copper Spin-1/2 Molecule:  Bis(4-cyano-2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II) David Wisbey, Danqin Feng, Marshall T. Bremer, Camelia N. Borca Anthony N. Caruso, Carter M. Silvernail, John Belot, Elio Vescovo, Laurent Ranno, and Peter A. Dowben pp 6249–6254 DOI: 10.1021/ja069236e Supporting Info

The Solvent Cage Effect:  Is There a Spin Barrier to Recombination of Transition Metal Radicals? John D. Harris, Alan B. Oelkers, and David R. Tyler pp 6255–6262 DOI: 10.1021/ja069295s Supporting Info

Computational Design and Experimental Discovery of an Antiestrogenic Peptide Derived from α-Fetoprotein Karl N. Kirschner, Katrina W. Lexa, Amanda M. Salisburg, Katherine A. Alser, Leroy Joseph, Thomas T. Andersen, James A. Bennett, Herbert I. Jacobson, and George C. Shields pp 6263–6268 DOI: 10.1021/ja070202w

Selective Bond Breaking in β-d-Ribose by Gas-Phase Electron Attachment around 8 eV Isabella Baccarelli, Franco A. Gianturco, Andrea Grandi, Nico Sanna, Robert R. Lucchese, Ilko Bald, Janina Kopyra, and Eugen Illenberger pp 6269–6277 DOI: 10.1021/ja070542h Supporting Info

Cisplatin Damage Overrides the Predefined Rotational Setting of Positioned Nucleosomes Matthias Ober and Stephen J. Lippard pp 6278–6286 DOI: 10.1021/ja0706145 Supporting Info

Gas-Phase Tautomeric Equilibrium of 4-Hydroxypyrimidine with Its Ketonic Forms:  A Free Jet Millimeterwave Spectroscopy Study Raquel Sanchez, B. Michela Giuliano, Sonia Melandri, Laura B. Favero, and Walther Caminati pp 6287–6290 DOI: 10.1021/ja070712q Supporting Info

Field Induced Formation of Mesoscopic Polymer Chains from Functional Ferromagnetic Colloids Jason J. Benkoski, Steven E. Bowles, Bryan D. Korth, Ronald L. Jones, Jack F. Douglas, Alamgir Karim, and Jeffrey Pyun pp 6291–6297 DOI: 10.1021/ja070779d

Aryl to Aryl Palladium Migration in the Heck and Suzuki Coupling of o-Halobiaryls Marino A. Campo, Haiming Zhang, Tuanli Yao, Abdellatif Ibdah, Ryan D. McCulla, Qinhua Huang, Jian Zhao, William S. Jenks, and Richard C. Larock pp 6298–6307 DOI: 10.1021/ja069238z Supporting Info

Tuning the Release Rate of Acidic Degradation Products through Macromolecular Design of Caprolactone-Based Copolymers Minna Hakkarainen, Anders Höglund, Karin Odelius, and Ann-Christine Albertsson pp 6308–6312 DOI: 10.1021/ja0702871 Supporting Info

NMR Studies of Coupled Low- and High-Barrier Hydrogen Bonds in Pyridoxal-5‘-phosphate Model Systems in Polar Solution Shasad Sharif, Gleb S. Denisov, Michael D. Toney, and Hans-Heinrich Limbach pp 6313–6327 DOI: 10.1021/ja070296+ Supporting Info

Two-Faced Reactivity of Alkenes:  cis- versus trans-Aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions Guosheng Liu and Shannon S. Stahl pp 6328–6335 DOI: 10.1021/ja070424u Supporting Info

Concise, Asymmetric, Stereocontrolled Total Synthesis of Stephacidins A, B and Notoamide B Gerald D. Artman III, Alan W. Grubbs, and Robert M. Williams pp 6336–6342 DOI: 10.1021/ja070259i Supporting Info

Scanning Probe Microscopies Beyond Imaging:  Manipulation of Molecules and Nanostructures Edited by Paolo Samori (CNR Bologna, Italy and Université Louis Pasteur, Strasbourg, France). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xxiv + 544 pp. $190. ISBN 3-527-31269-2. Joel A. Olson p 6343 DOI: 10.1021/ja069808v

Carbon Nanotubes, Properties and Applications Edited by Michael J. O'Connell (Theranos, Inc., Menlo Park, CA). CRC Press and Taylor & Francis Group:  Boca Raton, FL. 2006. xviii + 320 pages. $99.95. ISBN 0-8493-2748-2. Glen P. Miller pp 6343–6344 DOI: 10.1021/ja069764q

Applied Modeling and Computations in Nuclear Science. ACS Symposium Series 945 Edited by Thomas M. Semkow (New York State Department of Health, Albany, NY), Stefaan Pommé (Institute for Reference Materials and Measurements, Geel, Belgium), Simon M. Jerome (National Physical Laboratory, Teddington, U.K.), and Daniel J. Strom (Pacific Northwest National Laboratory, Richland, WA). American Chemical Society:  Washington, DC (distributed by Oxford University Press). 2007. xiv + 374 pp. $189.50. ISBN 0-8412-3982-7. p 6344 DOI: 10.1021/ja076933d

Issue 20

The Effect of a Water Molecule on the Mechanism of Formation of Compound 0 in Horseradish Peroxidase Etienne Derat, Sason Shaik, Carme Rovira, Pietro Vidossich, and Mercedes Alfonso-Prieto pp 6346–6347 DOI: 10.1021/ja0676861 Supporting Info

Synthesis and Self-Assembly of fcc Phase FePt Nanorods Min Chen, Timothy Pica, Ying-Bing Jiang, Peng Li, Kazuaki Yano, J. Ping Liu, Abhaya K. Datye, and Hongyou Fan pp 6348–6349 DOI: 10.1021/ja069057x Supporting Info

A Mechanism-Based Aryl Carrier Protein/Thiolation Domain Affinity Probe Chunhua Qiao, Daniel J. Wilson, Eric M. Bennett, and Courtney C. Aldrich pp 6350–6351 DOI: 10.1021/ja069201e Supporting Info

Fatty Acid Salts as Stabilizers in Size- and Shape-Controlled Nanocrystal Synthesis:  The Case of Inverse Spinel Iron Oxide Maksym V. Kovalenko, Maryna I. Bodnarchuk, Rainer T. Lechner, Günter Hesser, Friedrich Schäffler, and Wolfgang Heiss pp 6352–6353 DOI: 10.1021/ja0692478 Supporting Info

Enhancing One-Dimensional Charge Transport through Intermolecular π-Electron Delocalization:  Conductivity Improvement for Organic Nanobelts Yanke Che, Aniket Datar, Xiaomei Yang, Tammene Naddo, Jincai Zhao, and Ling Zang pp 6354–6355 DOI: 10.1021/ja070164g Supporting Info

Effect of the Surface Curvature on the Secondary Structure of Peptides Adsorbed on Nanoparticles Himadri S. Mandal and Heinz-Bernhard Kraatz pp 6356–6357 DOI: 10.1021/ja0703372 Supporting Info

Gold Catalysts Open a New General Chemoselective Route to Synthesize Oximes by Hydrogenation of α,β-Unsaturated Nitrocompounds with H2 Avelino Corma, Pedro Serna, and Hermenegildo García pp 6358–6359 DOI: 10.1021/ja0704131 Supporting Info

Carbon Dioxide Fixation into Chemicals (Methyl Formate) at High Yields by Surface Coupling over a Pd/Cu/ZnO Nanocatalyst K. M. Kerry Yu, Connie M. Y. Yeung, and Shik Chi Tsang pp 6360–6361 DOI: 10.1021/ja0706302 Supporting Info

Facile Synthesis of High Quality TiO2 Nanocrystals in Ionic Liquid via a Microwave-Assisted Process Kunlun Ding, Zhenjiang Miao, Zhimin Liu, Zhaofu Zhang, Buxing Han, Guimin An, Shiding Miao, and Yun Xie pp 6362–6363 DOI: 10.1021/ja070809c Supporting Info

Asymmetric Diels−Alder Reactions of 2-Pyrones with a Bifunctional Organic Catalyst Yi Wang, Hongming Li, Yong-Qiang Wang, Yan Liu, Bruce M. Foxman, and Li Deng pp 6364–6365 DOI: 10.1021/ja070859h Supporting Info

The Loading Module of Mycosubtilin:  An Adenylation Domain with Fatty Acid Selectivity Darren B. Hansen, Stefanie B. Bumpus, Zachary D. Aron, Neil L. Kelleher, and Christopher T. Walsh pp 6366–6367 DOI: 10.1021/ja070890j Supporting Info

Dipole-Driven Ferroelectric Assembly of Styrene on Au{111} Ashleigh E. Baber, Stephen C. Jensen, and E. Charles H. Sykes pp 6368–6369 DOI: 10.1021/ja0709526 Supporting Info

Understanding the Effect of Carbonate Ion on Cisplatin Binding to DNA Ryan C. Todd, Katherine S. Lovejoy, and Stephen J. Lippard pp 6370–6371 DOI: 10.1021/ja071143p Supporting Info

Liquid-Crystal Gel-Dispersed Quantum Dots:  Reversible Modulation of Photoluminescence Intensity Using an Electric Field Xia Tong and Yue Zhao pp 6372–6373 DOI: 10.1021/ja0711720 Supporting Info

Photoswitchable Electrocatalysis and Catalyzed Chemiluminescence Using Photoisomerizable Monolayer-Functionalized Surfaces and Pt Nanoparticles Tamara Niazov, Bella Shlyahovsky, and Itamar Willner pp 6374–6375 DOI: 10.1021/ja0707052 Supporting Info

Discrete Heterogeneous Quaternary Structure Formed by α/β-Peptide Foldamers and α-Peptides Joshua L. Price, W. Seth Horne, and Samuel H. Gellman pp 6376–6377 DOI: 10.1021/ja071203r Supporting Info

Surface-Enhanced Raman Spectroscopy for DNA Detection by Nanoparticle Assembly onto Smooth Metal Films Gary Braun, Seung Joon Lee, Mark Dante, Thuc-Quyen Nguyen, Martin Moskovits, and Norbert Reich pp 6378–6379 DOI: 10.1021/ja070514z Supporting Info

A Facile One-Step in situ Functionalization of Quantum Dots with Preserved Photoluminescence for Bioconjugation Qiangbin Wang, Yang Xu, Xiaohang Zhao, Yung Chang, Yan Liu, Lijing Jiang, Jaswinder Sharma, Dong-Kyun Seo, and Hao Yan pp 6380–6381 DOI: 10.1021/ja071434y Supporting Info

Resonance Raman Detection of the Hydroperoxo Intermediate in the Cytochrome P450 Enzymatic Cycle Piotr J. Mak, Ilia G. Denisov, Doreen Victoria, Thomas M. Makris, Tianjing Deng, Stephen G. Sligar, and James R. Kincaid pp 6382–6383 DOI: 10.1021/ja071426h Supporting Info

Ultrafast Energy Transfer within Cyclic Self-Assembled Chlorophyll Tetramers Richard F. Kelley, Randall H. Goldsmith, and Michael R. Wasielewski pp 6384–6385 DOI: 10.1021/ja071362a Supporting Info

Total Synthesis and Structure Revision of the Marine Metabolite Palmerolide A Xin Jiang, Bo Liu, Sylvain Lebreton, and Jef K. De Brabander pp 6386–6387 DOI: 10.1021/ja0715142 Supporting Info

Crystal Structure of Human Arginase I Complexed with Thiosemicarbazide Reveals an Unusual Thiocarbonyl μ-Sulfide Ligand in the Binuclear Manganese Cluster Luigi Di Costanzo, Michael E. Pique, and David W. Christianson pp 6388–6389 DOI: 10.1021/ja071567j Supporting Info

Remarkably Facile and Reversible Ru−C(sp3) Bond Cleavage to Give a Reactive 16-Electron Cp*Ru(κ2-P,Carbene) Zwitterion Matthew A. Rankin, Gabriele Schatte, Robert McDonald, and Mark Stradiotto pp 6390–6391 DOI: 10.1021/ja071684e Supporting Info

Porphyrin Pincer Complexes:  Peripherally Cyclometalated Porphyrins and Their Catalytic Activities Controlled by Central Metals Shigeru Yamaguchi, Taisuke Katoh, Hiroshi Shinokubo, and Atsuhiro Osuka pp 6392–6393 DOI: 10.1021/ja072218s Supporting Info

Cinchona Alkaloid-Catalyzed Enantioselective Monofluoromethylation Reaction Based on Fluorobis(phenylsulfonyl)methane Chemistry Combined with a Mannich-type Reaction Satoshi Mizuta, Norio Shibata, Yosuke Goto, Tatsuya Furukawa, Shuichi Nakamura, and Takeshi Toru pp 6394–6395 DOI: 10.1021/ja071509y Supporting Info

Thermal and Photochemical Switching of Conformation of Poly(ethylene glycol)-Substituted Cyclodextrin with an Azobenzene Group at the Chain End Youhei Inoue, Paul Kuad, Yasushi Okumura, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 6396–6397 DOI: 10.1021/ja071717q Supporting Info

Two-Step Formal [3+2] Cycloaddition of Enones/Enals and Allenyl MOM Ether:  Gold-Catalyzed Highly Diastereoselective Synthesis of Cyclopentanone Enol Ether Containing an All-Carbon Quaternary Center Xiaogen Huang and Liming Zhang pp 6398–6399 DOI: 10.1021/ja0717717 Supporting Info

Total Synthesis, Assignment of Absolute Stereochemistry, and Structural Revision of Chlorofusin Wen-Jian Qian, Wan-Guo Wei, Yong-Xia Zhang, and Zhu-Jun Yao pp 6400–6401 DOI: 10.1021/ja072225g Supporting Info

Glutathione- and Cysteine-Induced Transverse Overgrowth on Gold Nanorods Xiaoshan Kou, Shuzhuo Zhang, Zhi Yang, Chia-Kuang Tsung, Galen D. Stucky, Lingdong Sun, Jianfang Wang, and Chunhua Yan pp 6402–6404 DOI: 10.1021/ja0710508 Supporting Info

Ab initio Study of Ultrafast Photochemical Reaction Dynamics of Phenol Blue Takao Kobayashi, Motoyuki Shiga, Akinori Murakami, and Shinichiro Nakamura pp 6405–6424 DOI: 10.1021/ja066994w Supporting Info

Evidence from Raman Spectroscopy That InhA, the Mycobacterial Enoyl Reductase, Modulates the Conformation of the NADH Cofactor to Promote Catalysis Alasdair F. Bell, Christopher F. Stratton, Xujie Zhang, Polina Novichenok, Andrew A. Jaye, Pravin A. Nair, Sapan Parikh, Richa Rawat, and Peter J. Tonge pp 6425–6431 DOI: 10.1021/ja068219m

Adsorption Energy, Growth Mode, and Sticking Probability of Ca on Poly(methyl methacrylate) Surfaces with and without Electron Damage Junfa Zhu, Paul Goetsch, Nancy Ruzycki, and Charles T. Campbell pp 6432–6441 DOI: 10.1021/ja067437c

Infrared Characterization of Hydroxyl Groups on MgO:  A Periodic and Cluster Density Functional Theory Study Céline Chizallet, Guylène Costentin, Michel Che, Françoise Delbecq, and Philippe Sautet pp 6442–6452 DOI: 10.1021/ja068720e Supporting Info

A Complete Macroion−“Blackberry” Assembly−Macroion Transition with Continuously Adjustable Assembly Sizes in {Mo132} Water/Acetone Systems Melissa L. Kistler, Anish Bhatt, Guang Liu, Diego Casa, and Tianbo Liu pp 6453–6460 DOI: 10.1021/ja0685809

NMR Spin State Exchange Spectroscopy Reveals Equilibrium of Two Distinct Conformations of Leucine Zipper GCN4 in Solution Yaroslav Nikolaev and Konstantin Pervushin pp 6461–6469 DOI: 10.1021/ja0685295 Supporting Info

Hydroxyquinone O-Methylation in Mitomycin Biosynthesis Sabine Grüschow, Leng-Chee Chang, Yingqing Mao, and David H. Sherman pp 6470–6476 DOI: 10.1021/ja0700193 Supporting Info

Charge Injection Across Self-Assembly Monolayers in Organic Field-Effect Transistors:  Odd−Even Effects Pablo Stoliar, Rajendra Kshirsagar, Massimiliano Massi, Paolo Annibale, Cristiano Albonetti, Dago M. de Leeuw, and Fabio Biscarini pp 6477–6484 DOI: 10.1021/ja069235m Supporting Info

A Cu/Pt Near-Surface Alloy for Water−Gas Shift Catalysis Jan Knudsen, Anand U. Nilekar, Ronnie T. Vang, Joachim Schnadt, Edward L. Kunkes, James A. Dumesic, Manos Mavrikakis, and Flemming Besenbacher pp 6485–6490 DOI: 10.1021/ja0700855

Force-Induced Prolyl Cis−Trans Isomerization in Elastin-like Polypeptides Alexei Valiaev, Dong Woo Lim, Terrence G. Oas, Ashutosh Chilkoti, and Stefan Zauscher pp 6491–6497 DOI: 10.1021/ja070147r Supporting Info

Stabilized Phosphatidylinositol-5-Phosphate Analogues as Ligands for the Nuclear Protein ING2:  Chemistry, Biology, and Molecular Modeling Wei Huang, Honglu Zhang, Foteini Davrazou, Tatiana G. Kutateladze, Xiaobing Shi, Or Gozani, and Glenn D. Prestwich pp 6498–6506 DOI: 10.1021/ja070195b Supporting Info

Ruthenium(0) Nanoparticle-Catalyzed Isotope Exchange between 10B and 11B Nuclei in Decaborane(14) Zhu Yinghuai, Effendi Widjaja, Shirley Lo Pei Sia, Wang Zhan, Keith Carpenter, John A. Maguire, Narayan S. Hosmane, and M. Frederick Hawthorne pp 6507–6512 DOI: 10.1021/ja070210c Supporting Info

A para-Hydrogen Investigation of Palladium-Catalyzed Alkyne Hydrogenation Joaquín López-Serrano, Simon B. Duckett, Stuart Aiken, Karina Q. Almeida Leñero, Eite Drent, John P. Dunne, Denis Konya, and Adrian C. Whitwood pp 6513–6527 DOI: 10.1021/ja070331c Supporting Info

Isotopically Discriminated NMR Spectroscopy:  A Tool for Investigating Complex Protein Interactions in Vitro Alexander P. Golovanov, Richard T. Blankley, Johanna M. Avis, and Wolfgang Bermel pp 6528–6535 DOI: 10.1021/ja070505q Supporting Info

On the Mechanism of Peripentacene Formation from Pentacene:  Computational Studies of a Prototype for Graphene Formation from Smaller Acenes Brian H. Northrop, Joseph E. Norton, and K. N. Houk pp 6536–6546 DOI: 10.1021/ja070392a Supporting Info

Spin Switching via Targeted Structural Distortion Constantinos J. Milios, Alina Vinslava, Wolfgang Wernsdorfer, Alessandro Prescimone, Peter A. Wood, Simon Parsons, Spyros P. Perlepes, George Christou, and Euan K. Brechin pp 6547–6561 DOI: 10.1021/ja070411g Supporting Info

Acetylcholinesterase:  Mechanisms of Covalent Inhibition of Wild-Type and H447I Mutant Determined by Computational Analyses Yuhui Cheng, Xiaolin Cheng, Zoran Radić, and J. Andrew McCammon pp 6562–6570 DOI: 10.1021/ja070601r Supporting Info

Strong Intermolecular Electronic Coupling within a Tetrathiafulvalene Island Embedded in Self-Assembled Monolayers Yasuyuki Yokota, Ken-ichi Fukui, Toshiaki Enoki, and Masahiko Hara pp 6571–6575 DOI: 10.1021/ja070632m

Porphyrin-Diones and Porphyrin-Tetraones:  Reversible Redox Units Being Localized within the Porphyrin Macrocycle and Their Effect on Tautomerism Karl M. Kadish, W enbo E, Riqiang Zhan, Tony Khoury, Linda J. Govenlock, Jognandan K. Prashar, Paul J. Sintic, Kei Ohkubo, Shunichi Fukuzumi, and Maxwell J. Crossley pp 6576–6588 DOI: 10.1021/ja070759b Supporting Info

Syntheses of the Eastern Halves of Ritterazines B, F, G, and H, Leading to Reassignment of the 5,5-Spiroketal Stereochemistry of Ritterazines B and F Scott T. Phillips and Matthew D. Shair pp 6589–6598 DOI: 10.1021/ja0705487 Supporting Info

Polymer Electrolyte-Gated Organic Field-Effect Transistors:  Low-Voltage, High-Current Switches for Organic Electronics and Testbeds for Probing Electrical Transport at High Charge Carrier Density Matthew J. Panzer and C. Daniel Frisbie pp 6599–6607 DOI: 10.1021/ja0708767 Supporting Info

Crucial Role of Anions on the Deprotonation of the Cationic Dihydrogen Complex trans-[FeH(η2-H2)(dppe)2]+ Manuel G. Basallote, Maria Besora, C. Esther Castillo, María J. Fernández-Trujillo, Agustí Lledós, Feliu Maseras, and M. Angeles Máñez pp 6608–6618 DOI: 10.1021/ja070939l Supporting Info

Phage Display Evolution of a Peptide Substrate for Yeast Biotin Ligase and Application to Two-Color Quantum Dot Labeling of Cell Surface Proteins Irwin Chen, Yoon-Aa Choi, and Alice Y. Ting pp 6619–6625 DOI: 10.1021/ja071013g Supporting Info

Conductive Polymer Brushes of Regioregular Head-to-Tail Poly(3-alkylthiophenes) via Catalyst-Transfer Surface-Initiated Polycondensation Volodymyr Senkovskyy, Natalya Khanduyeva, Hartmut Komber, Ulrich Oertel, Manfred Stamm, Dirk Kuckling, and Anton Kiriy pp 6626–6632 DOI: 10.1021/ja0710306 Supporting Info

Synthesis of Molecular Brushes by “Grafting onto” Method:  Combination of ATRP and Click Reactions Haifeng Gao and Krzysztof Matyjaszewski pp 6633–6639 DOI: 10.1021/ja0711617 Supporting Info

Magnetic Tweezers Measurement of the Bond Lifetime−Force Behavior of the IgG−Protein A Specific Molecular Interaction Hao Shang and Gil U. Lee pp 6640–6646 DOI: 10.1021/ja071215c Supporting Info

Laser Photoexcitation of NAD(P)H Induces Reduction of P450 BM3 Heme Domain on the Microsecond Time Scale Hazel M. Girvan, Derren J. Heyes, Nigel S. Scrutton, and Andrew W. Munro pp 6647–6653 DOI: 10.1021/ja071355m

Reactivity of Platinum Metal with Organic Radical Anions from Metal to Negative Oxidation States Jalal Ghilane, Maryline Guilloux-Viry, Corinne Lagrost, Jacques Simonet, and Philippe Hapiot pp 6654–6661 DOI: 10.1021/ja071483a Supporting Info

Reactions of Monomeric [1,2,4-(Me3C)3C5H2]2CeH and CO with or without H2:  An Experimental and Computational Study [J. Am. Chem. Soc. 2007, 129, 2529−2541]. Evan L. Werkema, Laurent Maron, Odile Eisenstein, and Richard A. Andersen p 6662 DOI: 10.1021/ja072097w

Distinct Reaction Pathways Followed upon Reduction of Oxy-Heme Oxygenase and Oxy-Myoglobin as Characterized by Mössbauer Spectroscopy [J. Am. Chem. Soc. 2007, 129, 1402−1412]. Ricardo Garcia-Serres, Roman M. Davydov, Toshitaka Matsui, Masao Ikeda-Saito, Brian M. Hoffman, and Boi Hanh Huynh p 6662 DOI: 10.1021/ja0724285

Catalytic Enantioselective Synthesis of Chiral Phthalides by SmI2-Mediated Reductive Cyclization of 2-Acylarylcarboxylates [J. Am. Chem. Soc. 2006, 128, 5624−5625]. Ling-Lin Huang, Ming-Hua Xu, and Guo-Qiang Lin p 6662 DOI: 10.1021/ja0768892

Issue 21

Studying the Thermodynamics of Surface Reactions on Nanoparticles by Electrostatic Titrations Alexander M. Kalsin, Bartlomiej Kowalczyk, Paul Wesson, Maciej Paszewski, and Bartosz A. Grzybowski pp 6664–6665 DOI: 10.1021/ja068329t Supporting Info

Imaging the Structure of an Individual C60 Fullerene Molecule and its Deformation Process Using HRTEM with Atomic Sensitivity Zheng Liu, Kazu Suenaga, and Sumio Iijima pp 6666–6667 DOI: 10.1021/ja068516r Supporting Info

Positioning Scission of Single DNA Molecules with Nonspecific Endonuclease Based on Nanomanipulation Bin Li, Yi Zhang, Shu-hua Yan, Jun-hong Lü, Ming Ye, Min-qian Li, and Jun Hu pp 6668–6669 DOI: 10.1021/ja0687015

Solid-State NMR Reveals Structural and Dynamical Properties of a Membrane-Anchored Electron-Carrier Protein, Cytochrome b5 Ulrich H. N. Dürr, Kazutoshi Yamamoto, Sang-Choul Im, Lucy Waskell, and Ayyalusamy Ramamoorthy pp 6670–6671 DOI: 10.1021/ja069028m Supporting Info

Convergent Proton-Transfer Photocycles Violate Mirror-Image Symmetry in a Key Melanin Monomer Seth Olsen, Jennifer Riesz, Indu Mahadevan, Aaron Coutts, Jacques P. Bothma, Benjamin J. Powell, Ross H. McKenzie, Sean C. Smith, and Paul Meredith pp 6672–6673 DOI: 10.1021/ja069280u Supporting Info

Characterization of a Mixed Salt of 1-Hydroxypyridin-2-one Pu(IV) Complexes1 Anne E. V. Gorden, Jide Xu, Géza Szigethy, Allen Oliver, David K. Shuh, and Kenneth N. Raymond pp 6674–6675 DOI: 10.1021/ja070168l Supporting Info

Peptide Ligation Catalyzed by Functionalized Gold Nanoparticles Yannick Fillon, Ayush Verma, Partha Ghosh, Dawn Ernenwein, Vincent M. Rotello, and Jean Chmielewski pp 6676–6677 DOI: 10.1021/ja070301+ Supporting Info

Docosahexaenoyl Chains Isomerize on the Sub-Nanosecond Time Scale Olivier Soubias and Klaus Gawrisch pp 6678–6679 DOI: 10.1021/ja068856c Supporting Info

Development of an Electrolytic System for Non-Kolbe Electrolysis Based on the Acid−Base Reaction between Carboxylic Acids as a Substrate and Solid-Supported Bases Toshiki Tajima, Hitoshi Kurihara, and Toshio Fuchigami pp 6680–6681 DOI: 10.1021/ja070283w Supporting Info

J-Deconvolution Using Maximum Entropy Reconstruction Applied to 13C−13C Solid-State Cross-Polarization Magic-Angle-Spinning NMR of Proteins Ingo Scholz, Stefan Jehle, Peter Schmieder, Matthias Hiller, Frank Eisenmenger, Hartmut Oschkinat, and Barth-Jan van Rossum pp 6682–6683 DOI: 10.1021/ja070849g Supporting Info

A Modular Approach for Facile Biosynthesis of Labdane-Related Diterpenes Anthony Cyr, P. Ross Wilderman, Mara Determan, and Reuben J. Peters pp 6684–6685 DOI: 10.1021/ja071158n Supporting Info

Catalytic Enantioselective Petasis-Type Reaction of Quinolines Catalyzed by a Newly Designed Thiourea Catalyst Yousuke Yamaoka, Hideto Miyabe, and Yoshiji Takemoto pp 6686–6687 DOI: 10.1021/ja071470x Supporting Info

Chiral Amplification of Chiral Porphyrin Derivatives by Templated Heteroaggregation Donato Monti, Mariano Venanzi, Manuela Stefanelli, Alessandro Sorrenti, Giovanna Mancini, Corrado Di Natale, and Roberto Paolesse pp 6688–6689 DOI: 10.1021/ja071249k Supporting Info

Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N-Alkyl Arylamines Seth B. Herzon and John F. Hartwig pp 6690–6691 DOI: 10.1021/ja0718366 Supporting Info

Selectivity in the Ruthenium-Catalyzed Alder Ene Reactions of Di- and Triynes Eun Jin Cho and Daesung Lee pp 6692–6693 DOI: 10.1021/ja0719430 Supporting Info

Spatiotemporal Control of Migration of Single Cells on a Photoactivatable Cell Microarray Jun Nakanishi, Yukiko Kikuchi, Satoshi Inoue, Kazuo Yamaguchi, Tohru Takarada, and Mizuo Maeda pp 6694–6695 DOI: 10.1021/ja070294p Supporting Info

Highly Activatable and Rapidly Releasable Caged Fluorescein Derivatives Tomonori Kobayashi, Yasuteru Urano, Mako Kamiya, Tasuku Ueno, Hirotatsu Kojima, and Tetsuo Nagano pp 6696–6697 DOI: 10.1021/ja070376d Supporting Info

Ordered Mesoporous Ce1-xZrxO2 Solid Solutions with Crystalline Walls Quan Yuan, Qiang Liu, Wei-Guo Song, Wei Feng, Wan-Li Pu, Ling-Dong Sun, Ya-Wen Zhang, and Chun-Hua Yan pp 6698–6699 DOI: 10.1021/ja070908q Supporting Info

Microwave-Assisted Tandem Cross Metathesis Intramolecular Aza-Michael Reaction:  An Easy Entry to Cyclic β-Amino Carbonyl Derivatives Santos Fustero, Diego Jiménez, María Sánchez-Roselló, and Carlos del Pozo pp 6700–6701 DOI: 10.1021/ja0709829 Supporting Info

Bi2Te3/Te Multiple Heterostructure Nanowire Arrays Formed by Confined Precipitation Wei Wang, Xiaoli Lu, Tao Zhang, Genqiang Zhang, Wenjun Jiang, and Xiaoguang Li pp 6702–6703 DOI: 10.1021/ja070976c Supporting Info

Ultrahigh-Field Solid-State 59Co NMR Studies of Co(C2B9H11)2- and Co(C5H5)2+ Salts Kristopher J. Ooms, Victor V. Terskikh, and Roderick E. Wasylishen pp 6704–6705 DOI: 10.1021/ja0710095 Supporting Info

Poly(ethylene glycol) Ligands for High-Resolution Nanoparticle Mass Spectrometry Joseph B. Tracy, Gregory Kalyuzhny, Matthew C. Crowe, Ramjee Balasubramanian, Jai-Pil Choi, and Royce W. Murray pp 6706–6707 DOI: 10.1021/ja071042r Supporting Info

Tip-Enhanced Raman Spectra of Picomole Quantities of DNA Nucleobases at Au(111) Katrin F. Domke, Dai Zhang, and Bruno Pettinger pp 6708–6709 DOI: 10.1021/ja071107q

Magnesium Nanowires:  Enhanced Kinetics for Hydrogen Absorption and Desorption Weiyang Li, Chunsheng Li, Hua Ma, and Jun Chen pp 6710–6711 DOI: 10.1021/ja071323z Supporting Info

Preferential End Functionalization of Au Nanorods through Electrostatic Interactions P. Pramod, S. T. Shibu Joseph, and K. George Thomas pp 6712–6713 DOI: 10.1021/ja071536o Supporting Info

Single-Molecule Junction Conductance through Diaminoacenes Jordan R. Quinn, Frank W. Foss, Jr., Latha Venkataraman, Mark S. Hybertsen, and Ronald Breslow pp 6714–6715 DOI: 10.1021/ja0715804 Supporting Info

A Simple and Modular Strategy for Small Molecule Synthesis:  Iterative Suzuki−Miyaura Coupling of B-Protected Haloboronic Acid Building Blocks Eric P. Gillis and Martin D. Burke pp 6716–6717 DOI: 10.1021/ja0716204 Supporting Info

Intense Mechanoluminescence and Gas Phase Reactions from the Sonication of an Organic Slurry Nathan C. Eddingsaas and Kenneth S. Suslick pp 6718–6719 DOI: 10.1021/ja0716498 Supporting Info

Copper(II)−Hydroperoxo Complex Induced Oxidative N-Dealkylation Chemistry Debabrata Maiti, Amy A. Narducci Sarjeant, and Kenneth D. Karlin pp 6720–6721 DOI: 10.1021/ja0719024 Supporting Info

Stable Tetravalent Phosphonium Enolate Zwitterions Xue-Feng Zhu, Christopher E. Henry, and Ohyun Kwon pp 6722–6723 DOI: 10.1021/ja071990s Supporting Info

Asymmetric Coordination Polymerization of Acrylamides by Enantiomeric Metallocenium Ester Enolate Catalysts Garret M. Miyake, Wesley R. Mariott, and Eugene Y.-X. Chen pp 6724–6725 DOI: 10.1021/ja072073p Supporting Info

Fluorescence Probe of Trp-Cage Protein Conformation in Solution and in Gas Phase Anthony T. Iavarone, Alexandra Patriksson, David van der Spoel, and Joel H. Parks pp 6726–6735 DOI: 10.1021/ja065092s Supporting Info

Counting the Monomers in Nanometer-Sized Oligomers by Pulsed Electron−Electron Double Resonance Bela E. Bode, Dominik Margraf, Jörn Plackmeyer, Gerd Dürner, Thomas F. Prisner, and Olav Schiemann pp 6736–6745 DOI: 10.1021/ja065787t Supporting Info

Determination of Radical Re-encounter Probability Distributions from Magnetic Field Effects on Reaction Yields Christopher T. Rodgers, Stuart A. Norman, Kevin B. Henbest, Christiane R. Timmel, and P. J. Hore pp 6746–6755 DOI: 10.1021/ja068209l Supporting Info

Chiral Brønsted Acid Catalyzed Enantioselective Mannich-Type Reaction Masahiro Yamanaka, Junji Itoh, Kohei Fuchibe, and Takahiko Akiyama pp 6756–6764 DOI: 10.1021/ja0684803 Supporting Info

Comparative Reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3):  Impact of Ancillary Ligand L on Activation of Carbon−Hydrogen Bonds Including Catalytic Hydroarylation and Hydrovinylation/Oligomerization of Ethylene Nicholas A. Foley, Marty Lail, John P. Lee, T. Brent Gunnoe, Thomas R. Cundari, and Jeffrey L. Petersen pp 6765–6781 DOI: 10.1021/ja068542p Supporting Info

Dynamical Regulation of Ligand Migration by a Gate-Opening Molecular Switch in Truncated Hemoglobin-N from Mycobacterium tuberculosis Axel Bidon-Chanal, Marcelo A. Martí, Darío A. Estrin, and F. Javier Luque* pp 6782–6788 DOI: 10.1021/ja0689987 Supporting Info

Development of the Ca−Au−In Icosahedral Quasicrystal and Two Crystalline Approximants:  Practice via Pseudogap Electronic Tuning Qisheng Lin and John D. Corbett pp 6789–6797 DOI: 10.1021/ja069143x Supporting Info

Electronic Structure of the PYP Chromophore in Its Native Protein Environment Evgeniy V. Gromov, Irene Burghardt, Horst Köppel, and Lorenz S. Cederbaum pp 6798–6806 DOI: 10.1021/ja069185l Supporting Info

Guiding Bacteria with Small Molecules and RNA Shana Topp and Justin P. Gallivan pp 6807–6811 DOI: 10.1021/ja0692480 Supporting Info

Ultrafast Deactivation of an Excited Cytosine−Guanine Base Pair in DNA Gerrit Groenhof, Lars V. Schäfer, Martial Boggio-Pasqua, Maik Goette, Helmut Grubmüller, and Michael A. Robb pp 6812–6819 DOI: 10.1021/ja069176c Supporting Info

Short, Highly Ordered, Single-Walled Mixed-Oxide Nanotubes Assemble from Amorphous Nanoparticles Sanjoy Mukherjee, Keesuk Kim, and Sankar Nair pp 6820–6826 DOI: 10.1021/ja070124c Supporting Info

Methyl Rotation Barriers in Proteins from 2H Relaxation Data. Implications for Protein Structure Yi Xue, Maria S. Pavlova, Yaroslav E. Ryabov, Bernd Reif, and Nikolai R. Skrynnikov pp 6827–6838 DOI: 10.1021/ja0702061 Supporting Info

Intramolecular Electron Transfer within the Substituted Tetrathiafulvalene−Quinone Dyads:  Facilitated by Metal Ion and Photomodulation in the Presence of Spiropyran Hui Wu, Deqing Zhang, Lei Su, Kei Ohkubo, Chunxi Zhang, Shiwei Yin, Lanqun Mao, Zhigang Shuai, Shunichi Fukuzumi, and Daoben Zhu pp 6839–6846 DOI: 10.1021/ja0702824 Supporting Info

Palladium-Catalyzed Asymmetric Phosphination. Scope, Mechanism, and Origin of Enantioselectivity Natalia F. Blank, Jillian R. Moncarz, Tim J. Brunker, Corina Scriban, Brian J. Anderson, Omar Amir, David S. Glueck, Lev N. Zakharov, James A. Golen, Christopher D. Incarvito, and Arnold L. Rheingold pp 6847–6858 DOI: 10.1021/ja070225a Supporting Info

Template-Directed Oligonucleotide Strand Ligation, Covalent Intramolecular DNA Circularization and Catenation Using Click Chemistry Ravindra Kumar, Afaf El-Sagheer, John Tumpane, Per Lincoln, L. Marcus Wilhelmsson, and Tom Brown pp 6859–6864 DOI: 10.1021/ja070273v Supporting Info

Singlet Oxygen Production by Peptide-Coated Quantum Dot−Photosensitizer Conjugates James M. Tsay, Michael Trzoss, Lixin Shi, Xiangxu Kong, Matthias Selke, Michael E. Jung, and Shimon Weiss pp 6865–6871 DOI: 10.1021/ja070713i Supporting Info

Synthesis of 5‘-Methylthio Coformycins:  Specific Inhibitors for Malarial Adenosine Deaminase Peter C. Tyler, Erika A. Taylor, Richard F. G. Fröhlich, and Vern L. Schramm pp 6872–6879 DOI: 10.1021/ja0708363

Proton-Abstraction Mechanism in the Palladium-Catalyzed Intramolecular Arylation:  Substituent Effects Domingo García-Cuadrado, Paula de Mendoza, Ataualpa A. C. Braga, Feliu Maseras, and Antonio M. Echavarren pp 6880–6886 DOI: 10.1021/ja071034a Supporting Info

Oxidative Phenol Coupling Reactions Catalyzed by OxyB:  A Cytochrome P450 from the Vancomycin Producing Organism. Implications for Vancomycin Biosynthesis Katharina Woithe, Nina Geib, Katja Zerbe, Dong Bo Li, Markus Heck, Severine Fournier-Rousset, Odile Meyer, Francesca Vitali, Nobuatsu Matoba, Khaled Abou-Hadeed, and John A. Robinson pp 6887–6895 DOI: 10.1021/ja071038f Supporting Info

Metal-Dependent Global Folding and Activity of the 8-17 DNAzyme Studied by Fluorescence Resonance Energy Transfer Hee-Kyung Kim, Juewen Liu, Jing Li, Nandini Nagraj, Mingxi Li, Caroline M.-B. Pavot, and Yi Lu pp 6896–6902 DOI: 10.1021/ja0712625 Supporting Info

Nature of the Monoclinic to Cubic Phase Transition in the Fast Oxygen Ion Conductor La2Mo2O9 (LAMOX) Lorenzo Malavasi, HyunJeong Kim, Simon J. L. Billinge, Thomas Proffen, Cristina Tealdi, and Giorgio Flor pp 6903–6907 DOI: 10.1021/ja071281e

The Sila-Explosives Si(CH2N3)4 and Si(CH2ONO2)4:  Silicon Analogues of the Common Explosives Pentaerythrityl Tetraazide, C(CH2N3)4, and Pentaerythritol Tetranitrate, C(CH2ONO2)4 Thomas M. Klapötke, Burkhard Krumm, Rainer Ilg, Dennis Troegel, and Reinhold Tacke pp 6908–6915 DOI: 10.1021/ja071299p Supporting Info

Kinetics of the Oxygenation of Unsaturated Organics with Singlet Oxygen Generated from H2O2 by a Heterogeneous Molybdenum Catalyst Bert F. Sels, Dirk E. De Vos, and Pierre A. Jacobs pp 6916–6926 DOI: 10.1021/ja065849f Supporting Info

Building Layer-by-Layer a Bis(dithiocarbamato)copper(II) Complex on Au{111} Surfaces Roberto Cao, Jr., Alicia Díaz, Roberto Cao, Antonio Otero, Raymundo Cea, María C. Rodríguez-Argüelles, and Carmen Serra pp 6927–6930 DOI: 10.1021/ja068349v Supporting Info

Studies on the Heck Reaction with Alkenyl Phosphates:  Can the 1,2-Migration Be Controlled? Scope and Limitations Jean-Philippe Ebran, Anders L. Hansen, Thomas M. Gøgsig, and Troels Skrydstrup pp 6931–6942 DOI: 10.1021/ja070321b Supporting Info

Substrate- and Isoform-Specific Dioxygen Complexes of Nitric Oxide Synthase David Li, Mariam Kabir, Dennis J. Stuehr, Denis L. Rousseau, and Syun-Ru Yeh pp 6943–6951 DOI: 10.1021/ja070683j Supporting Info

A Marcus Treatment of Rate Constants for Protonation of Ring-Substituted α-Methoxystyrenes:  Intrinsic Reaction Barriers and the Shape of the Reaction Coordinate John P. Richard and Kathleen B. Williams pp 6952–6961 DOI: 10.1021/ja071007k Supporting Info

Time-Dependent Density Functional Theory. From the series:  Lecture Notes in Physics, Volume 706 Edited by Miguel A. L. Marques (Universidade de Coimbra, Portugal), Carsten A. Ullrich (University of Missouri-Columbia, MO), Fernando Nogueira (Universidade de Coimbra), Angel Rubio (Universidad del País Vasco, San Sebastián, Spain), Kieron Burke (Rutgers University, Piscataway, NJ), and Eberhard K. U. Gross (Freie Universität, Berlin, Germany). Springer:  Berlin, Heidelberg, New York. 2006. xxxiv + 590 pp. $99.00. ISBN 3-540-35422-0. Anna I. Krylov p 6962 DOI: 10.1021/ja069829p

Frontiers in Transition Metal-Containing Polymers Edited by Alaa S. Abd-El-Aziz (University of British Columbia Okanagan, Kelowna, Canada) and Ian Manners (University of Bristol, U.K.). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 534 pp. $135. ISBN:  0-471-73015-7. José Rodríguez and Jonathan G. C. Veinot pp 6962–6963 DOI: 10.1021/ja0769043

Nanocatalysis Edited by Ulrich Heiz (Technische Universität München, Germany) and Uzi Landman (Georgia Institute of Technology, Atlanta, GA). From the series:  Nanoscience and Technology. Edited by P. Avouris, B. Bhushan, D. Bimberg, K. von Klitzing, H. Sakaki, and R. Wiesendanger. Springer:  Berlin, Heidelberg, New York. 2007. xvi + 504 pp. $179.00. ISBN 978-3-540-32645-8. Steven L. Suib p 6963 DOI: 10.1021/ja0769200

Calixarenes in the Nanoworld Edited by Jacques Vicens (ECPM-ULP-CERNS, Strasbourg, France) and Jack Harrowfield (ISIS-ULP-CERNS, Strasbourg, France. Assistant Editor:  Lassaad Baklouti (FSB, Bizerte, Tunisia). Springer:  Dordrecht. 2007. x + 396 pp. $189.00. ISBN 1-40205-021-6. Michael T. Blanda pp 6963–6964 DOI: 10.1021/ja0769245

Advances in Biopolymers:  Molecules, Clusters, Networks, and Interactions. ACS Symposium Series 935 Edited by Marshall L. Fishman (U.S. Department of Agriculture), Phoebe X. Qi (U.S. Department of Agriculture), and Louise Wicker (University of Georgia). American Chemical Society:  Washington, DC (distributed by Oxford University Press). 2006. xii + 316 pp. $179.50. ISBN 0-8412-3959-2. p 6964 DOI: 10.1021/ja0769346

Multifunctional Conducting Molecular Materials Edited by Gunzi Saito (Kyoto University, Japan), Fred Wudl (University of California, Los Angeles, USA), Robert C. Haddon (Univeristy of California, Riverside, USA), Katsumi Tanigaki (Tohoku University, Miyagi, Japan), Toshiaki Enoki (Tokyo Institute of Technology, Japan), Howard E. Katz (Johns Hopkins University, Balitmore, USA), Mitsuhiko Maesato (Kyoto University). Royal Society of Chemistry:  Cambridge. 2007. xii + 305 pp. $189.00. ISBN 0-85404-496-5. p 6964 DOI: 10.1021/ja0769402

Issue 22

Inhibition of Pseudomonas aeruginosa Biofilm Formation with Bromoageliferin Analogues Robert W. Huigens III, Justin J. Richards, Gina Parise, T. Eric Ballard, Wei Zeng, Rajendar Deora, and Christian Melander pp 6966–6967 DOI: 10.1021/ja069017t Supporting Info

Excited-State Quenching by Proton-Coupled Electron Transfer Javier J. Concepcion, M. Kyle Brennaman, Jeremy R. Deyton, Natalia V. Lebedeva, Malcolm D. E. Forbes, John M. Papanikolas, and Thomas J. Meyer pp 6968–6969 DOI: 10.1021/ja069049g Supporting Info

Chromophore Channeling in the G-Protein Coupled Receptor Rhodopsin Ting Wang and Yong Duan pp 6970–6971 DOI: 10.1021/ja0691977 Supporting Info

Probing a Fibrillation Nucleus Directly by Deep Ultraviolet Raman Spectroscopy Victor Shashilov, Ming Xu, Vladimir V. Ermolenkov, Laura Fredriksen, and Igor K. Lednev pp 6972–6973 DOI: 10.1021/ja070038c Supporting Info

Synthesis of Monodisperse Pt Nanocubes and Their Enhanced Catalysis for Oxygen Reduction Chao Wang, Hideo Daimon, Youngmin Lee, Jaemin Kim, and Shouheng Sun pp 6974–6975 DOI: 10.1021/ja070440r Supporting Info

β-Elimination and Peptide Bond Hydrolysis:  Two Distinct Mechanisms of Human IgG1 Hinge Fragmentation upon Storage Steven L. Cohen, Colleen Price, and Josef Vlasak pp 6976–6977 DOI: 10.1021/ja0705994 Supporting Info

Detection of Explosives with a Fluorescent Nanofibril Film Tammene Naddo, Yanke Che, Wei Zhang, Kaushik Balakrishnan, Xiaomei Yang, Max Yen, Jincai Zhao, Jeffrey S. Moore, and Ling Zang pp 6978–6979 DOI: 10.1021/ja070747q Supporting Info

Highly Sensitive Nitric Oxide Detection Using X-ray Photoelectron Spectroscopy Manish Dubey, Steven L. Bernasek, and Jeffrey Schwartz pp 6980–6981 DOI: 10.1021/ja070943x Supporting Info

Metallodendrimers as Transphosphorylation Catalysts Marco Martin, Flavio Manea, Roberto Fiammengo, Leonard J. Prins, Lucia Pasquato, and Paolo Scrimin pp 6982–6983 DOI: 10.1021/ja070980o Supporting Info

Acyclic Ribooxacarbenium Ion Mimics as Transition State Analogues of Human and Malarial Purine Nucleoside Phosphorylases Erika A. Taylor, Keith Clinch, Peter M. Kelly, Lei Li, Gary B. Evans, Peter C. Tyler, and Vern L. Schramm pp 6984–6985 DOI: 10.1021/ja071087s Supporting Info

Facile and E-Selective Intramolecular Ring-Closing Metathesis Reactions in 310-Helical Peptides:  A 3D Structural Study Amie K. Boal, Ivan Guryanov, Alessandro Moretto, Marco Crisma, Erica L. Lanni, Claudio Toniolo, Robert H. Grubbs, and Daniel J. O'Leary pp 6986–6987 DOI: 10.1021/ja071148m Supporting Info

β-Styryl- and β-Aryl-β-alanine Products of Phenylalanine Aminomutase Catalysis Karin L. Klettke, Sanjit Sanyal, Washington Mutatu, and Kevin D. Walker pp 6988–6989 DOI: 10.1021/ja071328w Supporting Info

Challenging the Prediction of Anionogenic Ferromagnetism for Rb4O6 Jürgen Winterlik, Gerhard H. Fecher, and Claudia FelserClaus Mühle and Martin Jansen pp 6990–6991 DOI: 10.1021/ja071490z

A Self-Assembled DNA Bipyramid Christoph M. Erben, Russell P. Goodman, and Andrew J. Turberfield pp 6992–6993 DOI: 10.1021/ja071493b Supporting Info

Rapid, Efficient Synthesis of Heterobifunctional Biodegradable Dendrimers Andrew P. Goodwin, Stephanie S. Lam, and Jean M. J. Fréchet pp 6994–6995 DOI: 10.1021/ja071530z Supporting Info

Synthesis of Bulky Phosphines by Rhodium-Catalyzed Formal [2 + 2 + 2] Cycloaddition Reactions of Tethered Diynes with 1-Alkynylphosphine Sulfides Azusa Kondoh, Hideki Yorimitsu, and Koichiro Oshima pp 6996–6997 DOI: 10.1021/ja071622o Supporting Info

Aryl Hydroxylation from a Mononuclear Copper-Hydroperoxo Species Debabrata Maiti, Heather R. Lucas, Amy A. Narducci Sarjeant, and Kenneth D. Karlin pp 6998–6999 DOI: 10.1021/ja071704c Supporting Info

Unusual [2+4] and [2+2] Cycloadditions of Arenes in the Confined Cavity of Self-Assembled Cages Yuki Nishioka, Takumi Yamaguchi, Michito Yoshizawa, and Makoto Fujita pp 7000–7001 DOI: 10.1021/ja071591x Supporting Info

Cyclopolymerization of 1,6-Heptadienes Catalyzed by Iron and Cobalt Complexes:  Synthesis of Polymers with Trans- or Cis-Fused 1,2-Cyclopentanediyl Groups Depending on the Catalyst Daisuke Takeuchi, Ryuichi Matsuura, Sehoon Park, and Kohtaro Osakada pp 7002–7003 DOI: 10.1021/ja0718568 Supporting Info

Enantioselective Organocatalytic Singly Occupied Molecular Orbital Activation:  The Enantioselective α-Enolation of Aldehydes Hye-Young Jang, Jun-Bae Hong, and David W. C. MacMillan pp 7004–7005 DOI: 10.1021/ja0719428 Supporting Info

An Electron-Conducting Cross-Linked Polyaniline-Based Redox Hydrogel, Formed in One Step at pH 7.2, Wires Glucose Oxidase Nicolas Mano, Joung Eun Yoo, Jacob Tarver, Yueh-Lin Loo, and Adam Heller pp 7006–7007 DOI: 10.1021/ja071946c

A Mixed-Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site Tianbiao Liu and Marcetta Y. Darensbourg pp 7008–7009 DOI: 10.1021/ja071851a Supporting Info

Facile Quantification of Lesions Derived from 2‘-Deoxyguanosine in DNA Liang Xue and Marc M. Greenberg pp 7010–7011 DOI: 10.1021/ja072174n Supporting Info

Molecular Insight into the Pathway to Crystallization of Aluminum Caroline Desgranges and Jerome Delhommelle pp 7012–7013 DOI: 10.1021/ja072260n Supporting Info

Propagation of Blood Clotting in the Complex Biochemical Network of Hemostasis Is Described by a Simple Mechanism Matthew K. Runyon, Bethany L. Johnson-Kerner, Christian J. Kastrup, Thuong G. Van Ha, and Rustem F. Ismagilov pp 7014–7015 DOI: 10.1021/ja072602p Supporting Info

A Keplerate Magnetic Cluster Featuring an Icosidodecahedron of Ni(II) Ions Encapsulating a Dodecahedron of La(III) Ions Xiang-Jian Kong, Yan-Ping Ren, La-Sheng Long, Zhiping Zheng, Rong-Bin Huang, and Lan-Sun Zheng pp 7016–7017 DOI: 10.1021/ja0726198 Supporting Info

Nitroxide/Substrate Weak Hydrogen Bonding:  Attitude and Dynamics of Collisions in Solution Jennifer L. Russ, Juan Gu, Kun-Hsiang Tsai, Tom Glass, James C. Duchamp, and Harry C. Dorn pp 7018–7027 DOI: 10.1021/ja064632i Supporting Info

Transient Dimerization and Conformational Change of a BLUF Protein:  YcgF Yusuke Nakasone, Taka-aki Ono, Asako Ishii, Shinji Masuda, and Masahide Terazima pp 7028–7035 DOI: 10.1021/ja065682q

Solvent Control of Charge Localization in 11-Bond Bridged Dinitroaromatic Radical Anions Stephen F. Nelsen, Michael N. Weaver, and João P. Telo pp 7036–7043 DOI: 10.1021/ja067088m Supporting Info

Probing Excitation Delocalization in Supramolecular Chiral Stacks by Means of Circularly Polarized Light:  Experiment and Modeling Frank C. Spano, Stefan C. J. Meskers, Emanuelle Hennebicq, and David Beljonne pp 7044–7054 DOI: 10.1021/ja067321g Supporting Info

Transition State Analysis of Acid-Catalyzed dAMP Hydrolysis Joe A. B. McCann and Paul J. Berti pp 7055–7064 DOI: 10.1021/ja067371l Supporting Info

Penultimate Effect in Ethylene−Styrene Copolymerization and the Discovery of Highly Active Ethylene−Styrene Catalysts with Increased Styrene Reactivity Daniel J. Arriola, Marilyn Bokota, Richard E. Campbell, Jr., Jerzy Klosin, Robert E. LaPointe, O. David Redwine, Ravi B. Shankar, Francis J. Timmers, and Khalil A. Abboud pp 7065–7076 DOI: 10.1021/ja070061y Supporting Info

Solid-Phase Synthesis of Multiple Classes of Peptidomimetics from Versatile Resin-Bound Aldehyde Intermediates William L. Scott, Jacek G. Martynow, John C. Huffman, and Martin J. O'Donnell pp 7077–7088 DOI: 10.1021/ja069188y Supporting Info

Photoinduced Conformational Switch of Enantiopure Azobenzenes Controlled by a Sulfoxide M. Carmen Carreño, Isabel García, Irene Núñez, Estíbaliz Merino, María Ribagorda, Silvia Pieraccini, and Gian Piero Spada pp 7089–7100 DOI: 10.1021/ja070163o Supporting Info

Selective Hydrogenation of the CO Bond in Acrolein through the Architecture of Bimetallic Surface Structures Luis E. Murillo, Amit M. Goda, and Jingguang G. Chen pp 7101–7105 DOI: 10.1021/ja070264m Supporting Info

Double-Lanthanide-Binding Tags:  Design, Photophysical Properties, and NMR Applications Langdon J. Martin, Martin J. Hähnke, Mark Nitz, Jens Wöhnert, Nicholas R. Silvaggi, Karen N. Allen, Harald Schwalbe, and Barbara Imperiali pp 7106–7113 DOI: 10.1021/ja070480v Supporting Info

Double-Lanthanide-Binding Tags for Macromolecular Crystallographic Structure Determination Nicholas R. Silvaggi, Langdon J. Martin, Harald Schwalbe, Barbara Imperiali, and Karen N. Allen pp 7114–7120 DOI: 10.1021/ja070481n

Electromechanical Phase Transition in Hexacyanometallate Nanostructure (Prussian Blue) David Giménez-Romero, Jerónimo Agrisuelas, José Juan García-Jareño, Joan Gregori, Claude Gabrielli, Hubert Perrot, and Francisco Vicente pp 7121–7126 DOI: 10.1021/ja070895g

Synthesis and Characterization of the Keggin-Type Ruthenium-Nitrido Derivative [PW11O39{RuN}]4- and Evidence of Its Electrophilic Reactivity Vanina Lahootun, Claire Besson, Richard Villanneau, Françoise Villain, Lise-Marie Chamoreau, Kamal Boubekeur, Sébastien Blanchard, René Thouvenot, and Anna Proust pp 7127–7135 DOI: 10.1021/ja071137t Supporting Info

Influence of Connectivity and Porosity on Ligand-Based Luminescence in Zinc Metal−Organic Frameworks Christina A. Bauer, Tatiana V. Timofeeva, Thomas B. Settersten, Brian D. Patterson, Vincent H. Liu, Blake A. Simmons, and Mark D. Allendorf pp 7136–7144 DOI: 10.1021/ja0700395 Supporting Info

Well-Defined Protein−Polymer Conjugates via in Situ RAFT Polymerization Cyrille Boyer, Volga Bulmus, Jingquan Liu, Thomas P. Davis, Martina H. Stenzel, and Christopher Barner-Kowollik pp 7145–7154 DOI: 10.1021/ja070956a Supporting Info

Pyromellitamide Aggregates and Their Response to Anion Stimuli James E. A. Webb, Maxwell J. Crossley, Peter Turner, and Pall Thordarson pp 7155–7162 DOI: 10.1021/ja0713781 Supporting Info

Phenalenyl-Based Neutral Radical Molecular Conductors:  Substituent Effects on Solid-State Structures and Properties Sushanta K. Pal, Mikhail E. Itkis, Fook S. Tham, Robert W. Reed, Richard T. Oakley, Bruno Donnadieu, and Robert C. Haddon pp 7163–7174 DOI: 10.1021/ja070103i Supporting Info

Anion Chelation by Amido Acid Functionalized Fused Quartz/Water Interfaces Studied by Nonlinear Optics Julianne M. Gibbs-Davis, Patrick L. Hayes, Karl A. Scheidt, and Franz M. Geiger pp 7175–7184 DOI: 10.1021/ja068117w Supporting Info

Direct Access to N-H-Aziridines from Asymmetric Catalytic Aziridination with Borate Catalysts Derived from Vaulted Binaphthol and Vaulted Biphenanthrol Ligands Zhenjie Lu, Yu Zhang, and William D. Wulff pp 7185–7194 DOI: 10.1021/ja069371r Supporting Info

trans-W(Cmesityl)(dmpe)2H:  Revealing a Highly Polar W−H Bond and H-Mobility in Liquid and Solid State Fenglou Zou, Franck Furno, Thomas Fox, Helmut W. Schmalle, Heinz Berke, Jürgen Eckert, Zema Chowdhury, and Peter Burger pp 7195–7205 DOI: 10.1021/ja069140k Supporting Info

Total Syntheses, Fragmentation Studies, and Antitumor/Antiproliferative Activities of FR901464 and Its Low Picomolar Analogue [J. Am. Chem. Soc. 2007, 129, 2648−2659]. Brian J. Albert, Ananthapadmanabhan Sivaramakrishnan, Tadaatsu Naka, Nancy L. Czaicki, and Kazunori Koide p 7206 DOI: 10.1021/ja076891t

Issue 23

Rapid Injection NMR in Mechanistic Organocopper Chemistry. Preparation of the Elusive Copper(III) Intermediate1 Steven H. Bertz, Stephen Cope, Michael Murphy, Craig A. Ogle, and Brad J. Taylor pp 7208–7209 DOI: 10.1021/ja067533d Supporting Info

Organocuprate Conjugate Addition:  The Square-Planar “CuIII” Intermediate Haipeng Hu and James P. Snyder pp 7210–7211 DOI: 10.1021/ja0675346 Supporting Info

Iron Diazoalkane Chemistry:  N−N Bond Hydrogenation and Intramolecular C−H Activation Suzanne C. Bart, Amanda C. Bowman, Emil Lobkovsky, and Paul J. Chirik pp 7212–7213 DOI: 10.1021/ja070056u Supporting Info

Synthesis and Stabilization of FeCo Nanoparticles Girija S. Chaubey, Carlos Barcena, Narayan Poudyal, Chuanbing Rong, Jinming Gao, Shouheng Sun, and J. Ping. Liu pp 7214–7215 DOI: 10.1021/ja0708969 Supporting Info

Regulation of Orthogonal Functions in a Dual Catalyst System. Subservient Role of a Nonchiral Lewis Acid in an Asymmetric Catalytic Heteroatom Diels−Alder Reaction Cory A. Newman, Jon C. Antilla, Pei Chen, Alexander V. Predeus, Lee Fielding, and William D. Wulff pp 7216–7217 DOI: 10.1021/ja069019d Supporting Info

NIR-Emitting Colloidal Quantum Dots Having 26% Luminescence Quantum Yield in Buffer Solution Sean Hinds, Stefan Myrskog, Larissa Levina, Ghada Koleilat, Jun Yang, Shana O. Kelley, and Edward H. Sargent pp 7218–7219 DOI: 10.1021/ja070525s Supporting Info

Two-Photon Absorbing Block Copolymer as a Nanocarrier for Porphyrin:  Energy Transfer and Singlet Oxygen Generation in Micellar Aqueous Solution Ching-Yi Chen, Yanqing Tian, Yen-Ju Cheng, A. Cody Young, Jae-Won Ka, and Alex K.-Y. Jen pp 7220–7221 DOI: 10.1021/ja071057p Supporting Info

Temperature Sensitivity Control of Alkylamide-Terminated Poly(amidoamine) Dendrimers Induced by Guest Molecule Binding Kenji Kono, Takuma Miyoshi, Yasuhiro Haba, Etsuo Murakami, Chie Kojima, and Atsushi Harada pp 7222–7223 DOI: 10.1021/ja0711718 Supporting Info

Electron Localization in the Ground State of the Ruthenium Blue Dimer Enrique R. Batista and Richard L. Martin pp 7224–7225 DOI: 10.1021/ja0712773 Supporting Info

A Facile Method for Permanent and Functional Surface Modification of Poly(dimethylsiloxane) Yuanzi Wu, Yanyi Huang, and Hongwei Ma pp 7226–7227 DOI: 10.1021/ja071384x Supporting Info

Interfacing Silicon Nanowires with Mammalian Cells Woong Kim, Jennifer K. Ng, Miki E. Kunitake, Bruce R. Conklin, and Peidong Yang pp 7228–7229 DOI: 10.1021/ja071456k Supporting Info

Thiolate-Induced Structural Reconstruction of Gold Clusters Probed by 197Au Mössbauer Spectroscopy Kazuhiro Ikeda, Yasuhiro Kobayashi, Yuichi Negishi, Makoto Seto, Takeshi Iwasa, Katsuyuki Nobusada, Tatsuya Tsukuda, and Norimichi Kojima pp 7230–7231 DOI: 10.1021/ja071779g Supporting Info

Triplet (S = 1) Ground State Aminyl Diradical Andrzej Rajca, Kouichi Shiraishi, Maren Pink, and Suchada Rajca pp 7232–7233 DOI: 10.1021/ja071881d Supporting Info

Ultralong Nanobelts Self-Assembled from an Asymmetric Perylene Tetracarboxylic Diimide Yanke Che, Aniket Datar, Kaushik Balakrishnan, and Ling Zang pp 7234–7235 DOI: 10.1021/ja071903w Supporting Info

Chain-Growth Polymerization for the Synthesis of Polyfluorene via Suzuki−Miyaura Coupling Reaction from an Externally Added Initiator Unit Akihiro Yokoyama, Hirofumi Suzuki, Yasuhiro Kubota, Kazuei Ohuchi, Hideyuki Higashimura, and Tsutomu Yokozawa pp 7236–7237 DOI: 10.1021/ja070313v Supporting Info

Nanocrystalline TiO2-Catalyzed Solid-State Polymerization of Diacetylene in the Visible Region Yanping Wang, Lian Li, Ke Yang, Lynne A. Samuelson, and Jayant Kumar pp 7238–7239 DOI: 10.1021/ja071296c Supporting Info

Trityl Radicals as Persistent Dual Function pH and Oxygen Probes for in Vivo Electron Paramagnetic Resonance Spectroscopy and Imaging:  Concept and Experiment Andrey A. Bobko, Ilirian Dhimitruka, Jay L. Zweier, and Valery V. Khramtsov pp 7240–7241 DOI: 10.1021/ja071515u Supporting Info

Enantioselective Reductive Coupling of Acetylene to N-Arylsulfonyl Imines via Rhodium Catalyzed C−C Bond-Forming Hydrogenation:  (Z)-Dienyl Allylic Amines Eduardas Skucas, Jong Rock Kong, and Michael J. Krische pp 7242–7243 DOI: 10.1021/ja0715896 Supporting Info

Effective, Selective Hydroalkoxylation/Cyclization of Alkynyl and Allenyl Alcohols Mediated by Lanthanide Catalysts Xianghua Yu, SungYong Seo, and Tobin J. Marks pp 7244–7245 DOI: 10.1021/ja071707p Supporting Info

A High-Mobility Electron-Transport Polymer with Broad Absorption and Its Use in Field-Effect Transistors and All-Polymer Solar Cells Xiaowei Zhan, Zhan'ao Tan, Benoit Domercq, Zesheng An, Xuan Zhang, Stephen Barlow, Yongfang Li, Daoben Zhu, Bernard Kippelen, and Seth R. Marder pp 7246–7247 DOI: 10.1021/ja071760d Supporting Info

Aromatic Hydroxylation Reactivity of a Mononuclear Cu(II)−Alkylperoxo Complex Atsushi Kunishita, Junji Teraoka, Joseph D. Scanlon, Takahiro Matsumoto, Masatatsu Suzuki, Christopher J. Cramer, and Shinobu Itoh pp 7248–7249 DOI: 10.1021/ja071623g Supporting Info

[1 + 2] Cycloadditions of Sulfur Monoxide (SO) to Alkenes and Alkynes and [1 + 4] Cycloadditions to Dienes (Polyenes). Generation and Reactions of Singlet SO? Juzo Nakayama, Yumi Tajima, Piao Xue-hua, and Yoshiaki Sugihara pp 7250–7251 DOI: 10.1021/ja072044e Supporting Info

New Approach for Size- and Shape-Controlled Preparation of Pd Nanoparticles with Organic Ligands. Synthesis and Application in Catalysis Valentine P. Ananikov, Nikolay V. Orlov, Irina P. Beletskaya, Victor N. Khrustalev, Mikhail Yu. Antipin, and Tatiana V. Timofeeva pp 7252–7253 DOI: 10.1021/ja071727r Supporting Info

A Fluorescence Turn-On Mechanism to Detect High Explosives RDX and PETN Trisha L. Andrew and Timothy M. Swager pp 7254–7255 DOI: 10.1021/ja071911c Supporting Info

Asymmetric Amine-Intercepted Nazarov Cyclization Francis Dhoro, Tor E. Kristensen, Vegar Stockmann, Glenn P. A. Yap, and Marcus A. Tius pp 7256–7257 DOI: 10.1021/ja0718873 Supporting Info

Amine-Catalyzed Direct Aldol Addition Morris Markert, Michael Mulzer, Bernd Schetter, and Rainer Mahrwald pp 7258–7259 DOI: 10.1021/ja071926a Supporting Info

Smart Aptamers Facilitate Multi-Probe Affinity Analysis of Proteins with Ultra-Wide Dynamic Range of Measured Concentrations Andrei P. Drabovich, Victor Okhonin, Maxim Berezovski, and Sergey N. Krylov pp 7260–7261 DOI: 10.1021/ja072269p Supporting Info

Determination of Single Molecule Conductances of Alkanedithiols by Conducting-Atomic Force Microscopy with Large Gold Nanoparticles Tomoyuki Morita and Stuart Lindsay pp 7262–7263 DOI: 10.1021/ja072040+ Supporting Info

A Small Synthetic Molecule Forms Chloride Channels to Mediate Chloride Transport across Cell Membranes Xiang Li, Bing Shen, Xiao-Qiang Yao, and Dan Yang pp 7264–7265 DOI: 10.1021/ja071961h Supporting Info

Tailored Glycoproteomics and Glycan Site Mapping Using Saccharide-Selective Bioorthogonal Probes Sarah R. Hanson, Tsui-Ling Hsu, Eranthie Weerapana, Kuniyuki Kishikawa, Gabriel M. Simon, Benjamin F. Cravatt, and Chi-Huey Wong pp 7266–7267 DOI: 10.1021/ja0724083 Supporting Info

An Isolable Silanoic Ester by Oxygenation of a Stable Silylene Shenglai Yao, Yun Xiong, Markus Brym, and Matthias Driess pp 7268–7269 DOI: 10.1021/ja072425s Supporting Info

Superconductivity in an Inorganic Electride 12CaO·7Al2O3:e- Masashi Miyakawa, Sung Wng Kim, Masahiro Hirano, Yoshimitsu Kohama, Hitoshi Kawaji, Tooru Atake, Hiroki Ikegami, Kimitoshi Kono, and Hideo Hosono pp 7270–7271 DOI: 10.1021/ja0724644 Supporting Info

Nanometer-Sized Amino Acids for the Synthesis of Nanometer-Scale Water-Soluble Molecular Rods of Precise Length Chris M. Gothard, Nosheen A. Rao, and James S. Nowick pp 7272–7273 DOI: 10.1021/ja072648i Supporting Info

syn-1,2-Amino Alcohols via Diastereoselective Allylic C−H Amination Kenneth J. Fraunhoffer and M. Christina White pp 7274–7276 DOI: 10.1021/ja071905g Supporting Info

Preparation of Tungsten Alkyl Alkylidene Alkylidyne Complexes and Kinetic Studies of Their Formation Laurel A. Morton, Shujian Chen, He Qiu, and Zi-Ling Xue pp 7277–7283 DOI: 10.1021/ja067914r Supporting Info

Investigation of the Intracellular Delivery of Fluoresceinated Peptides by a Host-[2]Rotaxane Xiaoyang Wang, Xiaofeng Bao, Molly McFarland-Mancini, Idit Isaacsohn, Angela F. Drew, and David B. Smithrud pp 7284–7293 DOI: 10.1021/ja067928x Supporting Info

Palladium(0)-Catalyzed Trimerization of Arylisocyanates into 1,3,5-Triarylisocyanurates in the Presence of Diimines:  A Nonintuitive Mechanism Frédéric Paul, Solenne Moulin, Olivier Piechaczyk, Pascal Le Floch, and John A. Osborn pp 7294–7304 DOI: 10.1021/ja068291k Supporting Info

Colloid Chemical Reaction Route to the Preparation of Nearly Monodispersed Perylene Nanoparticles:  Size-Tunable Synthesis and Three-Dimensional Self-Organization Longtian Kang, Zhechen Wang, Zongwei Cao, Ying Ma, Hongbing Fu, and Jiannian Yao pp 7305–7312 DOI: 10.1021/ja068710d Supporting Info

Development of a Highly Specific Rhodamine-Based Fluorescence Probe for Hypochlorous Acid and Its Application to Real-Time Imaging of Phagocytosis Suguru Kenmoku, Yasuteru Urano, Hirotatsu Kojima, and Tetsuo Nagano pp 7313–7318 DOI: 10.1021/ja068740g Supporting Info

Photochromism of Mixed Crystals Containing Bisthienyl-, Bisthiazolyl-, and Bisoxazolylethene Derivatives Shizuka Takami, Lumi Kuroki, and Masahiro Irie pp 7319–7326 DOI: 10.1021/ja068786+ Supporting Info

Stereochemical Control Mechanisms in Propylene Polymerization Mediated by C1-Symmetric CGC Titanium Catalyst Centers Alessandro Motta, Ignazio L. Fragalà, and Tobin J. Marks pp 7327–7338 DOI: 10.1021/ja068990x Supporting Info

Shape-Controlled Conversion of β-Sn Nanocrystals into Intermetallic M-Sn (M = Fe, Co, Ni, Pd) Nanocrystals Nam Hawn Chou and Raymond E. Schaak pp 7339–7345 DOI: 10.1021/ja069032y Supporting Info

Interactions between Hydrophobic and Ionic Solutes in Aqueous Guanidinium Chloride and Urea Solutions:  Lessons for Protein Denaturation Mechanism Edward P. O'Brien, Ruxandra I. Dima, Bernard Brooks, and D. Thirumalai pp 7346–7353 DOI: 10.1021/ja069232+ Supporting Info

Two Classes of Alongside Charge-Transfer Interactions Defined in One [2]Catenane Sune Nygaard, Stinne W. Hansen, John C. Huffman, Frank Jensen, Amar H. Flood, and Jan O. Jeppesen pp 7354–7363 DOI: 10.1021/ja069047w Supporting Info

A Magnetism-Assisted Chemical Vapor Deposition Method To Produce Branched or Iron-Encapsulated Carbon Nanotubes Dacheng Wei, Yunqi Liu, Lingchao Cao, Lei Fu, Xianglong Li, Yu Wang, and Gui Yu pp 7364–7368 DOI: 10.1021/ja0702465 Supporting Info

Metastable Water Clusters in the Nonpolar Cavities of the Thermostable Protein Tetrabrachion Hao Yin, Gerhard Hummer, and Jayendran C. Rasaiah pp 7369–7377 DOI: 10.1021/ja070456h

Self-Organization of All-Inorganic Dodecatungstophosphate Nanocrystallites Keigo Okamoto, Sayaka Uchida, Takeru Ito, and Noritaka Mizuno pp 7378–7384 DOI: 10.1021/ja070694c Supporting Info

A Solid State 13C NMR, Crystallographic, and Quantum Chemical Investigation of Phenylalanine and Tyrosine Residues in Dipeptides and Proteins Dushyant Mukkamala, Yong Zhang, and Eric Oldfield pp 7385–7392 DOI: 10.1021/ja071227y Supporting Info

Switching from S- to R-Selectivity in the Candida antarctica Lipase B-Catalyzed Ring-Opening of ω-Methylated Lactones:  Tuning Polymerizations by Ring Size Jeroen van Buijtenen, Bart A. C. van As, Marloes Verbruggen, Luc Roumen, Jef A. J. M. Vekemans, Koen Pieterse, Peter A. J. Hilbers, Lumbertus A. Hulshof, Anja R. A. Palmans, and E. W. Meijer pp 7393–7398 DOI: 10.1021/ja071241a Supporting Info

SERS at Structured Palladium and Platinum Surfaces Mamdouh E. Abdelsalam, Sumeet Mahajan, Philip N. Bartlett, Jeremy J. Baumberg, and Andrea E. Russell pp 7399–7406 DOI: 10.1021/ja071269m

Triplet Reactivity and Regio-/Stereoselectivity in the Macrocyclization of Diastereomeric Ketoprofen−Quencher Conjugates via Remote Hydrogen Abstractions Sergio Abad, Francisco Boscá, Luis R. Domingo, Salvador Gil, Uwe Pischel, and Miguel A. Miranda pp 7407–7420 DOI: 10.1021/ja0712827 Supporting Info

Tuning of Redox Properties of Iron and Iron Oxides via Encapsulation within Carbon Nanotubes Wei Chen, Xiulian Pan, and Xinhe Bao pp 7421–7426 DOI: 10.1021/ja0713072 Supporting Info

VTVH-MCD and DFT Studies of Thiolate Bonding to {FeNO}7/{FeO2}8 Complexes of Isopenicillin N Synthase:  Substrate Determination of Oxidase versus Oxygenase Activity in Nonheme Fe Enzymes Christina D. Brown, Michael L. Neidig, Matthew B. Neibergall, John D. Lipscomb, and Edward I. Solomon pp 7427–7438 DOI: 10.1021/ja071364v Supporting Info

Catalytic Enantioselective Alkylative Aldol Reaction:  Efficient Multicomponent Assembly of Dialkylzincs, Allenic Esters, and Ketones toward Highly Functionalized δ-Lactones with Tetrasubstituted Chiral Centers Kounosuke Oisaki, Dongbo Zhao, Motomu Kanai, and Masakatsu Shibasaki pp 7439–7443 DOI: 10.1021/ja071512h Supporting Info

Nanosize Effect on High-Rate Li-Ion Intercalation in LiCoO2 Electrode Masashi Okubo, Eiji Hosono, Jedeok Kim, Masaya Enomoto, Norimichi Kojima, Tetsuichi Kudo, Haoshen Zhou, and Itaru Honma pp 7444–7452 DOI: 10.1021/ja0681927

Synthesis, Characterization, and Metal Coordinating Ability of Multifunctional Carbohydrate-Containing Compounds for Alzheimer's Therapy Tim Storr, Michael Merkel, George X. Song-Zhao, Lauren E. Scott, David E. Green, Meryn L. Bowen, Katherine H. Thompson, Brian O. Patrick, Harvey J. Schugar, and Chris Orvig pp 7453–7463 DOI: 10.1021/ja068965r Supporting Info

Cyclotetraphosphinophosphonium Ions:  Synthesis, Structures, and Pseudorotation C. Adam Dyker, Susanne D. Riegel, Neil Burford, Michael D. Lumsden, and Andreas Decken pp 7464–7474 DOI: 10.1021/ja070764f Supporting Info

Room Temperature Ring-Opening Metathesis of Pyridines by a Transient TiC Linkage [J. Am. Chem. Soc. 2006, 128, 6798−6799]. Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola p 7475 DOI: 10.1021/ja071777w Supporting Info

Domino Reactions in Organic Synthesis By Lutz Tietze, Gordon Brasche, and Kersten Matthias Gericke (Georg-August-Universität, Göttingen, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xiv + 618 pp. $200. ISBN 3-527-29060-5. Robert A. Batey p 7476 DOI: 10.1021/ja069820n

Issue 24

Doubly Ortho-Linked cis-4,4‘-Bis(diarylamino)stilbene/Fluorene Hybrids as Efficient Nondoped, Sky-Blue Fluorescent Materials for Optoelectronic Applications Yi Wei and Chien-Tien Chen pp 7478–7479 DOI: 10.1021/ja070822x Supporting Info

Dynamic Interconversion of Amorphous Microparticles and Crystalline Rods in Salen-Based Homochiral Infinite Coordination Polymers You-Moon Jeon, Jungseok Heo, and Chad A. Mirkin pp 7480–7481 DOI: 10.1021/ja071046w Supporting Info

NaxCoO2:  A New Opportunity for Rewritable Media? Olivier Schneegans, Alec Moradpour, Oana Dragos, Sylvain Franger, Nita Dragoe, Loreynne Pinsard-Gaudart, Pascal Chrétien, and Alexandre Revcolevschi pp 7482–7483 DOI: 10.1021/ja069158v Supporting Info

Single-Molecule Conformational Analysis of G-Quadruplex Formation in the Promoter DNA Duplex of the Proto-Oncogene C-Kit Pravin S. Shirude, Burak Okumus, Liming Ying, Taekjip Ha, and Shankar Balasubramanian pp 7484–7485 DOI: 10.1021/ja070497d Supporting Info

An Unprecedented FeIII(μ-OH)ZnII Complex that Mimics the Structural and Functional Properties of Purple Acid Phosphatases Ademir Neves, Mauricio Lanznaster, Adailton J. Bortoluzzi, Rosely A. Peralta, Annelise Casellato, Eduardo Ernesto Castellano, Paul Herrald, Mark J. Riley, and Gerhard Schenk pp 7486–7487 DOI: 10.1021/ja071184l Supporting Info

Substituted Diarylmethylamines by Stereospecific Intramolecular Electrophilic Arylation of Lithiated Ureas Jonathan Clayden, Jérémy Dufour, Damian M. Grainger, and Madeleine Helliwell pp 7488–7489 DOI: 10.1021/ja071523a Supporting Info

Computational Insights into Degenerate Ethylene Exchange with a Grubbs-Type Catalyst Charles Edwin Webster pp 7490–7491 DOI: 10.1021/ja071588d Supporting Info

Making “Sense” of DNA Grace Y. Stokes, Julianne M. Gibbs-Davis, Faith C. Boman, Brian R. Stepp, Allison G. Condie, SonBinh T. Nguyen, and Franz M. Geiger pp 7492–7493 DOI: 10.1021/ja071848r Supporting Info

Effect of Doping on Electronic Transport through Molecular Monolayer Junctions Oliver Seitz, Ayelet Vilan, Hagai Cohen, Calvin Chan, Jaehyung Hwang, Antoine Kahn, and David Cahen pp 7494–7495 DOI: 10.1021/ja071960p Supporting Info

A Pd(0)-Catalyzed Diamination of Terminal Olefins at Allylic and Homoallylic Carbons via Formal C−H Activation under Solvent-Free Conditions Haifeng Du, Weicheng Yuan, Baoguo Zhao, and Yian Shi pp 7496–7497 DOI: 10.1021/ja072080d Supporting Info

Organocatalytic Asymmetric Reaction Cascade to Substituted Cyclohexylamines Jian Zhou and Benjamin List pp 7498–7499 DOI: 10.1021/ja072134j Supporting Info

Intramolecular C−H Amination Reactions:  Exploitation of the Rh2(II)-Catalyzed Decomposition of Azidoacrylates Benjamin J. Stokes, Huijun Dong, Brooke E. Leslie, Ashley L. Pumphrey, and Tom G. Driver pp 7500–7501 DOI: 10.1021/ja072219k Supporting Info

Long-Range Structural Restraints in Spin-Labeled Proteins Probed by Solid-State Nuclear Magnetic Resonance Spectroscopy Philippe S. Nadaud, Jonathan J. Helmus, Nicole Höfer, and Christopher P. Jaroniec pp 7502–7503 DOI: 10.1021/ja072349t Supporting Info

The Active Form of Chlamydia trachomatis Ribonucleotide Reductase R2 Protein Contains a Heterodinuclear Mn(IV)/Fe(III) Cluster with S = 1 Ground State Wei Jiang, J. Martin Bollinger, Jr., and Carsten Krebs pp 7504–7505 DOI: 10.1021/ja072528a Supporting Info

Iridium-Catalyzed [3 + 2] Annulation of 1,3-Dienes with ortho-Carbonylated Phenylboronic Acids. A Catalytic Process Involving Regioselective 1,2-Addition Takahiro Nishimura, Yuichi Yasuhara, and Tamio Hayashi pp 7506–7507 DOI: 10.1021/ja072369v Supporting Info

Iridium-Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids Yasuhiro Yamashita, Apsara Gopalarathnam, and John F. Hartwig pp 7508–7509 DOI: 10.1021/ja0730718 Supporting Info

Enhancing Electron Accepting Ability of Triarylboron via π-Conjugation with 2,2‘-Bipy and Metal Chelation:  5,5‘-Bis(BMes2)-2,2‘-bipy and Its Metal Complexes Yi Sun, Nicole Ross, Shu-Bin Zhao, Krista Huszarik, Wen-Li Jia, Rui-Yao Wang, Donal Macartney, and Suning Wang pp 7510–7511 DOI: 10.1021/ja0725652 Supporting Info

Synthesis of Structural Analogues of the Oxidized Sites in the Xanthine Oxidoreductase Enzyme Family Jun-Jieh Wang, Stanislav Groysman, Sonny C. Lee, and R. H. Holm pp 7512–7513 DOI: 10.1021/ja0724442 Supporting Info

Regio- and Stereoselective Cross-Coupling of Substituted Olefins and Imines. A Convergent Stereoselective Synthesis of Saturated 1,5-Aminoalcohols and Substituted Piperidines Masayuki Takahashi and Glenn C. Micalizio pp 7514–7516 DOI: 10.1021/ja071974v Supporting Info

Conformational Indeterminism in Protein Misfolding:  Chiral Amplification on Amyloidogenic Pathway of Insulin Wojciech Dzwolak, Anna Loksztejn, Agnieszka Galinska-Rakoczy, Rumi Adachi, Yuji Goto, and Leszek Rupnicki pp 7517–7522 DOI: 10.1021/ja066703j Supporting Info

Theory-Guided Design and Synthesis of Multichromophore Dendrimers:  An Analysis of the Electro-optic Effect Philip A. Sullivan, Harrison Rommel, Yi Liao, Benjamin C. Olbricht, Andrew J. P. Akelaitis, Kimberly A. Firestone, Jae-Wook Kang, Jingdong Luo, Joshua A. Davies, Dong Hoon Choi, Bruce E. Eichinger, Philip J. Reid, Antao Chen, Alex K-Y. Jen, Bruce H. Robinson, and Larry R. Dalton pp 7523–7530 DOI: 10.1021/ja068322b Supporting Info

Kinetic and Spectroscopic Studies of N694C Lipoxygenase:  A Probe of the Substrate Activation Mechanism of a Nonheme Ferric Enzyme Michael L. Neidig, Aaron T. Wecksler, Gerhard Schenk, Theodore R. Holman, and Edward I. Solomon pp 7531–7537 DOI: 10.1021/ja068503d Supporting Info

Supramolecular Chemistry Approach to the Design of a High-Resolution Sensor Array for Multianion Detection in Water Manuel A. Palacios, Ryuhei Nishiyabu, Manuel Marquez, and Pavel Anzenbacher, Jr. pp 7538–7544 DOI: 10.1021/ja0704784 Supporting Info

Activation of Metal Hydride Complexes by Tri-tert-butylphosphine-Platinum and -Palladium Groups Richard D. Adams, Burjor Captain, Eszter Trufan, and Lei Zhu pp 7545–7556 DOI: 10.1021/ja070617h Supporting Info

A Nanotumbleweed:  Breaking Away a Covalently Tethered Polymer Molecule by Noncovalent Interactions Y. Deng and X.-Y. Zhu pp 7557–7561 DOI: 10.1021/ja0706807

Experimental and Theoretical Examination of C−CN and C−H Bond Activations of Acetonitrile Using Zerovalent Nickel Tülay A. Ateşin, Ting Li, Sébastien Lachaize, William W. Brennessel, Juventino J. García, and William D. Jones pp 7562–7569 DOI: 10.1021/ja0707153 Supporting Info

Cocktails of Tb3+ and Eu3+ Complexes:  A General Platform for the Design of Ratiometric Optical Probes Matthew S. Tremblay, Marlin Halim, and Dalibor Sames pp 7570–7577 DOI: 10.1021/ja070867y Supporting Info

Influence of Environment on the Electronic Structure of Cob(III)alamins:  Time-Resolved Absorption Studies of the S1 State Spectrum and Dynamics D. Ahmasi Harris, Andrew B. Stickrath, Elizabeth C. Carroll, and Roseanne J. Sension pp 7578–7585 DOI: 10.1021/ja066197y

Beyond Exciton Theory:  A Time-Dependent DFT and Franck−Condon Study of Perylene Diimide and Its Chromophoric Dimer Aurora E. Clark, Changyong Qin, and Alexander D. Q. Li pp 7586–7595 DOI: 10.1021/ja0687724 Supporting Info

Transition Metal−Carbon Complexes. A Theoretical Study Andreas Krapp, Krishna K. Pandey, and Gernot Frenking pp 7596–7610 DOI: 10.1021/ja0691324 Supporting Info

Polyethylene Imine Derivatives (‘Synzymes') Accelerate Phosphate Transfer in the Absence of Metal Frédéric Avenier, Josiel B. Domingos, Liisa D. Van Vliet, and Florian Hollfelder pp 7611–7619 DOI: 10.1021/ja069095g Supporting Info

Direct Immobilization of Fab‘ in Nanocapillaries for Manipulating Mass-Limited Samples Bo Young Kim, Carla B. Swearingen, Ja-an A. Ho, Elena V. Romanova, Paul W. Bohn, and Jonathan V. Sweedler pp 7620–7626 DOI: 10.1021/ja070041w Supporting Info

A Priori Phase Prediction of Zeolites:  Case Study of the Structure-Directing Effects in the Synthesis of MTT-Type Zeolites Allen W. Burton pp 7627–7637 DOI: 10.1021/ja070303u Supporting Info

Cyclization Cascade of Allenyl Azides:  A Dual Mechanism Carlos Silva López, Olalla Nieto Faza, Ken S. Feldman, Malliga R. Iyer, and D. Keith Hester II pp 7638–7646 DOI: 10.1021/ja070818l Supporting Info

Interaction of Plasmon and Molecular Resonances for Rhodamine 6G Adsorbed on Silver Nanoparticles Jing Zhao, Lasse Jensen, Jiha Sung, Shengli Zou, George C. Schatz, and Richard P. Van Duyne pp 7647–7656 DOI: 10.1021/ja0707106 Supporting Info

Emergence of Solution-Phase Homochirality via Crystal Engineering of Amino Acids Martin Klussmann, Toshiko Izumi, Andrew J. P. White, Alan Armstrong, and Donna G. Blackmond pp 7657–7660 DOI: 10.1021/ja0708870 Supporting Info

Antibiofouling Polymer-Coated Gold Nanoparticles as a Contrast Agent for in Vivo X-ray Computed Tomography Imaging Dongkyu Kim, Sangjin Park, Jae Hyuk Lee, Yong Yeon Jeong, and Sangyong Jon pp 7661–7665 DOI: 10.1021/ja071471p Supporting Info

Indirect ortho Functionalization of Substituted Toluenes through ortho Olefination of N,N-Dimethylbenzylamines Tuned by the Acidity of Reaction Conditions Guixin Cai, Ye Fu, Yizhou Li, Xiaobing Wan, and Zhangjie Shi pp 7666–7673 DOI: 10.1021/ja070588a Supporting Info

Growth Dynamics of CdTe Nanoparticles in Liquid and Crystalline Phases Marc-Oliver M. Piepenbrock, Tom Stirner, Mary O'Neill, and Stephen M. Kelly pp 7674–7679 DOI: 10.1021/ja070032n Supporting Info

Regioselectivity and Diasteroselectivity in Pt(II)-Mediated “Green” Catalytic Epoxidation of Terminal Alkenes with Hydrogen Peroxide:  Mechanistic Insight into a Peculiar Substrate Selectivity Marco Colladon, Alessandro Scarso, Paolo Sgarbossa, Rino A. Michelin, and Giorgio Strukul pp 7680–7689 DOI: 10.1021/ja071142x Supporting Info

Sugar-Assisted Ligation in Glycoprotein Synthesis Yu-Ying Yang, Simon Ficht, Ashraf Brik, and Chi-Huey Wong pp 7690–7701 DOI: 10.1021/ja0708971 Supporting Info

Core/Shell Quantum Dots with High Relaxivity and Photoluminescence for Multimodality Imaging [J. Am. Chem. Soc. 2007, 129, 3848−3856]. Shizhong Wang, Benjamin R. Jarrett, Susan M. Kauzlarich, and Angelique Y. Louie p 7702 DOI: 10.1021/ja0768901

Total Synthesis of Dimeric Pyrrole−Imidazole Alkaloids:  Sceptrin, Ageliferin, Nagelamide E, Oxysceptrin, Nakamuric Acid, and the Axinellamine Carbon Skeleton [J. Am. Chem. Soc. 2007, 129, 4762−4775]. Daniel P. O'Malley, Ke Li, Michael Maue, Alexandros L. Zografos, and Phil S. Baran p 7702 DOI: 10.1021/ja076893d Supporting Info

Issue 25

Transposing Molecular Fluorescent Switches into the Near-IR:  Development of Luminogenic Reporter Substrates for Redox Metabolism Marlin Halim, Matthew S. Tremblay, Steffen Jockusch, Nicholas J. Turro, and Dalibor Sames pp 7704–7705 DOI: 10.1021/ja071311d Supporting Info

Size-Controlled Interparticle Charge Transfer between TiO2 and Quantized Capacitors Junhyung Kim and Dongil Lee pp 7706–7707 DOI: 10.1021/ja071329o Supporting Info

Olefin Metathesis Reactions with Vinyl Halides:  Formation, Observation, Interception, and Fate of the Ruthenium−Monohalomethylidene Moiety Marisa L. Macnaughtan, Marc J. A. Johnson, and Jeff W. Kampf pp 7708–7709 DOI: 10.1021/ja0715952 Supporting Info

Determining the Helical Tilt Angle of a Transmembrane Helix in Mechanically Aligned Lipid Bilayers Using EPR Spectroscopy Johnson J. Inbaraj, Mikhail Laryukhin, and Gary A. Lorigan pp 7710–7711 DOI: 10.1021/ja071587l

Reversible Interconversion of Homochiral Triangular Macrocycles and Helical Coordination Polymers Jungseok Heo, You-Moon Jeon, and Chad A. Mirkin pp 7712–7713 DOI: 10.1021/ja0716812 Supporting Info

Functionalization of Single-Walled Carbon Nanotubes and Fullerenes via a Dimethyl Acetylenedicarboxylate−4-Dimethylaminopyridine Zwitterion Approach Wei Zhang and Timothy M. Swager pp 7714–7715 DOI: 10.1021/ja0717212 Supporting Info

Reduction Energy of 1 M Aqueous Ruthenium(III) Hexaammine in the Gas Phase:  A Route toward Establishing an Absolute Electrochemical Scale Ryan D. Leib, William A. Donald, Jeremy T. O'Brien, Matthew F. Bush, and Evan R. Williams pp 7716–7717 DOI: 10.1021/ja067794n Supporting Info

Highly Regio-, Diastereo-, and Enantioselective Pd-Catalyzed Allylic Alkylation of Acyclic Ketone Enolates with Monosubstituted Allyl Substrates Wen-Hua Zheng, Bao-Hui Zheng, Yan Zhang, and Xue-Long Hou pp 7718–7719 DOI: 10.1021/ja071098l Supporting Info

Regioselective and Enantioselective Iridium-Catalyzed Allylation of Enamines Daniel J. Weix and John F. Hartwig pp 7720–7721 DOI: 10.1021/ja071455s Supporting Info

Rapid Data Collection for Protein Structure Determination by NMR Spectroscopy Yingqi Xu, Dong Long, and Daiwen Yang pp 7722–7723 DOI: 10.1021/ja071442e Supporting Info

Substrate Specificity of Fpg (MutM) and hOGG1, Two Repair Glycosylases Michelle L. Hamm, Timothy J. Gill, Sarah C. Nicolson, and Matthew R. Summers pp 7724–7725 DOI: 10.1021/ja0716453 Supporting Info

Photogeneration of Hydrogen from Water Using an Integrated System Based on TiO2 and Platinum(II) Diimine Dithiolate Sensitizers Jie Zhang, Pingwu Du, Jacob Schneider, Paul Jarosz, and Richard Eisenberg pp 7726–7727 DOI: 10.1021/ja071789h Supporting Info

Characterization of NcsB2 as a Promiscuous Naphthoic Acid/Coenzyme A Ligase Integral to the Biosynthesis of the Enediyne Antitumor Antibiotic Neocarzinostatin Heather A. Cooke, Jian Zhang, Meghan A. Griffin, Koichi Nonaka, Steven G. Van Lanen, Ben Shen, and Steven D. Bruner pp 7728–7729 DOI: 10.1021/ja071886a Supporting Info

Ruthenium-Catalyzed [2 + 2 + 2] Cocyclization of Diene-yne Daisuke Tanaka, Yoshihiro Sato, and Miwako Mori pp 7730–7731 DOI: 10.1021/ja071954t Supporting Info

Nanoparticle Film ChargingIon Rectified or Ion Limited? Timo Laaksonen, Virginia Ruiz, Lasse Murtomäki, and Bernadette M. Quinn pp 7732–7733 DOI: 10.1021/ja0720107 Supporting Info

Lewis Acid Acceleration of C−N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides Qilong Shen and John F. Hartwig pp 7734–7735 DOI: 10.1021/ja0722473 Supporting Info

Reversible C−F Bond Formation and the Au-Catalyzed Hydrofluorination of Alkynes Jennifer A. Akana, Koyel X. Bhattacharyya, Peter Müller, and Joseph P. Sadighi pp 7736–7737 DOI: 10.1021/ja0723784 Supporting Info

Photochemically Induced Autocatalysis in the Chlorate Ion−Iodine System Mónika Galajda, Gábor Lente, and István Fábián pp 7738–7739 DOI: 10.1021/ja072361l Supporting Info

Type-2 Isopentenyl Diphosphate Isomerase. Mechanistic Studies with Cyclopropyl and Epoxy Analogues Jonathan B. Johnston, Joel R. Walker, Steven C. Rothman, and C. Dale Poulter pp 7740–7741 DOI: 10.1021/ja072501r Supporting Info

Direct Palladium-Catalyzed Alkynylation of N-Fused Heterocycles Ilya V. Seregin, Victoria Ryabova, and Vladimir Gevorgyan pp 7742–7743 DOI: 10.1021/ja072718l Supporting Info

Synthesis of Pyrrolo-isoquinolines Related to the Lamellarins Using Silver-Catalyzed Cycloisomerization/Dipolar Cycloaddition Shun Su and John A. Porco, Jr. pp 7744–7745 DOI: 10.1021/ja072737v Supporting Info

Mesoporous Carbon Single-Crystals from Organic−Organic Self-Assembly Fuqiang Zhang, Dong Gu, Ting Yu, Fan Zhang, Songhai Xie, Lijuan Zhang, Yonghui Deng, Ying Wan, Bo Tu, and Dongyuan Zhao pp 7746–7747 DOI: 10.1021/ja072316d Supporting Info

Chromophore Structure of the Kindling Fluorescent Protein asFP595 from Anemonia sulcata Yulia A. Tretyakova, Alexey A. Pakhomov, and Vladimir I. Martynov pp 7748–7749 DOI: 10.1021/ja071992c Supporting Info

Identification of a Peptoid Inhibitor of the Proteasome 19S Regulatory Particle Hyun-Suk Lim, Chase T. Archer, and Thomas Kodadek pp 7750–7751 DOI: 10.1021/ja072027p Supporting Info

Exploiting Ligand Conformation in Selective Inhibition of Non-Ribosomal Peptide Synthetase Amino Acid Adenylation with Designed Macrocyclic Small Molecules Justin S. Cisar, Julian A. Ferreras, Rajesh K. Soni, Luis E. N. Quadri, and Derek S. Tan pp 7752–7753 DOI: 10.1021/ja0721521 Supporting Info

Boronic Esters as a System for Crystallization-Induced Dynamic Self-Assembly Equipped with an “On−Off” Switch for Equilibration Nobuharu Iwasawa and Hiroki Takahagi pp 7754–7755 DOI: 10.1021/ja072319q Supporting Info

Liquid Crystalline Ordering in the Self-Assembled Monolayers of Tethered Rodlike Polymers Jee-Hyuk Kim, M. Shahinur Rahman, Jae-Suk Lee, and Ji-Woong Park pp 7756–7757 DOI: 10.1021/ja072412e Supporting Info

Effect of Acid Treatment on Carbon Nanotube-Based Flexible Transparent Conducting Films Hong-Zhang Geng, Ki Kang Kim, Kang Pyo So, Young Sil Lee, Youngkyu Chang, and Young Hee Lee pp 7758–7759 DOI: 10.1021/ja0722224 Supporting Info

Chemically Patterned Microspheres for Controlled Nanoparticle Assembly in the Construction of SERS Hot Spots Gary Braun, Ioana Pavel, Andrew R. Morrill, Dwight S. Seferos, Guillermo C. Bazan, Norbert O. Reich, and Martin Moskovits pp 7760–7761 DOI: 10.1021/ja072533e Supporting Info

Hydrazine Fuels for Bimetallic Catalytic Microfluidic Pumping Michael E. Ibele, Yang Wang, Timothy R. Kline, Thomas E. Mallouk, and Ayusman Sen pp 7762–7763 DOI: 10.1021/ja0726512 Supporting Info

Remarkable Loop Flexibility in Avian Influenza N1 and Its Implications for Antiviral Drug Design Rommie E. Amaro, David D. L. Minh, Lily S. Cheng, William M. Lindstrom, Jr., Arthur J. Olson, Jung-Hsin Lin, Wilfred W. Li, and J. Andrew McCammon pp 7764–7765 DOI: 10.1021/ja0723535 Supporting Info

Reactivity of a Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward π-Bonds:  Stereospecific Addition and a New Route to an Isolable 1,2-Disilabenzene Rei Kinjo, Masaaki Ichinohe, Akira Sekiguchi, Nozomi Takagi, Michinori Sumimoto, and Shigeru Nagase pp 7766–7767 DOI: 10.1021/ja072759h Supporting Info

Palladium-Catalyzed Direct Functionalization of Imidazolinone:  Synthesis of Dibromophakellstatin Jianming Lu, Xianghui Tan, and Chuo Chen pp 7768–7769 DOI: 10.1021/ja072844p Supporting Info

Alternating Copolymerization of Vinyl Acetate with Carbon Monoxide Takuya Kochi, Akifumi Nakamura, Hirotsugu Ida, and Kyoko Nozaki pp 7770–7771 DOI: 10.1021/ja072859n Supporting Info

Rearrangement of Propargylic Esters:  Metal-Based Stereospecific Synthesis of (E)- and (Z)-Knoevenagel Derivatives José Barluenga, Lorena Riesgo, Rubén Vicente, Luis A. López, and Miguel Tomás pp 7772–7773 DOI: 10.1021/ja072864r Supporting Info

On-Demand Protection of Electrochemical Sensors Based on Adaptive Nanowires Rawiwan Laocharoensuk, Andrea Bulbarello, Samo B. Hocevar, Saverio Mannino, Bozidar Ogorevc, and Joseph Wang pp 7774–7775 DOI: 10.1021/ja0729736 Supporting Info

Which One among Zn(II), Co(II), Mn(II), and Fe(II) is the Most Efficient Ion for the Methionine Aminopeptidase Catalyzed Reaction? Monica Leopoldini, Nino Russo, and Marirosa Toscano pp 7776–7784 DOI: 10.1021/ja068168t Supporting Info

A Time-Resolved Electron Paramagnetic Resonance Investigation of the Spin Exchange and Chemical Interactions of Reactive Free Radicals with Isotopically Symmetric (14N−X−14N) and Isotopically Asymmetric (14N−X−15N) Nitroxyl Biradicals Elena Sartori, Igor V. Khudyakov, Xuegong Lei, and Nicholas J. Turro pp 7785–7792 DOI: 10.1021/ja0687670 Supporting Info

Evolution of Size and Shape in the Colloidal Crystallization of Gold Nanoparticles Owen C. Compton and Frank E. Osterloh pp 7793–7798 DOI: 10.1021/ja069033q Supporting Info

Prototype Protein Assembly as Scaffold for Time-Resolved Fluoroimmuno Assays Hannah N. Barnhill, Stéphanie Claudel-Gillet, Raymond Ziessel, Loïc J. Charbonnière, and Qian Wang pp 7799–7806 DOI: 10.1021/ja069148u Supporting Info

Gas Phase Formation of Dense Alkanethiol Layers on GaAs(110) Luis M. Rodríguez, J. Esteban Gayone, Esteban A. Sánchez, Oscar Grizzi, Bárbara Blum, Roberto C. Salvarezza, Luan Xi, and Woon Ming Lau pp 7807–7813 DOI: 10.1021/ja069007s

Luminescent Silica Nanobeads:  Characterization and Evaluation as Efficient Cytoplasmatic Transporters for T-Lymphocytes Massimo Bottini, Fabio Cerignoli, David M. Mills, Federica D'Annibale, Marilisa Leone, Nicola Rosato, Andrea Magrini, Maurizio Pellecchia, Antonio Bergamaschi, and Tomas Mustelin pp 7814–7823 DOI: 10.1021/ja070245c Supporting Info

Vibrational Spectroscopy Reveals Electrostatic and Electrochemical Doping in Organic Thin Film Transistors Gated with a Polymer Electrolyte Dielectric L. G. Kaake, Y. Zou, M. J. Panzer, C. D. Frisbie, and X.-Y. Zhu pp 7824–7830 DOI: 10.1021/ja070615x

Mechanism of Activation of a Hafnium Pyridyl−Amide Olefin Polymerization Catalyst:  Ligand Modification by Monomer Robert D. J. Froese, Phillip D. Hustad, Roger L. Kuhlman, and Timothy T. Wenzel pp 7831–7840 DOI: 10.1021/ja070718f Supporting Info

Reversible Oxidation State Change in Germanium(tetraphenylporphyrin) Induced by a Dative Ligand:  Aromatic GeII(TPP) and Antiaromatic GeIV(TPP)(pyridine)2 Julie A. Cissell, Thomas P. Vaid, and Glenn P. A. Yap pp 7841–7847 DOI: 10.1021/ja070794i Supporting Info

Inhibitor Fingerprinting of Matrix Metalloproteases Using a Combinatorial Peptide Hydroxamate Library Mahesh Uttamchandani, Jun Wang, Junqi Li, Mingyu Hu, Hongyan Sun, Kitty Y.-T. Chen, Kai Liu, and Shao Q. Yao pp 7848–7858 DOI: 10.1021/ja070870h Supporting Info

A Surface Functional Monomer-Directing Strategy for Highly Dense Imprinting of TNT at Surface of Silica Nanoparticles Daming Gao, Zhongping Zhang, Minghong Wu, Chenggen Xie, Guijian Guan, and Dapeng Wang pp 7859–7866 DOI: 10.1021/ja070975k

Solution NMR Studies of the Maturation Intermediates of a 13 MDa Viral Capsid Blair R. Szymczyna, Lu Gan, John E. Johnson, and James R. Williamson pp 7867–7876 DOI: 10.1021/ja071118j Supporting Info

FTIR Studies of Collagen Model Peptides:  Complementary Experimental and Simulation Approaches to Conformation and Unfolding Michael A. Bryan, Joseph W. Brauner, Gloria Anderle, Carol R. Flach, Barbara Brodsky, and Richard Mendelsohn pp 7877–7884 DOI: 10.1021/ja071154i

Heteroatomic Deltahedral Clusters:  Synthesis and Structures of closo-[Bi3Ni4(CO)6]3-, closo-[Bi4Ni4(CO)6]2-, the Open Cluster [Bi3Ni6(CO)9]3-, and the Intermetalloid closo-[Nix@{Bi6Ni6(CO)8}]4- Jose M. Goicoechea, Michael W. Hull, and Slavi C. Sevov pp 7885–7893 DOI: 10.1021/ja071044b Supporting Info

Structural Assembly of Multidomain Proteins and Protein Complexes Guided by the Overall Rotational Diffusion Tensor Yaroslav Ryabov and David Fushman pp 7894–7902 DOI: 10.1021/ja071185d Supporting Info

An Alternating π-Stacked Bisdithiazolyl Radical Conductor Alicea A. Leitch, Robert W. Reed, Craig M. Robertson, James F. Britten, Xueyang Yu, Richard A. Secco, and Richard T. Oakley pp 7903–7914 DOI: 10.1021/ja071218p Supporting Info

An Experimental and Computational Approach to Defining Structure/Reactivity Relationships for Intramolecular Addition Reactions to Bicyclic Epoxonium Ions Shuangyi Wan, Hakan Gunaydin, K. N. Houk, and Paul E. Floreancig pp 7915–7923 DOI: 10.1021/ja0709674 Supporting Info

“Simulating Synthesis”:  Ceria Nanosphere Self-Assembly into Nanorods and Framework Architectures Dean C. Sayle, Xiangdong Feng, Yong Ding, Zhong Lin Wang, and Thi X. T. Sayle pp 7924–7935 DOI: 10.1021/ja070893w Supporting Info

Dissecting the Proline Effect:  Dissociations of Proline Radicals Formed by Electron Transfer to Protonated Pro-Gly and Gly-Pro Dipeptides in the Gas Phase Shigeo Hayakawa, Mami Hashimoto, Hiroshi Matsubara, and František Tureek pp 7936–7949 DOI: 10.1021/ja0712571 Supporting Info

ClnH6-nSiGe Compounds for CMOS Compatible Semiconductor Applications:  Synthesis and Fundamental Studies Jesse B. Tice, Andrew V. G. Chizmeshya, Radek Roucka, John Tolle, Brian R. Cherry, and John Kouvetakis pp 7950–7960 DOI: 10.1021/ja0713680 Supporting Info

Decomposition of Ruthenium Olefin Metathesis Catalysts Soon Hyeok Hong, Anna G. Wenzel, Tina T. Salguero, Michael W. Day, and Robert H. Grubbs pp 7961–7968 DOI: 10.1021/ja0713577 Supporting Info

Prototypical Phosphorus Analogues of Ethane:  General and Versatile Synthetic Approaches to Hexaalkylated P−P Diphosphonium Cations Jan. J. Weigand, Susanne D. Riegel, Neil Burford, and Andreas Decken pp 7969–7976 DOI: 10.1021/ja071306+ Supporting Info

Surface Effects on Quantum Dot-Based Energy Transfer Smita Dayal and Clemens Burda pp 7977–7981 DOI: 10.1021/ja071457c

Monomeric and Heterodimeric Triple Helical DNA Mimics Ivan Trkulja and Robert Häner pp 7982–7989 DOI: 10.1021/ja0715501

Heterobimetallic Dioxygen Activation:  Synthesis and Reactivity of Mixed Cu−Pd and Cu−Pt Bis(μ-oxo) Complexes John T. York, Antoni Llobet, Christopher J. Cramer, and William B. Tolman pp 7990–7999 DOI: 10.1021/ja071744g Supporting Info

Layer-by-Layer Assembly and Spontaneous Flocculation of Oppositely Charged Oxide and Hydroxide Nanosheets into Inorganic Sandwich Layered Materials Liang Li, Renzhi Ma, Yasuo Ebina, Katsutoshi Fukuda, Kazunori Takada, and Takayoshi Sasaki pp 8000–8007 DOI: 10.1021/ja0719172 Supporting Info

Transition-State Variation in Human, Bovine, and Plasmodium falciparum Adenosine Deaminases Minkui Luo, Vipender Singh, Erika A. Taylor, and Vern L. Schramm pp 8008–8017 DOI: 10.1021/ja072122y Supporting Info

Nucleophilic 18F-Fluorination of Heteroaromatic Iodonium Salts with No-Carrier-Added [18F]Fluoride Tobias L. Ross, Johannes Ermert, Carsten Hocke, and Heinz H. Coenen pp 8018–8025 DOI: 10.1021/ja066850h

Metallic versus Covalent Bonding:  Ga Nanoparticles as a Case Study Paolo Ghigna, Giorgio Spinolo, Giovanni Battista Parravicini, Angiolino Stella, Andrea Migliori, and Richard Kofman pp 8026–8033 DOI: 10.1021/ja0706100 Supporting Info

One-Electron Photooxidation and Site-Selective Strand Cleavage at 5-Methylcytosine in DNA by Sensitization with 2-Methyl-1,4-naphthoquinone-Tethered Oligonucleotides Kazuhito Tanabe, Hisatsugu Yamada, and Sei-ichi Nishimoto pp 8034–8040 DOI: 10.1021/ja071369s Supporting Info

Intracrystalline Diffusivities and Surface Permeabilities Deduced from Transient Concentration Profiles:  Methanol in MOF Manganese Formate Pavel V. Kortunov, Lars Heinke, Mirko Arnold, Yannic Nedellec, Deborah J. Jones, Jürgen Caro, and Jörg Kärger pp 8041–8047 DOI: 10.1021/ja071265h

Dynamic Effects on J-Couplings across Hydrogen Bonds in Proteins [J. Am. Chem. Soc. 2003, 125, 644−645]. Phineus R. L. Markwick, Remco Sprangers, and Michael Sattler p 8048 DOI: 10.1021/ja072740e Supporting Info

ChemKey Search Database. Heterodata, Inc. 1055 Rosewood Drive, Atlanta, GA 30306. http://euch6f.chem.emory.edu/index.html. $325.00. William H. Pearson pp 8049–8050 DOI: 10.1021/ja076956s

Issue 26

JACS Policy on Manuscript Organization:  Changes Concerning Back-to-Back Publications and Length of Communications Peter J. Stang, Editor p 8051 DOI: 10.1021/ja0768946

Oriented Growth of the Metal Organic Framework Cu3(BTC)2(H2O)3·xH2O Tunable with Functionalized Self-Assembled Monolayers Enrica Biemmi, Camilla Scherb, and Thomas Bein pp 8054–8055 DOI: 10.1021/ja0701208 Supporting Info

Synthesis and Characterization of Monodisperse Poly(organosiloxane) Nanocapsules with or without Magnetic Cores Anuj Shukla, Patrick Degen, and Heinz Rehage pp 8056–8057 DOI: 10.1021/ja070502d Supporting Info

Quantum Yield Heterogeneities of Aqueous Single-Wall Carbon Nanotube Suspensions Jared Crochet, Michael Clemens, and Tobias Hertel pp 8058–8059 DOI: 10.1021/ja071553d Supporting Info

Development of a Nazarov Cyclization/Wagner−Meerwein Rearrangement Sequence for the Stereoselective Synthesis of Spirocycles Jie Huang and Alison J. Frontier pp 8060–8061 DOI: 10.1021/ja0716148 Supporting Info

Switching Off and On the Supramolecular Chiral Memory in Porphyrin Assemblies Angela Mammana, Alessandro D'Urso, Rosaria Lauceri, and Roberto Purrello pp 8062–8063 DOI: 10.1021/ja071447b

Organocatalysis in Conjugate Amine Additions. Synthesis of β-Amino Acid Derivatives Mukund P. Sibi and Kennosuke Itoh pp 8064–8065 DOI: 10.1021/ja071739c Supporting Info

Inverted-Sandwich Dichromium(I) Complexes Supported by Two β-Diketiminates:  A Multielectron Reductant and Syntheses of Chromium Dioxo and Imido Yi-Chou Tsai, Po-Yang Wang, Shin-An Chen, and Jin-Ming Chen pp 8066–8067 DOI: 10.1021/ja072003i Supporting Info

Covalent Capture of Phospho-Dependent Protein Oligomerization by Site-Specific Incorporation of a Diazirine Photo-Cross-Linker Miquel Vila-Perelló, Matthew R. Pratt, Frej Tulin, and Tom W. Muir pp 8068–8069 DOI: 10.1021/ja072013j Supporting Info

Structural Characterization of Quaterphenyl Cation Radical:  X-ray Crystallographic Evidence of Quinoidal Charge Delocalization in Poly-p-phenylene Cation Radicals Moloy Banerjee, Sergey V. Lindeman, and Rajendra Rathore pp 8070–8071 DOI: 10.1021/ja0720356 Supporting Info

Separation of Membrane-Bound Compounds by Solid-Supported Bilayer Electrophoresis Susan Daniel, Arnaldo J. Diaz, Kelly M. Martinez, Bennie J. Bench, Fernando Albertorio, and Paul S. Cremer pp 8072–8073 DOI: 10.1021/ja0720816 Supporting Info

Electrochemiluminescence of Zeolite-Encapsulated Poly(p-phenylenevinylene) Mercedes Álvaro, Jose F. Cabeza, Avelino Corma, Hermenegildo García, and Encarna Peris pp 8074–8075 DOI: 10.1021/ja0718265 Supporting Info

Direct Visualization of an Aniline Admolecule and Its Electropolymerization on Au(111) with in Situ Scanning Tunneling Microscope Liang Yueh Ou Yang, ChinZen Chang, SuHar Liu, ChunGuey Wu, and Shueh Lin Yau pp 8076–8077 DOI: 10.1021/ja072201+ Supporting Info

Structural Similarity of a Membrane Protein in Micelles and Membranes Carla M. Franzin, Peter Teriete, and Francesca M. Marassi pp 8078–8079 DOI: 10.1021/ja0728371

Rh-Catalyzed Arylation and Alkenylation of C60 Using Organoboron Compounds Masakazu Nambo, Ryoji Noyori, and Kenichiro Itami pp 8080–8081 DOI: 10.1021/ja073042x Supporting Info

Two Components in a Molecule:  Highly Efficient and Thermally Robust Catalytic System for CO2/Epoxide Copolymerization Eun Kyung Noh, Sung Jae Na, Sujith S, Sang-Wook Kim, and Bun Yeoul Lee pp 8082–8083 DOI: 10.1021/ja071290n Supporting Info

Surface Transfer Doping of Diamond (100) by Tetrafluoro-tetracyanoquinodimethane Dongchen Qi, Wei Chen, Xingyu Gao, Li Wang, Shi Chen, Kian Ping Loh, and Andrew T. S. Wee pp 8084–8085 DOI: 10.1021/ja072133r Supporting Info

Observation of Exceptionally Strong Binding of Molecular Hydrogen in a Porous Material:  Formation of an η2-H2 Complex in a Cu-Exchanged ZSM-5 Zeolite Peter A. Georgiev, Alberto Albinati, Barbara L. Mojet, Jacques Ollivier, and Juergen Eckert pp 8086–8087 DOI: 10.1021/ja072240l Supporting Info

Janus Microgels Prepared by Surfactant-Free Pickering Emulsion-Based Modification and Their Self-Assembly Daisuke Suzuki, Sakiko Tsuji, and Haruma Kawaguchi pp 8088–8089 DOI: 10.1021/ja072258w Supporting Info

Binding and Activation of Small Molecules by Three-Coordinate Cr(I) Wesley H. Monillas, Glenn P. A. Yap, Leonard A. MacAdams, and Klaus H. Theopold pp 8090–8091 DOI: 10.1021/ja0725549 Supporting Info

Preference of 4-exo Ring Closure in Copper-Catalyzed Intramolecular Coupling of Vinyl Bromides with Alcohols Yewen Fang and Chaozhong Li pp 8092–8093 DOI: 10.1021/ja072793w Supporting Info

Structure of Ethene Adsorption Sites on Supported Metal Catalysts from in Situ XANES Analysis Eveline Bus, David E. Ramaker, and Jeroen A. van Bokhoven pp 8094–8102 DOI: 10.1021/ja0689233

The Development of Scalemic Multidentate Niobium Complexes as Catalysts for the Highly Stereoselective Ring Opening of meso-Epoxides and meso-Aziridines Kenzo Arai, Simone Lucarini, Matthew M. Salter, Kentaro Ohta, Yasuhiro Yamashita, and Shū Kobayashi pp 8103–8111 DOI: 10.1021/ja0708666 Supporting Info

Mechanistic Insight into NN Cleavage by a Low-Coordinate Iron(II) Hydride Complex Azwana R. Sadique, Elizabeth A. Gregory, William W. Brennessel, and Patrick L. Holland pp 8112–8121 DOI: 10.1021/ja069199r Supporting Info

Proton Transport and the Water Environment in Nafion Fuel Cell Membranes and AOT Reverse Micelles D. B. Spry, A. Goun, K. Glusac, David E. Moilanen, and M. D. Fayer pp 8122–8130 DOI: 10.1021/ja071939o

Oxidation Reaction by Xanthine Oxidase. Theoretical Study of Reaction Mechanism Tatsuo Amano, Noriaki Ochi, Hirofumi Sato, and Shigeyoshi Sakaki pp 8131–8138 DOI: 10.1021/ja068584d Supporting Info

A Family of Mixed-Metal Cyanide Cubes with Alternating Octahedral and Tetrahedral Corners Exhibiting a Variety of Magnetic Behaviors Including Single Molecule Magnetism Eric J. Schelter, Ferdi Karadas, Carolina Avendano, Andrey V. Prosvirin, Wolfgang Wernsdorfer, and Kim R. Dunbar pp 8139–8149 DOI: 10.1021/ja0683281 Supporting Info

Model for Antibiotic Optimization via Neoglycosylation:  Synthesis of Liponeoglycopeptides Active against VRE Byron R. Griffith, Candace Krepel, Xun Fu, Sophie Blanchard, Aqeel Ahmed, Charles E. Edmiston, and Jon S. Thorson pp 8150–8155 DOI: 10.1021/ja068602r Supporting Info

A New Multicomponent Reaction Catalyzed by a [Lewis Acid]+[Co(CO)4]- Catalyst:  Stereospecific Synthesis of 1,3-Oxazinane-2,4-diones from Epoxides, Isocyanates, and CO Tamara L. Church, Christopher M. Byrne, Emil B. Lobkovsky, and Geoffrey W. Coates pp 8156–8162 DOI: 10.1021/ja069065d Supporting Info

Photoreaction at 5‘-(G/C)AABrUT-3‘ Sequence in Duplex DNA:  Efficent Generation of Uracil-5-yl Radical by Charge Transfer Takayoshi Watanabe, Ryu Tashiro, and Hiroshi Sugiyama pp 8163–8168 DOI: 10.1021/ja0692736 Supporting Info

Assembly and Characterization of 8-Arm and 12-Arm DNA Branched Junctions Xing Wang and Nadrian C. Seeman pp 8169–8176 DOI: 10.1021/ja0693441 Supporting Info

Reactivity of Superoxide Radical Anion with Cyclic Nitrones:  Role of Intramolecular H-Bond and Electrostatic Effects Frederick A. Villamena, Shijing Xia, John K. Merle, Robert Lauricella, Beatrice Tuccio, Christopher M. Hadad, and Jay L. Zweier pp 8177–8191 DOI: 10.1021/ja0702622 Supporting Info

Catalase and Epoxidation Activity of Manganese Salen Complexes Bearing Two Xanthene Scaffolds Jenny Y. Yang and Daniel G. Nocera pp 8192–8198 DOI: 10.1021/ja070358w Supporting Info

Ultrafast Nonadiabatic Dynamics of [FeII(bpy)3]2+ in Solution Wojciech Gawelda, Andrea Cannizzo, Van-Thai Pham, Frank van Mourik, Christian Bressler, and Majed Chergui pp 8199–8206 DOI: 10.1021/ja070454x Supporting Info

Understanding d0-Olefin Metathesis Catalysts:  Which Metal, Which Ligands? Albert Poater, Xavier Solans-Monfort, Eric Clot, Christophe Copéret, and Odile Eisenstein pp 8207–8216 DOI: 10.1021/ja070625y Supporting Info

Barriers to Ion Translocation in Cationic and Anionic Receptors from the Cys-Loop Family Ivaylo Ivanov, Xiaolin Cheng, Steven M. Sine, and J. Andrew McCammon pp 8217–8224 DOI: 10.1021/ja070778l Supporting Info

Exploring Experimental Sources of Multiple Protein Conformations in Structure-Based Drug Design Kelly L. Damm and Heather A. Carlson pp 8225–8235 DOI: 10.1021/ja0709728 Supporting Info

Structural and Co-conformational Effects of Alkyne-Derived Subunits in Charged Donor−Acceptor [2]Catenanes Ognjen Š. Miljanić, William R. Dichtel, Saeed I. Khan, Shahab Mortezaei, James R. Heath, and J. Fraser Stoddart pp 8236–8246 DOI: 10.1021/ja071319n Supporting Info

Influence of Substituents on the Energy and Nature of the Lowest Excited States of Heteroleptic Phosphorescent Ir(III) Complexes:  A Joint Theoretical and Experimental Study Igor Avilov, Payam Minoofar, Jérôme Cornil, and Luisa De Cola pp 8247–8258 DOI: 10.1021/ja0711011 Supporting Info

Oxepane Nucleic Acids:  Synthesis, Characterization, and Properties of Oligonucleotides Bearing a Seven-Membered Carbohydrate Ring David Sabatino and Masad J. Damha pp 8259–8270 DOI: 10.1021/ja071336c Supporting Info

Synthesis and Characterization of meso-Triarylsubporphyrins Yuichi Takeuchi, Atsushi Matsuda, and Nagao Kobayashi pp 8271–8281 DOI: 10.1021/ja0712120 Supporting Info

sp Carbon Chains Surrounded by sp3 Carbon Double Helices:  Coordination-Driven Self-Assembly of Wirelike Pt(CC)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages Jürgen Stahl, Wolfgang Mohr, Laura de Quadras, Thomas B. Peters, James C. Bohling, José Miguel Martín-Alvarez, Gareth R. Owen, Frank Hampel, and John A. Gladysz pp 8282–8295 DOI: 10.1021/ja0716103 Supporting Info

sp Carbon Chains Surrounded by sp3 Carbon Double Helices:  Directed Syntheses of Wirelike Pt(CC)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages via Alkene Metathesis Laura de Quadras, Eike B. Bauer, Wolfgang Mohr, James C. Bohling, Thomas B. Peters, José Miguel Martín-Alvarez, Frank Hampel, and John A. Gladysz pp 8296–8309 DOI: 10.1021/ja071612n Supporting Info

Elastic and Inelastic Electron Tunneling Spectroscopy of a New Rectifying Monolayer Andrei Honciuc, Robert M. Metzger, Aijun Gong, and Charles W. Spangler pp 8310–8319 DOI: 10.1021/ja068729g Supporting Info

Role of Aromatic Side Chains in the Folding and Thermodynamic Stability of Integral Membrane Proteins Heedeok Hong, Sangho Park, Ricardo H. Flores Jiménez, Dennis Rinehart, and Lukas K. Tamm pp 8320–8327 DOI: 10.1021/ja068849o Supporting Info

Structure-Based Design Leads to the Identification of Lithium Mimetics That Block Mania-like Effects in Rodents. Possible New GSK-3β Therapies for Bipolar Disorders Alan P. Kozikowski, Irina N. Gaisina, Hongbin Yuan, Pavel A. Petukhov, Sylvie Y. Blond, Allison Fedolak, Barbara Caldarone, and Paul McGonigle pp 8328–8332 DOI: 10.1021/ja068969w Supporting Info

Aluminosilicate Surfaces as Promoters for Peptide Bond Formation:  An Assessment of Bernal's Hypothesis by ab Initio Methods Albert Rimola, Mariona Sodupe, and Piero Ugliengo pp 8333–8344 DOI: 10.1021/ja070451k Supporting Info

Phosphate-Mediated Molecular Memory Driven by Two Different Protein Kinases as Information Input Elements Kin-ya Tomizaki and Hisakazu Mihara pp 8345–8352 DOI: 10.1021/ja0703067 Supporting Info

Influence of Stereochemistry and Redox Potentials on the Single- and Double-Strand DNA Cleavage Efficiency of Cu(II)· and Ni(II)·Lys-Gly-His-Derived ATCUN Metallopeptides Yan Jin, Mark A. Lewis, Nikhil H. Gokhale, Eric C. Long, and J. A. Cowan pp 8353–8361 DOI: 10.1021/ja0705083 Supporting Info

Five- and Six-Membered Conformationally Locked 2‘,4‘-Carbocyclic ribo-Thymidines:  Synthesis, Structure, and Biochemical Studies Puneet Srivastava, Jharna Barman, Wimal Pathmasiri, Oleksandr Plashkevych, Małgorzata Wenska, and Jyoti Chattopadhyaya pp 8362–8379 DOI: 10.1021/ja071106y Supporting Info

Ultrafast Spectroscopic and Matrix Isolation Studies of p-Biphenylyl, o-Biphenylyl, and 1-Naphthylnitrenium Cations Jin Wang, Gotard Burdzinski, Zhendong Zhu, Matthew S. Platz, Claudio Carra, and Thomas Bally pp 8380–8388 DOI: 10.1021/ja071325j Supporting Info

Multidrug-Binding Transcription Factor QacR Binds the Bivalent Aromatic Diamidines DB75 and DB359 in Multiple Positions Benjamin E. Brooks, Kevin M. Piro, and Richard G. Brennan pp 8389–8395 DOI: 10.1021/ja072576v

Multiple Bonds Between Metal Atoms, 3rd ed Edited by F. Albert Cotton, Carlos A. Murillo (Texas A&M University), and Richard A. Walton (Purdue University). Springer Science + Business Media, Inc.:  New York. 2005. xxx + 818 pp. $149.00. ISBN 0-387-25084-0. Eric Rivard and Philip P. Power p 8396 DOI: 10.1021/ja0697267

Theilheimer's Synthetic Methods of Organic Chemistry, Volume 70 Edited by Alan F. Finch (Cambridge). S. Karger AG and the Thomson Corporation:  Basel, Switzerland. 2006. xxvi + 430 pp. $659.25. ISBN 3-8055-8217-X. p 8396 DOI: 10.1021/ja076937i

The Investigation of Organic Reactions and Their Mechanisms Edited by Howard Maskill (University of Newcastle upon Tyne, U.K. and University of Santiago de Compostela, Spain). Blackwell Publishing:  Oxford. 2006. xxii + 370 pp. $199.99. ISBN 978-01-4051-3142-1. pp 8396–8397 DOI: 10.1021/ja076936q

Biomaterials From Aquatic and Terrestrial Organisms Edited by Milton Fingerman and Rachakonda Nagabhushanam (Tulane University, New Orleans). Science Publishers:  Enfield, NH. 2006. xii + 610 pp. $128.00. ISBN 1-57808-429-6. p 8397 DOI: 10.1021/ja076943e

Metal Ions in the Life Sciences, Volume 2:  Nickel and Its Surprising Impact in Nature Edited by Astrid Sigel, Helmut Sigel (University of Basel), and Roland K. O. Sigel (University of Zürich). John Wiley & Sons, Ltd.:  Chichester. 2007. xxvi + 702 pp. $355.00. ISBN 978-0-470-01671-8. p 8397 DOI: 10.1021/ja076945z

The Chemistry of Organozinc Compounds, Parts 1−2 Edited by Zvi Rappoport (The Hebrew University, Jerusalem, Israel) and Ilan Marek (Technion-Israel Institute of Technology, Haifa, Israel). John Wiley & Sons, Ltd:  Chichester. 2006. 1140 pp. $930.00. ISBN 0-470-09337-4. Patrick J. Walsh pp 8397–8398 DOI: 10.1021/ja076912j

Issue 27

Imaging Cell Surface Glycans with Bioorthogonal Chemical Reporters Pamela V. Chang, Jennifer A. Prescher, Matthew J. Hangauer, and Carolyn R. Bertozzi pp 8400–8401 DOI: 10.1021/ja070238o Supporting Info

Probing the Lewis Acid Sites and CO Catalytic Oxidation Activity of the Porous Metal−Organic Polymer [Cu(5-methylisophthalate)] Ru-Qiang Zou, Hiroaki Sakurai, Song Han, Rui-Qin Zhong, and Qiang Xu pp 8402–8403 DOI: 10.1021/ja071662s Supporting Info

Photoinduced Construction of a Second Covalently Bonded Organic Layer on the Si(111)-7 × 7 Surface Ying Hui Cai, Yan Xia Shao, and Guo Qin Xu pp 8404–8405 DOI: 10.1021/ja0716655 Supporting Info

Mesoporous Titania Spheres with Tunable Chamber Stucture and Enhanced Photocatalytic Activity Hexing Li, Zhenfeng Bian, Jian Zhu, Dieqing Zhang, Guisheng Li, Yuning Huo, Hui Li, and Yunfeng Lu pp 8406–8407 DOI: 10.1021/ja072191c Supporting Info

Steric Effects on Water Accessability Control Sequence-Selectivity of Radical Cation Reactions in DNA Charles L. Cleveland, Robert N. Barnett, Angelo Bongiorno, Joshy Joseph, Chusheng Liu, Gary B. Schuster, and Uzi Landman pp 8408–8409 DOI: 10.1021/ja071893z Supporting Info

One-Step Polymer Grafting from Silicon Nitride SPM Probes:  From Isolated Chains to Brush Regime Sabine Gabriel, Christine Jérôme, Robert Jérôme, Charles-André Fustin, Antoine Pallandre, Jérôme Plain, Alain M. Jonas, and Anne-Sophie Duwez pp 8410–8411 DOI: 10.1021/ja071723m Supporting Info

Chiral Semiconductor Frameworks from Cadmium Sulfide Clusters Qichun Zhang, Xianhui Bu, Jian Zhang, Tao Wu, and Pingyun Feng pp 8412–8413 DOI: 10.1021/ja072274t Supporting Info

Organic Spirocyclic Initiators for the Ring-Expansion Polymerization of β-Lactones Wonhee Jeong, James L. Hedrick, and Robert M. Waymouth pp 8414–8415 DOI: 10.1021/ja072037q Supporting Info

Enzymatic Logic of Anthrax Stealth Siderophore Biosynthesis:  AsbA Catalyzes ATP-Dependent Condensation of Citric Acid and Spermidine Daniel Oves-Costales, Nadia Kadi, Mark J. Fogg, Lijiang Song, Keith S. Wilson, and Gregory L. Challis pp 8416–8417 DOI: 10.1021/ja072391o Supporting Info

Ion-Selective Nano-optodes Incorporating Quantum Dots J. Matthew Dubach, Daniel I. Harjes, and Heather A. Clark pp 8418–8419 DOI: 10.1021/ja072522l Supporting Info

Sensitive Probing of DNA Binding to a Cationic Lipid Monolayer George W. H. Wurpel, Maria Sovago, and Mischa Bonn pp 8420–8421 DOI: 10.1021/ja072552o Supporting Info

Lithium-Doped Metal-Organic Frameworks for Reversible H2 Storage at Ambient Temperature Sang Soo Han and William A. Goddard III pp 8422–8423 DOI: 10.1021/ja072599+ Supporting Info

Colorimetric Detection of Anthrax DNA with a Peptide Nucleic Acid Sandwich-Hybridization Assay Ning Zhang and Daniel H. Appella pp 8424–8425 DOI: 10.1021/ja072744j Supporting Info

Sulfonic Acid Functionalized SBA-15 Silica as a Methylaluminoxane-Free Cocatalyst/Support for Ethylene Polymerization Jason C. Hicks, Brooke A. Mullis, and Christopher W. Jones pp 8426–8427 DOI: 10.1021/ja0727870 Supporting Info

Ultraviolet Spectroscopy of Peptide and Protein Polyanions in Vacuo:  Signature of the Ionization State of Tyrosine Laure Joly, Rodolphe Antoine, Abdul-Rahman Allouche, Michel Broyer, Jérôme Lemoine, and Philippe Dugourd pp 8428–8429 DOI: 10.1021/ja072818r Supporting Info

The Membrane Alignment of Helical Peptides from Non-oriented 15N Chemical Shift Solid-State NMR Spectroscopy Lydia Prongidi-Fix, Philippe Bertani, and Burkhard Bechinger pp 8430–8431 DOI: 10.1021/ja072668k Supporting Info

Allylic Amines via Iridium-Catalyzed C−C Bond Forming Hydrogenation:  Imine Vinylation in the Absence of Stoichiometric Byproducts or Metallic Reagents Andriy Barchuk, Ming-Yu Ngai, and Michael J. Krische pp 8432–8433 DOI: 10.1021/ja073018j Supporting Info

Dramatic Improvements of Well-Defined Silica Supported Mo-Based Olefin Metathesis Catalysts by Tuning the N-Containing Ligands Frédéric Blanc, Romain Berthoud, Alain Salameh, Jean-Marie Basset, Christophe Copéret, Rojendra Singh, and Richard R. Schrock pp 8434–8435 DOI: 10.1021/ja073095e Supporting Info

A β-Diketiminate-Supported Boron Dication Dragoslav Vidovic, Michael Findlater, and Alan H. Cowley pp 8436–8437 DOI: 10.1021/ja072865j Supporting Info

Soluble Single-Walled Carbon Nanotubes as Longboat Delivery Systems for Platinum(IV) Anticancer Drug Design Rodney P. Feazell, Nozomi Nakayama-Ratchford, Hongjie Dai, and Stephen J. Lippard pp 8438–8439 DOI: 10.1021/ja073231f Supporting Info

Size-Selective Supramolecular Chemistry in a Hydrocarbon Nanoring Yan Zhao and Donald G. Truhlar pp 8440–8442 DOI: 10.1021/ja071884q Supporting Info

Engineered Chimeric Enzymes as Tools for Drug Discovery:  Generating Reliable Bacterial Screens for the Detection, Discovery, and Assessment of Estrogen Receptor Modulators Georgios Skretas, Aggeliki K. Meligova, Carolina Villalonga-Barber, Dimitra J. Mitsiou, Michael N. Alexis, Maria Micha-Screttas, Barry R. Steele, Constantinos G. Screttas, and David W. Wood pp 8443–8457 DOI: 10.1021/ja067754j Supporting Info

Convergent Synthesis of Alternating Fluorene-p-xylene Oligomers and Delineation of the (Silver) Cation-Induced Folding Vincent J. Chebny and Rajendra Rathore pp 8458–8465 DOI: 10.1021/ja0687522 Supporting Info

Geminate Charge Recombination in Alternating Polyfluorene Copolymer/Fullerene Blends Swati De, Torbjörn Pascher, Manisankar Maiti, Kim G. Jespersen, Tero Kesti, Fengling Zhang, Olle Inganäs, Arkady Yartsev, and Villy Sundström pp 8466–8472 DOI: 10.1021/ja068909q

Stern−Gerlach Experiments of One-Dimensional Metal−Benzene Sandwich Clusters:  Mn(C6H6)m (M = Al, Sc, Ti, and V) Ken Miyajima, Satoshi Yabushita, Mark B. Knickelbein, and Atsushi Nakajima pp 8473–8480 DOI: 10.1021/ja070137q

Protein Folding through Kinetic Discrimination Sara Linse and Björn Linse pp 8481–8486 DOI: 10.1021/ja070386e Supporting Info

Activity of Rhodium-Catalyzed Hydroformylation:  Added Insight and Predictions from Theory Manuel Sparta, Knut J. Børve, and Vidar R. Jensen pp 8487–8499 DOI: 10.1021/ja070395n Supporting Info

Photoactive Peptides for Light-Initiated Tyrosyl Radical Generation and Transport into Ribonucleotide Reductase Steven Y. Reece, Mohammad R. Seyedsayamdost, JoAnne Stubbe, and Daniel G. Nocera pp 8500–8509 DOI: 10.1021/ja0704434 Supporting Info

Metal−Insulator Transition of Charge-Transfer Salts Based on Unsymmetrical Donor DMET and Metal Halide Anions (DMET)4(MCl4)(TCE)2 (M = Mn, Co, Cu, Zn; TCE = 1,1,2-trichloroethane) Hiroshi Ito, Daichi Suzuki, Harutaka Watanabe, Hisaaki Tanaka, Shin-ichi Kuroda, Masamichi Umemiya, Norihito Kobayashi, Makoto Goto, Ken-ichi Sugiura, Hitoshi Miyasaka, Shinya Takaishi, Takashi Kajiwara, Masahiro Yamashita, Eiji Ohmichi, and Toshihito Osada pp 8510–8518 DOI: 10.1021/ja070672q Supporting Info

Highly Twisted Helical Polyacetylene with Morphology Free From the Bundle of Fibrils Synthesized in Chiral Nematic Liquid Crystal Reaction Field Munju Goh, Mutsumasa Kyotani, and Kazuo Akagi pp 8519–8527 DOI: 10.1021/ja070701x Supporting Info

Time-Domain ab Initio Study of Charge Relaxation and Recombination in Dye-Sensitized TiO2 Walter R. Duncan, Colleen F. Craig, and Oleg V. Prezhdo pp 8528–8543 DOI: 10.1021/ja0707198 Supporting Info

Ruthenium Complexes That Break the Rules:  Structural Features Controlling Dual Emission Edith C. Glazer, Douglas Magde, and Yitzhak Tor pp 8544–8551 DOI: 10.1021/ja071124f Supporting Info

Applicability of the BET Method for Determining Surface Areas of Microporous Metal−Organic Frameworks Krista S. Walton and Randall Q. Snurr pp 8552–8556 DOI: 10.1021/ja071174k Supporting Info

Protein Film Voltammetry of Copper-Containing Nitrite Reductase Reveals Reversible Inactivation Hein J. Wijma, Lars J. C. Jeuken, Martin Ph. Verbeet, Fraser A. Armstrong, and Gerard W. Canters pp 8557–8565 DOI: 10.1021/ja071274q

2D Multinuclear NMR, Hyperpolarized Xenon and Gas Storage in Organosilica Nanochannels with Crystalline Order in the Walls Angiolina Comotti, Silvia Bracco, Patrizia Valsesia, Lisa Ferretti, and Piero Sozzani pp 8566–8576 DOI: 10.1021/ja071348y Supporting Info

Comparing a Photoinduced Pericyclic Ring Opening and Closure:  Differences in the Excited State Pathways Björn Heinz, Stephan Malkmus, Stefan Laimgruber, Steffen Dietrich, Christine Schulz, Karola Rück-Braun, Markus Braun, Wolfgang Zinth, and Peter Gilch pp 8577–8584 DOI: 10.1021/ja071396i

Three-Dimensional Energy Transport in Highly Luminescent Host−Guest Crystals:  A Quantitative Experimental and Theoretical Study Lars Poulsen, Mikael Jazdzyk, Jean-Edouard Communal, Juan Carlos Sancho-García, Andrea Mura, Giovanni Bongiovanni, David Beljonne, Jérôme Cornil, Michael Hanack, Hans-Joachim Egelhaaf, and Johannes Gierschner pp 8585–8593 DOI: 10.1021/ja0714437

Phase-Controlled Growth of Metastable Fe5Si3 Nanowires by a Vapor Transport Method Kumar S. K. Varadwaj, Kwanyong Seo, Juneho In, Paritosh Mohanty, Jeunghee Park, and Bongsoo Kim pp 8594–8599 DOI: 10.1021/ja071439v Supporting Info

Inside Powders:  A Theoretical Model of Interfaces between MgO Nanocrystallites Keith P. McKenna, Peter V. Sushko, and Alexander L. Shluger pp 8600–8608 DOI: 10.1021/ja071602m Supporting Info

Toward Controlled Spacing in One-Dimensional Molecular Chains:  Alkyl-Chain-Functionalized Fullerenes in Carbon Nanotubes Thomas W. Chamberlain, Andrew Camenisch, Neil R. Champness, G. Andrew D. Briggs, Simon C. Benjamin, Arzhang Ardavan, and Andrei N. Khlobystov pp 8609–8614 DOI: 10.1021/ja071803q Supporting Info

Theoretical Study of C−H and N−H σ-Bond Activation Reactions by Titinium(IV)-Imido Complex. Good Understanding Based on Orbital Interaction and Theoretical Proposal for N−H σ-Bond Activation of Ammonia Noriaki Ochi, Yoshihide Nakao, Hirofumi Sato, and Shigeyoshi Sakaki pp 8615–8624 DOI: 10.1021/ja071825c Supporting Info

General Method for Ultrathin Free-Standing Films of Nanofibrous Composite Materials Xinsheng Peng, Jian Jin, Emma M. Ericsson, and Izumi Ichinose pp 8625–8633 DOI: 10.1021/ja0718974 Supporting Info

Non-Base Pairing DNA Provides a New Dimension for Controlling Aptamer-Linked Nanoparticles and Sensors Juewen Liu and Yi Lu pp 8634–8643 DOI: 10.1021/ja072075+ Supporting Info

Photochromism of Anabaena Sensory Rhodopsin Akira Kawanabe, Yuji Furutani, Kwang-Hwan Jung, and Hideki Kandori pp 8644–8649 DOI: 10.1021/ja072085a Supporting Info

Functional Bionetworks from Nanoliter Water Droplets Matthew A. Holden, David Needham, and Hagan Bayley pp 8650–8655 DOI: 10.1021/ja072292a Supporting Info

Origin of Attraction, Magnitude, and Directionality of Interactions in Benzene Complexes with Pyridinium Cations Seiji Tsuzuki, Masuhiro Mikami, and Shinji Yamada pp 8656–8662 DOI: 10.1021/ja071372b Supporting Info

Insight into the Permeation Barrier of Glued Langmuir−Blodgett Bilayers Donald H. McCullough, III, Ruslan Grygorash, James T. Hsu, and Steven L. Regen pp 8663–8667 DOI: 10.1021/ja071936b Supporting Info

The Chlorate−Iodine Clock Reaction  [J. Am. Chem. Soc. 2005, 127, 18022−18023].  André P. Oliveira and Roberto B. Faria p 8668 DOI: 10.1021/ja076895y

Advances in Photochemistry, Volume 29 Edited by Douglas C. Neckers (Bowling Green State University, Bowling Green, Ohio), William S. Jenks (Iowa State University, Ames, Iowa), and Thomas Wolff (Technische Universität Dresden, Germany). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 384 pp. $145.00. ISBN 0-471-68240-3. V. Ramamurthy p 8669 DOI: 10.1021/ja0698329

High-Performance Gradient Elution:  The Practical Application of the Linear-Solvent-Strength Model By Lloyd R. Snyder (LC Resources, Inc., Orinda, CA) and John W. Dolan (LC Resources, Inc., Amity, OR). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xxviii + 462 pp. $115.00. ISBN 0-471-70646-9. Victoria L. McGuffin pp 8669–8670 DOI: 10.1021/ja069848z

Metal Ions in Life Sciences, Volume 1:  Neurodegenerative Diseases and Metal Ions Edited by Astrid Sigel, Helmut Sigel (University of Basel, Switzerland), and Roland K. O. Sigel (University of Zürich, Switzerland). John Wiley & Sons, Ltd:  Chichester. 2006. xxiv + 464 pp. $200. ISBN 0-470-01488-1. Giuseppe L. Squadrito p 8670 DOI: 10.1021/ja076902i

Issue 28

A Red Cy3-Based Biarsenical Fluorescent Probe Targeted to a Complementary Binding Peptide Haishi Cao, Yijia Xiong, Ting Wang, Baowei Chen, Thomas C. Squier, and M. Uljana Mayer pp 8672–8673 DOI: 10.1021/ja070003c Supporting Info

Equivalency of Binding Sites in Protein−Ligand Complexes Revealed by Time-Resolved Tandem Mass Spectrometry Glen K. Shoemaker, Elena N. Kitova, Monica M. Palcic, and John S. Klassen pp 8674–8675 DOI: 10.1021/ja068421p Supporting Info

In Vivo Site-Specific DNA Methylation with a Designed Sequence-Enabled DNA Methylase Wataru Nomura and Carlos F. Barbas, III pp 8676–8677 DOI: 10.1021/ja0705588 Supporting Info

Photoregulation of a Peptide−RNA Interaction on a Gold Surface Gosuke Hayashi, Masaki Hagihara, Chikara Dohno, and Kazuhiko Nakatani pp 8678–8679 DOI: 10.1021/ja071298x Supporting Info

Inorganic−Organic Hybrid Luminescent Binary Probe for DNA Detection Based on Spin-Forbidden Resonance Energy Transfer Angel A. Martí, Cindy A. Puckett, Joanne Dyer, Nathan Stevens, Steffen Jockusch, Jingyue Ju, Jacqueline K. Barton, and Nicholas J. Turro pp 8680–8681 DOI: 10.1021/ja0717257 Supporting Info

Covalent Immobilization of Peptides on Self-Assembled Monolayer Surfaces Using Soft-Landing of Mass-Selected Ions Peng Wang, Omar Hadjar, and Julia Laskin pp 8682–8683 DOI: 10.1021/ja071804i Supporting Info

Synthesis and Characterization of Ordered Intermetallic PtPb Nanorods Sean Maksimuk, Shengchun Yang, Zhenmeng Peng, and Hong Yang pp 8684–8685 DOI: 10.1021/ja071980r Supporting Info

Transition-State Complexation in Palladium-Promoted [3,3] Sigmatropic Shifts Matthew R. Siebert and Dean J. Tantillo pp 8686–8687 DOI: 10.1021/ja072159i Supporting Info

Equilibration between Three Different Excited States in a Bichromophoric Copper(I) Polypyridine Complex Yoann Leydet, Dario M. Bassani, Gediminas Jonusauskas, and Nathan D. McClenaghan pp 8688–8689 DOI: 10.1021/ja072335n Supporting Info

Magnesium Isotopic Equilibrium in Chlorophylls Jay R. Black, Qing-zhu Yin, James R. Rustad, and William H. Casey pp 8690–8691 DOI: 10.1021/ja072573i Supporting Info

Encircled Proton Victor W. Day, Md. Alamgir Hossain, Sung Ok Kang, Douglas Powell, Gerald Lushington, and Kristin Bowman-James pp 8692–8693 DOI: 10.1021/ja0724745 Supporting Info

Magnetic Assembly and Pyrolysis of Functional Ferromagnetic Colloids into One-Dimensional Carbon Nanostructures Steven E. Bowles, Wei Wu, Tomasz Kowalewski, Matthew C. Schalnat, Robert J. Davis, Jeanne E. Pemberton, Inbo Shim, Bryan D. Korth, and Jeffrey Pyun pp 8694–8695 DOI: 10.1021/ja072757x Supporting Info

DNA-Directed Assembly of Single-Wall Carbon Nanotubes Yi Chen, Haipeng Liu, Tao Ye, Junghwa Kim, and Chengde Mao pp 8696–8697 DOI: 10.1021/ja072838t Supporting Info

Magnetic Core/Shell Fe3O4/Au and Fe3O4/Au/Ag Nanoparticles with Tunable Plasmonic Properties Zhichuan Xu, Yanglong Hou, and Shouheng Sun pp 8698–8699 DOI: 10.1021/ja073057v Supporting Info

Ionic Conductivity in the Solid Glyme Complexes [CH3O(CH2CH2O)nCH3]:LiAsF6 (n = 3,4) Chuhong Zhang, David Ainsworth, Yuri G. Andreev, and Peter G. Bruce pp 8700–8701 DOI: 10.1021/ja073145f Supporting Info

Selective Detection and Quantification of Oxidized Abasic Lesions in DNA Shanta Dhar, Tetsuya Kodama, and Marc M. Greenberg pp 8702–8703 DOI: 10.1021/ja073014e Supporting Info

Mesitylborane as a Bis(σ-B−H) Ligand:  An Unprecedented Bonding Mode to a Metal Center Gilles Alcaraz, Eric Clot, Ulrike Helmstedt, Laure Vendier, and Sylviane Sabo-Etienne pp 8704–8705 DOI: 10.1021/ja0733538 Supporting Info

Facile Hydrogenation of N2O by an Operationally Unsaturated Osmium Polyhydride Joo-Ho Lee, Maren Pink, John Tomaszewski, Hongjun Fan, and Kenneth G. Caulton pp 8706–8707 DOI: 10.1021/ja071452f Supporting Info

Palladium-Catalyzed Cross-Coupling of Aryl or Vinyl Iodides with Ethyl Diazoacetate Cheng Peng, Jiajia Cheng, and Jianbo Wang pp 8708–8709 DOI: 10.1021/ja073010+ Supporting Info

Aspartate-Catalyzed Asymmetric Epoxidation Reactions Gorka Peris, Charles E. Jakobsche, and Scott J. Miller pp 8710–8711 DOI: 10.1021/ja073055a Supporting Info

Catalytic Intermolecular Reductive Coupling of Enones and Alkynes Ananda Herath, Benjamin B. Thompson, and John Montgomery pp 8712–8713 DOI: 10.1021/ja073300q Supporting Info

Exploiting Temperature-Dependent Substrate Promiscuity for Nucleoside Analogue Activation by Thymidine Kinase from Thermotoga maritima Stefan Lutz, Joseph Lichter, and Lingfeng Liu pp 8714–8715 DOI: 10.1021/ja0734391 Supporting Info

One-Electron Reduction of Methanesulfonyl Chloride. The Fate of MeSO2Cl•- and MeSO2• Intermediates in Oxygenated Solutions and Their Role in the Cis−Trans Isomerization of Mono-unsaturated Fatty Acids Maurizio Tamba, Katalin Dajka, Carla Ferreri, Klaus-Dieter Asmus, and Chryssostomos Chatgilialoglu pp 8716–8723 DOI: 10.1021/ja070626q

Photochemical Growth of Silver Nanoparticles on c- and c+ Domains on Lead Zirconate Titanate Thin Films Steve Dunn, Paul M. Jones, and Diego E. Gallardo pp 8724–8728 DOI: 10.1021/ja071451n

Cleavage of Carbon−Carbon Bonds of Diphenylacetylene and Its Derivatives via Photolysis of Pt Complexes:  Tuning the C−C Bond Formation Energy toward Selective C−C Bond Activation Ahmet Gunay and William D. Jones pp 8729–8735 DOI: 10.1021/ja071698k Supporting Info

Effects of Molecular Confinement inside Single Walled Carbon Nanotubes on Chemical Reactivity − Atomic H + 1-Heptene Peter Kondratyuk and John T. Yates, Jr. pp 8736–8739 DOI: 10.1021/ja067142z

Evidence for Micellar Structure in the Gas Phase Michal Sharon, Leopold L. Ilag, and Carol V. Robinson pp 8740–8746 DOI: 10.1021/ja067820h Supporting Info

Alanine Scan of [l-Dap2]Ramoplanin A2 Aglycon:  Assessment of the Importance of Each Residue Joonwoo Nam, Dongwoo Shin, Yosup Rew, and Dale L. Boger pp 8747–8755 DOI: 10.1021/ja068573k Supporting Info

Red Light in Chemiluminescence and Yellow-Green Light in Bioluminescence:  Color-Tuning Mechanism of Firefly, Photinus pyralis, Studied by the Symmetry-Adapted Cluster−Configuration Interaction Method Naoki Nakatani, Jun-ya Hasegawa, and Hiroshi Nakatsuji pp 8756–8765 DOI: 10.1021/ja0611691 Supporting Info

Development, Mechanism, and Scope of the Palladium-Catalyzed Enantioselective Allene Diboration Heather E. Burks, Shubin Liu, and James P. Morken pp 8766–8773 DOI: 10.1021/ja070572k Supporting Info

Self-Sorting Chiral Subcomponent Rearrangement During Crystallization Marie Hutin, Christopher J. Cramer, Laura Gagliardi, Abdul Rehaman Moughal Shahi, Gérald Bernardinelli, Radovan Cerny, and Jonathan R. Nitschke pp 8774–8780 DOI: 10.1021/ja070320j Supporting Info

Intermolecular C−H Bond Activation Reactions Promoted by Transient Titanium Alkylidynes. Synthesis, Reactivity, Kinetic, and Theoretical Studies of the TiC Linkage Brad C. Bailey, Hongjun Fan, John C. Huffman, Mu-Hyun Baik, and Daniel J. Mindiola pp 8781–8793 DOI: 10.1021/ja070989q Supporting Info

Not All G-Quadruplexes Exhibit Ion-Channel-like Properties:  NMR Study of Ammonium Ion (Non)movement within the d(G3T4G4)2 Quadruplex Primož Šket and Janez Plavec pp 8794–8800 DOI: 10.1021/ja0710003 Supporting Info

Monocopper Center Embedded in a Biomimetic Cavity:  From Supramolecular Control of Copper Coordination to Redox Regulation Nicolas Le Poul, Morgan Campion, Bénédicte Douziech, Yannick Rondelez, Loïc Le Clainche, Olivia Reinaud, and Yves Le Mest pp 8801–8810 DOI: 10.1021/ja071219h Supporting Info

Probing the Formation of Stable Tertiary Structure in a Model Miniprotein at Atomic Resolution:  Determinants of Stability of a Helical Hairpin Alexey Neumoin, Jiri Mares, Mirjam Lerch-Bader, Reto Bader, and Oliver Zerbe pp 8811–8817 DOI: 10.1021/ja0716960 Supporting Info

Self-Assembly Dynamics of a Cylindrical Capsule Monitored by Fluorescence Resonance Energy Transfer Elizabeth S. Barrett, Trevor J. Dale, and Julius Rebek, Jr. pp 8818–8824 DOI: 10.1021/ja071774j Supporting Info

Control and Measurement of the Phase Behavior of Aqueous Solutions Using Microfluidics Jung-uk Shim, Galder Cristobal, Darren R. Link, Todd Thorsen, Yanwei Jia, Katie Piattelli, and Seth Fraden pp 8825–8835 DOI: 10.1021/ja071820f Supporting Info

Nonpolar Isosteres of Damaged DNA Bases:  Effective Mimicry of Mutagenic Properties of 8-Oxopurines Yosuke Taniguchi and Eric T. Kool pp 8836–8844 DOI: 10.1021/ja071970q Supporting Info

Mesoporous Silica Nanoparticles for Intracellular Delivery of Membrane-Impermeable Proteins Igor I. Slowing, Brian G. Trewyn, and Victor S.-Y. Lin pp 8845–8849 DOI: 10.1021/ja0719780 Supporting Info

Sequential and Selective Hydrogenation of the Cα−Cβ and M−Cα Double Bonds of an Allenylidene Ligand Coordinated to Osmium:  New Reaction Patterns between an Allenylidene Complex and Alcohols Tamara Bolaño, Ricardo Castarlenas, Miguel A. Esteruelas, and Enrique Oñate pp 8850–8859 DOI: 10.1021/ja071972a Supporting Info

Cobalt-Catalyzed Cyclotrimerization of Alkynes:  The Answer to the Puzzle of Parallel Reaction Pathways Nicolas Agenet, Vincent Gandon, K. Peter C. Vollhardt, Max Malacria, and Corinne Aubert pp 8860–8871 DOI: 10.1021/ja072208r Supporting Info

Redox Regulation of Protein Tyrosine Phosphatase 1B (PTP1B):  A Biomimetic Study on the Unexpected Formation of a Sulfenyl Amide Intermediate Bani Kanta Sarma and Govindasamy Mugesh pp 8872–8881 DOI: 10.1021/ja070410o Supporting Info

Copper(I)/S8 Reversible Reactions Leading to an End-On Bound Dicopper(II) Disulfide Complex:  Nucleophilic Reactivity and Analogies to Copper−Dioxygen Chemistry Debabrata Maiti, Julia S. Woertink, Michael A. Vance, Ashley E. Milligan, Amy A. Narducci Sarjeant, Edward I. Solomon, and Kenneth D. Karlin pp 8882–8892 DOI: 10.1021/ja071968z Supporting Info

Ansa [1]Trochrocenophanes and Their Related Unstrained 1,1‘-Disubstituted Counterparts:  Synthesis and Electronic Structure Holger Braunschweig, Thomas Kupfer, Matthias Lutz, and Krzysztof Radacki pp 8893–8906 DOI: 10.1021/ja0724947 Supporting Info

Tubular Graphite Cones with Single-Crystal Nanotips and Their Antioxygenic Properties Naigui Shang, William I. Milne, and Xin Jiang pp 8907–8911 DOI: 10.1021/ja071830g

Spectroscopically Distinct Sites Present in Methyltrioxorhenium Grafted onto Silica−Alumina, and Their Abilities to Initiate Olefin Metathesis Anthony W. Moses, Christina Raab, Ryan C. Nelson, Heather D. Leifeste, Naseem A. Ramsahye, Swarup Chattopadhyay, Juergen Eckert, Bradley F. Chmelka, and Susannah L. Scott pp 8912–8920 DOI: 10.1021/ja072707s Supporting Info

Self-Assembled Heterotrimeric Collagen Triple Helices Directed through Electrostatic Interactions [J. Am. Chem. Soc. 2007, 129, 2683−2690]. Varun Gauba and Jeffrey D. Hartgerink p 8921 DOI: 10.1021/ja073864u

Molecular Theory of Solutions By Arieh Ben-Naim (The Hebrew University, Jerusalem, Israel). Oxford University Press:  Oxford, New York. 2006. xviii + 380 pp. $64.50. ISBN:  0-19-929970-6. Jayendran C. Rasaiah p 8922 DOI: 10.1021/ja0698174

Chiral Separation Techniques:  A Practical Approach, Completely Revised and Updated 3rd ed Edited by Ganapathy Subramanian (Canterbury, U.K.). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xxii + 618 pp. $200. ISBN 978-3-527-31509-3. Apryll M. Stalcup pp 8922–8923 DOI: 10.1021/ja076917g

N-Heterocyclic Carbenes in Transition Metal Catalysis. Topics in Organometallic Chemistry 21 Edited by Frank Glorius (Philipps-Universität Marburg, Germany). Springer:  Berlin, Heidelberg, New York. 2007. xii + 232 pp. $199.00. ISBN 978-3-540-36929-5. Cathleen M. Crudden and Jeremy M. Praetorius pp 8923–8924 DOI: 10.1021/ja076926p

Hydrogen-Transfer Reactions, Volumes 1−4 Edited by James T. Hynes (University of Colorado, Boulder and École Normale Supérieure, Paris), Judith P. Klinman (University of California, Berkeley), Hans-Heinrich Limbach (Freie Universität Berlin), Richard L. Schowen (University of Kansas). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim, Germany. 2007. 1603 pp. $650.00. ISBN 978-3-527-30777-7. Charles L. Perrin pp 8924–8925 DOI: 10.1021/ja076906n

HPLC for Pharmaceutical Scientists Edited by Yuri Kazakevich (Seton Hall University, South Orange, NJ) and Rosario LoBrutto (Novartis Pharmaceuticals, East Hanover, NJ). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xxvi + 1104 pp. $175.00. ISBN 0-471-68162-8. Ira Krull pp 8925–8926 DOI: 10.1021/ja076910z

Flavins:  Photochemistry and Photobiology. Comprehensive Series in Photochemical and Photobiological Sciences Edited by Eduardo Silva and Ana M. Edwards (P. Universidad Catolica de Chile, Santiago). Royal Society of Chemistry:  Cambridge. 2006. x + 328 pp. $329.00. ISBN 0-85404-331-4. Giovanni Gadda p 8926 DOI: 10.1021/ja069844u

Issue 29

Local and Tunable n→π* Interactions Regulate Amide Isomerism in the Peptoid Backbone Benjamin C. Gorske, Brent L. Bastian, Grant D. Geske, and Helen E. Blackwell pp 8928–8929 DOI: 10.1021/ja071310l Supporting Info

Enantioselective [2 + 2] Cycloaddition of Unactivated Alkenes with α-Acyloxyacroleins Catalyzed by Chiral Organoammonium Salts Kazuaki Ishihara and Kazuhiko Nakano pp 8930–8931 DOI: 10.1021/ja073435w Supporting Info

Resolving Structures from Powders by NMR Crystallography Using Combined Proton Spin Diffusion and Plane Wave DFT Calculations Chris J. Pickard, Elodie Salager, Guido Pintacuda, Bénédicte Elena, and Lyndon Emsley pp 8932–8933 DOI: 10.1021/ja071829h Supporting Info

Relaxation Dynamics of Cr(acac)3 Probed by Ultrafast Infrared Spectroscopy Ermelinda M. S. Maçôas, Robertas Kananavicius, Pasi Myllyperkiö, Mika Pettersson, and Henrik Kunttu pp 8934–8935 DOI: 10.1021/ja071859k Supporting Info

Photodynamics of a Single Quantum Dot:  Fluorescence Activation, Enhancement, Intermittency, and Decay Steven F. Lee and Mark A. Osborne pp 8936–8937 DOI: 10.1021/ja071876+ Supporting Info

Quantitative Analysis of Nonequilibrium, Denaturant-Dependent Protein Folding Transitions Denis Erilov, Chasper Puorger, and Rudi Glockshuber pp 8938–8939 DOI: 10.1021/ja0718927 Supporting Info

Fe(salan)-Catalyzed Asymmetric Oxidation of Sulfides with Hydrogen Peroxide in Water Hiromichi Egami and Tsutomu Katsuki pp 8940–8941 DOI: 10.1021/ja071916+ Supporting Info

Multi-Emissive Difluoroboron Dibenzoylmethane Polylactide Exhibiting Intense Fluorescence and Oxygen-Sensitive Room-Temperature Phosphorescence Guoqing Zhang, Jianbin Chen, Sarah J. Payne, Steven E. Kooi, J. N. Demas, and Cassandra L. Fraser pp 8942–8943 DOI: 10.1021/ja0720255 Supporting Info

Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers Erin N. Guidry, Jean Li, J. Fraser Stoddart, and Robert H. Grubbs pp 8944–8945 DOI: 10.1021/ja0725100 Supporting Info

Copolymerization of Ethylene and Alkyl Vinyl Ethers by a (Phosphine- sulfonate)PdMe Catalyst Shuji Luo, Javier Vela, Graham R. Lief, and Richard F. Jordan pp 8946–8947 DOI: 10.1021/ja072562p Supporting Info

Formation of Linear Copolymers of Ethylene and Acrylonitrile Catalyzed by Phosphine Sulfonate Palladium Complexes Takuya Kochi, Shusuke Noda, Kenji Yoshimura, and Kyoko Nozaki pp 8948–8949 DOI: 10.1021/ja0725504 Supporting Info

The Electrochemical Monitoring of the Perturbation of Charge Transfer through DNA by Cisplatin Elicia L. S. Wong and J. Justin Gooding pp 8950–8951 DOI: 10.1021/ja0723075 Supporting Info

Crystal Structures of the Chiral Diamine (R,R)-TMCDA with the Commonly Used Alkyllithium Bases Methyllithium, iso-Propyllithium, and sec-Butyllithium Carsten Strohmann and Viktoria H. Gessner pp 8952–8953 DOI: 10.1021/ja072970t Supporting Info

Coalescence of C60 Molecules Assisted by Doped Iodine Inside Carbon Nanotubes Lunhui Guan, Kazu Suenaga, Toshiya Okazaki, Zujin Shi, Zhennan Gu, and Sumio Iijima pp 8954–8955 DOI: 10.1021/ja073033o Supporting Info

Preparation of a Blue Luminescent Nanosheet Derived from Layered Perovskite Bi2SrTa2O9 Shintaro Ida, Chikako Ogata, Ugur Unal, Kazuyoshi Izawa, Taishi Inoue, Ozge Altuntasoglu, and Yasumichi Matsumoto pp 8956–8957 DOI: 10.1021/ja073105b Supporting Info

Hyperbranched Conjugated Polyelectrolyte Bilayers for Solar-Cell Applications Prasad Taranekar, Qiquan Qiao, Hui Jiang, Ion Ghiviriga, Kirk S. Schanze, and John R. Reynolds pp 8958–8959 DOI: 10.1021/ja073216a Supporting Info

Total Synthesis of (−)-Archazolid B Paul A. Roethle, Ingrid T. Chen, and Dirk Trauner pp 8960–8961 DOI: 10.1021/ja0733033 Supporting Info

Self-Assembled Hybrid Nanoparticles for Cancer-Specific Multimodal Imaging Jason S. Kim, William J. Rieter, Kathryn M. L. Taylor, Hongyu An, Weili Lin, and Wenbin Lin pp 8962–8963 DOI: 10.1021/ja073062z Supporting Info

Synthesis and Crystal Structure of a 13-Vertex Carborane Radical Anion with 2n + 3 Framework Electrons Xiaodu Fu, Hoi-Shan Chan, and Zuowei Xie pp 8964–8965 DOI: 10.1021/ja073390z Supporting Info

Attachment of Cells to Islands Presenting Gradients of Adhesion Ligands Rafe T. Petty, Hung-Wing Li, Jane H. Maduram, Rustem Ismagilov, and Milan Mrksich pp 8966–8967 DOI: 10.1021/ja0735709 Supporting Info

Asymmetric Synthesis of Salvinorin A, A Potent κ Opioid Receptor Agonist Jonathan R. Scheerer, Jonathan F. Lawrence, Grace C. Wang, and David A. Evans pp 8968–8969 DOI: 10.1021/ja073590a Supporting Info

Two-Photon Fluorescent Holographic Rewritable Micropatterning Eléna Ishow, Arnaud Brosseau, Gilles Clavier, Keitaro Nakatani, Robert B. Pansu, Jean-Jacques Vachon, Patrick Tauc, Dominique Chauvat, Cleber R. Mendonça, and Erick Piovesan pp 8970–8971 DOI: 10.1021/ja0735756 Supporting Info

Enhancing Enantioselectivity of Electrodeposited CuO Films by Chiral Etching Shaibal K. Sarkar, Niharika Burla, Eric W. Bohannan, and Jay A. Switzer pp 8972–8973 DOI: 10.1021/ja073640b

Superparamagnetic Composite Colloids with Anisotropic Structures Jianping Ge, Yongxing Hu, Tierui Zhang, and Yadong Yin pp 8974–8975 DOI: 10.1021/ja0736461 Supporting Info

Organocatalytic Asymmetric Transfer Hydrogenation of Nitroolefins Nolwenn J. A. Martin, Lidia Ozores, and Benjamin List pp 8976–8977 DOI: 10.1021/ja074045c Supporting Info

What is the Active Species of Cytochrome P450 during Camphor Hydroxylation? QM/MM Studies of Different Electronic States of Compound I and of Reduced and Oxidized Iron−Oxo Intermediates Ahmet Altun, Sason Shaik, and Walter Thiel pp 8978–8987 DOI: 10.1021/ja066847y Supporting Info

Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes Xile Hu, Bruce S. Brunschwig, and Jonas C. Peters pp 8988–8998 DOI: 10.1021/ja067876b Supporting Info

Computational Study of Hydrogen Storage Characteristics of Covalent-Bonded Graphenes Noejung Park, Suklyun Hong, Gyubong Kim, and Seung-Hoon Jhi pp 8999–9003 DOI: 10.1021/ja0703527 Supporting Info

Spin Relaxation Effects in Photochemically Induced Dynamic Nuclear Polarization Spectroscopy of Nuclei with Strongly Anisotropic Hyperfine Couplings Ilya Kuprov, Timothy D. Craggs, Sophie E. Jackson, and P. J. Hore pp 9004–9013 DOI: 10.1021/ja0705792 Supporting Info

(n,m) Selectivity of Single-Walled Carbon Nanotubes by Different Carbon Precursors on Co−Mo Catalysts Bo Wang, C. H. Patrick Poa, Li Wei, Lain-Jong Li, Yanhui Yang, and Yuan Chen pp 9014–9019 DOI: 10.1021/ja070808k Supporting Info

Radical Carbonylation with [11C]Carbon Monoxide Promoted by Oxygen-Centered Radicals:  Experimental and DFT Studies of the Mechanism Oleksiy Itsenko, Daniel Norberg, Torben Rasmussen, Bengt Långström, and Chryssostomos Chatgilialoglu pp 9020–9031 DOI: 10.1021/ja0707714 Supporting Info

Thermoluminescence and a New Organic Light-Emitting Diode (OLED) Based on Triplet−Triplet Fluorescence of the Trimethylenemethane (TMM) Biradical Hayato Namai, Hiroshi Ikeda, Yosuke Hoshi, Nobuyuki Kato, Yoshii Morishita, and Kazuhiko Mizuno pp 9032–9036 DOI: 10.1021/ja070946+ Supporting Info

Nanoscale Patterning in Mixed Fluorocarbon−Hydrocarbon Phospholipid Bilayers Nicholas C. Yoder, Venkateshwarlu Kalsani, Steffen Schuy, Reiner Vogel, Andreas Janshoff, and Krishna Kumar pp 9037–9043 DOI: 10.1021/ja070950l Supporting Info

Hard-Sphere Packing and Icosahedral Assembly in the Formation of Mesoporous Materials Jiawei Tang, Xufeng Zhou, Dongyuan Zhao, Gao Qing Lu, Jin Zou, and Chengzhong Yu pp 9044–9048 DOI: 10.1021/ja070999r Supporting Info

Spectroscopic and Electronic Structure Studies of Intermediate X in Ribonucleotide Reductase R2 and Two Variants:  A Description of the FeIV-Oxo Bond in the FeIII−O−FeIV Dimer Nataša Mitić, Michael D. Clay, Lana Saleh, J. Martin Bollinger, Jr., and Edward I. Solomon pp 9049–9065 DOI: 10.1021/ja070909i Supporting Info

A Study of Piperidinium Structure-Directing Agents in the Synthesis of Silica Molecular Sieves under Fluoride-Based Conditions Stacey I. Zones, Allen W. Burton, Greg S. Lee, and Marilyn M. Olmstead pp 9066–9079 DOI: 10.1021/ja0709122 Supporting Info

Weak Calcium-Mediated Interactions between Lewis X-Related Trisaccharides Studied by NMR Measurements of Residual Dipolar Couplings Gabrielle Nodet, Luisa Poggi, Daniel Abergel, Chafika Gourmala, Dengxiang Dong, Yongmin Zhang, Jean-Maurice Mallet, and Geoffrey Bodenhausen pp 9080–9085 DOI: 10.1021/ja0711056 Supporting Info

Asymmetric Synthesis of All Eight Seven-Carbon Dipropionate Stereotetrads Ahmad El-Awa, Xavier Mollat du Jourdin, and Philip L. Fuchs pp 9086–9093 DOI: 10.1021/ja071217x Supporting Info

Exciplex Fluorescence as a Diagnostic Probe of Structure in Coordination Polymers of Zn2+ and 4,4‘-Bipyridine Containing Intercalated Pyrene and Enclathrated Aromatic Solvent Guests Gregory J. McManus, John J. Perry IV, Mark Perry,Mark Perry, Brian D. Wagner, and Michael J. Zaworotko pp 9094–9101 DOI: 10.1021/ja071271d Supporting Info

Synthesis and Size-Dependent Exchange Bias in Inverted Core−Shell MnO|Mn3O4 Nanoparticles German Salazar-Alvarez, Jordi Sort, Santiago Suriñach, M. Dolors Baró, and Josep Nogués pp 9102–9108 DOI: 10.1021/ja0714282 Supporting Info

Synthesis of Tetra-ortho-substituted, Phosphorus-Containing and Carbonyl-Containing Biaryls Utilizing a Diels−Alder Approach Bradley O. Ashburn, Rich G. Carter, and Lev N. Zakharov pp 9109–9116 DOI: 10.1021/ja071163r Supporting Info

Enzymatic Effects on Reactant and Transition States. The Case of Chalcone Isomerase J. Javier Ruiz-Pernía, Estanislao Silla, and Iñaki Tuñón pp 9117–9124 DOI: 10.1021/ja071720+

Synthesis, Characterization, and Application of Indolo[3,2-b]carbazole Semiconductors Pierre-Luc T. Boudreault, Salem Wakim, Nicolas Blouin, Michel Simard, Christian Tessier, Ye Tao, and Mario Leclerc pp 9125–9136 DOI: 10.1021/ja071923y Supporting Info

Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as Mild and Reproducible Agents for Rhodium-Catalyzed 1,4-Addition Reactions Yoshiaki Nakao, Jinshui Chen, Hidekazu Imanaka, Tamejiro Hiyama, Yoshitaka Ichikawa, Wei-Liang Duan, Ryo Shintani, and Tamio Hayashi pp 9137–9143 DOI: 10.1021/ja071969r Supporting Info

Efficient Solution-Processed Photovoltaic Cells Based on an Anthradithiophene/Fullerene Blend Matthew T. Lloyd, Alex C. Mayer, Sankar Subramanian, Devin A. Mourey, Dave J. Herman, Amit V. Bapat, John E. Anthony, and George G. Malliaras pp 9144–9149 DOI: 10.1021/ja072147x Supporting Info

Total Synthesis of Iejimalide A−D and Assessment of the Remarkable Actin-Depolymerizing Capacity of These Polyene Macrolides Alois Fürstner, Cristina Nevado, Mario Waser, Martin Tremblay, Carine Chevrier, Filip Teplý, Christophe Aïssa, Emilie Moulin, and Oliver Müller pp 9150–9161 DOI: 10.1021/ja072334v Supporting Info

Intrinsic Multistate Switching of Gold Clusters through Electrochemical Gating Tim Albrecht, Stijn F. L. Mertens, and J. Ulstrup pp 9162–9167 DOI: 10.1021/ja072517h Supporting Info

Double Helical Oligoresorcinols Specifically Recognize Oligosaccharides via Heteroduplex Formation through Noncovalent Interactions in Water Hidetoshi Goto, Yoshio Furusho, and Eiji Yashima pp 9168–9174 DOI: 10.1021/ja0730359 Supporting Info

Duplex Polarons in DNA Esther M. Conwell, Steven M. Bloch, Patrick M. McLaughlin, and Denis M. Basko pp 9175–9181 DOI: 10.1021/ja0691472 Supporting Info

New Nickel(II) Diimine Complexes and the Control of Polyethylene Microstructure by Catalyst Design Dieter Meinhard, Marcus Wegner, Georgy Kipiani, Andrew Hearley, Peter Reuter, Stefan Fischer, Othmar Marti, and Bernhard Rieger pp 9182–9191 DOI: 10.1021/ja070224i Supporting Info

Modeling the Metal Center of Cys4 Zinc Proteins Andrew S. Lipton and Paul D. Ellis pp 9192–9200 DOI: 10.1021/ja071430t Supporting Info

Electrochemical Study of a Reconstituted Photosynthetic Electron-Transfer Chain Vincent Fourmond, Bernard Lagoutte, Pierre Sétif, Winfried Leibl, and Christophe Demaille pp 9201–9209 DOI: 10.1021/ja0714787 Supporting Info

A Stabilized β-Oxaphosphoniumbetaine:  An Elusive Zwitterion Alex S. Ionkin, William J. Marshall, Brian M. Fish, Matthew F. Schiffhauer, and Fredric Davidson pp 9210–9215 DOI: 10.1021/ja071644a Supporting Info

Mechanism and Application of a Microcapsule Enabled Multicatalyst Reaction Sarah L. Poe, Muris Kobašlija, and D. Tyler McQuade pp 9216–9221 DOI: 10.1021/ja071706x Supporting Info

“Super Armed” Glycosyl Donors:  Conformational Arming of Thioglycosides by Silylation Christian Marcus Pedersen, Lars Ulrik Nordstrøm, and Mikael Bols pp 9222–9235 DOI: 10.1021/ja071955l Supporting Info

Sulfur Radical Cation−Peptide Bond Complex in the One-Electron Oxidation of S-Methylglutathione Krzysztof Bobrowski, Gordon L. Hug, Dariusz Pogocki, Bronislaw Marciniak, and Christian Schöneich pp 9236–9245 DOI: 10.1021/ja072301f Supporting Info

Analytical Ultracentrifugation:  Techniques and Methods Edited by David J. Scott, Stephen E. Harding, and Arthur J. Rowe (University of Nottingham). Royal Society of Chemistry:  Cambridge. 2005. xxiv + 588 pp. $250.00. ISBN 0-85404-547-3. Ronald D. Macfarlane p 9246 DOI: 10.1021/ja069738s

Issue 30

A Bell-Shaped Mn11Gd2 Single-Molecule Magnet Valeriu M. Mereacre, Ayuk M. Ako, Rodolphe Clérac, Wolfgang Wernsdorfer, George Filoti, Juan Bartolomé, Christopher E. Anson, and Annie K. Powell pp 9248–9249 DOI: 10.1021/ja071073m Supporting Info

Slow Electron Injection on Ru−Phthalocyanine Sensitized TiO2 Ana Morandeira, Ismael López-Duarte, M. Victoria Martínez-Díaz, Brian O'Regan, Chris Shuttle, Nor A. Haji-Zainulabidin, Tomás Torres, Emilio Palomares, and James R. Durrant pp 9250–9251 DOI: 10.1021/ja0722980 Supporting Info

Direct Adsorption and Detection of Proteins, Including Ferritin, onto Microlens Array Patterned Bioarrays Feng Zhang, Richard J. Gates, Vincent S. Smentkowski, Sriram Natarajan, Bruce K. Gale, Richard K. Watt, Matthew C. Asplund, and Matthew R. Linford pp 9252–9253 DOI: 10.1021/ja072250m Supporting Info

Boronyls as Key Structural Units in Boron Oxide Clusters:  B(BO)2- and B(BO)3- Hua-Jin Zhai, Si-Dian Li, and Lai-Sheng Wang pp 9254–9255 DOI: 10.1021/ja072611y Supporting Info

Additive-Free Synthesis of Poly(phenylene oxide):  Aerobic Oxidative Polymerization in a Base-Condensed Dendrimer Capsule Kimihisa Yamamoto, Yuki Kawana, Masahiro Tsuji, Misa Hayashi, and Takane Imaoka pp 9256–9257 DOI: 10.1021/ja0727518 Supporting Info

Synthetic Small Molecules that Induce Neurogenesis in Skeletal Muscle Darren R. Williams, Myung-Ryul Lee, Young-Ah Song, Sung-Kyun Ko, Gun-Hee Kim, and Injae Shin pp 9258–9259 DOI: 10.1021/ja072817z Supporting Info

Self-Aggregation of Spin-Labeled Alamethicin in ePC Vesicles Studied by Pulsed Electron−Electron Double Resonance Alexander D. Milov, Rimma I. Samoilova, Yuri D. Tsvetkov, Fernando Formaggio, Claudio Toniolo, and Jan Raap pp 9260–9261 DOI: 10.1021/ja072851d Supporting Info

Thermodynamics of Xenon Binding to Cryptophane in Water and Human Plasma P. Aru Hill, Qian Wei, Roderic G. Eckenhoff, and Ivan J. Dmochowski pp 9262–9263 DOI: 10.1021/ja072965p Supporting Info

Combining Surface Chemistry with a FRET-Based Biosensor to Study the Dynamics of RhoA GTPase Activation in Cells on Patterned Substrates Louis Hodgson, Eugene W. L. Chan, Klaus M. Hahn, and Muhammad N. Yousaf pp 9264–9265 DOI: 10.1021/ja072900m Supporting Info

Gas-Phase Reactions of ClMn(H2O)+ with Polar and Nonpolar Hydrocarbons in a Mass Spectrometer Penggao Duan, Mingkun Fu, David S. Pinkston, Steven C. Habicht, and Hilkka I. Kenttämaa pp 9266–9267 DOI: 10.1021/ja073270r

Control of Supramolecular Rectangle Self-Assembly with a Molecular Template Shan-Shan Li, Hui-Juan Yan, Li-Jun Wan, Hai-Bo Yang, Brian H. Northrop, and Peter J. Stang pp 9268–9269 DOI: 10.1021/ja0733282 Supporting Info

An Ordered Assembly of Filled Nanoscale Tubules of Europium Seleno-silicate in the Crystal Structure of a Quaternary Compound Amitava Choudhury and Peter K. Dorhout pp 9270–9271 DOI: 10.1021/ja073335q Supporting Info

Ultrafast Electronic Relaxation in Guanosine is Promoted by Hydrogen Bonding with Cytidine Nina K. Schwalb and Friedrich Temps pp 9272–9273 DOI: 10.1021/ja073448+ Supporting Info

Coupling of Liquid Crystals to Silica Nanoparticles Vincent Rachet, Khalid Lahlil, Mathieu Bérard, Thierry Gacoin, and Jean-Pierre Boilot pp 9274–9275 DOI: 10.1021/ja0735608 Supporting Info

Molecular Engineering of Coaxial Donor−Acceptor Heterojunction by Coassembly of Two Different Hexabenzocoronenes:  Graphitic Nanotubes with Enhanced Photoconducting Properties Yohei Yamamoto, Takanori Fukushima, Akinori Saeki, Shu Seki, Seiichi Tagawa, Noriyuki Ishii, and Takuzo Aida pp 9276–9277 DOI: 10.1021/ja073577q Supporting Info

Detection of Transient Intermediates in the Metal-Dependent Nonoxidative Decarboxylation Catalyzed by α-Amino-β-Carboxymuconate-ε-Semialdehyde Decarboxylase Tingfeng Li, John K. Ma, Jonathan P. Hosler, Victor L. Davidson, and Aimin Liu pp 9278–9279 DOI: 10.1021/ja073648l Supporting Info

Kinetic Solvent Effects on the Reaction of an Aromatic Ketone π,π* Triplet with Phenol. Rate-Retarding and Rate-Accelerating Effects of Hydrogen-Bond Acceptor Solvents Raquel E. Galian, Grzegorz Litwinienko, Julia Pérez-Prieto, and Keith U. Ingold pp 9280–9281 DOI: 10.1021/ja071716y Supporting Info

Evidence for Mixed-Ion Clusters in Metallocene Catalysts:  Influence on Ligand Exchange Dynamics and Catalyst Activity Carlos Alonso-Moreno, Simon J. Lancaster, Cristiano Zuccaccia, Alceo Macchioni, and Manfred Bochmann pp 9282–9283 DOI: 10.1021/ja072028h Supporting Info

Dinitrogen Activation at Ambient Temperatures:  New Modes of H2 and PhSiH3 Additions for an “End-On-Bridged” [Ta(IV)]2(μ-η1:η1-N2) Complex and for the Bis(μ-nitrido) [Ta(V)(μ-N)]2 Product Derived from Facile NN Bond Cleavage Masakazu Hirotsu, Philip P. Fontaine, Albert Epshteyn, Peter Y. Zavalij, and Lawrence R. Sita pp 9284–9285 DOI: 10.1021/ja072248v Supporting Info

Methyl Transfer from Methylcobaloxime to (Triphos)Ni(PPh3):  Relevance to the Mechanism of Acetyl Coenzyme A Synthase Nathan A. Eckert, William G. Dougherty, Glenn P. A. Yap, and Charles G. Riordan pp 9286–9287 DOI: 10.1021/ja072063o Supporting Info

Ultraviolet-Assisted Curing of Polycrystalline Pure-Silica Zeolites:  Hydrophobization, Functionalization, and Cross-Linking of Grains Salvador Eslava, Francesca Iacopi, Mikhail R. Baklanov, Christine E. A. Kirschhock, Karen Maex, and Johan A. Martens pp 9288–9289 DOI: 10.1021/ja0723737 Supporting Info

Influence of Hydrostatic Pressure and Cosolutes on RNA Tertiary Structure Christopher D. Downey, Ryan L. Crisman, Theodore W. Randolph, and Arthur Pardi pp 9290–9291 DOI: 10.1021/ja072179k Supporting Info

Increased Paramagnetic Effect of a Lanthanide Protein Probe by Two-Point Attachment Peter H. J. Keizers, Jean F. Desreux, Mark Overhand, and Marcellus Ubbink pp 9292–9293 DOI: 10.1021/ja0725201 Supporting Info

Differentiating Metabolites Formed from de Novo Synthesis versus Macromolecule Decomposition Jie Yuan and Joshua D. Rabinowitz pp 9294–9295 DOI: 10.1021/ja072997c Supporting Info

Relative Binding Affinities of Fructose-1,6-Bisphosphatase Inhibitors Calculated Using a Quantum Mechanics-Based Free Energy Perturbation Method M. Rami Reddy and Mark D. Erion pp 9296–9297 DOI: 10.1021/ja072905j Supporting Info

Base-Promoted Tautomerization of Imidazole Ligands to N-Heterocyclic Carbenes and Subsequent Transmetalation Reaction Javier Ruiz and Bernabé F. Perandones pp 9298–9299 DOI: 10.1021/ja073144n Supporting Info

Enantioselective Addition of Activated Terminal Alkynes to 1-Acylpyridinium Salts Catalyzed by Cu−Bis(oxazoline) Complexes Zhankui Sun, Shouyun Yu, Zuoding Ding, and Dawei Ma pp 9300–9301 DOI: 10.1021/ja0734849 Supporting Info

Rhodium-Catalyzed Enantioselective Desymmetrization of meso-3,5-Dimethyl Glutaric Anhydride:  A General Strategy to syn-Deoxypolypropionate Synthons Matthew J. Cook and Tomislav Rovis pp 9302–9303 DOI: 10.1021/ja073269s Supporting Info

A New Mechanism for Benzopyrone Formation in Aromatic Polyketide Biosynthesis Wenjun Zhang, Burkhardt I. Wilke, Jixun Zhan, Kenji Watanabe, Christopher N. Boddy, and Yi Tang pp 9304–9305 DOI: 10.1021/ja0736919 Supporting Info

Biosynthesis of Pentangular Polyphenols:  Deductions from the Benastatin and Griseorhodin Pathways Gerald Lackner, Angéla Schenk, Zhongli Xu, Kathrin Reinhardt, Zeynep S. Yunt, Jörn Piel, and Christian Hertweck pp 9306–9312 DOI: 10.1021/ja0718624

[1]Molybdarenophanes:  Strained Metallarenophanes with Aluminum, Gallium, and Silicon in Bridging Positions Clinton L. Lund, Jörg A. Schachner, J. Wilson Quail, and Jens Müller pp 9313–9320 DOI: 10.1021/ja072747w Supporting Info

Photosensitized Oxidative DNA Damage:  From Hole Injection to Chemical Product Formation and Strand Cleavage Byeong Hwa Yun, Young Ae Lee, Seog K. Kim, Vladimir Kuzmin, Alexander Kolbanovskiy, Peter C. Dedon, Nicholas E. Geacintov, and Vladimir Shafirovich pp 9321–9332 DOI: 10.1021/ja066954s Supporting Info

Toward Quantitative Prediction of Molecular Fluorescence Quantum Efficiency:  Role of Duschinsky Rotation Qian Peng, Yuanping Yi, Zhigang Shuai, and Jiushu Shao pp 9333–9339 DOI: 10.1021/ja067946e Supporting Info

Structural Characterization and Biological Evaluation of Small Interfering RNAs Containing Cyclohexenyl Nucleosides Koen Nauwelaerts, Michael Fisher, Matheus Froeyen, Eveline Lescrinier, Arthur Van Aerschot, Dong Xu, Robert DeLong, Hyumin Kang, Rudolph L. Juliano, and Piet Herdewijn pp 9340–9348 DOI: 10.1021/ja067047q Supporting Info

Dendron Arrays for the Force-Based Detection of DNA Hybridization Events Yu Jin Jung, Bong Jin Hong, Wenke Zhang, Saul J. B. Tendler, Philip M. Williams, Stephanie Allen, and Joon Won Park pp 9349–9355 DOI: 10.1021/ja0676105 Supporting Info

Experimental Electron Density of the Complex Carbides Sc3[Fe(C2)2] and Sc3[Co(C2)2] Benjamin Rohrmoser, Georg Eickerling, Manuel Presnitz, Wolfgang Scherer, Volker Eyert, Rolf-Dieter Hoffmann, Ute Ch. Rodewald, Christian Vogt, and Rainer Pöttgen pp 9356–9365 DOI: 10.1021/ja068137y Supporting Info

Hydroxy-Terminated Organic Semiconductor-Based Field-Effect Transistors for Phosphonate Vapor Detection Jia Huang, Joseph Miragliotta, Alan Becknell, and Howard E. Katz pp 9366–9376 DOI: 10.1021/ja068964z

Limits on Variations in Protein Backbone Dynamics from Precise Measurements of Scalar Couplings Beat Vögeli, Jinfa Ying, Alexander Grishaev, and Ad Bax pp 9377–9385 DOI: 10.1021/ja070324o Supporting Info

Fatty Acid Chemistry at the Oil−Water Interface:  Self-Propelled Oil Droplets Martin M. Hanczyc, Taro Toyota, Takashi Ikegami, Norman Packard, and Tadashi Sugawara pp 9386–9391 DOI: 10.1021/ja0706955 Supporting Info

Effective Modulation of DNA Duplex Stability by Reversible Transition Metal Complex Formation in the Minor Groove Marcin Kalek, Andreas S. Madsen, and Jesper Wengel pp 9392–9400 DOI: 10.1021/ja071076z Supporting Info

Preparation of Nanocomposites of Metals, Metal Oxides, and Carbon Nanotubes via Self-Assembly Jing Li, Songbai Tang, Li Lu, and Hua Chun Zeng pp 9401–9409 DOI: 10.1021/ja071122v Supporting Info

Polyfunctional Inorganic−Organic Hybrid Materials:  An Unusual Kind of NLO Active Layered Mixed Metal Oxalates with Tunable Magnetic Properties and Very Large Second Harmonic Generation Elena Cariati, Roberto Macchi, Dominique Roberto, Renato Ugo, Simona Galli, Nicola Casati, Piero Macchi, Angelo Sironi, Lapo Bogani, Andrea Caneschi, and Dante Gatteschi pp 9410–9420 DOI: 10.1021/ja0710712 Supporting Info

Modified Active Site Coordination in a Clinical Mutant of Sulfite Oxidase Christian J. Doonan, Heather L. Wilson, K. V. Rajagopalan, Robert M. Garrett, Brian Bennett, Roger C. Prince, and Graham N. George pp 9421–9428 DOI: 10.1021/ja071402a Supporting Info

Fluorescence, XPS, and TOF-SIMS Surface Chemical State Image Analysis of DNA Microarrays Chi-Ying Lee, Gregory M. Harbers, David W. Grainger, Lara J. Gamble, and David G. Castner pp 9429–9438 DOI: 10.1021/ja071879m Supporting Info

Photochromic Dibenzobarrlenes:  Long-Lived Triplet Biradical Intermediates Meledathu C. Sajimon, Danaboyina Ramaiah, Cherumuttathu H. Suresh, Waldemar Adam, Frederick D. Lewis, and Manapurathu V. George pp 9439–9445 DOI: 10.1021/ja0719125 Supporting Info

Depth Profiling of Water Molecules at the Liquid−Liquid Interface Using a Combined Surface Vibrational Spectroscopy and Molecular Dynamics Approach Dave S. Walker and Geraldine L. Richmond pp 9446–9451 DOI: 10.1021/ja071740b Supporting Info

Liquid Crystal Behavior of Single-Walled Carbon Nanotubes Dispersed in Biological Hyaluronic Acid Solutions Simon E. Moulton, Maryse Maugey, Philippe Poulin, and Gordon G. Wallace pp 9452–9457 DOI: 10.1021/ja072160h Supporting Info

Serine versus Threonine Glycosylation:  The Methyl Group Causes a Drastic Alteration on the Carbohydrate Orientation and on the Surrounding Water Shell Francisco Corzana, Jesús H. Busto, Gonzalo Jiménez-Osés, Marisa García de Luis, Juan L. Asensio, Jesús Jiménez-Barbero, Jesús M. Peregrina, and Alberto Avenoza pp 9458–9467 DOI: 10.1021/ja072181b Supporting Info

Modulation of Heme Redox Potential in the Cytochrome c6 Family Jonathan A. R. Worrall, Beatrix G. Schlarb-Ridley, Torsten Reda, Maria J. Marcaida, Robert J. Moorlen, Juergen Wastl, Judy Hirst, Derek S. Bendall, Ben F. Luisi, and Christopher J. Howe pp 9468–9475 DOI: 10.1021/ja072346g Supporting Info

Principle and Mechanism of Direct Porphyrin Metalation:  Joint Experimental and Theoretical Investigation Tatyana E. Shubina, Hubertus Marbach, Ken Flechtner, Andreas Kretschmann, Norbert Jux, Florian Buchner, Hans-Peter Steinrück, Timothy Clark, and J. Michael Gottfried pp 9476–9483 DOI: 10.1021/ja072360t Supporting Info

“Switching On” the Properties of Single-Molecule Magnetism in Triangular Manganese(III) Complexes Theocharis C. Stamatatos, Dolos Foguet-Albiol, Sheng-Chiang Lee, Constantinos C. Stoumpos, Catherine P. Raptopoulou, Aris Terzis, Wolfgang Wernsdorfer, Stephen O. Hill, Spyros P. Perlepes, and George Christou pp 9484–9499 DOI: 10.1021/ja072194p Supporting Info

Surface Ligand Dynamics in Growth of Nanocrystals Narayan Pradhan, Danielle Reifsnyder, Renguo Xie, Jose Aldana, and Xiaogang Peng pp 9500–9509 DOI: 10.1021/ja0725089 Supporting Info

IR Spectroscopic Observation of Molecular Transport through Pt@CoO Yolk−Shell Nanostructures Sunhee Kim, Yadong Yin, A. Paul Alivisatos, Gabor A. Somorjai, and John T. Yates, Jr. pp 9510–9513 DOI: 10.1021/ja072588g

Separating Degenerate 1H Transitions in Methyl Group Probes for Single-Quantum 1H-CPMG Relaxation Dispersion NMR Spectroscopy Vitali Tugarinov and Lewis E. Kay pp 9514–9521 DOI: 10.1021/ja0726456

Synthesis of Highly Ordered Mesoporous Crystalline WS2 and MoS2 via a High-Temperature Reductive Sulfuration Route Yifeng Shi, Ying Wan, Ruili Liu, Bo Tu, and Dongyuan Zhao pp 9522–9531 DOI: 10.1021/ja072910n Supporting Info

Organic Azide Inhibitors of Cysteine Proteases [J. Am. Chem. Soc. 2006, 128, 12396−12397]. Giang Thanh Le, Giovanni Abbenante, Praveen K. Madala, Huy N. Hoang, and David P. Fairlie p 9532 DOI: 10.1021/ja076897i

Issue 31

Enantioselective Route to Platensimycin:  An Intramolecular Robinson Annulation Approach Pingfan Li, Joshua N. Payette, and Hisashi Yamamoto pp 9534–9535 DOI: 10.1021/ja073547n Supporting Info

Regioselective and Asymmetric Diels−Alder Reaction of 1- and 2-Substituted Cyclopentadienes Catalyzed by a Brønsted Acid Activated Chiral Oxazaborolidine Joshua N. Payette and Hisashi Yamamoto pp 9536–9537 DOI: 10.1021/ja0735958 Supporting Info

Mechanistic Study of Competitive sp3-sp3 and sp2-sp3 Carbon−Carbon Reductive Elimination from a Platinum (IV) Center and the Isolation of a C−C Agostic Complex Brian L. Madison, Summer B. Thyme, Sarra Keene, and B. Scott Williams pp 9538–9539 DOI: 10.1021/ja066195d Supporting Info

Heterogeneous Organic Base-Catalyzed Reactions Enhanced by Acid Supports Ken Motokura, Mizuki Tada, and Yasuhiro Iwasawa pp 9540–9541 DOI: 10.1021/ja0704333 Supporting Info

A Facile Procedure for Controlling Monomer Sequence Distribution in Radical Chain Polymerizations Sebastian Pfeifer and Jean-François Lutz pp 9542–9543 DOI: 10.1021/ja0717616 Supporting Info

A Hydrogen Clathrate Hydrate with Cyclohexanone:  Structure and Stability Timothy A. Strobel, Keith C. Hester, E. Dendy Sloan Jr., and Carolyn A. Koh pp 9544–9545 DOI: 10.1021/ja072074h Supporting Info

Creating Ordered Small-Scale Biologically-Based Rods through Force-Controlled Stamping Chao-Min Cheng and Philip R. LeDuc pp 9546–9547 DOI: 10.1021/ja072079e

O-Aryloxycarbonyl Hydroxamates:  New β-Lactamase Inhibitors That Cross-Link the Active Site Pauline N. Wyrembak, Kerim Babaoglu, Ryan B. Pelto, Brian K. Shoichet, and R. F. Pratt pp 9548–9549 DOI: 10.1021/ja072370u Supporting Info

Diesterase Activity and Substrate Binding in Purple Acid Phosphatases Robynn S. Cox, Gerhard Schenk, Nataša Mitić, Lawrence R. Gahan, and Alvan C. Hengge pp 9550–9551 DOI: 10.1021/ja072647q Supporting Info

Apatite-Coated Ag/AgBr/TiO2 Visible-Light Photocatalyst for Destruction of Bacteria Mohammad R. Elahifard, Sara Rahimnejad, Saeed Haghighi, and Mohammad R. Gholami pp 9552–9553 DOI: 10.1021/ja072492m

Ordered Iron Oxide Nanotube Arrays of Controlled Geometry and Tunable Magnetism by Atomic Layer Deposition Julien Bachmann, Jing Jing, Mato Knez, Sven Barth, Hao Shen, Sanjay Mathur, Ulrich Gösele, and Kornelius Nielsch pp 9554–9555 DOI: 10.1021/ja072465w Supporting Info

Formation of a β-Pyrimidine Nucleoside by a Free Pyrimidine Base and Ribose in a Plausible Prebiotic Reaction Heather D. Bean, Yinghong Sheng, James P. Collins, Frank A. L. Anet, Jerzy Leszczynski, and Nicholas V. Hud pp 9556–9557 DOI: 10.1021/ja072781a Supporting Info

NMR Localization of Protons in Critical Enzyme Hydrogen Bonds Shasad Sharif, Emily Fogle, Michael D. Toney, Gleb S. Denisov, Ilya G. Shenderovich, Gerd Buntkowsky, Peter M. Tolstoy, Monique Chan Huot, and Hans-Heinrich Limbach pp 9558–9559 DOI: 10.1021/ja0728223 Supporting Info

Pd2@Sn184-:  Fusion of Two Endohedral Stannaspherenes Zhong-Ming Sun, Hai Xiao, Jun Li, and Lai-Sheng Wang pp 9560–9561 DOI: 10.1021/ja0728674 Supporting Info

Multiwall Boron Carbonitride/Carbon Nanotube Junction and Its Rectification Behavior Lei Liao, Kaihui Liu, Wenlong Wang, Xuedong Bai, Enge Wang, Yueli Liu, Jinchai Li, and Chang Liu pp 9562–9563 DOI: 10.1021/ja072861e Supporting Info

Molecular Basis of Cytochalasan Biosynthesis in Fungi:  Gene Cluster Analysis and Evidence for the Involvement of a PKS-NRPS Hybrid Synthase by RNA Silencing Julia Schümann and Christian Hertweck pp 9564–9565 DOI: 10.1021/ja072884t Supporting Info

Synthesis of P-Stereogenic Phosphorus Compounds. Asymmetric Oxidation of Phosphines under Appel Conditions Enda Bergin, Cormac T. O'Connor, Shane B. Robinson, Eoghan M. McGarrigle, Colm P. O'Mahony, and Declan G. Gilheany pp 9566–9567 DOI: 10.1021/ja072925l Supporting Info

New N-Heterocyclic Carbene Ligand and Its Application in Asymmetric Nickel-Catalyzed Aldehyde/Alkyne Reductive Couplings Mani Raj Chaulagain, Grant J. Sormunen, and John Montgomery pp 9568–9569 DOI: 10.1021/ja072992f Supporting Info

Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane Makoto Yamashita, Yuta Suzuki, Yasutomo Segawa, and Kyoko Nozaki pp 9570–9571 DOI: 10.1021/ja073037t Supporting Info

Light-Triggered Molecule-Scale Drug Dosing Devices Colin P. McCoy, Clare Rooney, Christopher R. Edwards, David S. Jones, and Sean P. Gorman pp 9572–9573 DOI: 10.1021/ja073053q Supporting Info

New Type of Membrane Material for Water Desalination Based on a Cross-Linked Bicontinuous Cubic Lyotropic Liquid Crystal Assembly Meijuan Zhou, Parag R. Nemade, Xiaoyun Lu, Xiaohui Zeng, Evan S. Hatakeyama, Richard D. Noble, and Douglas L. Gin pp 9574–9575 DOI: 10.1021/ja073067w Supporting Info

Simple Vapor-Phase Synthesis of Single-Crystalline Ag Nanowires and Single-Nanowire Surface-Enhanced Raman Scattering Paritosh Mohanty, Ilsun Yoon, Taejoon Kang, Kwanyong Seo, Kumar S. K. Varadwaj, Wonjun Choi, Q-Han Park, Jae Pyung Ahn, Yung Doug Suh, Hyotcherl Ihee, and Bongsoo Kim pp 9576–9577 DOI: 10.1021/ja073050d Supporting Info

The Triangular Cylinder Phase:  A New Mode of Self-Assembly in Liquid-Crystalline Soft Matter Feng Liu, Bin Chen, Ute Baumeister, Xiangbing Zeng, Goran Ungar, and Carsten Tschierske pp 9578–9579 DOI: 10.1021/ja073079h Supporting Info

Trapping and Structural Elucidation of an Intermediate in the Macrophomate Synthase Reaction Pathway Jörg M. Serafimov, Thomas Westfeld, Beat H. Meier, and Donald Hilvert pp 9580–9581 DOI: 10.1021/ja073087y Supporting Info

New Insight into the Mechanism of Action of and Resistance to Isoniazid:  Interaction of Mycobacterium tuberculosis enoyl-ACP Reductase with INH-NADP Argyrides Argyrou, Matthew W. Vetting, and John S. Blanchard pp 9582–9583 DOI: 10.1021/ja073160k Supporting Info

DNA-Induced Programmable Fusion of Phospholipid Vesicles Gudrun Stengel, Raphael Zahn, and Fredrik Höök pp 9584–9585 DOI: 10.1021/ja073200k Supporting Info

A Linear Lignin Analogue:  Phenolic Alternating Copolymers from Naturally Occurring β-Methylstyrene via Aqueous-Controlled Cationic Copolymerization Kotaro Satoh, Shoichi Saitoh, and Masami Kamigaito pp 9586–9587 DOI: 10.1021/ja0732227 Supporting Info

Lanthanum Aryloxide/Pybox-Catalyzed Direct Asymmetric Mannich-Type Reactions Using a Trichloromethyl Ketone as a Propionate Equivalent Donor Hiroyuki Morimoto, Gang Lu, Naohiro Aoyama, Shigeki Matsunaga, and Masakatsu Shibasaki pp 9588–9589 DOI: 10.1021/ja073285p Supporting Info

Photolysis of the HNO Adduct of Myoglobin:  Transient Generation of the Aminoxyl Radical Dmitry Pervitsky, Chad Immoos, Wytze van der Veer, and Patrick J. Farmer pp 9590–9591 DOI: 10.1021/ja073420y Supporting Info

Extensive Isomerization of Alkenes Using a Bifunctional Catalyst:  An Alkene Zipper Douglas B. Grotjahn, Casey R. Larsen, Jeffery L. Gustafson, Reji Nair, and Abhinandini Sharma pp 9592–9593 DOI: 10.1021/ja073457i Supporting Info

A Functional Proteomic Strategy to Discover Inhibitors for Uncharacterized Hydrolases Weiwei Li, Jacqueline L. Blankman, and Benjamin F. Cravatt pp 9594–9595 DOI: 10.1021/ja073650c Supporting Info

Design of All-Inorganic Molecular-Based Photocatalysts Sensitive to Visible Light:  Ti(IV)−O−Ce(III) Bimetallic Assemblies on Mesoporous Silica Ryuhei Nakamura, Akihiro Okamoto, Hitoshi Osawa, Hiroshi Irie, and Kazuhito Hashimoto pp 9596–9597 DOI: 10.1021/ja073668n Supporting Info

Is Dissociation of Peptide Radical Cations an Ergodic Process? Julia Laskin, Jean H. Futrell, and Ivan K. Chu pp 9598–9599 DOI: 10.1021/ja073748r Supporting Info

Spectroscopic Identification of C2P and C2As, Two New Main Group Dicarbides Fumie X. Sunahori, Jie Wei, and Dennis J. Clouthier pp 9600–9601 DOI: 10.1021/ja0738475

Alkyl−Alkyl Suzuki Cross-Couplings of Unactivated Secondary Alkyl Halides at Room Temperature Bunnai Saito and Gregory C. Fu pp 9602–9603 DOI: 10.1021/ja074008l Supporting Info

Chemical Reduction of Metal−Organic Framework Materials as a Method to Enhance Gas Uptake and Binding Karen L. Mulfort and Joseph T. Hupp pp 9604–9605 DOI: 10.1021/ja0740364 Supporting Info

Aluminum-Catalyzed Enantio- and Diastereoselective Carbonyl Addition of Propargylsilanes. A New Approach to Enantioenriched Vinyl Epoxides David A. Evans and Yimon Aye pp 9606–9607 DOI: 10.1021/ja0740420 Supporting Info

Membrane-Bound Water is Energetically Decoupled from Nearby Bulk Water:  An Ultrafast Surface-Specific Investigation Avishek Ghosh, Marc Smits, Jens Bredenbeck, and Mischa Bonn pp 9608–9609 DOI: 10.1021/ja073130h Supporting Info

Observing Single Nanoparticle Collisions at an Ultramicroelectrode by Electrocatalytic Amplification Xiaoyin Xiao and Allen J. Bard pp 9610–9612 DOI: 10.1021/ja072344w Supporting Info

Fragment-Based Substrate Activity Screening Method for the Identification of Potent Inhibitors of the Mycobacterium tuberculosis Phosphatase PtpB Matthew B. Soellner, Katherine A. Rawls, Christoph Grundner, Tom Alber, and Jonathan A. Ellman pp 9613–9615 DOI: 10.1021/ja0727520 Supporting Info

Tracking Electrons and Atoms in a Photoexcited Metalloporphyrin by X-ray Transient Absorption Spectroscopy Lin X. Chen, Xiaoyi Zhang, Erik C. Wasinger, Klaus Attenkofer, Guy Jennings, Ana Z. Muresan, and Jonathan S. Lindsey pp 9616–9618 DOI: 10.1021/ja072979v Supporting Info

Synthesis of Dendronized Diblock Copolymers via Ring-Opening Metathesis Polymerization and Their Visualization Using Atomic Force Microscopy Sridhar Rajaram, Tae-Lim Choi, Marco Rolandi, and Jean M. J. Fréchet pp 9619–9621 DOI: 10.1021/ja0741980 Supporting Info

Excited State Intervalence Transfer in a Rigid Polymeric Film Cavan N. Fleming, Dana M. Dattelbaum, David W. Thompson, Aleksei Yu. Ershov, and Thomas J. Meyer pp 9622–9630 DOI: 10.1021/ja068074j

C-2/C-3 Annulation and C-2 Alkylation of Indoles with 2-Alkoxycyclopropanoate Esters Barbora Bajtos, Ming Yu, Hongda Zhao, and Brian L. Pagenkopf pp 9631–9634 DOI: 10.1021/ja067821+ Supporting Info

Cluster Chemistry:  Size-Dependent Reactivity Induced by Reverse Spill-Over Martin A. Röttgen, Stephane Abbet, Ken Judai, Jean-Marie Antonietti, Anke S. Wörz, Matthias Arenz, Claude R. Henry, and Ulrich Heiz pp 9635–9639 DOI: 10.1021/ja068437f Supporting Info

Nanoscale Protein Pores Modified with PAMAM Dendrimers Hugh Martin, Helen Kinns, Nick Mitchell, Yann Astier, Rethi Madathil, and Stefan Howorka pp 9640–9649 DOI: 10.1021/ja0689029 Supporting Info

Characterization of a Distinct Arabinofuranosyltransferase in Mycobacterium smegmatis Jian Zhang, Kay-Hooi Khoo, Sz-Wei Wu, and Delphi Chatterjee pp 9650–9662 DOI: 10.1021/ja070330k Supporting Info

Possible Mechanism of Proton Transfer through Peptide Groups in the H-Pathway of the Bovine Cytochrome c Oxidase Katsumasa Kamiya, Mauro Boero, Masaru Tateno, Kenji Shiraishi, and Atsushi Oshiyama pp 9663–9673 DOI: 10.1021/ja070464y

Diffusion-Based Deprotection in Mesoporous Materials:  A Strategy for Differential Functionalization of Porous Silica Particles Kai Cheng and Christopher C. Landry pp 9674–9685 DOI: 10.1021/ja070598b Supporting Info

Oxygen Activation by Cytochrome P450:  A Thermodynamic Analysis Willem H. Koppenol pp 9686–9690 DOI: 10.1021/ja071546p

Molecular Engineering of Intensely Near-Infrared Absorbing Excited States in Highly Conjugated Oligo(porphinato)zinc−(Polypyridyl)metal(II) Supermolecules Timothy V. Duncan, Tomoya Ishizuka, and Michael J. Therien pp 9691–9703 DOI: 10.1021/ja0707512 Supporting Info

Sulfate as a Synergistic Anion Facilitating Iron Binding by the Bacterial Transferrin FbpA:  The Origins and Effects of Anion Promiscuity J. J. Heymann, K. D. Weaver, T. A. Mietzner, and A. L. Crumbliss pp 9704–9712 DOI: 10.1021/ja0709268 Supporting Info

Cation-Modulated Electron-Transfer Channel:  H-Atom Transfer vs Proton-Coupled Electron Transfer with a Variable Electron-Transfer Channel in Acylamide Units Xiaohua Chen and Yuxiang Bu pp 9713–9720 DOI: 10.1021/ja071194m Supporting Info

The Stereochemical Dependence of Unimolecular Dissociation of Monosaccharide-Glycolaldehyde Anions in the Gas Phase:  A Basis for Assignment of the Stereochemistry and Anomeric Configuration of Monosaccharides in Oligosaccharides by Mass Spectrometry via a Key Discriminatory Product Ion of Disaccharide Fragmentation, m/z 221 Tammy T. Fang and Brad Bendiak pp 9721–9736 DOI: 10.1021/ja0717313 Supporting Info

Designing Nanosensors Based on Charged Derivatives of Gramicidin A Ricardo Capone, Steven Blake, Marcela Rincon Restrepo, Jerry Yang, and Michael Mayer pp 9737–9745 DOI: 10.1021/ja0711819

One-Step Chemical Vapor Growth of Ge/SiCxNy Nanocables Sanjay Mathur, Hao Shen, Nicole Donia, Thomas Rügamer, Vladimir Sivakov, and Ulf Werner pp 9746–9752 DOI: 10.1021/ja071931e Supporting Info

Inverse Solvent Effects in Carbocation Carbanion Combination Reactions:  The Unique Behavior of Trifluoromethylsulfonyl Stabilized Carbanions Stefan T. A. Berger, Armin R. Ofial, and Herbert Mayr pp 9753–9761 DOI: 10.1021/ja072135b Supporting Info

A 10-Å Spectroscopic Ruler Applied to Short Polyprolines Harekrushna Sahoo, Danilo Roccatano, Andreas Hennig, and Werner M. Nau pp 9762–9772 DOI: 10.1021/ja072178s Supporting Info

Guest Recognition with Micelle-Bound Cavitands Michael P. Schramm, Richard J. Hooley, and Julius Rebek Jr. pp 9773–9779 DOI: 10.1021/ja0723378 Supporting Info

Spinodal Decomposition and Nucleation and Growth as a Means to Bulk Nanostructured Thermoelectrics:  Enhanced Performance in Pb1-xSnxTe−PbS John Androulakis, Chia-Her Lin, Hun-Jin Kong, Ctirad Uher, Chun-I Wu, Timothy Hogan, Bruce A. Cook, Thierry Caillat, Konstantinos M. Paraskevopoulos, and Mercouri G. Kanatzidis pp 9780–9788 DOI: 10.1021/ja071875h

Kinetic Isotope Effects for Alkaline Phosphatase Reactions:  Implications for the Role of Active-Site Metal Ions in Catalysis Jesse G. Zalatan, Irina Catrina, Rebecca Mitchell, Piotr K. Grzyska, Patrick J. O'Brien, Daniel Herschlag, and Alvan C. Hengge pp 9789–9798 DOI: 10.1021/ja072196+ Supporting Info

Mapping the Conformational Landscape of Urea-Denatured Ubiquitin Using Residual Dipolar Couplings Sebastian Meier, Stephan Grzesiek, and Martin Blackledge pp 9799–9807 DOI: 10.1021/ja0724339 Supporting Info

Inorganic Cluster Syntheses of TM2+-Doped Quantum Dots (CdSe, CdS, CdSe/CdS):  Physical Property Dependence on Dopant Locale Paul I. Archer, Steven A. Santangelo, and Daniel R. Gamelin pp 9808–9818 DOI: 10.1021/ja072436l Supporting Info

Influence of Supramolecular Organization on Energy Transfer Properties in Chiral Oligo(p-phenylene vinylene) Porphyrin Assemblies Freek J. M. Hoeben, Martin Wolffs, Jian Zhang, Steven De Feyter, Philippe Leclère, Albertus P. H. J. Schenning, and E. W. Meijer pp 9819–9828 DOI: 10.1021/ja072548c Supporting Info

Microwaves in Organic Synthesis, Completely Revised and Enlarged 2nd ed., Volumes 1−2 Edited by André Loupy (Université Paris-Sud, France). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. 1033 pp. $375.00. ISBN 3-527-31452-0. James J. Kiddle p 9829 DOI: 10.1021/ja076903a

Analytical Chemistry:  Theoretical and Metrological Fundamentals By K. Danzer (Jena, Germany). Springer:  Berlin, Heidelberg, New York. 2007. xxxii + 316 pp. $99.00. ISBN 978-3-540-35988-3. Mark R. Anderson pp 9829–9830 DOI: 10.1021/ja076923c

The Chemistry of Anilines, Parts 1−2. From the Patai Series:  The Chemistry of Functional Groups Volume and Series Edited by Zvi Rappoport (The Hebrew University, Jerusalem). John Wiley & Sons, Ltd.:  Chichester. 2007. 1180 pp. $945.00. ISBN 978- 0-470-87171-3. p 9830 DOI: 10.1021/ja0769548

Atomistic Approaches in Modern Biology:  From Quantum Chemistry to Molecular Simulations. Topics in Current Chemistry, Volume 268 Edited by Markus Reiher (ETH Zürich). Springer:  Berlin, Heidelberg, New York. 2007. xii + 362 pp. $329.00. ISBN 978-3-540-38082-5. Robert Q. Topper pp 9830–9831 DOI: 10.1021/ja076953f

Current Fluoroorganic Chemistry:  New Synthetic Directions, Technologies, Materials, and Biological Applications Edited by Vadim A. Soloshonok (The University of Oklahoma), Koichi Mikami (Tokyo Institute of Technology), Takashi Yamazaki (Tokyo University of Agriculture and Technology), John T. Welch (State University of New York at Albany), and John F. Honek (The University of Waterloo). American Chemical Society:  Washington, DC (distributed by Oxford University Press). 2007. xiv + 520 pp. $189.50. ISBN 0-8412-7403-7. p 9831 DOI: 10.1021/ja0769550

X-ray Absorption and EPR Spectroscopic Studies of the Biotransformations of Chromium(VI) in Mammalian Cells. Is Chromodulin an Artifact of Isolation Methods? [J. Am. Chem. Soc. 2007, 129, 1065−1075]. Aviva Levina, Hugh H. Harris, and Peter A. Lay p 9832 DOI: 10.1021/ja074677z

Issue 32

Bifunctional Anchors Connecting Carbon Nanotubes to Metal Electrodes for Improved Nanoelectronics Wei-Qiao Deng, Yuki Matsuda, and William A. Goddard III pp 9834–9835 DOI: 10.1021/ja061443r Supporting Info

Molecular Electron-Transfer Properties of Au38 Clusters Sabrina Antonello, Allan H. Holm, Emanuele Instuli, and Flavio Maran pp 9836–9837 DOI: 10.1021/ja071191+ Supporting Info

A DNAzyme Catalytic Beacon Sensor for Paramagnetic Cu2+ Ions in Aqueous Solution with High Sensitivity and Selectivity Juewen Liu and Yi Lu pp 9838–9839 DOI: 10.1021/ja0717358 Supporting Info

“Squaring the Circle”:  Molecular Squares and Rectangles from Chelate-Induced Structural Transformations of Known Fe10 and New Fe12 Ferric Wheels Theocharis C. Stamatatos, Alexander G. Christou, Candace M. Jones, Brian J. O'Callaghan, Khalil A. Abboud, Ted A. O'Brien, and George Christou pp 9840–9841 DOI: 10.1021/ja073236c Supporting Info

Synthesis and Nonvolatile Memory Behavior of Redox-Active Conjugated Polymer-Containing Ferrocene Tae-Lim Choi, Kwang-Hee Lee, Won-Jae Joo, Sangkyun Lee, Tae-Woo Lee, and Mi Young Chae pp 9842–9843 DOI: 10.1021/ja0717459 Supporting Info

Iron-Catalyzed Selective Biaryl Coupling:  Remarkable Suppression of Homocoupling by the Fluoride Anion Takuji Hatakeyama and Masaharu Nakamura pp 9844–9845 DOI: 10.1021/ja073084l Supporting Info

The Photoarrangement of α-Santonin is a Single-Crystal-to-Single-Crystal Reaction:  A Long Kept Secret in Solid-State Organic Chemistry Revealed Arunkumar Natarajan, C. K. Tsai, Saeed I. Khan, Patrick McCarren, K. N. Houk, and Miguel A. Garcia-Garibay pp 9846–9847 DOI: 10.1021/ja073189o Supporting Info

Molecular Wire Behavior in π-Stacked Donor-Bridge-Acceptor Tertiary Arylureas Tarek A. Zeidan, Qiang Wang, Torsten Fiebig, and Frederick D. Lewis pp 9848–9849 DOI: 10.1021/ja073219n Supporting Info

Microwave-Triggered Surface Plasmon Coupled Chemiluminescence Michael J. R. Previte and Chris D. Geddes pp 9850–9851 DOI: 10.1021/ja073029c Supporting Info

Surface Modification and Functionalization of Nanoscale Metal-Organic Frameworks for Controlled Release and Luminescence Sensing William J. Rieter, Kathryn M. L. Taylor, and Wenbin Lin pp 9852–9853 DOI: 10.1021/ja073506r Supporting Info

Anti-Polarity in Ideal BiMnO3 Pio Baettig, Ram Seshadri, and Nicola A. Spaldin pp 9854–9855 DOI: 10.1021/ja073415u

Array-Based Sensing of Proteins Using Conjugated Polymers Oscar R. Miranda, Chang-Cheng You, Ronnie Phillips, Ik-Bum Kim, Partha S. Ghosh, Uwe H. F. Bunz, and Vincent M. Rotello pp 9856–9857 DOI: 10.1021/ja0737927 Supporting Info

The Ru(cod)(cot)-Catalyzed Alkenylation of Aromatic C−H Bonds with Alkenyl Acetates Yusuke Matsuura, Masaru Tamura, Takuya Kochi, Mitsuo Sato, Naoto Chatani, and Fumitoshi Kakiuchi pp 9858–9859 DOI: 10.1021/ja071965m Supporting Info

Total Synthesis, Stereochemical Reassignment, and Absolute Configuration of Chlorofusin Sang Yeul Lee, Ryan C. Clark, and Dale L. Boger pp 9860–9861 DOI: 10.1021/ja073264v Supporting Info

Total Synthesis of Methyl Sarcophytoate Takahiro Ichige, Yusuke Okano, Naoki Kanoh, and Masaya Nakata pp 9862–9863 DOI: 10.1021/ja073952e Supporting Info

Shape, Size, and Assembly Control of PbTe Nanocrystals Taleb Mokari, Minjuan Zhang, and Peidong Yang pp 9864–9865 DOI: 10.1021/ja074145i Supporting Info

Stereocontrolled Synthesis of Dafachronic Acid A, the Ligand for the DAF-12 Nuclear Receptor of Caenorhabditis elegans Simon Giroux and E. J. Corey pp 9866–9867 DOI: 10.1021/ja074306i Supporting Info

Mechanistically Diverse Copper-, Silver-, and Gold-Catalyzed Acyloxy and Phosphatyloxy Migrations:  Efficient Synthesis of Heterocycles via Cascade Migration/Cycloisomerization Approach Todd Schwier, Anna W. Sromek, Dahrika M. L. Yap, Dmitri Chernyak, and Vladimir Gevorgyan pp 9868–9878 DOI: 10.1021/ja072446m Supporting Info

Two Methods for Direct ortho-Arylation of Benzoic Acids Hendrich A. Chiong, Quynh-Nhu Pham, and Olafs Daugulis pp 9879–9884 DOI: 10.1021/ja071845e Supporting Info

Synthesis of the Docosanasaccharide Arabinan Domain of Mycobacterial Arabinogalactan and a Proposed Octadecasaccharide Biosynthetic Precursor Maju Joe, Yu Bai, Ruel C. Nacario, and Todd L. Lowary pp 9885–9901 DOI: 10.1021/ja072892+ Supporting Info

Field-Induced Ferrimagnetic State in a Molecule-Based Magnet Consisting of a CoII Ion and a Chiral Triplet Bis(nitroxide) Radical Youhei Numata, Katsuya Inoue, Nikolai Baranov, Mohamedally Kurmoo, and Koichi Kikuchi pp 9902–9909 DOI: 10.1021/ja064828i Supporting Info

Gas-Phase Ionic Syntheses of Amino Acids:  β versus α Jamie L. Snow, Galina Orlova, Voislav Blagojevic, and Diethard K. Bohme pp 9910–9917 DOI: 10.1021/ja068725b Supporting Info

Rapidly in Situ Forming Biodegradable Robust Hydrogels by Combining Stereocomplexation and Photopolymerization Christine Hiemstra, Wei Zhou, Zhiyuan Zhong, Mariëlle Wouters, and Jan Feijen pp 9918–9926 DOI: 10.1021/ja072113p

How Can a Single Second Sphere Amino Acid Substitution Cause Reduction Midpoint Potential Changes of Hundreds of Millivolts? Emine Yikilmaz, Jason Porta, Laurie E. Grove, Ardeschir Vahedi-Faridi, Yuriy Bronshteyn, Thomas C. Brunold, Gloria E. O. Borgstahl, and Anne-Frances Miller pp 9927–9940 DOI: 10.1021/ja069224t Supporting Info

Liquid−Crystalline Janus-Type Fullerodendrimers Displaying Tunable Smectic−Columnar Mesomorphism Julie Lenoble, Stéphane Campidelli, Natacha Maringa, Bertrand Donnio, Daniel Guillon, Natalia Yevlampieva, and Robert Deschenaux pp 9941–9952 DOI: 10.1021/ja071012o Supporting Info

Adiabatic and Non-adiabatic Concerted Proton−Electron Transfers. Temperature Effects in the Oxidation of Intramolecularly Hydrogen-Bonded Phenols Cyrille Costentin, Marc Robert, and Jean-Michel Savéant pp 9953–9963 DOI: 10.1021/ja071150d Supporting Info

(+)-Saxitoxin:  A First and Second Generation Stereoselective Synthesis James J. Fleming, Matthew D. McReynolds, and J. Du Bois pp 9964–9975 DOI: 10.1021/ja071501o Supporting Info

A Direct Dynamics Trajectory Study of F- + CH3OOH Reactive Collisions Reveals a Major Non-IRC Reaction Path José G. López, Grigoriy Vayner, Upakarasamy Lourderaj, Srirangam V. Addepalli, Shuji Kato, Wibe A. deJong, Theresa L. Windus, and William L. Hase pp 9976–9985 DOI: 10.1021/ja0717360 Supporting Info

Two-Photon Uncaging with Fluorescence Reporting:  Evaluation of the o-Hydroxycinnamic Platform Nathalie Gagey, Pierre Neveu, Chouaha Benbrahim, Bernard Goetz, Isabelle Aujard, Jean-Bernard Baudin, and Ludovic Jullien pp 9986–9998 DOI: 10.1021/ja0722022 Supporting Info

Poly(vinylpyrrolidone)-Modified Graphite Carbon Nanofibers as Promising Supports for PtRu Catalysts in Direct Methanol Fuel Cells Yu Lin Hsin, Kuo Chu Hwang, and Chuin-Tih Yeh pp 9999–10010 DOI: 10.1021/ja072367a Supporting Info

Interplay between Size and Electronic Effects in Determining the Homogeneity Range of the A9Zn4+xPn9 and A9Cd4+xPn9 Phases (0 ≤ x ≤ 0.5), A = Ca, Sr, Yb, Eu; Pn = Sb, Bi Sheng-qing Xia and Svilen Bobev pp 10011–10018 DOI: 10.1021/ja0728425 Supporting Info

Tracking “Invisible” Alkylchlorocarbenes by Their σ → p Absorptions:  Dynamics and Solvent Interactions Robert A. Moss, Jingzhi Tian, Ronald R. Sauers, and Karsten Krogh-Jespersen pp 10019–10028 DOI: 10.1021/ja071799i Supporting Info

Enantioselective Friedel−Crafts Alkylations Catalyzed by Bis(oxazolinyl)pyridine−Scandium(III) Triflate Complexes David A. Evans, Keith R. Fandrick, Hyun-Ji Song, Karl A. Scheidt, and Risheng Xu pp 10029–10041 DOI: 10.1021/ja072976i Supporting Info

Chemoinformatics:  Theory, Practice, and Products By Barry A. Bunin (Collaborative Drug Discovery, San Mateo, CA), Jürgen Bajorath (Reinische Friedrich- Wilhelms-Universität, Bonn, Germany), Brian Siesel (Merrill Lynch & Co., San Francisco, CA), and Guillermo A. Morales (Telik Inc., Palo Alto, CA). Springer:  Dordrecht. 2007. $129.00. xii + 296 pp. ISBN 978-1-4020-5000-8. p 10042 DOI: 10.1021/ja0769595

Ionic Liquids in Organic Synthesis. ACS Symposium Series 950 Edited by Sanjay V. Malhotra (New Jersey Institute of Technology, Newark, NJ). American Chemical Society:  Washington, DC (distributed by Oxford University Press). xiv + 306 pp. $184.50. ISBN 0-8412-7407-X. p 10042 DOI: 10.1021/ja0769651

Structure-Based Drug Discovery Edited by Harren Jhoti (Astex Therapeutics, Cambridge, U.K.) and Andrew R. Leach (GlaxoSmithKline, Stevenage, U.K.). Springer:  Dordrecht. 2007. xii + 250 pp. $169.00. ISBN 978-1-4020-4406-9. Robert Powers pp 10042–10043 DOI: 10.1021/ja076951v

Columns for Gas Chromatography:  Performance and Selection By Eugene F. Barry (University of Massachusetts Lowell) and Robert L. Grob (Villanova University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xiv + 298 pp. ISBN 978-0-471-74043-8. p 10043 DOI: 10.1021/ja076958c

Catalysis from A to Z:  A Concise Encyclopedia, Volumes 1−3, Completely Revised and Enlarged 3rd ed Edited by Boy Cornils (Hofheim, Germany), Wolfgang A. Herrmann (Technische Universität München, Germany), Martin Muhler (Ruhr-Universität, Bochum, Germany), and Chi-Huey Wong (Scripps Research Institute, La Jolla, CA). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. 1560 pp. $560.00. ISBN 978-3-527-31438-6. p 10043 DOI: 10.1021/ja076972p

Activation of Small Molecules:  Organometallic and Bioinorganic Perspectives Edited by William B. Tolman (University of Minnesota, Minneapolis). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xviii + 364 pp. $185.00. ISBN 3-527-31312-5. Alan F. Heyduk pp 10043–10044 DOI: 10.1021/ja076963g

Characterization II. From the series Molecular Sieves:  Science and Technology, Volume 5 Edited by Hellmut G. Karge (Fritz Haber Institute of the Max Planck Society, Berlin, Germany) and Jens Weitkamp (University of Stuttgart, Germany). Springer:  Berlin, Heidelberg, New York. 2007. x + 516 pp. $399.00. ISBN 978-3-540-30457-9. p 10044 DOI: 10.1021/ja076946r

Nanotechnology in Catalysis, Volume 3 Edited by Bing Zhou (Headwaters Nano Kinetix Inc., Lawrenceville, NJ), Scott Han (Rohm & Haas Company, Spring House, PA), Robert Raja (University of Southhampton, U.K.), and Gabor Somorjai (University of California at Berkeley). From the Series, Nano-structure Science and Technology. Series Edited by David J. Lockwood. Springer Science + Business Media, LLC:  New York. xxii + 334 pp. $129.00. ISBN 0-387-34687-2. p 10044 DOI: 10.1021/ja0769494

Issue 33

Force-Induced Globule-Coil Transition in Single Polystyrene Chains in Water Nikhil Gunari, Anna C. Balazs, and Gilbert C. Walker pp 10046–10047 DOI: 10.1021/ja068652w Supporting Info

A Self-Assembled Monolayers Assisted Solid-State Conversion of Boehmite Particles to Aluminum Oxide Film Naoko Sakuragi, Shintaro Yamamoto, and Yoshihiro Koide pp 10048–10049 DOI: 10.1021/ja068981o Supporting Info

Employing an Amphipathic Viral Peptide to Create a Lipid Bilayer on Au and TiO2 Nam-Joon Cho, Sang-Joon Cho, Kwang Ho Cheong, Jeffrey S. Glenn, and Curtis W. Frank pp 10050–10051 DOI: 10.1021/ja0701412 Supporting Info

Reaction-Path Selection with Molecular Orientation of CH3Cl on Si{100} Michio Okada, Seishiro Goto, and Toshio Kasai pp 10052–10053 DOI: 10.1021/ja070931b

Design of Axially Chiral Dicarboxylic Acid for Asymmetric Mannich Reaction of Arylaldehyde N-Boc Imines and Diazo Compounds Takuya Hashimoto and Keiji Maruoka pp 10054–10055 DOI: 10.1021/ja0713375 Supporting Info

Phase-Sensitive Sum-Frequency Vibrational Spectroscopy and Its Application to Studies of Interfacial Alkyl Chains Na Ji, Victor Ostroverkhov, Chao-Yuan Chen, and Yuen-Ron Shen pp 10056–10057 DOI: 10.1021/ja071989t Supporting Info

Modulation of the Supramolecular Structure of G-Quartet Assemblies by Dynamic Covalent Decoration Eric Buhler, Nampally Sreenivasachary, Sauveur-Jean Candau, and Jean-Marie Lehn pp 10058–10059 DOI: 10.1021/ja072109d

A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-vinylcyclopropanes and CO for the Synthesis of Cyclooctenones Yuanyuan Wang, Jingxin Wang, Jiachun Su, Feng Huang, Lei Jiao, Yong Liang, Dazhi Yang, Shiwei Zhang, Paul A. Wender, and Zhi-Xiang Yu pp 10060–10061 DOI: 10.1021/ja072505w Supporting Info

Efficient Incorporation of Polar Comonomers in Copolymerizations with Ethylene Using a Cyclophane-Based Pd(II) α-Diimine Catalyst Christopher S. Popeney, Drexel H. Camacho, and Zhibin Guan pp 10062–10063 DOI: 10.1021/ja072502j Supporting Info

Native Chemical Ligation at Phenylalanine David Crich and Abhisek Banerjee pp 10064–10065 DOI: 10.1021/ja072804l Supporting Info

Chiral Polyoxometalate-Induced Enantiomerically 3D Architectures:  A New Route for Synthesis of High-Dimensional Chiral Compounds Huaqiao Tan, Yangguang Li, Zhiming Zhang, Chao Qin, Xinlong Wang, Enbo Wang, and Zhongmin Su pp 10066–10067 DOI: 10.1021/ja073153w Supporting Info

Synthesis of Bi2Te3 Nanotubes by Galvanic Displacement Feng Xiao, Bongyoung Yoo, Kyu Hwan Lee, and Nosang V. Myung pp 10068–10069 DOI: 10.1021/ja073032w Supporting Info

Guest-Mediated Access to a Single DNA Nanostructure from a Library of Multiple Assemblies Faisal A. Aldaye and Hanadi F. Sleiman pp 10070–10071 DOI: 10.1021/ja073305n Supporting Info

Nanoparticle Synthesis via the Photochemical Polythiol Process Scott C. Warren, Aaron C. Jackson, Zachary D. Cater-Cyker, Francis J. DiSalvo, and Ulrich Wiesner pp 10072–10073 DOI: 10.1021/ja0733639 Supporting Info

A Coordination Chemistry Approach to a Multieffector Enzyme Mimic Junpei Kuwabara, Charlotte L. Stern, and Chad A. Mirkin pp 10074–10075 DOI: 10.1021/ja073447h Supporting Info

Bottom up Synthesis That Does Not Start at the Bottom:  Quadruple Covalent Cross-Linking of Nanoscale Faceted Polyhedra John J. Perry IV, Victor Ch. Kravtsov, Gregory J. McManus, and Michael J. Zaworotko pp 10076–10077 DOI: 10.1021/ja0734952 Supporting Info

Creating Quaternary Centers with High Exo Stereoselectivity Using Activated α-Alkynyl Dienophiles Sun-Joon Min, Gavin O. Jones, K. N. Houk, and Samuel J. Danishefsky pp 10078–10079 DOI: 10.1021/ja073528d Supporting Info

Photophysics of meso-β Doubly Linked Ni(II) Porphyrin Arrays:  Large Two-Photon Absorption Cross-Section and Fast Energy Relaxation Dynamics Min-Chul Yoon, Su Bum Noh, Akihiko Tsuda, Yasuyuki Nakamura, Atsuhiro Osuka, and Dongho Kim pp 10080–10081 DOI: 10.1021/ja0735655 Supporting Info

Kinetic Analysis of Teicoplanin Glycosyltransferases and Acyltransferase Reveal Ordered Tailoring of Aglycone Scaffold to Reconstitute Mature Teicoplanin Annaleise R. Howard-Jones, Ryan G. Kruger, Wei Lu, Junhua Tao, Catherine Leimkuhler, Daniel Kahne, and Christopher T. Walsh pp 10082–10083 DOI: 10.1021/ja0735857 Supporting Info

The Meta-Green Fluorescent Protein Chromophore Jian Dong, Kyril M. Solntsev, Olivier Poizat, and Laren M. Tolbert pp 10084–10085 DOI: 10.1021/ja073622u Supporting Info

Well-Defined Vinyl Ketone-Based Polymers by Reversible Addition−Fragmentation Chain Transfer Polymerization Chong Cheng, Guorong Sun, Ezat Khoshdel, and Karen L. Wooley pp 10086–10087 DOI: 10.1021/ja073541y Supporting Info

Large Area-Aligned Arrays from Direct Deposition of Single-Wall Carbon Nanotube Inks Trevor J. Simmons, Daniel Hashim, Robert Vajtai, and Pulickel M. Ajayan pp 10088–10089 DOI: 10.1021/ja073745e Supporting Info

Pressure Enhancement of Negative Thermal Expansion Behavior and Induced Framework Softening in Zinc Cyanide Karena W. Chapman and Peter J. Chupas pp 10090–10091 DOI: 10.1021/ja073791e Supporting Info

Observation of a Rectangular DNA Superlattice in the Liquid-Crystalline Phase of Cationic Lipid/DNA Complexes Giulio Caracciolo, Daniela Pozzi, Ruggero Caminiti, Giovanna Mancini, Paola Luciani, and Heinz Amenitsch pp 10092–10093 DOI: 10.1021/ja073890s

Metal−Halide Bond Photoactivation from a PtIII−AuII Complex Timothy R. Cook, Arthur J. Esswein, and Daniel G. Nocera pp 10094–10095 DOI: 10.1021/ja073908z Supporting Info

Direct Synthesis of Pyridine Derivatives Mohammad Movassaghi, Matthew D. Hill, and Omar K. Ahmad pp 10096–10097 DOI: 10.1021/ja073912a Supporting Info

Enantioselective Synthesis of α,α-Disubstituted Cyclopentenes by an N-Heterocyclic Carbene-Catalyzed Desymmetrization of 1,3-Diketones Manabu Wadamoto, Eric M. Phillips, Troy E. Reynolds, and Karl A. Scheidt pp 10098–10099 DOI: 10.1021/ja073987e Supporting Info

Structure and Reactivity of the β-Agostic [ansa-Cp-arene]Ta(nPr) Cation:  Ambivalent Behavior Induced by Intramolecular Arene Coordination Edwin Otten, Auke Meetsma, and Bart Hessen pp 10100–10101 DOI: 10.1021/ja073956j Supporting Info

Organolanthanide-Catalyzed Synthesis of Amine-Capped Polyethylenes Smruti B. Amin and Tobin J. Marks pp 10102–10103 DOI: 10.1021/ja0740465 Supporting Info

Synthesis of Aligned Single-Walled Nanotubes Using Catalysts Defined by Nanosphere Lithography Koungmin Ryu, Alexander Badmaev, Lewis Gomez, Fumiaki Ishikawa, Bo Lei, and Chongwu Zhou pp 10104–10105 DOI: 10.1021/ja074078s Supporting Info

Observation of the Coexistence of Sodium and Calcium Ions in a DNA G-Quadruplex Ion Channel Michael P. H. Lee, Gary N. Parkinson, Pascale Hazel, and Stephen Neidle pp 10106–10107 DOI: 10.1021/ja0740869 Supporting Info

Rapid Transfer of Hydride Ion from a Ruthenium Complex to C1 Species in Water Carol Creutz and Mei H. Chou pp 10108–10109 DOI: 10.1021/ja074158w Supporting Info

Supercharging Proteins Can Impart Unusual Resilience Michael S. Lawrence, Kevin J. Phillips, and David R. Liu pp 10110–10112 DOI: 10.1021/ja071641y Supporting Info

Benzylic Cations with Triplet Ground States:  Computational Studies of Aryl Carbenium Ions, Silylenium Ions, Nitrenium Ions, and Oxenium Ions Substituted with Meta π Donors Arthur H. Winter, Daniel E. Falvey, Christopher J. Cramer, and Benjamin F. Gherman pp 10113–10119 DOI: 10.1021/ja070143m Supporting Info

Preferential Oxidation of Carbon Monoxide Catalyzed by Platinum Nanoparticles in Mesoporous Silica Atsushi Fukuoka, Jun-ichi Kimura, Tadashi Oshio, Yuzuru Sakamoto, and Masaru Ichikawa pp 10120–10125 DOI: 10.1021/ja0703123 Supporting Info

G Protein-Coupled Receptors Self-Assemble in Dynamics Simulations of Model Bilayers Xavier Periole, Thomas Huber, Siewert-Jan Marrink, and Thomas P. Sakmar pp 10126–10132 DOI: 10.1021/ja0706246 Supporting Info

Non-van der Waals Treatment of the Hydrophobic Solubilities of CF4 D. Asthagiri, H. S. Ashbaugh, A. Piryatinski, M. E. Paulaitis, and L. R. Pratt pp 10133–10140 DOI: 10.1021/ja071037n

Dissociation Reactions of Free Tetrapyridinium Tetracations and of Their Catenanes Jana Roithová, Petr Milko, Claire L. Ricketts, Detlef Schröder, Thierry Besson, Václav Dekoj, and Martin Bělohradský pp 10141–10148 DOI: 10.1021/ja071058h Supporting Info

Allosterically Regulated Supramolecular Catalysis of Acyl Transfer Reactions for Signal Amplification and Detection of Small Molecules Martin S. Masar III, Nathan C. Gianneschi, Christopher G. Oliveri, Charlotte L. Stern, SonBinh T. Nguyen, and Chad A. Mirkin pp 10149–10158 DOI: 10.1021/ja0711516 Supporting Info

Conformationally Constrained, Stable, Triplet Ground State (S = 1) Nitroxide Diradicals. Antiferromagnetic Chains of S = 1 Diradicals Andrzej Rajca, Masahiro Takahashi, Maren Pink, Gaëlle Spagnol, and Suchada Rajca pp 10159–10170 DOI: 10.1021/ja0712017 Supporting Info

Nitrate Adsorption and Reduction on Cu(100) in Acidic Solution Sang-Eun Bae, Karen L. Stewart, and Andrew A. Gewirth pp 10171–10180 DOI: 10.1021/ja071330n Supporting Info

Single-Molecule Study of the Inhibition of HIV-1 Transactivation Response Region DNA/DNA Annealing by Argininamide Christy F. Landes, Yining Zeng, Hsiao-Wei Liu, Karin Musier-Forsyth, and Paul F. Barbara pp 10181–10188 DOI: 10.1021/ja071491r Supporting Info

Superatom Compounds, Clusters, and Assemblies:  Ultra Alkali Motifs and Architectures Arthur C. Reber, Shiv N. Khanna, and A. Welford Castleman, Jr. pp 10189–10194 DOI: 10.1021/ja071647n

Differential Line Broadening in MAS Solid-State NMR due to Dynamic Interference Veniamin Chevelkov, Katja Faelber, Anna Schrey, Kristina Rehbein, Anne Diehl, and Bernd Reif pp 10195–10200 DOI: 10.1021/ja072024c Supporting Info

Hydrogen Spillover Mechanism on a Pd-Doped Mg Surface as Revealed by ab initio Density Functional Calculation A. J. Du, Sean C. Smith, X. D. Yao, and G. Q. Lu pp 10201–10204 DOI: 10.1021/ja0722776

Scaffold-Independent Analysis of RNA−Protein Interactions:  The Nova-1 KH3−RNA Complex Barbara Beuth, María Flor García-Mayoral, Ian A. Taylor, and Andres Ramos pp 10205–10210 DOI: 10.1021/ja072365q Supporting Info

Tetrahydro-1,8-naphthyridinol Analogues of α-Tocopherol as Antioxidants in Lipid Membranes and Low-Density Lipoproteins Tae-gyu Nam, Christopher L. Rector, Hye-young Kim, Andreas F.-P. Sonnen, Roland Meyer, Werner M. Nau, Jeffrey Atkinson, Julia Rintoul, Derek A. Pratt, and Ned A. Porter pp 10211–10219 DOI: 10.1021/ja072371m Supporting Info

Formation of Pseudosymmetrical G-Quadruplex and i-Motif Structures in the Proximal Promoter Region of the RET Oncogene Kexiao Guo, Alan Pourpak, Kara Beetz-Rogers, Vijay Gokhale, Daekyu Sun, and Laurence H. Hurley pp 10220–10228 DOI: 10.1021/ja072185g

Ionization Thresholds of Small Carbon Clusters:  Tunable VUV Experiments and Theory Leonid Belau, Steven E. Wheeler, Brian W. Ticknor, Musahid Ahmed, Stephen R. Leone, Wesley D. Allen, Henry F. Schaefer III, and Michael A. Duncan pp 10229–10243 DOI: 10.1021/ja072526q Supporting Info

Structural Studies of TcO2 by Neutron Powder Diffraction and First-Principles Calculations Efrain E. Rodriguez, Frederic Poineau, Anna Llobet, Alfred P. Sattelberger, Joydeep Bhattacharjee, Umesh V. Waghmare, Thomas Hartmann, and Anthony K. Cheetham pp 10244–10248 DOI: 10.1021/ja0727363 Supporting Info

Measuring Location, Size, Distribution, and Loading of NiO Crystallites in Individual SBA-15 Pores by Electron Tomography Heiner Friedrich, Jelle R. A. Sietsma, Petra E. de Jongh, Arie J. Verkleij, and Krijn P. de Jong pp 10249–10254 DOI: 10.1021/ja0728876 Supporting Info

Variable Stability Heterodimeric Coiled-Coils from Manipulation of Electrostatic Interface Residue Chain Length Shannon J. Ryan and Alan J. Kennan pp 10255–10260 DOI: 10.1021/ja073717w Supporting Info

Activation Mechanism of a Signaling Protein at Atomic Resolution from Advanced Computations Liang Ma and Qiang Cui pp 10261–10268 DOI: 10.1021/ja073059f Supporting Info

The Thermodynamics of the Transformation of Graphite to Multiwalled Carbon Nanotubes Daniele Gozzi, Massimiliano Iervolino, and Alessandro Latini pp 10269–10275 DOI: 10.1021/ja072120d

A Steric Deuterium Isotope Effect in 1,1,3,3-Tetramethylcyclohexane Martin Saunders, Max Wolfsberg, Frank A. L. Anet, and Olga Kronja pp 10276–10281 DOI: 10.1021/ja072375r Supporting Info

Dechalcogenative Allylic Selenosulfide and Disulfide Rearrangements:  Complementary Methods for the Formation of Allylic Sulfides in the Absence of Electrophiles. Scope, Limitations, and Application to the Functionalization of Unprotected Peptides in Aqueous Media David Crich, Venkataramanan Krishnamurthy, Franck Brebion, Maheswaran Karatholuvhu, Venkataraman Subramanian, and Thomas K. Hutton pp 10282–10294 DOI: 10.1021/ja072969u Supporting Info

Radioanalytical Chemistry Edited by Bernd Kahn (Georgia Institute of Technology, Atlanta, GA, USA). Springer Science + Business Media, LLC:  New York. 2007. viii + 474 pp. $89.95. ISBN 0-387-34122-6. Kenneth L. Nash pp 10295–10296 DOI: 10.1021/ja076927h

Reviews in Computational Chemistry, Volume 23 Edited by Kenny B. Lipkowitz (Howard University, Washington, D.C.), Thomas R. Cundari (University of North Texas, Denton), and Donald B. Boyd, Editor Emeritus (Indiana University-Purdue University, Indianapolis). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xxxii + 484 pp. $160. ISBN 978-0-470-08201-0. Kim K. Baldridge pp 10296–10297 DOI: 10.1021/ja076928+

The Handbook of Homogeneous Hydrogenation, Volumes 1−3 Edited by Johannes G. de Vries (DSM Pharmaceutical Products, Geleen, The Netherlands) and Cornelis J. Elsevier (Universiteit van Amsterdam, The Netherlands). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. 1632 pp. $625.00. ISBN 978-3-527-31161-3. Lothar Stahl pp 10297–10298 DOI: 10.1021/ja0769292

Organic Syntheses, Volume 83 Edited by Dennis P. Curran (University of Pittsburgh, PA). John Wiley & Sons, Inc:  Hoboken, NJ. 2006. xliv + 254 pp. $59.95. ISBN 0-471-97987-2. p 10298 DOI: 10.1021/ja0769447

Organic Synthesis:  Strategy and Control. Edited by Paul Wyatt (University of Bristol, U.K.) and Stuart Warren (University of Cambridge, U.K.). John Wiley & Sons, Ltd:  Chichester. 2007. viii + 910 pp. $90.00. ISBN 978-0-471-92963-5. p 10298 DOI: 10.1021/ja076988f

Issue 34

Modular Bent DNAs:  A New Class of Artificial DNAs with a Protein Binding Ability Shunpei Murata, Youko Mizumura, Kaori Hino, Yoshihito Ueno, Satoshi Ichikawa, and Akira Matsuda pp 10300–10301 DOI: 10.1021/ja071335k Supporting Info

A Molecular Thermometer Based on Fluorescent Protein Blinking Felix H. C. Wong, Daniel S. Banks, Asmahan Abu-Arish, and Cécile Fradin pp 10302–10303 DOI: 10.1021/ja0715905 Supporting Info

Spatially Addressable Multiprotein Nanoarrays Templated by Aptamer-Tagged DNA Nanoarchitectures Rahul Chhabra, Jaswinder Sharma, Yonggang Ke, Yan Liu, Sherri Rinker, Stuart Lindsay, and Hao Yan pp 10304–10305 DOI: 10.1021/ja072410u Supporting Info

Definitive Determination of Zero-Field Splitting and Exchange Interactions in a Ni(II) Dimer:  Investigation of [Ni2(en)4Cl2]Cl2 Using Magnetization and Tunable-Frequency High-Field Electron Paramagnetic Resonance Radovan Herchel, Roman Boa, J. Krzystek, Andrew Ozarowski, Marc Durán, and Joris van Slageren pp 10306–10307 DOI: 10.1021/ja0725807 Supporting Info

Synthesis of Solution-Soluble Pentacene-Containing Conjugated Copolymers Toshihiro Okamoto and Zhenan Bao pp 10308–10309 DOI: 10.1021/ja0725403 Supporting Info

Resolution of the Spectroscopy versus Crystallography Issue for NO Intermediates of Nitrite Reductase from Rhodobacter sphaeroides Somdatta Ghosh, Abhishek Dey, Oleg M. Usov, Yan Sun, Vladimir M. Grigoryants, Charles P. Scholes, and Edward I. Solomon pp 10310–10311 DOI: 10.1021/ja072841c Supporting Info

Asymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] Cycloaddition Ravisekhara P. Reddy and Huw M. L. Davies pp 10312–10313 DOI: 10.1021/ja072936e Supporting Info

The Leader Peptide Is Not Required for Post-Translational Modification by Lacticin 481 Synthetase Matthew R. Levengood, Gregory C. Patton, and Wilfred A. van der Donk pp 10314–10315 DOI: 10.1021/ja072967+ Supporting Info

Determination of the Crystal Structure of Substrate-Induced Pentacene Polymorphs in Fiber Structured Thin Films Stefan Schiefer, Martin Huth, Alexander Dobrinevski, and Bert Nickel pp 10316–10317 DOI: 10.1021/ja0730516 Supporting Info

Addition of Ammonia, Water, and Dihydrogen Across a Single Pd−Pd Bond Claudia M. Fafard, Debashis Adhikari, Bruce M. Foxman, Daniel J. Mindiola, and Oleg V. Ozerov pp 10318–10319 DOI: 10.1021/ja0731571 Supporting Info

Efficient Far Red Sensitization of Nanocrystalline TiO2 Films by an Unsymmetrical Squaraine Dye Jun-Ho Yum, Pablo Walter, Simon Huber, Daniel Rentsch, Thomas Geiger, Frank Nüesch, Filippo De Angelis, Michael Grätzel, and Mohammad K. Nazeeruddin pp 10320–10321 DOI: 10.1021/ja0731470 Supporting Info

A Highly Selective Fluorescence Turn-on Sensor for Cysteine/Homocysteine and Its Application in Bioimaging Meng Zhang, Mengxiao Yu, Fuyou Li, Minwei Zhu, Manyu Li, Yanhong Gao, Lei Li, Zhiqiang Liu, Jianping Zhang, Dengqing Zhang, Tao Yi, and Chunhui Huang pp 10322–10323 DOI: 10.1021/ja073140i Supporting Info

Design and Synthesis of Fluorescent Probes for Selective Detection of Highly Reactive Oxygen Species in Mitochondria of Living Cells Yuichiro Koide, Yasuteru Urano, Suguru Kenmoku, Hirotatsu Kojima, and Tetsuo Nagano pp 10324–10325 DOI: 10.1021/ja073220m Supporting Info

Supramolecular Hemoprotein Linear Assembly by Successive Interprotein Heme−Heme Pocket Interactions Hiroaki Kitagishi, Koji Oohora, Hiroyasu Yamaguchi, Hideaki Sato, Takashi Matsuo, Akira Harada, and Takashi Hayashi pp 10326–10327 DOI: 10.1021/ja073295q Supporting Info

Rapid and Efficient Electrocatalytic CO2/CO Interconversions by Carboxydothermus hydrogenoformans CO Dehydrogenase I on an Electrode Alison Parkin, Javier Seravalli, Kylie A. Vincent, Stephen W. Ragsdale, and Fraser A. Armstrong pp 10328–10329 DOI: 10.1021/ja073643o Supporting Info

A Simple Method To Determine Kinetic Deuterium Isotope Effects Provides Evidence that Proton Transfer to Carbon Proceeds over and Not through the Reaction Barrier Wing-Yin Tsang and John P. Richard pp 10330–10331 DOI: 10.1021/ja073679g

A Cryptophane Core Optimized for Xenon Encapsulation Heather A. Fogarty, Patrick Berthault, Thierry Brotin, Gaspard Huber, Hervé Desvaux, and Jean-Pierre Dutasta pp 10332–10333 DOI: 10.1021/ja073771c Supporting Info

Anion Control in the Ionothermal Synthesis of Coordination Polymers Zhuojia Lin, David S. Wragg, John E. Warren, and Russell E. Morris pp 10334–10335 DOI: 10.1021/ja0737671 Supporting Info

Chiral Brønsted Acid-Catalyzed Tandem Aza-Ene Type Reaction/Cyclization Cascade for a One-Pot Entry to Enantioenriched Piperidines Masahiro Terada, Kyoko Machioka, and Keiichi Sorimachi pp 10336–10337 DOI: 10.1021/ja0739584 Supporting Info

Cucurbit[7]uril Induces Superior Probe Performance for Single-Molecule Detection Tami A. Martyn, Jason L. Moore, Ronald L. Halterman, and Wai Tak Yip pp 10338–10339 DOI: 10.1021/ja073996n Supporting Info

Heavy Ferrocene:  A Sandwich Complex Containing Si and Ge Atoms Vladimir Ya. Lee, Risa Kato, Akira Sekiguchi, Andreas Krapp, and Gernot Frenking pp 10340–10341 DOI: 10.1021/ja0740162 Supporting Info

Construction of Bridged and Fused Ring Systems via Intramolecular Michael Reactions of Vinylnitroso Compounds Ilia Korboukh, Praveen Kumar, and Steven M. Weinreb pp 10342–10343 DOI: 10.1021/ja074108r Supporting Info

Direct Assessment of Transport Properties of Supercritical Fluids Confined to Nanopores Muslim Dvoyashkin, Rustem Valiullin, Jörg Kärger, Wolf-Dietrich Einicke, and Roger Gläser pp 10344–10345 DOI: 10.1021/ja074101+ Supporting Info

Conversion of Torgov's Synthesis of Estrone into a Highly Enantioselective and Efficient Process Ying-Yeung Yeung, Rong-Jie Chein, and E. J. Corey pp 10346–10347 DOI: 10.1021/ja0742434 Supporting Info

Facile Strategy to Well-Defined Water-Soluble Boronic Acid (Co)polymers Jennifer N. Cambre, Debashish Roy, Sudershan R. Gondi, and Brent S. Sumerlin pp 10348–10349 DOI: 10.1021/ja074239s Supporting Info

Reactivity of a Platinum Iminoboryl Complex toward Lewis and Brønsted Acids Holger Braunschweig, Krzysztof Radacki, Daniela Rais, Achim Schneider, and Fabian Seeler pp 10350–10351 DOI: 10.1021/ja0742636 Supporting Info

Real-Time Measurements of Conductance Switching and Motion of Single Oligo(phenylene ethynylene) Molecules Amanda M. Moore, Brent A. Mantooth, Zachary J. Donhauser, Yuxing Yao, James M. Tour, and Paul S. Weiss pp 10352–10353 DOI: 10.1021/ja0745153

Selective Palladium-Catalyzed Arylation of Ammonia:  Synthesis of Anilines as Well as Symmetrical and Unsymmetrical Di- and Triarylamines David S. Surry and Stephen L. Buchwald pp 10354–10355 DOI: 10.1021/ja074681a Supporting Info

Total Synthesis of Kinamycins C, F, and J K. C. Nicolaou, Hongming Li, Andrea L. Nold, Doron Pappo, and Achim Lenzen pp 10356–10357 DOI: 10.1021/ja074297d Supporting Info

Vacancy Coalescence during Oxidation of Iron Nanoparticles Andreu Cabot, Victor F. Puntes, Elena Shevchenko, Yadong Yin, Lluís Balcells, Matthew A. Marcus, Steven M. Hughes, and A. Paul Alivisatos pp 10358–10360 DOI: 10.1021/ja072574a Supporting Info

Pd-Mediated Activation of Molecular Oxygen:  Pd(0) versus Direct Insertion Jason M. Keith, William A. Goddard, III, and Jonas Oxgaard pp 10361–10369 DOI: 10.1021/ja070462d Supporting Info

Structural Development of Mercaptophenol Self-Assembled Monolayers and the Overlying Mineral Phase during Templated CaCO3 Crystallization from a Transient Amorphous Film Jonathan R. I. Lee, T. Yong-Jin Han, Trevor M. Willey, Dongbo Wang, Robert W. Meulenberg, Joakim Nilsson, Patricia M. Dove, Louis J. Terminello, Tony van Buuren, and James J. De Yoreo pp 10370–10381 DOI: 10.1021/ja071535w Supporting Info

Alkyl Carbon−Nitrogen Reductive Elimination from Platinum(IV)−Sulfonamide Complexes Andrew V. Pawlikowski, April D. Getty, and Karen I. Goldberg pp 10382–10393 DOI: 10.1021/ja069191h Supporting Info

Electrochemical Quantification of Single-Nucleotide Polymorphisms Using Nanoparticle Probes Guodong Liu and Yuehe Lin pp 10394–10401 DOI: 10.1021/ja070429r

Successful a Priori Modeling of CO Adsorption on Pt(111) Using Periodic Hybrid Density Functional Theory Yun Wang, Stefano de Gironcoli, Noel S. Hush, and Jeffrey R. Reimers pp 10402–10407 DOI: 10.1021/ja0712367 Supporting Info

Triple-Helical Transition State Analogues:  A New Class of Selective Matrix Metalloproteinase Inhibitors Janelle Lauer-Fields, Keith Brew, John K. Whitehead, Shunzi Li, Robert P. Hammer, and Gregg B. Fields pp 10408–10417 DOI: 10.1021/ja0715849 Supporting Info

Surface Transfer p-Type Doping of Epitaxial Graphene Wei Chen, Shi Chen, Dong Chen Qi, Xing Yu Gao, and Andrew Thye Shen Wee pp 10418–10422 DOI: 10.1021/ja071658g Supporting Info

“Open Rather than Closed” Malonate Methano-Fullerene Derivatives. The Formation of Methanofulleroid Adducts of Y3N@C80 Olena Lukoyanova, Claudia M. Cardona, José Rivera, Leyda Z. Lugo-Morales, Christopher J. Chancellor, Marilyn M. Olmstead, Antonio Rodríguez-Fortea, Josep M. Poblet, Alan L. Balch, and Luis Echegoyen pp 10423–10430 DOI: 10.1021/ja071733n Supporting Info

Site-Specific Incorporation of Tryptophan Analogues into Recombinant Proteins in Bacterial Cells Inchan Kwon and David A. Tirrell pp 10431–10437 DOI: 10.1021/ja071773r Supporting Info

Simulation of Adsorption of DNA on Carbon Nanotubes Xiongce Zhao and J. Karl Johnson pp 10438–10445 DOI: 10.1021/ja071844m Supporting Info

Electronic Structure and FeNO Conformation of Nonheme Iron−Thiolate−NO Complexes:  An Experimental and DFT Study Jeanet Conradie, Duncan A. Quarless, Jr., Hua-Fen Hsu, Todd C. Harrop, Stephen J. Lippard, Stephen A. Koch, and Abhik Ghosh pp 10446–10456 DOI: 10.1021/ja0719982 Supporting Info

Synthesis of New [8Fe-7S] Clusters:  A Topological Link between the Core Structures of P-Cluster, FeMo-co, and FeFe-co of Nitrogenases Yasuhiro Ohki, Yohei Ikagawa, and Kazuyuki Tatsumi pp 10457–10465 DOI: 10.1021/ja072256b Supporting Info

Efforts toward Expansion of the Genetic Alphabet:  Structure and Replication of Unnatural Base Pairs Shigeo Matsuda, Jeremiah D. Fillo, Allison A. Henry, Priyamrada Rai, Steven J. Wilkens, Tammy J. Dwyer, Bernhard H. Geierstanger, David E. Wemmer, Peter G. Schultz, Glen Spraggon, and Floyd E. Romesberg pp 10466–10473 DOI: 10.1021/ja072276d Supporting Info

Surface Structures of Rutile TiO2 (011) Toshitaka Kubo, Hideo Orita, and Hisakazu Nozoye pp 10474–10478 DOI: 10.1021/ja072281h

Self-Assembled Light-Harvesting Systems:  Ru(II) Complexes Assembled about Rh−Rh Cores Michael W. Cooke, Garry S. Hanan, Frédérique Loiseau, Sebastiano Campagna, Masashi Watanabe, and Yasutaka Tanaka pp 10479–10488 DOI: 10.1021/ja072153t Supporting Info

Ligand Specificity of CS-35, a Monoclonal Antibody That Recognizes Mycobacterial Lipoarabinomannan:  A Model System for Oligofuranoside−Protein Recognition Christoph Rademacher, Glen K. Shoemaker, Hyo-Sun Kim, Ruixiang Blake Zheng, Hashem Taha, Chunjuan Liu, Ruel C. Nacario, David C. Schriemer, John S. Klassen, Thomas Peters, and Todd L. Lowary pp 10489–10502 DOI: 10.1021/ja0723380 Supporting Info

Kinetic Discrimination of Sequence-Specific DNA−Drug Binding Measured by Surface Plasmon Resonance Imaging and Comparison to Solution-Phase Measurements Lauren K. Wolf, Yang Gao, and Rosina M. Georgiadis pp 10503–10511 DOI: 10.1021/ja072401l Supporting Info

Ligand Effects on the Ferro- to Antiferromagnetic Exchange Ratio in Bis(o-Semiquinonato)copper(II) Victor I. Ovcharenko, Elena V. Gorelik, Sergey V. Fokin, Galina V. Romanenko, Vladimir N. Ikorskii, Anna V. Krashilina, Vladimir K. Cherkasov, and Gleb A. Abakumov pp 10512–10521 DOI: 10.1021/ja072463b Supporting Info

Structure of Tetracarbonylethyleneosmium:  Ethylene Structure Changes upon Complex Formation Chandana Karunatilaka, Brandon S. Tackett, John Washington, and Stephen G. Kukolich pp 10522–10530 DOI: 10.1021/ja0727969 Supporting Info

Direct and Remarkably Efficient Conversion of Methane into Acetic Acid Catalyzed by Amavadine and Related Vanadium Complexes. A Synthetic and a Theoretical DFT Mechanistic Study Marina V. Kirillova, Maxim L. Kuznetsov, Patrícia M. Reis, José A. L. da Silva, João J. R. Fraústo da Silva, and Armando J. L. Pombeiro pp 10531–10545 DOI: 10.1021/ja072531u Supporting Info

Characterization of Rhodosaminyl Transfer by the AknS/AknT Glycosylation Complex and Its Use in Reconstituting the Biosynthetic Pathway of Aclacinomycin A Catherine Leimkuhler, Micha Fridman, Tania Lupoli, Suzanne Walker, Christopher T. Walsh, and Daniel Kahne pp 10546–10550 DOI: 10.1021/ja072909o Supporting Info

Synthesis of High Molecular Weight Comb Block Copolymers and Their Assembly into Ordered Morphologies in the Solid State M. Brett Runge and Ned B. Bowden pp 10551–10560 DOI: 10.1021/ja072929q

Diffusion in Coiled Pores − Learning from Microrelease and Microsurgery Magdalena Stempniewicz, Ahmed S. G. Khalil, Michael Rohwerder, and Frank Marlow pp 10561–10566 DOI: 10.1021/ja0728167

The α,α-(1→1) Linkage of Trehalose Is Key to Anhydrobiotic Preservation Fernando Albertorio, Vanessa A. Chapa, Xin Chen, Arnaldo J. Diaz, and Paul S. Cremer pp 10567–10574 DOI: 10.1021/ja0731266

Partially Hydroxylated Polycrystalline Ionic Oxides:  A New Route toward Electron-Rich Surfaces Francesco Napoli, Mario Chiesa, Elio Giamello, Emanuele Finazzi, Cristiana Di Valentin, and Gianfranco Pacchioni pp 10575–10581 DOI: 10.1021/ja073114k Supporting Info

Role of Guiding Groups in Cinchona-Modified Platinum for Controlling the Sense of Enantiodifferentiation in the Hydrogenation of Ketones Fatos Hoxha, Lucia Königsmann, Angelo Vargas, Davide Ferri, Tamas Mallat, and Alfons Baiker pp 10582–10590 DOI: 10.1021/ja073446p Supporting Info

Versatile and Practical Macrocyclic Reagent with Multiple Hydrogen-Bonding Sites for Chiral Discrimination in NMR Tadashi Ema, Daisuke Tanida, and Takashi Sakai pp 10591–10596 DOI: 10.1021/ja073476s Supporting Info

Mechanism of Nitrite Formation by Nitrate Photolysis in Aqueous Solutions:  The Role of Peroxynitrite, Nitrogen Dioxide, and Hydroxyl Radical Sara Goldstein and Joseph Rabani pp 10597–10601 DOI: 10.1021/ja073609+

General Approach for the Synthesis of Organic−Inorganic Hybrid Nanoparticles Mediated by Supercritical CO2 Sandy Moisan, Victor Martinez, Patrick Weisbecker, François Cansell, Stefan Mecking, and Cyril Aymonier pp 10602–10606 DOI: 10.1021/ja074069j

Length-Dependent Optical Effects in Single-Wall Carbon Nanotubes Jeffrey A. Fagan, Jeffrey R. Simpson, Barry J. Bauer, Silvia H. De Paoli Lacerda, Matthew L. Becker, Jaehun Chun, Kalman B. Migler, Angela R. Hight Walker, and Erik K. Hobbie pp 10607–10612 DOI: 10.1021/ja073115c Supporting Info

Electronic Coupling and Exciton Energy Transfer in CdTe Quantum-Dot Molecules [J. Am. Chem. Soc. 2006, 128, 10436−10441]. Rolf Koole, Peter Liljeroth, Celso de Mello Donegá, Daniël Vanmaekelbergh, and Andries Meijerink p 10613 DOI: 10.1021/ja076896q

Organic Reactions, Volume 68 Editor-in-Chief:  Larry E. Overman (University of California, Irvine). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. viii + 552 pp. $130.00. ISBN 978-0-470-09898-1. p 10614 DOI: 10.1021/ja076971x

Handbook of Industrial Water Soluble Polymers Edited by Peter A. Williams (Centre for Water Soluble Polymers, North East Wales Institute, U.K.). Blackwell Publishing Ltd.:  Oxford. 2007. xii + 332 pp. $199.99. ISBN 978-1-4051-3242-8. p 10614 DOI: 10.1021/ja076976u

Systematic Nomenclature of Organic, Organometallic and Coordination Chemistry:  Chemcial-Abstracts Guidelines with IUPAC Recommendations and Many Trivial Names By Ursula Bünzli-Trepp (Cugy/Lausanne). EPFL Press:  Lausanne, Switzerland (distributed by CRC Press). x + 636 pp. $161.96. ISBN 978-1-4200-4615-1. p 10614 DOI: 10.1021/ja076977m

The Art of Drug Synthesis Edited by Douglas S. Johnson and Jie Jack Li (Pfizer Global Research and Development). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xvi + 276 pp. $90.00. ISBN 978-0-471-75215-8. p 10614 DOI: 10.1021/ja0769999

Issue 35

Photoactivatable and Water Soluble FRET Dyes with High Uncaging Cross Section Genhua Zheng, Yan-Ming Guo, and Wen-Hong Li pp 10616–10617 DOI: 10.1021/ja071427+ Supporting Info

The Twisted C11C12 Bond of the Rhodopsin ChromophoreA Photochemical Hot Spot Oliver Weingart pp 10618–10619 DOI: 10.1021/ja071793t Supporting Info

Tunable Luminescent Lanthanide Coordination Polymers Based on Reversible Solid-State Ion-Exchange Monitored by Ion-Dependent Photoinduced Emission Spectra Peng Wang, Jian-Ping Ma, Yu-Bin Dong, and Ru-Qi Huang pp 10620–10621 DOI: 10.1021/ja072442h Supporting Info

Interparticle Charge Transfer Mediated by π−π Stacking of Aromatic Moieties Sulolit Pradhan, Debraj Ghosh, Li-Ping Xu, and Shaowei Chen pp 10622–10623 DOI: 10.1021/ja072597p Supporting Info

Enhanced Stability of Large Molecules Vacuum-Sublimated onto Au(111) Achieved by Incorporation of Coordinated Au-Atoms Wei Xu, Mingdong Dong, Socorro Vázquez-Campos, Henkjan Gersen, Erik Lægsgaard, Ivan Stensgaard, Mercedes Crego-Calama, David N. Reinhoudt, Trolle R. Linderoth, and Flemming Besenbacher pp 10624–10625 DOI: 10.1021/ja0725448 Supporting Info

RNA Probes of Steric Effects in Active Sites:  High Flexibility of HIV-1 Reverse Transcriptase Adam P. Silverman and Eric T. Kool pp 10626–10627 DOI: 10.1021/ja072791b Supporting Info

Tungsten(II) Monocarbonyl Bis(acetylacetonate):  A Fourteen-Electron Docking Site for η2 Four-Electron Donor Ligands Andrew B. Jackson, Cynthia K. Schauer, Peter S. White, and Joseph L. Templeton pp 10628–10629 DOI: 10.1021/ja0728270 Supporting Info

Enzymatic Synthesis of Fluorinated Mechanistic Probes for Sialidases and Sialyltransferases Harshal A. Chokhawala, Hongzhi Cao, Hai Yu, and Xi Chen pp 10630–10631 DOI: 10.1021/ja072687u Supporting Info

Direct Catalytic Enantioselective Mannich Reactions:  Synthesis of Protected anti-α,β-Diamino Acids Gary A. Cutting, Nikki E. Stainforth, Matthew P. John, Gabriele Kociok-Köhn, and Michael C. Willis pp 10632–10633 DOI: 10.1021/ja073473f Supporting Info

Growing Pt Nanowires as a Densely Packed Array on Metal Gauze Eric P. Lee, Zhenmeng Peng, David M. Cate, Hong Yang, Charles T. Campbell, and Younan Xia pp 10634–10635 DOI: 10.1021/ja074312e Supporting Info

Synthesis of a Dy@C82 Derivative Bearing a Single Phosphorus Substituent via a Zwitterion Approach Xiaofang Li, Louzhen Fan, Dongfang Liu, Herman H. Y. Sung, Ian D. Williams, Shihe Yang, Kai Tan, and Xin Lu pp 10636–10637 DOI: 10.1021/ja074321n Supporting Info

Thermal and Photochemical Cleavage of SiSi Double Bond in Tetrasila-1,3-diene Kei Uchiyama, Selvarajan Nagendran, Shintaro Ishida, Takeaki Iwamoto, and Mitsuo Kira pp 10638–10639 DOI: 10.1021/ja0741473 Supporting Info

Total Synthesis of (+)-Suaveolindole:  Establishment of Its Absolute Configuration Emile J. Velthuisen and Samuel J. Danishefsky pp 10640–10641 DOI: 10.1021/ja075100k Supporting Info

Enzymatic Synthesis of Aromatic Polyketides Using PKS4 from Gibberella fujikuroi Suzanne M. Ma, Jixun Zhan, Kenji Watanabe, Xinkai Xie, Wenjun Zhang, Clay C. Wang, and Yi Tang pp 10642–10643 DOI: 10.1021/ja074865p Supporting Info

Photocatalytic Hydrogen Production from Water Employing A Ru, Rh, Ru Molecular Device for Photoinitiated Electron Collection Mark Elvington, Jared Brown, Shamindri M. Arachchige, and Karen J. Brewer pp 10644–10645 DOI: 10.1021/ja073123t Supporting Info

Distortion/Interaction Energy Control of 1,3-Dipolar Cycloaddition Reactivity Daniel H. Ess and K. N. Houk pp 10646–10647 DOI: 10.1021/ja0734086 Supporting Info

Crystal Structure of a Biosynthetic Sulfo-hirudin Complexed to Thrombin Chang C. Liu, Eric Brustad, Wenshe Liu, and Peter G. Schultz pp 10648–10649 DOI: 10.1021/ja0735002 Supporting Info

Backbone Assignments in Solid-State Proteins Using J-Based 3D Heteronuclear Correlation Spectroscopy Lingling Chen, J. Michael Kaiser, Tatyana Polenova, Jun Yang, Chad M. Rienstra, and Leonard J. Mueller pp 10650–10651 DOI: 10.1021/ja073498e Supporting Info

Endohedral Peptide Lining of a Self-Assembled Molecular Sphere To Generate Chirality-Confined Hollows Kosuke Suzuki, Masaki Kawano, Sota Sato, and Makoto Fujita pp 10652–10653 DOI: 10.1021/ja073629b Supporting Info

Transcriptional Up-regulation in Cells Mediated by a Small Molecule Steven P. Rowe, Ryan J. Casey, Brian B. Brennan, Sara J. Buhrlage, and Anna K. Mapp pp 10654–10655 DOI: 10.1021/ja0736865 Supporting Info

Construction and DNA Condensation of Cyclodextrin-Based Polypseudorotaxanes with Anthryl Grafts Yu Liu, Lu Yu, Yong Chen, Yan-Li Zhao, and Hua Yang pp 10656–10657 DOI: 10.1021/ja073882b Supporting Info

Thermodynamics of Phosphopeptide Tethering to BRCT:  The Structural Minima for Inhibitor Design G. L. Lokesh, B. K. Muralidhara, Surendra S. Negi, and Amarnath Natarajan pp 10658–10659 DOI: 10.1021/ja0739178 Supporting Info

Stresses at the Interface of Micro with Nano Nicholas Leventis, Sudhir Mulik, Xiaojiang Wang, Amala Dass, Chariklia Sotiriou-Leventis, and Hongbing Lu pp 10660–10661 DOI: 10.1021/ja074010c

Self-Organization of Room-Temperature Ionic Liquids Exhibiting Liquid-Crystalline Bicontinuous Cubic Phases:  Formation of Nano-Ion Channel Networks Takahiro Ichikawa, Masafumi Yoshio, Atsushi Hamasaki, Tomohiro Mukai, Hiroyuki Ohno, and Takashi Kato pp 10662–10663 DOI: 10.1021/ja0740418 Supporting Info

Exceptional Coupling of Tetrachloroperylene Bisimide:  Combination of Ullmann Reaction and C−H Transformation Hualei Qian, Zhaohui Wang, Wan Yue, and Daoben Zhu pp 10664–10665 DOI: 10.1021/ja0740972 Supporting Info

Self-Separating Homogeneous Copper (I) Catalysts David E. Bergbreiter, Patrick N. Hamilton, and Nirmal M. Koshti pp 10666–10667 DOI: 10.1021/ja0741372 Supporting Info

Synthesis and Characterization of Manganese-Doped Silicon Nanoparticles:  Bifunctional Paramagnetic-Optical Nanomaterial Xiaoming Zhang, Marcin Brynda, R. David Britt, Elizabeth C. Carroll, Delmar S. Larsen, Angelique Y. Louie, and Susan M. Kauzlarich pp 10668–10669 DOI: 10.1021/ja074144q Supporting Info

Vapor−Solid−Solid Synthesis of Ge Nanowires from Vapor-Phase-Deposited Manganese Germanide Seeds Jessica L. Lensch-Falk, Eric R. Hemesath, Francisco J. Lopez, and Lincoln J. Lauhon pp 10670–10671 DOI: 10.1021/ja074276j Supporting Info

Magnetic Exchange Coupling in Chloride-Bridged 5f−3d Heterometallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate Dimer Stosh A. Kozimor, Bart M. Bartlett, Jeffrey D. Rinehart, and Jeffrey R. Long pp 10672–10674 DOI: 10.1021/ja0725044 Supporting Info

Charge Density Waves in the Square Nets of Tellurium of AMRETe4 (A = K, Na; M = Cu, Ag; RE = La, Ce) Christos D. Malliakas and Mercouri G. Kanatzidis pp 10675–10677 DOI: 10.1021/ja073986m Supporting Info

Intrinsic Primary and Secondary Hydrogen Kinetic Isotope Effects for Alanine Racemase from Global Analysis of Progress Curves M. Ashley Spies and Michael D. Toney pp 10678–10685 DOI: 10.1021/ja067643k Supporting Info

The Conformational Free Energy Landscape of β-d-Glucopyranose. Implications for Substrate Preactivation in β-Glucoside Hydrolases Xevi Biarnés, Albert Ardèvol, Antoni Planas, Carme Rovira, Alessandro Laio, and Michele Parrinello pp 10686–10693 DOI: 10.1021/ja068411o Supporting Info

Chiral Ethylhexyl Substituents for Optically Active Aggregates of π-Conjugated Polymers Christophe R. G. Grenier, Subi J. George, Thomas J. Joncheray, E. W. Meijer, and John R. Reynolds pp 10694–10699 DOI: 10.1021/ja068461t Supporting Info

Mechanism of Ammonia Detection by Chemically Functionalized Single-Walled Carbon Nanotubes:  In Situ Electrical and Optical Study of Gas Analyte Detection Elena Bekyarova, Irina Kalinina, Mikhail E. Itkis, Leanne Beer, Nelson Cabrera, and Robert C. Haddon pp 10700–10706 DOI: 10.1021/ja0703271 Supporting Info

Mechanistic Investigation of the Cobalt-Catalyzed Selective Conversion of Diallylanilines to Quinolines Involving C−N and C−H Activations Ling Li and William D. Jones pp 10707–10713 DOI: 10.1021/ja070551q Supporting Info

Photoswitchable Dendritic Hosts:  A Dendrimer with Peripheral Azobenzene Groups Fausto Puntoriero, Paola Ceroni, Vincenzo Balzani, Giacomo Bergamini, and Fritz Vögtle pp 10714–10719 DOI: 10.1021/ja070636r

Prediction of the 3D Structure and Dynamics of Human DP G-Protein Coupled Receptor Bound to an Agonist and an Antagonist Youyong Li, Fangqiang Zhu, Nagarajan Vaidehi, William A. Goddard, III, Felix Sheinerman, Stephan Reiling, Isabelle Morize, Lan Mu, Keith Harris, Ali Ardati, and Abdelazize Laoui pp 10720–10731 DOI: 10.1021/ja070865d Supporting Info

De Novo Design of a Single-Chain Diphenylporphyrin Metalloprotein Gretchen M. Bender, Andreas Lehmann, Hongling Zou, Hong Cheng, H. Christopher Fry, Don Engel, Michael J. Therien, J. Kent Blasie, Heinrich Roder, Jeffrey G. Saven, and William F. DeGrado pp 10732–10740 DOI: 10.1021/ja071199j Supporting Info

1-Adamantanethiolate Monolayer Displacement Kinetics Follow a Universal Form Héctor M. Saavedra, Corina M. Barbu, Arrelaine A. Dameron, Thomas J. Mullen, Vincent H. Crespi, and Paul S. Weiss pp 10741–10746 DOI: 10.1021/ja071116z

Biomimetic Interactions of Proteins with Functionalized Nanoparticles:  A Thermodynamic Study Mrinmoy De, Chang-Cheng You, Sudhanshu Srivastava, and Vincent M. Rotello pp 10747–10753 DOI: 10.1021/ja071642q Supporting Info

The Origin of Transverse Anisotropy in Axially Symmetric Single Molecule Magnets Anne-Laure Barra, Andrea Caneschi, Andrea Cornia, Dante Gatteschi, Lapo Gorini, Leo-Philipp Heiniger, Roberta Sessoli, and Lorenzo Sorace pp 10754–10762 DOI: 10.1021/ja0717921 Supporting Info

Mechanistic Studies of UV Assisted [4 + 2] Cycloadditions in Synthetic Efforts toward Vibsanin E Joachim Nikolai, Øystein Loe, Paulina M. Dominiak, Oksana O. Gerlitz, Jochen Autschbach, and Huw M. L. Davies pp 10763–10772 DOI: 10.1021/ja072090e Supporting Info

Mechanistic Twist of the [8+2] Cycloadditions of Dienylisobenzofurans and Dimethyl Acetylenedicarboxylate:  Stepwise [8+2] versus [4+2]/[1,5]-Vinyl Shift Mechanisms Revealed through a Theoretical and Experimental Study Yuanyuan Chen, Siyu Ye, Lei Jiao, Yong Liang, Dilip K. Sinha-Mahapatra, James W. Herndon, and Zhi-Xiang Yu pp 10773–10784 DOI: 10.1021/ja072203u Supporting Info

Calculations of the Effects of Substituents on Bond Localization in Annelated Cyclopentadienyl Radicals Xin Zhou, David A. Hrovat, and Weston Thatcher Borden pp 10785–10794 DOI: 10.1021/ja072314t Supporting Info

Sc3N@C78:  Encapsulated Cluster Regiocontrol of Adduct Docking on an Ellipsoidal Metallofullerene Sphere Ting Cai, Liaosa Xu, Harry W. Gibson, Harry C. Dorn, Christopher J. Chancellor, Marilyn M. Olmstead, and Alan L. Balch pp 10795–10800 DOI: 10.1021/ja072345o Supporting Info

Polyelectrolyte Diode:  Nonlinear Current Response of a Junction between Aqueous Ionic Gels Olivier J. Cayre, Suk Tai Chang, and Orlin D. Velev pp 10801–10806 DOI: 10.1021/ja072449z Supporting Info

Quantitative in Vitro Biopolymerization to Chitin in Native Chitosomal Membranes Supported by Silica Microparticles Stefan Kaufmann, Ingrid M. Weiss, and Motomu Tanaka pp 10807–10813 DOI: 10.1021/ja072234p

Antibiotic Deactivation by a Dizinc β-Lactamase:  Mechanistic Insights from QM/MM and DFT Studies Dingguo Xu, Hua Guo, and Qiang Cui pp 10814–10822 DOI: 10.1021/ja072532m Supporting Info

Sequence-Specific Resonance Assignment of Soluble Nonglobular Proteins by 7D APSY-NMR Spectroscopy Sebastian Hiller, Christian Wasmer, Gerhard Wider, and Kurt Wüthrich pp 10823–10828 DOI: 10.1021/ja072564+ Supporting Info

Ultrafast Energy Transfer and Strong Dynamic Non-Condon Effect on Ligand Field Transitions by Coherent Phonon in γ-Fe2O3 Nanocrystals Tai-Yen Chen, Chih-Hao Hsia, Hyung Su Son, and Dong Hee Son pp 10829–10836 DOI: 10.1021/ja072578f

Hydrogen-Bond Interaction in Organic Conductors:  Redox Activation, Molecular Recognition, Structural Regulation, and Proton Transfer in Donor−Acceptor Charge-Transfer Complexes of TTF-Imidazole Tsuyoshi Murata, Yasushi Morita, Yumi Yakiyama, Kozo Fukui, Hideki Yamochi, Gunzi Saito, and Kazuhiro Nakasuji pp 10837–10846 DOI: 10.1021/ja072607m Supporting Info

Synthesis and Characterization of the Homologous M−M Bonded Series Ar‘MMAr‘ (M = Zn, Cd, or Hg; Ar‘ = C6H3-2,6-(C6H3-2,6-Pri2)2) and Related Arylmetal Halides and Hydride Species Zhongliang Zhu, Marcin Brynda, Robert J. Wright, Roland C. Fischer, W. Alexander Merrill, Eric Rivard, Robert Wolf, James C. Fettinger, Marilyn M. Olmstead, and Philip P. Power pp 10847–10857 DOI: 10.1021/ja072682x Supporting Info

Systematic Exploration of the Structural Features of Yatakemycin Impacting DNA Alkylation and Biological Activity Mark S. Tichenor, Karen S. MacMillan, John D. Trzupek, Thomas J. Rayl, Inkyu Hwang, and Dale L. Boger pp 10858–10869 DOI: 10.1021/ja072777z Supporting Info

Synthesis, Crystal Structure, Characterization, and Catalytic Properties of TNU-9 Suk Bong Hong, Hyung-Ki Min, Chae-Ho Shin, Paul A. Cox, Stewart J. Warrender, and Paul A. Wright pp 10870–10885 DOI: 10.1021/ja073109g Supporting Info

Organocatalytic Enantioselective Cascade Michael-Alkylation Reactions:  Synthesis of Chiral Cyclopropanes and Investigation of Unexpected Organocatalyzed Stereoselective Ring Opening of Cyclopropanes Hexin Xie, Liansuo Zu, Hao Li, Jian Wang, and Wei Wang pp 10886–10894 DOI: 10.1021/ja073262a Supporting Info

New Side-On Bound Dinitrogen Complexes of Zirconium Supported by an Arene-Bridged Diamidophosphine Ligand and Their Reactivity with Dihydrogen Erin A. MacLachlan, Fiona M. Hess, Brian O. Patrick, and Michael D. Fryzuk pp 10895–10905 DOI: 10.1021/ja073753v Supporting Info

Protein-Templated Organic/Inorganic Hybrid Materials Prepared by Liquid-Phase Deposition Mayuko Tatemichi, Mune-aki Sakamoto, Minoru Mizuhata, Shigehito Deki, and Toshifumi Takeuchi pp 10906–10910 DOI: 10.1021/ja071890m Supporting Info

Dual Nanomolar and Picomolar Zn(II) Binding Properties of Metallothionein Artur Krżel and Wolfgang Maret pp 10911–10921 DOI: 10.1021/ja071979s Supporting Info

Electrochemical Generation of Glycosyl Triflate Pools Toshiki Nokami, Akito Shibuya, Hiroaki Tsuyama, Seiji Suga, Albert A. Bowers, David Crich, and Jun-ichi Yoshida pp 10922–10928 DOI: 10.1021/ja072440x Supporting Info

Catalytic Efficiency of Iron(III) Oxides in Decomposition of Hydrogen Peroxide:  Competition between the Surface Area and Crystallinity of Nanoparticles Martin Hermanek, Radek Zboril, Ivo Medrik, Jiri Pechousek, and Cenek Gregor pp 10929–10936 DOI: 10.1021/ja072918x Supporting Info

Formation of Monodisperse and Shape-Controlled MnO Nanocrystals in Non-Injection Synthesis:  Self-Focusing via Ripening Yongfen Chen, Eric Johnson, and Xiaogang Peng pp 10937–10947 DOI: 10.1021/ja073023n Supporting Info

Palladium Acetate-Catalyzed Cyclization Reaction of 2,3-Allenoic Acids in the Presence of Simple Allenes: An Efficient Synthesis of 4-(1‘-Bromoalk-2‘(Z)-en-2‘-yl)furan-2(5H)-one Derivatives and the Synthetic Application Zhenhua Gu, Xinke Wang, Wei Shu, and Shengming Ma pp 10948–10956 DOI: 10.1021/ja072790j Supporting Info

Total Synthesis of (+)-Tedanolide Amos B. Smith, III and Dongjoo Lee pp 10957–10962 DOI: 10.1021/ja073329u Supporting Info

Nanomaterials for Biosensors. Nanotechnologies for the Life Sciences, Volume 8 Edited by Challa S. S. R. Kumar (Louisiana State University, Baton Rouge). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xxii + 408 pp. $175.00 ISBN 978-3-527-31388-4. Paul Pantano p 10963 DOI: 10.1021/ja0769393

Free Energy Calculations:  Theory and Applications in Chemistry and Biology Springer Series in Chemical Physics, 86 Edited by Christophe Chipot (Université Henri Poincaré Vandoeuvre-lès-Nancy, France) and Andrew Pohorille (University of California, San Francisco, USA). Springer:  Berlin, Heidelberg, New York. 2007. xviii + 518 pp. $199.00. ISBN 978-3-540-38447-2. Mark E. Tuckerman pp 10963–10964 DOI: 10.1021/ja076952n

Boronic Acids in Saccharide Recognition By Tony D. James (University of Bath, U.K.), Marcus D. Phillips (University of Bath, U.K.), and Seiji Shinkai (Kyushu University, Fukuoka, Japan). Royal Society of Chemistry:  Cambridge. 2006. x + 174 pp. $189.00. ISBN 0-85404-537-6. John J. Lavigne p 10964 DOI: 10.1021/ja076942m

Issue 36

Atomic-Scale Detection of Organic Molecules Coupled to Single-Walled Carbon Nanotubes Sung You Hong, Gerard Tobias, Belén Ballesteros, Farid El Oualid, James C. Errey, Katie J. Doores, Angus I. Kirkland, Peter D. Nellist, Malcolm L. H. Green, and Benjamin G. Davis pp 10966–10967 DOI: 10.1021/ja069080i Supporting Info

Characterization of Polymorphs and Solid-State Reactions for Paramagnetic Systems by 13C Solid-State NMR and ab Initio Calculations Medhat A. Shaibat, Leah B. Casabianca, Nalinda P. Wickramasinghe, Stephen Guggenheim, Angel C. de Dios, and Yoshitaka Ishii pp 10968–10969 DOI: 10.1021/ja0703980 Supporting Info

Crystal Structure of a Cerium(IV) Bis(phosphate) Derivative Miguel A. Salvadó, Pilar Pertierra, Camino Trobajo, and José R. García pp 10970–10971 DOI: 10.1021/ja0710297 Supporting Info

Residual Dipolar Couplings by Off-Magic-Angle Spinning in Solid-State Nuclear Magnetic Resonance Spectroscopy Giuseppe Pileio, Ying Guo, Tran N. Pham, John M. Griffin, Malcolm H. Levitt, and Steven P. Brown pp 10972–10973 DOI: 10.1021/ja0721115 Supporting Info

Synthesis and Structure of Pentaorganostannate Having Five Carbon Substituents Masaichi Saito, Sanae Imaizumi, Tomoyuki Tajima, Kazuya Ishimura, and Shigeru Nagase pp 10974–10975 DOI: 10.1021/ja072478+ Supporting Info

Ion Motion in Conjugated Polyelectrolyte Electron Transporting Layers Corey Hoven, Renqiang Yang, Andres Garcia, Alan J. Heeger, Thuc-Quyen Nguyen, and Guillermo C. Bazan pp 10976–10977 DOI: 10.1021/ja072612q

Tangential Ligand-Induced Strain in Icosahedral Au13 Olga Guliamov, Anatoly I. Frenkel, Laurent D. Menard, Ralph G. Nuzzo, and Leeor Kronik pp 10978–10979 DOI: 10.1021/ja0725706 Supporting Info

Dopant Ion Concentration Dependence of Growth and Faceting of Manganese-Doped GaN Nanowires Pavle V. Radovanovic, Kevin G. Stamplecoskie, and Brent G. Pautler pp 10980–10981 DOI: 10.1021/ja073310r Supporting Info

Trace Level Cyclic Voltammetry Facilitated by Single-Walled Carbon Nanotube Network Electrodes Paolo Bertoncello, Jonathan P. Edgeworth, Julie V. Macpherson, and Patrick R. Unwin pp 10982–10983 DOI: 10.1021/ja073360w Supporting Info

Different Dynamics of Chiral and Racemic (l- and dl-) Serine Crystals:  Evidenced by Incoherent Inelastic Neutron and Raman Scattering Heloisa N. Bordallo, Boris A. Kolesov, Elena V. Boldyreva, and Fanni Juranyi pp 10984–10985 DOI: 10.1021/ja073351n Supporting Info

Self-Assembly of Chiral Luminescent Lanthanide Coordination Bundles Joseph P. Leonard, Paul Jensen, Thomas McCabe, John E. O'Brien, Robert D. Peacock, Paul E. Kruger, and Thorfinnur Gunnlaugsson pp 10986–10987 DOI: 10.1021/ja073049e Supporting Info

Enantioselective [3 + 2]-Cycloadditions Catalyzed by a Protected, Multifunctional Phosphine-Containing α-Amino Acid Bryan J. Cowen and Scott J. Miller pp 10988–10989 DOI: 10.1021/ja0734243 Supporting Info

Guest-Specific Function of a Flexible Undulating Channel in a 7,7,8,8-Tetracyano-p-quinodimethane Dimer-Based Porous Coordination Polymer Satoru Shimomura, Satoshi Horike, Ryotaro Matsuda, and Susumu Kitagawa pp 10990–10991 DOI: 10.1021/ja073505z Supporting Info

Detection and Memory of Nonracemic Molecules by a Racemic Host Polymer Film Anna Maria Buono, Ivano Immediata, Paola Rizzo, and Gaetano Guerra pp 10992–10993 DOI: 10.1021/ja0732936 Supporting Info

Dynamic Extension−Contraction Motion in Supramolecular Springs Ho-Joong Kim, Eunji Lee, Hye-seo Park, and Myongsoo Lee pp 10994–10995 DOI: 10.1021/ja073554b Supporting Info

Ultrafast Deactivation Channel for Thymine Dimerization Martial Boggio-Pasqua, Gerrit Groenhof, Lars V. Schäfer, Helmut Grubmüller, and Michael A. Robb pp 10996–10997 DOI: 10.1021/ja073628j Supporting Info

Understanding the Formation of N−H Tautomers from α-Substituted Pyridines:  Tautomerization of 2-Ethylpyridine Promoted by Osmium María L. Buil, Miguel A. Esteruelas, Karin Garcés, Montserrat Oliván, and Enrique Oñate pp 10998–10999 DOI: 10.1021/ja073673r Supporting Info

Regulating Gene Expression in Zebrafish Embryos Using Light-Activated, Negatively Charged Peptide Nucleic Acids XinJing Tang, Shingo Maegawa, Eric S. Weinberg, and Ivan J. Dmochowski pp 11000–11001 DOI: 10.1021/ja073723s Supporting Info

Probing the Cross-β Core Structure of Amyloid Fibrils by Hydrogen−Deuterium Exchange Deep Ultraviolet Resonance Raman Spectroscopy Ming Xu, Victor Shashilov, and Igor K. Lednev pp 11002–11003 DOI: 10.1021/ja073798w Supporting Info

Interflap Distances in HIV-1 Protease Determined by Pulsed EPR Measurements Luis Galiano, Marco Bonora, and Gail E. Fanucci pp 11004–11005 DOI: 10.1021/ja073684k Supporting Info

Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by Diruthenium Complexes Takashi Kawashima, Toshiro Takao, and Hiroharu Suzuki pp 11006–11007 DOI: 10.1021/ja074224u Supporting Info

Multiparameter Fluorescence Spectroscopy of Single Quantum Dot−Dye FRET Hybrids C. Shan Xu, Hahkjoon Kim, Haw Yang, and Carl C. Hayden pp 11008–11009 DOI: 10.1021/ja074279w Supporting Info

[2+2] Cycloaddition Reactions with a Tungsten-Stabilized 2H-Phenol Michael A. Todd, Michal Sabat, William H. Myers, and W. Dean Harman pp 11010–11011 DOI: 10.1021/ja0739279 Supporting Info

Detection of Picomole Amounts of Biological Substrates by para-Hydrogen-Enhanced NMR Methods in Conjunction with a Suitable Receptor Complex Nicholas J. Wood, James A. Brannigan, Simon B. Duckett, Sarah L. Heath, and Jane Wagstaff pp 11012–11013 DOI: 10.1021/ja074286k Supporting Info

Control of Bacterial Aggregation by Thermoresponsive Glycopolymers George Pasparakis, Alan Cockayne, and Cameron Alexander pp 11014–11015 DOI: 10.1021/ja074349z Supporting Info

Nonenzymatic Oxidative Steps Accompanying Action of the Cytochrome P450 Enzymes StaP and RebP in the Biosynthesis of Staurosporine and Rebeccamycin Annaleise R. Howard-Jones and Christopher T. Walsh pp 11016–11017 DOI: 10.1021/ja0743801 Supporting Info

Redox-Mediated Negative Differential Resistance Behavior from Metalloproteins Connected through Carbon Nanotube Nanogap Electrodes Qun Tang, Hye Kyung Moon, Yoonmi Lee, Seok Min Yoon, Hyun Jae Song, Hyunseob Lim, and Hee Cheul Choi pp 11018–11019 DOI: 10.1021/ja074412k Supporting Info

Octamethyl-octaundecylcyclo[8]pyrrole:  A Promising Sulfate Anion Extractant Leah R. Eller, Marcin Stpień, Christopher J. Fowler, Jeong Tae Lee, Jonathan L. Sessler, and Bruce A. Moyer pp 11020–11021 DOI: 10.1021/ja074568k Supporting Info

One-Pot Separation of Tea Components through Selective Adsorption on Pore-Engineered Nanocarbon, Carbon Nanocage Katsuhiko Ariga, Ajayan Vinu, Masahiko Miyahara, Jonathan P. Hill, and Toshiyuki Mori pp 11022–11023 DOI: 10.1021/ja074870t Supporting Info

Engineering a Monomeric Miniature Protein Abby M. Hodges and Alanna Schepartz pp 11024–11025 DOI: 10.1021/ja074859t Supporting Info

Palladium-Catalyzed [4 + 3] Intramolecular Cycloaddition of Alkylidenecyclopropanes and Dienes Moisés Gulías, Juan Durán, Fernando López, Luis Castedo, and Jose L. Mascareñas pp 11026–11027 DOI: 10.1021/ja0756467 Supporting Info

Formation of a Nickel−Methyl Species in Methyl-Coenzyme M Reductase, an Enzyme Catalyzing Methane Formation Na Yang, Markus Reiher, Mi Wang, Jeffrey Harmer, and Evert C. Duin pp 11028–11029 DOI: 10.1021/ja0734501 Supporting Info

Biochemical and Spectroscopic Studies of the Electronic Structure and Reactivity of a Methyl−Ni Species Formed on Methyl-Coenzyme M Reductase Mishtu Dey, Joshua Telser, Ryan C. Kunz, Nicholas S. Lees, Stephen W. Ragsdale, and Brian M. Hoffman pp 11030–11032 DOI: 10.1021/ja074556z Supporting Info

Direct Observation of Electrocatalytic Synergy Lin Zhuang, Jing Jin, and Héctor D. Abruña pp 11033–11035 DOI: 10.1021/ja0724792 Supporting Info

Facile Synthesis of Well-Defined Block Copolymers Containing Regioregular Poly(3-hexyl thiophene) via Anionic Macroinitiation Method and Their Self-Assembly Behavior Chi-An Dai, Wei-Che Yen, Yi-Huan Lee, Chun-Chi Ho, and Wei-Fang Su pp 11036–11038 DOI: 10.1021/ja0733991 Supporting Info

Oligomeric Electrolyte as a Multifunctional Gelator Masaru Yoshida, Nagatoshi Koumura, Yoshihiro Misawa, Nobuyuki Tamaoki, Hajime Matsumoto, Hajime Kawanami, Said Kazaoui, and Nobutsugu Minami pp 11039–11041 DOI: 10.1021/ja0738677 Supporting Info

Fully Synthetic Carbohydrate HIV Antigens Designed on the Logic of the 2G12 Antibody Isaac J. Krauss, Joseph G. Joyce, Adam C. Finnefrock, Hong C. Song, Vadim Y. Dudkin, Xudong Geng, J. David Warren, Michael Chastain, John W. Shiver, and Samuel J. Danishefsky pp 11042–11044 DOI: 10.1021/ja074804r Supporting Info

Vibrational Recognition of Adsorption Sites for CO on Platinum and Platinum−Ruthenium Surfaces Ismaila Dabo, Andrzej Wieckowski, and Nicola Marzari pp 11045–11052 DOI: 10.1021/ja067944u Supporting Info

Characterization of a Genuine Iron(V)−Nitrido Species by Nuclear Resonant Vibrational Spectroscopy Coupled to Density Functional Calculations Taras Petrenko, Serena DeBeer George, Núria Aliaga-Alcalde, Eckhard Bill, Bernd Mienert, Yuming Xiao, YiSong Guo, Wolfgang Sturhahn, Stephen P. Cramer, Karl Wieghardt, and Frank Neese pp 11053–11060 DOI: 10.1021/ja070792y Supporting Info

Transparent CoAl2O4 Hybrid Nano Pigment by Organic Ligand-Assisted Supercritical Water Dinesh Rangappa, Takashi Naka, Akitsugu Kondo, Masahiko Ishii, Toshikatsu Kobayashi, and Tadafumi Adschiri pp 11061–11066 DOI: 10.1021/ja0711009 Supporting Info

Specificity of Acyl Transfer from 2-Mercaptobenzamide Thioesters to the HIV-1 Nucleocapsid Protein Lisa M. Miller Jenkins, Toshiaki Hara, Stewart R. Durell, Ryo Hayashi, John K. Inman, Jean-Philip Piquemal, Nohad Gresh, and Ettore Appella pp 11067–11078 DOI: 10.1021/ja071254o Supporting Info

Calcium-Induced Phospholipid Ordering Depends on Surface Pressure Maria Sovago, George W. H. Wurpel, Marc Smits, Michiel Müller, and Mischa Bonn pp 11079–11084 DOI: 10.1021/ja071189i Supporting Info

Modeling [Fe−Fe] Hydrogenase:  Evidence for Bridging Carbonyl and Distal Iron Coordination Vacancy in an Electrocatalytically Competent Proton Reduction by an Iron Thiolate Assembly That Operates through Fe(0)−Fe(II) Levels Mun Hon Cheah, Cédric Tard, Stacey J. Borg, Xiaoming Liu, Saad K. Ibrahim, Christopher J. Pickett, and Stephen P. Best pp 11085–11092 DOI: 10.1021/ja071331f Supporting Info

Molecular Dynamics Computational Study of the 199Hg−199Hg NMR Spin−Spin Coupling Constants of [Hg−Hg−Hg]2+ in SO2 Solution Jochen Autschbach and Mariusz Sterzel pp 11093–11099 DOI: 10.1021/ja073166+ Supporting Info

DNA Polymerase β Catalysis:  Are Different Mechanisms Possible? Ian L. Alberts, Yanli Wang, and Tamar Schlick pp 11100–11110 DOI: 10.1021/ja071533b Supporting Info

Encapsidation of Nanoparticles by Red Clover Necrotic Mosaic Virus LiNa Loo, Richard H. Guenther, Steven A. Lommel, and Stefan Franzen pp 11111–11117 DOI: 10.1021/ja071896b Supporting Info

Terminal Gold-Oxo Complexes Rui Cao, Travis M. Anderson, Paula M. B. Piccoli, Arthur J. Schultz, Thomas F. Koetzle, Yurii V. Geletii, Elena Slonkina, Britt Hedman, Keith O. Hodgson, Kenneth I. Hardcastle, Xikui Fang, Martin L. Kirk, Sushilla Knottenbelt, Paul Kögerler, Djamaladdin G. Musaev, Keiji Morokuma, Masashi Takahashi, and Craig L. Hill pp 11118–11133 DOI: 10.1021/ja072456n Supporting Info

Design of Cationic Conjugated Polyelectrolytes for DNA Concentration Determination Chunyan Chi, Alexander Mikhailovsky, and Guillermo C. Bazan pp 11134–11145 DOI: 10.1021/ja072471s Supporting Info

Buffer-Assisted Proton-Coupled Electron Transfer in a Model Rhenium−Tyrosine Complex Hiroshi Ishikita, Alexander V. Soudackov, and Sharon Hammes-Schiffer pp 11146–11152 DOI: 10.1021/ja072708k Supporting Info

The Lanthanide Contraction Revisited Michael Seitz, Allen G. Oliver, and Kenneth N. Raymond pp 11153–11160 DOI: 10.1021/ja072750f Supporting Info

Brønsted/Lewis Acid Synergy in Dealuminated HY Zeolite:  A Combined Solid-State NMR and Theoretical Calculation Study Shenhui Li, Anmin Zheng, Yongchao Su, Hailu Zhang, Lei Chen, Jun Yang, Chaohui Ye, and Feng Deng pp 11161–11171 DOI: 10.1021/ja072767y Supporting Info

High-Enthalpy Hydrogen Adsorption in Cation-Exchanged Variants of the Microporous Metal−Organic Framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2 Mircea Dinc and Jeffrey R. Long pp 11172–11176 DOI: 10.1021/ja072871f Supporting Info

Quantitative Analysis of Carbohydrate−Protein Interactions Using Glycan Microarrays:  Determination of Surface and Solution Dissociation Constants Pi-Hui Liang, Sheng-Kai Wang, and Chi-Huey Wong pp 11177–11184 DOI: 10.1021/ja072931h Supporting Info

Human Telomeric DNA Forms Parallel-Stranded Intramolecular G-Quadruplex in K+ Solution under Molecular Crowding Condition Yong Xue, Zhong-yuan Kan, Quan Wang, Yuan Yao, Jiang Liu, Yu-hua Hao, and Zheng Tan pp 11185–11191 DOI: 10.1021/ja0730462

Topotactic Oxidative and Reductive Control of the Structures and Properties of Layered Manganese Oxychalcogenides Geoffrey Hyett, Nicolas Barrier, Simon J. Clarke, and Joke Hadermann pp 11192–11201 DOI: 10.1021/ja073048m Supporting Info

Nitrosonium Complexes of Resorc[4]arenes:  Spectral, Kinetic, and Theoretical Studies Bruno Botta, Ilaria D'Acquarica, Giuliano Delle Monache, Laura Nevola, Danila Tullo, Franco Ugozzoli, and Marco Pierini pp 11202–11212 DOI: 10.1021/ja072855i Supporting Info

An Oxidosqualene Cyclase Makes Numerous Products by Diverse Mechanisms:  A Challenge to Prevailing Concepts of Triterpene Biosynthesis Silvia Lodeiro, Quanbo Xiong, William K. Wilson, Mariya D. Kolesnikova, Carl S. Onak, and Seiichi P. T. Matsuda pp 11213–11222 DOI: 10.1021/ja073133u Supporting Info

Using Measurements of Anchoring Energies of Liquid Crystals on Surfaces To Quantify Proteins Captured by Immobilized Ligands Thimmaiah Govindaraju, Paul J. Bertics, Ronald T. Raines, and Nicholas L. Abbott pp 11223–11231 DOI: 10.1021/ja073203x Supporting Info

Refolding Foldamers:  Triazene-Arylene Oligomers That Change Shape with Chemical Stimuli Simin Liu, Peter Y. Zavalij, Yiu-Fai Lam, and Lyle Isaacs pp 11232–11241 DOI: 10.1021/ja073320s Supporting Info

Conversion of Cyclic Vinyl Sulfones to Transposed Vinyl Phosphonates Mohammad N. Noshi, Ahmad El-awa, Eduardo Torres, and Philip L. Fuchs pp 11242–11247 DOI: 10.1021/ja072890p Supporting Info

Unraveling Solvent-Driven Equilibria between α- and 310-Helices through an Integrated Spin Labeling and Computational Approach Silvia Carlotto, Paola Cimino, Mirco Zerbetto, Lorenzo Franco, Carlo Corvaja, Marco Crisma, Fernando Formaggio, Claudio Toniolo, Antonino Polimeno, and Vincenzo Barone pp 11248–11258 DOI: 10.1021/ja073516s Supporting Info

C−H Bond Activation by Hyperconjugation with Al−C Bonds and by Chelating Coordination of the Hydride Ion Werner Uhl, Andrej Vinogradov, and Stefan Grimme pp 11259–11264 DOI: 10.1021/ja073657u Supporting Info

Expanding the Structural Diversity of Self-Assembling Dendrons and Supramolecular Dendrimers via Complex Building Blocks Virgil Percec, Betty C. Won, Mihai Peterca, and Paul A. Heiney pp 11265–11278 DOI: 10.1021/ja073714j Supporting Info

Conformational Adaptation and Selective Adatom Capturing of Tetrapyridyl-porphyrin Molecules on a Copper (111) Surface Willi Auwärter, Florian Klappenberger, Alexander Weber-Bargioni, Agustin Schiffrin, Thomas Strunskus, Christof Wöll, Yan Pennec, Andreas Riemann, and Johannes V. Barth pp 11279–11285 DOI: 10.1021/ja071572n

Genetic Engineering of the Heme Pocket in Human Serum Albumin:  Modulation of O2 Binding of Iron Protoporphyrin IX by Variation of Distal Amino Acids Teruyuki Komatsu, Akito Nakagawa, Patricia A. Zunszain, Stephen Curry, and Eishun Tsuchida pp 11286–11295 DOI: 10.1021/ja074179q Supporting Info

Why Are Ionic Liquids Liquid? A Simple Explanation Based on Lattice and Solvation Energies [J. Am. Chem. Soc. 2006, 128, 13427−13434]. Ingo Krossing, John M. Slattery, Corinne Daguenet, Paul J. Dyson, Alla Oleinikova, and Hermann Weingärtner p 11296 DOI: 10.1021/ja073579a Supporting Info

A β-Diketiminate-Supported Boron Dication [J. Am. Chem. Soc. 2007, 129, 8436−8437]. Dragoslav Vidovic, Michael Findlater, and Alan H. Cowley p 11296 DOI: 10.1021/ja075594l

Issue 37

Hydrogen-Bonding and π−π Base-Stacking Interactions Are Coupled in DNA, As Suggested by Calculated and Experimental Trans-Hbond Deuterium Isotope Shifts Marlon N. Manalo, Lisa M. Pérez, and Andy LiWang pp 11298–11299 DOI: 10.1021/ja0692940 Supporting Info

A Single-Point Mutation Converts the Highly Amyloidogenic Human Islet Amyloid Polypeptide into a Potent Fibrillization Inhibitor Andisheh Abedini, Fanling Meng, and Daniel P. Raleigh pp 11300–11301 DOI: 10.1021/ja072157y Supporting Info

Superconducting MgB2 Nanohelices Grown on Various Substrates Manashi Nath and B. A. Parkinson pp 11302–11303 DOI: 10.1021/ja072475x Supporting Info

Advancing Decal-Transfer Lithography with a Reusable PDMS-Coated Nanoscale Stamp Mihee Kim and Youn Sang Kim pp 11304–11305 DOI: 10.1021/ja072981m Supporting Info

Identification of a Selective Small-Molecule Ligand for HIV-1 Frameshift-Inducing Stem-Loop RNA from an 11,325 Member Resin Bound Dynamic Combinatorial Library Brian R. McNaughton, Peter C. Gareiss, and Benjamin L. Miller pp 11306–11307 DOI: 10.1021/ja072114h Supporting Info

Ligand-Directed Dynamics of Adenine Riboswitch Conformers Saman Eskandari, Oksana Prychyna, Jessica Leung, Dijana Avdic, and Melanie A. O'Neill pp 11308–11309 DOI: 10.1021/ja073159l Supporting Info

Poly(3,4-ethylenedioxythiophene)−Semiconductor Nanoparticle Composite Thin Films Tethered to Indium Tin Oxide Substrates via Electropolymerization R. Clayton Shallcross, Gemma D. D'Ambruoso, Bryan D. Korth, H. K. Hall Jr., Zhiping Zheng, Jeffrey Pyun, and Neal R. Armstrong pp 11310–11311 DOI: 10.1021/ja073332d Supporting Info

Infrared Multiple Photon Dissociation Spectroscopy as Structural Confirmation for GlyGlyGlyH+ and AlaAlaAlaH+ in the Gas Phase. Evidence for Amide Oxygen as the Protonation Site Ronghu Wu and Terry B. McMahon pp 11312–11313 DOI: 10.1021/ja0734492 Supporting Info

Three-Dimensional Architectures for Highly Stable Pure Blue Emission Jia Luo, Yan Zhou, Zhi-Qiang Niu, Qi-Feng Zhou, Yuguo Ma, and Jian Pei pp 11314–11315 DOI: 10.1021/ja073466r Supporting Info

Specificity of Translation for N-Alkyl Amino Acids Baolin Zhang, Zhongping Tan, Lucas Gartenmann Dickson, Madhavi N. L. Nalam, Virginia W. Cornish, and Anthony C. Forster pp 11316–11317 DOI: 10.1021/ja073487l Supporting Info

Carbon Dots for Multiphoton Bioimaging Li Cao, Xin Wang, Mohammed J. Meziani, Fushen Lu, Haifang Wang, Pengju G. Luo, Yi Lin, Barbara A. Harruff, L. Monica Veca, Davoy Murray, Su-Yuan Xie, and Ya-Ping Sun pp 11318–11319 DOI: 10.1021/ja073527l Supporting Info

Solid-State NMR Structural Measurements on the Membrane-Associated Influenza Fusion Protein Ectodomain Jaime Curtis-Fisk, Casey Preston, Zhaoxiong Zheng, R. Mark Worden, and David P. Weliky pp 11320–11321 DOI: 10.1021/ja073644g Supporting Info

Origin of Magic Stability of Thiolated Gold Clusters:  A Case Study on Au25(SC6H13)18 Yuichi Negishi, Nirmalya K. Chaki, Yukatsu Shichibu, Robert L. Whetten, and Tatsuya Tsukuda pp 11322–11323 DOI: 10.1021/ja073580+ Supporting Info

Photopolymerization of Gold Nanoparticles:  Size-Related Charge Separation and Emission Xichen Cai, Kelechi C. Anyaogu, and Douglas C. Neckers pp 11324–11325 DOI: 10.1021/ja073899u Supporting Info

Modulating Protein Alignment in a Liquid-Crystalline Medium through Conservative Mutagenesis Lishan Yao and Ad Bax pp 11326–11327 DOI: 10.1021/ja073937+ Supporting Info

Dissociation of DNA-Histone Assemblies Resulting from Protein Side-Chain Functionalization Mitchell P. Maddox III, Christine M. Colton, Matthew J. Patterson, and Debra L. Mohler pp 11328–11329 DOI: 10.1021/ja073683s Supporting Info

Alternating Copolymerization of Epoxides and Cyclic Anhydrides:  An Improved Route to Aliphatic Polyesters Ryan C. Jeske, Angela M. DiCiccio, and Geoffrey W. Coates pp 11330–11331 DOI: 10.1021/ja0737568 Supporting Info

Self-Assembly of Highly Oriented Lamellar Nanoparticle-Phospholipid Nanocomposites on Solid Surfaces Bing Yuan, Li-Li Xing, Yu-Dong Zhang, Ying Lu, Zhen-Hong Mai, and Ming Li pp 11332–11333 DOI: 10.1021/ja074235n Supporting Info

Direct Spectroscopic Evidence for a High-Spin Fe(IV) Intermediate in Tyrosine Hydroxylase Bekir E. Eser, Eric W. Barr, Patrick A. Frantom, Lana Saleh, J. Martin Bollinger, Jr., Carsten Krebs, and Paul F. Fitzpatrick pp 11334–11335 DOI: 10.1021/ja074446s Supporting Info

Chiral Counteranions in Asymmetric Transition-Metal Catalysis:  Highly Enantioselective Pd/Brønsted Acid-Catalyzed Direct α-Allylation of Aldehydes Santanu Mukherjee and Benjamin List pp 11336–11337 DOI: 10.1021/ja074678r Supporting Info

Reactions of Hydrido(hydrosilylene)tungsten Complexes with α,β-Unsaturated Carbonyl Compounds:  Selective Formation of (η3-Siloxyallyl)tungsten Complexes Takahito Watanabe, Hisako Hashimoto, and Hiromi Tobita pp 11338–11339 DOI: 10.1021/ja074629e Supporting Info

Intramolecular Heck Reactions of Unactivated Alkyl Halides Luke Firmansjah and Gregory C. Fu pp 11340–11341 DOI: 10.1021/ja075245r Supporting Info

En Route to an Efficient Catalytic Asymmetric Synthesis of AS-3201 Tomoyuki Mashiko, Keiichi Hara, Daisuke Tanaka, Yuji Fujiwara, Naoya Kumagai, and Masakatsu Shibasaki pp 11342–11343 DOI: 10.1021/ja0752585 Supporting Info

Peripheral Fabrications of a Bis-Gold(III) Complex of [26]Hexaphyrin(1.1.1.1.1.1) and Aromatic versus Antiaromatic Effect on Two-Photon Absorption Cross Section Shigeki Mori, Kil Suk Kim, Zin Seok Yoon, Su Bum Noh, Dongho Kim, and Atsuhiro Osuka pp 11344–11345 DOI: 10.1021/ja0744908 Supporting Info

Detecting Binding Interactions Using Microarrays of Natural Product Extracts Katja Schmitz, Stephen J. Haggarty, Olivia M. McPherson, Jon Clardy, and Angela N. Koehler pp 11346–11347 DOI: 10.1021/ja073965s Supporting Info

The Herringbone Helix:  A Noncanonical Folding in Aromatic−Aliphatic Peptides Nicolas Delsuc, Frédéric Godde, Brice Kauffmann, Jean-Michel Léger, and Ivan Huc pp 11348–11349 DOI: 10.1021/ja074285s Supporting Info

Formation of Nanoparticles by Intramolecular Cross-Linking:  Following the Reaction Progress of Single Polymer Chains by Atomic Force Microscopy Anna E. Cherian, Frank C. Sun, Sergei S. Sheiko, and Geoffrey W. Coates pp 11350–11351 DOI: 10.1021/ja074301l Supporting Info

Direct Electrochemical Evaluation of Plasma Membrane Cholesterol in Live Mammalian Cells Dechen Jiang, Anando Devadoss, M. Simona Palencsár, Danjun Fang, Nicole M. White, Thomas J. Kelley, Jonathan D. Smith, and James D. Burgess pp 11352–11353 DOI: 10.1021/ja074373c Supporting Info

SnTe Nanocrystals:  A New Example of Narrow-Gap Semiconductor Quantum Dots Maksym V. Kovalenko, Wolfgang Heiss, Elena V. Shevchenko, Jong-Soo Lee, Harald Schwinghammer, A. Paul Alivisatos, and Dmitri V. Talapin pp 11354–11355 DOI: 10.1021/ja074481z Supporting Info

Ultrasensitive Detection of Enzymatic Activity with Nanowire Electrodes Marcel A. Roberts and Shana O. Kelley pp 11356–11357 DOI: 10.1021/ja074546y Supporting Info

PtCl2-Catalyzed Rapid Access to Tetracyclic 2,3-Indoline-Fused Cyclopentenes:  Reactivity Divergent from Cationic Au(I) Catalysis and Synthetic Potential Guozhu Zhang, Vincent J. Catalano, and Liming Zhang pp 11358–11359 DOI: 10.1021/ja074536x Supporting Info

Metal-Mediated J Coupling in DNA Base Pairs:  Relativistic DFT Predictions Alessandro Bagno and Giacomo Saielli pp 11360–11361 DOI: 10.1021/ja0746417 Supporting Info

NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates Tobias Gärtner, Wolfram Henze, and Ruth M. Gschwind pp 11362–11363 DOI: 10.1021/ja074788y Supporting Info

Ion-Induced Nucleation in Solution:  Promotion of Solute Nucleation in Charged Levitated Droplets Neil D. Draper, Samuel F. Bakhoum, Allen E. Haddrell, and George R. Agnes pp 11364–11377 DOI: 10.1021/ja067094i

Metal-ion-dependent GFP Emission in Vivo by Combining a Circularly Permutated Green Fluorescent Protein with an Engineered Metal-Ion-Binding Coiled-coil Toshihisa Mizuno, Kaori Murao, Yoichi Tanabe, Masayuki Oda, and Toshiki Tanaka pp 11378–11383 DOI: 10.1021/ja0685102

Photochemistry of Neutral Isonitrile Gold(I) Complexes:  Modulation of Photoreactivity by Aurophilicity and π-Acceptance Ability Oussama Elbjeirami and Mohammad A. Omary pp 11384–11393 DOI: 10.1021/ja0703933 Supporting Info

Characterization of Protein Conformational States by Normal-Mode Frequencies Benjamin A. Hall, Samantha L. Kaye, Andy Pang, Rafael Perera, and Philip C. Biggin pp 11394–11401 DOI: 10.1021/ja071797y Supporting Info

Organic Bonding to Silicon via a Carbonyl Group:  New Insights from Atomic-Scale Images Steven R. Schofield, Sherin A. Saraireh, Phillip V. Smith, Marian W. Radny, and Bruce V. King pp 11402–11407 DOI: 10.1021/ja0719069

Dramatic Influence of the Orientation of Linker between Hydrophilic and Hydrophobic Lipid Moiety in Liposomal Gene Delivery Mukthavaram Rajesh, Joyeeta Sen, Marepally Srujan, Koushik Mukherjee, Bojja Sreedhar, and Arabinda Chaudhuri pp 11408–11420 DOI: 10.1021/ja0704683 Supporting Info

Water-Soluble Phosphinothiols for Traceless Staudinger Ligation and Integration with Expressed Protein Ligation Annie Tam, Matthew B. Soellner, and Ronald T. Raines pp 11421–11430 DOI: 10.1021/ja073204p Supporting Info

Brønsted Acid Catalyzed Formal Insertion of Isocyanides into a C−O Bond of Acetals Mamoru Tobisu, Aki Kitajima, Sachiko Yoshioka, Isao Hyodo, Masayuki Oshita, and Naoto Chatani pp 11431–11437 DOI: 10.1021/ja073286h Supporting Info

Phosphate-Mediated Arginine Insertion into Lipid Membranes and Pore Formation by a Cationic Membrane Peptide from Solid-State NMR Ming Tang, Alan J. Waring, and Mei Hong pp 11438–11446 DOI: 10.1021/ja072511s Supporting Info

The Electronic Structure of the H-Cluster in the [FeFe]-Hydrogenase from Desulfovibrio desulfuricans: A Q-band 57Fe-ENDOR and HYSCORE Study Alexey Silakov, Eduard J. Reijerse, Simon P. J. Albracht, E. Claude Hatchikian, and Wolfgang Lubitz pp 11447–11458 DOI: 10.1021/ja072592s

Making Amines Strong Bases:  Thermodynamic Stabilization of Protonated Guests in a Highly-Charged Supramolecular Host1 Michael D. Pluth, Robert G. Bergman, and Kenneth N. Raymond pp 11459–11467 DOI: 10.1021/ja072654e Supporting Info

An Exchange-Free Measure of 15N Transverse Relaxation:  An NMR Spectroscopy Application to the Study of a Folding Intermediate with Pervasive Chemical Exchange D. Flemming Hansen, Daiwen Yang, Haniqiao Feng, Zheng Zhou, Silke Wiesner, Yawen Bai, and Lewis E. Kay pp 11468–11479 DOI: 10.1021/ja072717t Supporting Info

Modular Total Chemical Synthesis of a Human Immunodeficiency Virus Type 1 Protease Erik C. B. Johnson, Enrico Malito, Yuequan Shen, Dan Rich, Wei-Jen Tang, and Stephen B. H. Kent pp 11480–11490 DOI: 10.1021/ja072870n Supporting Info

Photophysical and Structural Properties of Cyanoruthenate Complexes of Hexaazatriphenylene Juan-Manuel Herrera, Simon J. A. Pope, Anthony J. H. M. Meijer, Timothy L. Easun, Harry Adams, Wassim Z. Alsindi, Xue-Zhong Sun, Michael W. George, Stephen Faulkner, and Michael D. Ward pp 11491–11504 DOI: 10.1021/ja072672w Supporting Info

Hydrogen Atom Transfer Reactions of Imido Manganese(V) Corrole:  One Reaction with Two Mechanistic Pathways Michael J. Zdilla, Jennifer L. Dexheimer, and Mahdi M. Abu-Omar pp 11505–11511 DOI: 10.1021/ja073027s Supporting Info

Structure, Vibrational Analysis, and Insights into Host−Guest Interactions in As-Synthesized Pure Silica ITQ-12 Zeolite by Periodic B3LYP Calculations Claudio Marcelo Zicovich-Wilson, María Luisa San-Román, Miguel Angel Camblor, Fabien Pascale, and José Sergio Durand-Niconoff pp 11512–11523 DOI: 10.1021/ja0730361 Supporting Info

Trapping of a Dopaquinone Intermediate in the TPQ Cofactor Biogenesis in a Copper-Containing Amine Oxidase from Arthrobacter globiformis Robyn H. Moore, M. Ashley Spies, Matthew B. Culpepper, Takeshi Murakawa, Shun Hirota, Toshihide Okajima, Katsuyuki Tanizawa, and Minae Mure pp 11524–11534 DOI: 10.1021/ja0731165 Supporting Info

Thermally Activated Electron Transport in Single Redox Molecules Xiulan Li, Joshua Hihath, Fang Chen, Takuya Masuda, Ling Zang, and Nongjian Tao pp 11535–11542 DOI: 10.1021/ja072990v Supporting Info

Synthetic Analogues of Glycosylphosphatidylinositol-Anchored Proteins and Their Behavior in Supported Lipid Bilayers Margot G. Paulick, Amber R. Wise, Martin B. Forstner, Jay T. Groves, and Carolyn R. Bertozzi pp 11543–11550 DOI: 10.1021/ja073271j Supporting Info

Electrochemical, Spectroscopic, and DFT Study of C60(CF3)n Frontier Orbitals (n = 2−18):  The Link between Double Bonds in Pentagons and Reduction Potentials Alexey A. Popov, Ivan E. Kareev, Natalia B. Shustova, Evgeny B. Stukalin, Sergey F. Lebedkin, Konrad Seppelt, Steven H. Strauss, Olga V. Boltalina, and Lothar Dunsch pp 11551–11568 DOI: 10.1021/ja073181e Supporting Info

Mechanism of Water Photooxidation Reaction at Atomically Flat TiO2 (Rutile) (110) and (100) Surfaces:  Dependence on Solution pH Akihito Imanishi, Tomoaki Okamura, Naomichi Ohashi, Ryuhei Nakamura, and Yoshihiro Nakato pp 11569–11578 DOI: 10.1021/ja073206+

Molecular Recognition and Screening Using a 15N Group Selective STD NMR Method Katalin E. Kövér, Patrick Groves, Jesús Jiménez-Barbero, and Gyula Batta pp 11579–11582 DOI: 10.1021/ja073291l

Scope and Mechanism of Enantioselective Michael Additions of 1,3-Dicarbonyl Compounds to Nitroalkenes Catalyzed by Nickel(II)−Diamine Complexes David A. Evans, Shizue Mito, and Daniel Seidel pp 11583–11592 DOI: 10.1021/ja0735913 Supporting Info

Dendrimer-Mediated Transfer Printing of DNA and RNA Microarrays Dorota I. Rozkiewicz, Wim Brugman, Ron M. Kerkhoven, Bart Jan Ravoo, and David N. Reinhoudt pp 11593–11599 DOI: 10.1021/ja073574d

trans-RhCl(CO)(PPh3)2-Catalyzed Monomeric and Dimeric Cycloisomerization of Propargylic 2,3-Dienoates. Establishment of α,β-Unsaturated δ-Lactone Rings by Cyclometallation Xuefeng Jiang and Shengming Ma pp 11600–11607 DOI: 10.1021/ja073582u Supporting Info

Tetrahedral Zinc Complexes with Liquid Crystalline and Luminescent Properties:  Interplay Between Nonconventional Molecular Shapes and Supramolecular Mesomorphic Order Emma Cavero, Santiago Uriel, Pilar Romero, José Luis Serrano, and Raquel Giménez pp 11608–11618 DOI: 10.1021/ja073639c Supporting Info

Nanosized (μ12-Pt)Pd164-xPtx(CO)72(PPh3)20 (x ≈ 7) Containing Pt-Centered Four-Shell 165-Atom Pd−Pt Core with Unprecedented Intershell Bridging Carbonyl Ligands:  Comparative Analysis of Icosahedral Shell-Growth Patterns with Geometrically Related Pd145(CO)x(PEt3)30 (x ≈ 60) Containing Capped Three-Shell Pd145 Core Evgueni G. Mednikov, Matthew C. Jewell, and Lawrence F. Dahl pp 11619–11630 DOI: 10.1021/ja073945q Supporting Info

Rh-Mediated Polymerization of Carbenes:  Mechanism and Stereoregulation Erica Jellema, Peter H. M. Budzelaar, Joost N. H. Reek, and Bas de Bruin pp 11631–11641 DOI: 10.1021/ja073897+ Supporting Info

Rapid Three-Step Cleavage of RNA and DNA Model Systems Promoted by a Dinuclear Cu(II) Complex in Methanol. Energetic Origins of the Catalytic Efficacy Zhong-Lin Lu, C. Tony Liu, Alexei A. Neverov, and R. Stan Brown pp 11642–11652 DOI: 10.1021/ja073780l Supporting Info

Paclitaxel-Functionalized Gold Nanoparticles Jacob D. Gibson, Bishnu P. Khanal, and Eugene R. Zubarev pp 11653–11661 DOI: 10.1021/ja075181k Supporting Info

A Meta Effect in Organic Photochemistry? The Case of SN1 Reactions in Methoxyphenyl Derivatives [J. Am. Chem. Soc. 2007, 129, 5605−5611]. Valentina Dichiarante, Daniele Dondi, Stefano Protti, Maurizio Fagnoni, and Angelo Albini p 11662 DOI: 10.1021/ja075050j

Thermodynamics of Xenon Binding to Cryptophane in Water and Human Plasma [J. Am. Chem. Soc. 2007, 129, 9262−9263]. P. Aru Hill, Qian Wei, Roderic G. Eckenhoff, and Ivan J. Dmochowski p 11662 DOI: 10.1021/ja075845q

A Class of Luminescent Cyclometalated Alkynylgold(III) Complexes:  Synthesis, Characterization, and Electrochemical, Photophysical, and Computational Studies of [Au(CNC)(CCR)] (CNC = κ3C,N,C Bis-cyclometalated 2,6-Diphenylpyridyl) [J. Am. Chem. Soc. 2007, 129, 4350−4365]. Keith Man-Chung Wong, Ling-Ling Hung, Wai Han Lam, Nianyong Zhu, and Vivian Wing-Wah Yam* p 11662 DOI: 10.1021/ja0768993

Issue 38

Nucleolipoplexes:  A New Paradigm for Phospholipid Bilayer−Nucleic Acid Interactions Silvia Milani, Francesca Baldelli Bombelli, Debora Berti, and Piero Baglioni pp 11664–11665 DOI: 10.1021/ja0714134 Supporting Info

A Rhodamine-Based Fluorescent Probe Containing a Se−N Bond for Detecting Thiols and Its Application in Living Cells Bo Tang, Yanlong Xing, Ping Li, Ning Zhang, Fabiao Yu, and Guiwen Yang pp 11666–11667 DOI: 10.1021/ja072572q Supporting Info

Keto-Enol Driven Assembly of Methyl Pyruvate on Pt(111) Stéphane Lavoie, Marc-André Laliberté, Gautier Mahieu, Vincent Demers-Carpentier, and Peter McBreen pp 11668–11669 DOI: 10.1021/ja072638h Supporting Info

Effects of Glycosylation of (2S,4R)-4-Hydroxyproline on the Conformation, Kinetics, and Thermodynamics of Prolyl Amide Isomerization Neil W. Owens, Craig Braun, Joe D. O'Neil, Kirk Marat, and Frank Schweizer pp 11670–11671 DOI: 10.1021/ja073488d Supporting Info

A Remodelled Protease That Cleaves Phosphotyrosine Substrates Zachary A. Knight, Jennifer L. Garrison, Karina Chan, David S. King, and Kevan M. Shokat pp 11672–11673 DOI: 10.1021/ja073875n Supporting Info

A Triphenylamine-Containing Donor−Acceptor Molecule for Stable, Reversible, Ultrahigh Density Data Storage Yanli Shang, Yongqiang Wen, Shaolu Li, Shixuan Du, Xiaobo He, Li Cai, Yingfeng Li, Lianming Yang, Hongjun Gao, and Yanlin Song pp 11674–11675 DOI: 10.1021/ja074226e Supporting Info

Radical Trifluoromethylation of Sc3N@C80 Natalia B. Shustova, Alexey A. Popov, Mary A. Mackey, Curtis E. Coumbe, J. Paige Phillips, Steven Stevenson, Steven H. Strauss, and Olga V. Boltalina pp 11676–11677 DOI: 10.1021/ja074332g

1-Chloro-4,5,6,7-tetraalkyldihydroindene Formation by Reaction of Bis(cyclopentadienyl)titanacyclopentadienes with Titanium Chloride Tamotsu Takahashi, Zhiyi Song, Kimihiko Sato, Yuichi Kuzuba, Kiyohiko Nakajima, and Ken-ichiro Kanno pp 11678–11679 DOI: 10.1021/ja074180p Supporting Info

Resting State and Kinetic Studies on the Asymmetric Allylic Substitutions Catalyzed by Iridium−Phosphoramidite Complexes Dean Marković and John F. Hartwig pp 11680–11681 DOI: 10.1021/ja074584h Supporting Info

Programmed Dynamic Covalent Assembly of Unsymmetrical Macrocycles C. Scott Hartley and Jeffrey S. Moore pp 11682–11683 DOI: 10.1021/ja0745963 Supporting Info

Solution-Processible n-Channel Organic Field-Effect Transistors Based on Dicyanomethylene-Substituted Terthienoquinoid Derivative Sayuri Handa, Eigo Miyazaki, Kazuo Takimiya, and Yoshihito Kunugi pp 11684–11685 DOI: 10.1021/ja074607s Supporting Info

Tandem Reductive Perfluoroalkylation of Esters with Perfluoroalkyl Titanate-Type Reagents Koichi Mikami, Tatsushi Murase, and Yoshimitsu Itoh pp 11686–11687 DOI: 10.1021/ja074642z Supporting Info

Catalytic Asymmetric Diamination of Conjugated Dienes and Triene Haifeng Du, Weicheng Yuan, Baoguo Zhao, and Yian Shi pp 11688–11689 DOI: 10.1021/ja074698t Supporting Info

Catalytic Asymmetric [4 + 2] Cycloadditions of Ketenes and N-Thioacyl Imines:  Alternatives for Direct Mannich Reactions of Enolizable Imines Xuan Xu, Kan Wang, and Scott G. Nelson pp 11690–11691 DOI: 10.1021/ja074845n Supporting Info

A New Approach to Anodic Substitution Reaction Using Parallel Laminar Flow in a Micro-Flow Reactor Daisuke Horii, Toshio Fuchigami, and Mahito Atobe pp 11692–11693 DOI: 10.1021/ja075180s Supporting Info

A Silicon-Based Approach to Oligoarenes by Iterative Cross-Coupling Reactions of Halogenated Organo[(2-hydroxymethyl)phenyl]dimethylsilanes Yoshiaki Nakao, Jinshui Chen, Masaaki Tanaka, and Tamejiro Hiyama pp 11694–11695 DOI: 10.1021/ja074728s Supporting Info

Design and Synthesis of Polymetallic Complexes Based on meso-Calix[4]pyrrole:  Platforms for Multielectron Chemistry Luciano Cuesta, Dustin Gross, Vincent M. Lynch, Zhongping Ou, Wiroaj Kajonkijya, Kei Ohkubo, Shunichi Fukuzumi, Karl M. Kadish, and Jonathan L. Sessler pp 11696–11697 DOI: 10.1021/ja075613r Supporting Info

Selective Transport of Water Mediated by Porous Dendritic Dipeptides Mark S. Kaucher, Mihai Peterca, Andrés E. Dulcey, Anthony J. Kim, Sergei A. Vinogradov, Danniel A. Hammer, Paul A. Heiney, and Virgil Percec pp 11698–11699 DOI: 10.1021/ja076066c Supporting Info

Long Distance Electron-Transfer Mechanism in Peptidylglycine α-Hydroxylating Monooxygenase:  A Perfect Fitting for a Water Bridge Aurélien de la Lande, Sergio Martí, Olivier Parisel, and Vicent Moliner pp 11700–11707 DOI: 10.1021/ja070329l Supporting Info

Type-II Core/Shell CdS/ZnSe Nanocrystals:  Synthesis, Electronic Structures, and Spectroscopic Properties Sergei A. Ivanov, Andrei Piryatinski, Jagjit Nanda, Sergei Tretiak, Kevin R. Zavadil, William O. Wallace, Don Werder, and Victor I. Klimov pp 11708–11719 DOI: 10.1021/ja068351m Supporting Info

Time-Resolved Studies of Water Dynamics and Proton Transfer at the Alumina−Air Interface Sophie Le Caër, D. Jason Palmer, Manuela Lima, Jean Philippe Renault, Georges Vigneron, Roberto Righini, and Stanislas Pommeret pp 11720–11729 DOI: 10.1021/ja0691730 Supporting Info

The Hydrogen-Bonding Network in Heme Oxygenase Also Functions as a Modulator of Enzyme Dynamics:  Chaotic Motions upon Disrupting the H-Bond Network in Heme Oxygenase from Pseudomonas aeruginosa Juan Carlos Rodrguez, Yuhong Zeng, Angela Wilks, and Mario Rivera pp 11730–11742 DOI: 10.1021/ja072405q Supporting Info

Electron-Deficient N-Heteroaromatic Linkers for the Elaboration of Large, Soluble Polycyclic Aromatic Hydrocarbons and Their Use in the Synthesis of Some Very Large Transition Metal Complexes Yulia Fogel, Marcel Kastler, Zhaohui Wang, Denis Andrienko, Graham J. Bodwell, and Klaus Müllen pp 11743–11749 DOI: 10.1021/ja072521t Supporting Info

Ruthenium Catalyzed Decarbonylative Arylation at sp3 Carbon Centers in Pyrrolidine and Piperidine Heterocycles Denis V. Gribkov, Stefan J. Pastine, Michael Schnürch, and Dalibor Sames pp 11750–11755 DOI: 10.1021/ja072577n Supporting Info

Synthesis and Glycosylation of a Series of 6-Mono-, Di-, and Trifluoro S-Phenyl 2,3,4-Tri-O-benzyl-thiorhamnopyranosides. Effect of the Fluorine Substituents on Glycosylation Stereoselectivity David Crich and Olga Vinogradova pp 11756–11765 DOI: 10.1021/ja0730258 Supporting Info

Single Ion-Channel Recordings Using Glass Nanopore Membranes Ryan J. White, Eric N. Ervin, Tinglu Yang, Xin Chen, Susan Daniel, Paul S. Cremer, and Henry S. White pp 11766–11775 DOI: 10.1021/ja073174q

Integrated Magnetic Bionanocomposites through Nanoparticle-Mediated Assembly of Ferritin Sudhanshu Srivastava, Bappaditya Samanta, Brian J. Jordan, Rui Hong, Qijun Xiao, Mark T. Tuominen, and Vincent M. Rotello pp 11776–11780 DOI: 10.1021/ja073163x Supporting Info

Total Synthesis of (+)-Frondosin A. Application of the Ru-Catalyzed [5+2] Cycloaddition Barry M. Trost, Yimin Hu, and Daniel B. Horne pp 11781–11790 DOI: 10.1021/ja073272b Supporting Info

Proton-Detected Solid-State NMR Spectroscopy of Fully Protonated Proteins at 40 kHz Magic-Angle Spinning Donghua H. Zhou, Gautam Shah, Mircea Cormos, Charles Mullen, Dennis Sandoz, and Chad M. Rienstra pp 11791–11801 DOI: 10.1021/ja073462m Supporting Info

Diketopiperazines as a Tool for the Study of Transport across the Blood−Brain Barrier (BBB) and Their Potential Use as BBB-Shuttles Meritxell Teixidó, Esther Zurita, Morteza Malakoutikhah, Teresa Tarragó, and Ernest Giralt pp 11802–11813 DOI: 10.1021/ja073522o Supporting Info

Conformation-Specific Spectroscopy and Photodissociation of Cold, Protonated Tyrosine and Phenylalanine Jaime A. Stearns, Sébastien Mercier, Caroline Seaiby, Monia Guidi, Oleg V. Boyarkin, and Thomas R. Rizzo pp 11814–11820 DOI: 10.1021/ja0736010 Supporting Info

Intramolecular Trapping of an Intermediate in the Reduction of Imines by a Hydroxycyclopentadienyl Ruthenium Hydride:  Support for a Concerted Outer Sphere Mechanism Charles P. Casey, Timothy B. Clark, and Ilia A. Guzei pp 11821–11827 DOI: 10.1021/ja073370x Supporting Info

Arm-First Method As a Simple and General Method for Synthesis of Miktoarm Star Copolymers Haifeng Gao and Krzysztof Matyjaszewski pp 11828–11834 DOI: 10.1021/ja073690g Supporting Info

Structure, Stability, and Cluster-Cage Interactions in Nitride Clusterfullerenes M3N@C2n (M = Sc, Y; 2n = 68−98):  a Density Functional Theory Study Alexey A. Popov and Lothar Dunsch pp 11835–11849 DOI: 10.1021/ja073809l Supporting Info

trans-Cyclohexane-1,2-diamine Is a Weak Director of Absolute Helicity in Chiral Nickel−Salen Complexes Zhenzhen Dong, Glenn P. A. Yap, and Joseph M. Fox pp 11850–11853 DOI: 10.1021/ja073900p Supporting Info

Electrical Behavior of Droplet Interface Bilayer Networks:  Experimental Analysis and Modeling William L. Hwang, Matthew A. Holden, Steven White, and Hagan Bayley pp 11854–11864 DOI: 10.1021/ja074071a Supporting Info

Second SH3 Domain of Ponsin Solved from Powder Diffraction Irene Margiolaki, Jonathan P. Wright, Matthias Wilmanns, Andrew N. Fitch, and Nikos Pinotsis pp 11865–11871 DOI: 10.1021/ja073846c Supporting Info

Dissection of Aminoglycoside−Enzyme Interactions:  A Calorimetric and NMR Study of Noemycin B Binding to the Aminoglycoside Phosphotransferase(3‘)-IIIa [J. Am. Chem. Soc. 2006, 128, 15248−15254]. Can Özen, Joseph M. Malek, and Engin H. Serpersu p 11872 DOI: 10.1021/ja076898a

Protein Folding Protocols. Methods in Molecular Biology, 350 Edited by Yawen Bai (National Institutes of Health, Bethesda, MD) and Ruth Nussinov (National Cancer Institute, Frederick, MD and Tel Aviv University, Israel). Humana Press:  Totowa, NJ. 2006. xiv + 328 pp. $99.50. ISBN 1-58829-622-9. Jean Baum p 11873 DOI: 10.1021/ja0698127

Mass Spectra of Designer Drugs, Including Drugs, Chemical Warfare Agents, and Precursors, Volume 1−2 By Peter Rösner (Altenholz, Germany), Thomas Junge (Landeskriminalamt Schleswig-Holstein, Kiel, Germany), Folker Westphal (Landeskriminalamt Schleswig-Holstein, Kiel; Germany), and Giselher Fritschi (Hessisches Landeskriminalamt, Wiesbaden, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xiv + 1034 pp. $815.00. ISBN 978-3-527-30798-2. p 11873 DOI: 10.1021/ja076978e

Aminoglycoside Antibiotics:  From Chemical Biology to Drug Discovery Edited by Dev P. Arya (Clemson University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 320 pp. $115. ISBN 978-0-471-74302-6. James Ricky Cox pp 11873–11874 DOI: 10.1021/ja076997o

Corrosion Handbook:  Corrosive Agents and Their Interaction with Materials, Volume 7:  Sodium Chloride, Competely Revised and Extended 2nd ed By G. Kreysa and M. Schütze (DECHEMA Society e.V. for Chemical Engineering and Biotechnology, Frankfurt, Germany). DECHEMA e.V.:  Frankfurt and Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xiv + 854 pp. $500. ISBN 978-3-527-31123-1. p 11874 DOI: 10.1021/ja0769797

Name Reactions for Functional Group Transformations Edited by Jie Jack Li (Pfizer Global Research & Development, Ann Arbor, MI). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xiv + 754 pp. $130.00. ISBN 978-0-471-74868-7. p 11874 DOI: 10.1021/ja077000k

Issue 39

The Inner-Sphere Process in the Enantioselective Tsuji Allylation Reaction with (S)-t-Bu-phosphinooxazoline Ligands John A. Keith, Douglas C. Behenna, Justin T. Mohr, Sandy Ma, Smaranda C. Marinescu, Jonas Oxgaard, Brian M. Stoltz, and William A. Goddard, III pp 11876–11877 DOI: 10.1021/ja070516j Supporting Info

Facile One-Step Synthesis of Highly Ordered Bimodal Mesoporous Phosphosilicate Monoliths Liangming Xiong, Jianlin Shi, Lingxia Zhang, and Masayuki Nogami pp 11878–11879 DOI: 10.1021/ja070466i Supporting Info

Regioselective Oxidative Cation-Olefin Cyclization of Poly-enes:  Catalyst Turnover via Hydride Abstraction Charles A. Mullen and Michel R. Gagné pp 11880–11881 DOI: 10.1021/ja073573l Supporting Info

Independent Switching of Cubic Nonlinear Optical Properties in a Ruthenium Alkynyl Cruciform Complex by Employing Protic and Electrochemical Stimuli1 Gulliver T. Dalton, Marie P. Cifuentes, Simon Petrie, Robert Stranger, Mark G. Humphrey, and Marek Samoc pp 11882–11883 DOI: 10.1021/ja074205k Supporting Info

The Met Axial Ligand Determines the Redox Potential in CuA Sites Gabriela N. Ledesma, Daniel H. Murgida, Hoang Khoa Ly, Hainer Wackerbarth, Jens Ulstrup, Antonio J. Costa-Filho, and Alejandro J. Vila pp 11884–11885 DOI: 10.1021/ja0731221 Supporting Info

Hyperfine Coupling to the Bridging 17O in the Di-μ-oxo Core of a MnIII−MnIV Model Significant to the Core Electronic Structure of the O2-Evolving Complex in Photosystem II Oleg M. Usov, Vladimir M. Grigoryants, Ranitendranath Tagore, Gary W. Brudvig, and Charles P. Scholes pp 11886–11887 DOI: 10.1021/ja073179n Supporting Info

Design of Emission Ratiometric Metal-Ion Sensors with Enhanced Two-Photon Cross Section and Brightness S. Sumalekshmy, Maged M. Henary, Nisan Siegel, PaDreyia V. Lawson, Yonggang Wu, Karin Schmidt, Jean-Luc Brédas, Joseph W. Perry, and Christoph J. Fahrni pp 11888–11889 DOI: 10.1021/ja073240o Supporting Info

Macrocyclic and Helical Oligoamides as a New Class of G-Quadruplex Ligands Pravin S. Shirude, Elizabeth R. Gillies, Sylvain Ladame, Frédéric Godde, Kazuo Shin-ya, Ivan Huc, and Shankar Balasubramanian pp 11890–11891 DOI: 10.1021/ja073775h Supporting Info

Synthesis of Tamiflu and its Phosphonate Congeners Possessing Potent Anti-Influenza Activity Jiun-Jie Shie, Jim-Min Fang, Shi-Yun Wang, Keng-Chang Tsai, Yih-Shyun E. Cheng, An-Suei Yang, Shih-Chia Hsiao, Ching-Yao Su, and Chi-Huey Wong pp 11892–11893 DOI: 10.1021/ja073992i Supporting Info

Insights in the Organization of DNA−Surfactant Monolayers Using Cryo-Electron Tomography Matthijn R. J. Vos, Paul H. H. Bomans, Felix de Haas, Peter M. Frederik, John A. Jansen, Roeland J. M. Nolte, and Nico A. J. M. Sommerdijk pp 11894–11895 DOI: 10.1021/ja0736515 Supporting Info

Label-Free Electrochemical Detection of DNA in Blood Serum via Target-Induced Resolution of an Electrode-Bound DNA Pseudoknot Yi Xiao, Xiaogang Qu, Kevin W. Plaxco, and Alan J. Heeger pp 11896–11897 DOI: 10.1021/ja074218y Supporting Info

Photoswitchable Molecular Glue for DNA Chikara Dohno, Shin-nosuke Uno, and Kazuhiko Nakatani pp 11898–11899 DOI: 10.1021/ja074325s Supporting Info

Bisdeoxycoelenterazine Derivatives for Improvement of Bioluminescence Resonance Energy Transfer Assays Jelena Levi, Abhijit De, Zhen Cheng, and Sanjiv Sam Gambhir pp 11900–11901 DOI: 10.1021/ja073936h Supporting Info

Synthesis and Properties of 2,3,6,7-Tetraarylbenzo[1,2-b:4,5-b‘]difurans as Hole-Transporting Material Hayato Tsuji, Chikahiko Mitsui, Laurean Ilies, Yoshiharu Sato, and Eiichi Nakamura pp 11902–11903 DOI: 10.1021/ja074365w Supporting Info

Catalytic and Highly Regioselective Cross-Coupling of Aromatic C−H Substrates Kami L. Hull and Melanie S. Sanford pp 11904–11905 DOI: 10.1021/ja074395z Supporting Info

Charge Dependence of a Nanoscale Supercrystal Phase in a Supported Lipid Bilayer Tighe A. Spurlin and Andrew A. Gewirth pp 11906–11907 DOI: 10.1021/ja074502p Supporting Info

Metal−Semiconductor Hybrid Nanostructure Ag−Zn0.9Co0.1O:  Synthesis and Room-Temperature Ferromagnetism Xiaoqing Qiu, Liping Li, Changlin Tang, and Guangshe Li pp 11908–11909 DOI: 10.1021/ja074630d Supporting Info

Polyfluorenes without Monoalkylfluorene Defects Sung Yong Cho, Andrew C. Grimsdale, David J. Jones, Scott E. Watkins, and Andrew B. Holmes pp 11910–11911 DOI: 10.1021/ja074634i Supporting Info

Hosting Fullerenes by Dynamic Bond Formation with an Iridium Porphyrin Cyclic Dimer:  A “Chemical Friction” for Rotary Guest Motions Makoto Yanagisawa, Kentaro Tashiro, Mikio Yamasaki, and Takuzo Aida pp 11912–11913 DOI: 10.1021/ja0747526 Supporting Info

Facile Access to Pentavalent Uranium Organometallics:  One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(I) Salts Christopher R. Graves, Brian L. Scott, David E. Morris, and Jaqueline L. Kiplinger pp 11914–11915 DOI: 10.1021/ja074889w Supporting Info

Hyperdimensional Protein NMR Spectroscopy in Peptide-Sequence Space Ewen Lescop and Bernhard Brutscher pp 11916–11917 DOI: 10.1021/ja0751577 Supporting Info

Chemoenzymatic Synthesis of Size-Defined Polysaccharides by Sialyltransferase-Catalyzed Block Transfer of Oligosaccharides Saddam Muthana, Hai Yu, Shengshu Huang, and Xi Chen pp 11918–11919 DOI: 10.1021/ja075736b Supporting Info

The Ultimate Speed Limit to Protein Folding Is Conformational Searching Kingshuk Ghosh, S. Banu Ozkan, and Ken A. Dill pp 11920–11927 DOI: 10.1021/ja066785b Supporting Info

Fluorescent Magnetic Nanocrystals by Sequential Addition of Reagents in a One-Pot Reaction:  A Simple Preparation for Multifunctional Nanostructures Jinhao Gao, Bei Zhang, Yuan Gao, Yue Pan, Xixiang Zhang, and Bing Xu pp 11928–11935 DOI: 10.1021/ja0731017 Supporting Info

When is a Nanoparticle a Cluster? An Operando EXAFS Study of Amine Borane Dehydrocoupling by Rh4-6 Clusters John L. Fulton, John C. Linehan, Tom Autrey, Mahalingam Balasubramanian, Yongsheng Chen, and Nathaniel K. Szymczak pp 11936–11949 DOI: 10.1021/ja073331l Supporting Info

Catalytic “Active-Metal” Template Synthesis of [2]Rotaxanes, [3]Rotaxanes, and Molecular Shuttles, and Some Observations on the Mechanism of the Cu(I)-Catalyzed Azide−Alkyne 1,3-Cycloaddition Vincent Aucagne, José Berná, James D. Crowley, Stephen M. Goldup, Kevin D. Hänni, David A. Leigh, Paul J. Lusby, Vicki E. Ronaldson, Alexandra M. Z. Slawin, Aurélien Viterisi, and D. Barney Walker pp 11950–11963 DOI: 10.1021/ja073513f Supporting Info

Chemically Assisted Directed Assembly of Carbon Nanotubes for the Fabrication of Large-Scale Device Arrays George S. Tulevski, James Hannon, Ali Afzali, Zhihong Chen, Phaedon Avouris, and Cherie R. Kagan pp 11964–11968 DOI: 10.1021/ja073647t Supporting Info

Convergent Preparation and Photophysical Characterization of Dimaleimide Dansyl Fluorogens:  Elucidation of the Maleimide Fluorescence Quenching Mechanism Julia Guy, Karine Caron, Stéphane Dufresne, Stephen W. Michnick, W.G. Skene, and Jeffrey W. Keillor pp 11969–11977 DOI: 10.1021/ja0738125

Ammonium Boranes for the Selective Complexation of Cyanide or Fluoride Ions in Water Todd W. Hudnall and François P. Gabbaï pp 11978–11986 DOI: 10.1021/ja073793z Supporting Info

Total Synthesis of (−)-Sarain A Michael H. Becker, Peter Chua, Robert Downham, Christopher J. Douglas, Neil K. Garg, Sheldon Hiebert, Stefan Jaroch, Richard T. Matsuoka, Joy A. Middleton, Fay W. Ng, and Larry E. Overman pp 11987–12002 DOI: 10.1021/ja074300t Supporting Info

Insights into Amine Binding to Biaryl Phosphine Palladium Oxidative Addition Complexes and Reductive Elimination from Biaryl Phosphine Arylpalladium Amido Complexes via Density Functional Theory Timothy E. Barder and Stephen L. Buchwald pp 12003–12010 DOI: 10.1021/ja073747z Supporting Info

Stereospecific Enzymatic Transformation of α-Ketoglutarate to (2S,3R)-3-Methyl Glutamate during Acidic Lipopeptide Biosynthesis Christoph Mahlert, Florian Kopp, Jenny Thirlway, Jason Micklefield, and Mohamed A. Marahiel pp 12011–12018 DOI: 10.1021/ja074427i Supporting Info

Domino Electrocyclization/Azide-Capture/Schmidt Rearrangement of Dienones:  One-Step Synthesis of Dihydropyridones from Simple Building Blocks Dong Song, Ali Rostami, and F. G. West pp 12019–12022 DOI: 10.1021/ja071041z Supporting Info

Lithium Hexamethyldisilazide-Mediated Enolizations:  Influence of Chelating Ligands and Hydrocarbon Cosolvents on the Rates and Mechanisms Peter F. Godenschwager and David B. Collum pp 12023–12031 DOI: 10.1021/ja074018m Supporting Info

Cobalt-Catalyzed Reductive Coupling of Activated Alkenes with Alkynes Hong-Tai Chang, Thiruvellore Thatai Jayanth, Chun-Chih Wang, and Chien-Hong Cheng pp 12032–12041 DOI: 10.1021/ja073604c Supporting Info

Kinetics and Equilibria of Cis/Trans Isomerization of Backbone Amide Bonds in Peptoids Qiang Sui, Dan Borchardt, and Dallas L. Rabenstein pp 12042–12048 DOI: 10.1021/ja0740925 Supporting Info

Synthesis and Structures of Heteroleptic Silylenes Cheuk-Wai So, Herbert W. Roesky, Prabhuodeyara M. Gurubasavaraj, Rainer B. Oswald, Michael T. Gamer, Peter G. Jones, and Steffen Blaurock pp 12049–12054 DOI: 10.1021/ja074019e Supporting Info

Issue 40

A Quantitative Approach to Hydrogen Bonding at a Metal Surface Greg Pawin, Urvinee Solanki, Ki-Young Kwon, Kin L. Wong, Xing Lin, Tong Jiao, and Ludwig Bartels pp 12056–12057 DOI: 10.1021/ja0724341 Supporting Info

Gold(III)-Catalyzed Nitrene Insertion into Aromatic and Benzylic C−H Groups Zigang Li, David A. Capretto, Ronald O. Rahaman, and Chuan He pp 12058–12059 DOI: 10.1021/ja0724137 Supporting Info

Thermosensitive Gold Nanoclusters Stabilized by Well-Defined Vinyl Ether Star Polymers:  Reusable and Durable Catalysts for Aerobic Alcohol Oxidation Shokyoku Kanaoka, Naoto Yagi, Yukiko Fukuyama, Sadahito Aoshima, Hironori Tsunoyama, Tatsuya Tsukuda, and Hidehiro Sakurai pp 12060–12061 DOI: 10.1021/ja0735599 Supporting Info

Synthesis and Unusual Reactivity of N-Tosyl-4,5-benzoazacyclodeca-2,6-diyne, Yneamino-Containing Enediyne Andrei Poloukhtine and Vladimir V. Popik pp 12062–12063 DOI: 10.1021/ja073614d Supporting Info

Selective CO Oxidation in Excess H2 over Copper−Ceria Catalysts:  Identification of Active Entities/Species Daniel Gamarra, Carolina Belver, Marcos Fernández-García, and Arturo Martínez-Arias pp 12064–12065 DOI: 10.1021/ja073926g Supporting Info

Copper-Catalyzed Asymmetric N−H Insertion Reactions:  Couplings of Diazo Compounds with Carbamates to Generate α-Amino Acids Elaine C. Lee and Gregory C. Fu pp 12066–12067 DOI: 10.1021/ja074483j Supporting Info

Carbon−Hydrogen Bond Activation:  Two, Three, or More Mechanisms? Benjamin Alan Vastine and Michael B. Hall pp 12068–12069 DOI: 10.1021/ja074518f Supporting Info

A Au(I)-Catalyzed N-Acyl Iminium Ion Cyclization Cascade Ting Yang, Leonie Campbell, and Darren J. Dixon pp 12070–12071 DOI: 10.1021/ja074550+ Supporting Info

Elements of Regiocontrol in Palladium-Catalyzed Oxidative Arene Cross-Coupling David R. Stuart, Elisia Villemure, and Keith Fagnou pp 12072–12073 DOI: 10.1021/ja0745862 Supporting Info

Cobalt-Catalyzed Asymmetric Cyclopropanation of Electron-Deficient Olefins Ying Chen, Joshua V. Ruppel, and X. Peter Zhang pp 12074–12075 DOI: 10.1021/ja074613o Supporting Info

Chemical Shift Correlation NMR Spectroscopy with Indirect Detection in Fast Rotating Solids:  Studies of Organically Functionalized Mesoporous Silicas Jerzy W. Wiench, Charles E. Bronnimann, Victor S.-Y Lin, and Marek Pruski pp 12076–12077 DOI: 10.1021/ja074746+ Supporting Info

Rh-Catalyzed Synthesis of Helically Chiral and Ladder-Type Molecules via [2 + 2 + 2] and Formal [2 + 1 + 2 + 1] Cycloadditions Involving C−C Triple Bond Cleavage Ken Tanaka, Akiyoshi Kamisawa, Takeshi Suda, Keiichi Noguchi, and Masao Hirano pp 12078–12079 DOI: 10.1021/ja074914y Supporting Info

Magnetic Assembly and Patterning of Vesicle/Nanoparticle Aggregates Kwan Ping Liem, Robert J. Mart, and Simon J. Webb pp 12080–12081 DOI: 10.1021/ja075000e Supporting Info

A Self-Assembled Nanofiber Catalyst for Ester Hydrolysis Mustafa O. Guler and Samuel I. Stupp pp 12082–12083 DOI: 10.1021/ja075044n Supporting Info

Brønsted Acid-Catalyzed Desymmetrization of meso-Aziridines Emily B. Rowland, Gerald B. Rowland, Edwin Rivera-Otero, and Jon C. Antilla pp 12084–12085 DOI: 10.1021/ja0751779 Supporting Info

Asymmetric Synthesis of 3,4-Dihydrocoumarins by Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanones Takanori Matsuda, Masanori Shigeno, and Masahiro Murakami pp 12086–12087 DOI: 10.1021/ja075141g Supporting Info

Directed Hydrozirconation of Propargylic Alcohols Donghui Zhang and Joseph M. Ready pp 12088–12089 DOI: 10.1021/ja075215o Supporting Info

Silicon Quantum Dots:  A General Photocatalyst for Reduction, Decomposition, and Selective Oxidation Reactions Zhenhui Kang, Chi Him A. Tsang, Ning-Bew Wong, Zhendong Zhang, and Shuit-Tong Lee pp 12090–12091 DOI: 10.1021/ja075184x Supporting Info

[2]Rotaxanes through Palladium Active-Template Oxidative Heck Cross-Couplings James D. Crowley, Kevin D. Hänni, Ai-Lan Lee, and David A. Leigh pp 12092–12093 DOI: 10.1021/ja075219t Supporting Info

The Hydrophobic Effect Drives the Recognition of Hydrocarbons by an Anionic Metal−Ligand Cluster1 Shannon M. Biros, Robert G. Bergman, and Kenneth N. Raymond pp 12094–12095 DOI: 10.1021/ja075236i Supporting Info

Giant Enhancement in UV Response of ZnO Nanobelts by Polymer Surface-Functionalization Chang Shi Lao, Myung-Chul Park, Qin Kuang, Yulin Deng, Ashok K. Sood, Dennis L. Polla, and Zhong L. Wang pp 12096–12097 DOI: 10.1021/ja075249w Supporting Info

Active Cytotoxic Reagents Based on Non-metallocene Non-diketonato Well-Defined C2-Symmetrical Titanium Complexes of Tetradentate Bis(phenolato) Ligands Michal Shavit, Dani Peri, Cesar M. Manna, Jacob S. Alexander, and Edit Y. Tshuva pp 12098–12099 DOI: 10.1021/ja0753086 Supporting Info

Role of Cation−π Interactions in the Photodimerization of trans-4-Styrylpyridines Shinji Yamada, Naoko Uematsu, and Kaori Yamashita pp 12100–12101 DOI: 10.1021/ja074874y Supporting Info

Natural Products from isnA-Containing Biosynthetic Gene Clusters Recovered from the Genomes of Cultured and Uncultured Bacteria Sean F. Brady, John D. Bauer, Michael F. Clarke-Pearson, and Rachel Daniels pp 12102–12103 DOI: 10.1021/ja075492v Supporting Info

Do Ligand Binding and Solvent Exclusion Alter the Electrostatic Character within the Oxyanion Hole of an Enzymatic Active Site? Paul A. Sigala, Aaron T. Fafarman, Patrick E. Bogard, Steven G. Boxer, and Daniel Herschlag pp 12104–12105 DOI: 10.1021/ja075605a Supporting Info

Heterobivalent Library Expansion by “Living Radical” Processes:  Thiocarbonyl Addition/Elimination, and Nitroxide-Based Reactions with Fluorous Deconvolution David Crich, Daniel Grant, and Albert A. Bowers pp 12106–12107 DOI: 10.1021/ja0756321 Supporting Info

Probing the Thermodynamics of Aminofluorene-Induced Translesion DNA Synthesis by Differential Scanning Calorimetry Fengting Liang and Bongsup P. Cho pp 12108–12109 DOI: 10.1021/ja075271p Supporting Info

NO-Induced Reversible Switching of the Electronic Interaction between a Porphyrin-Coordinated Cobalt Ion and a Silver Surface Ken Flechtner, Andreas Kretschmann, Hans-Peter Steinrück, and J. Michael Gottfried pp 12110–12111 DOI: 10.1021/ja0756725 Supporting Info

Phenomenon of Optical Self-Purification of Chiral Non-Racemic Compounds Vadim A. Soloshonok, Hisanori Ueki, Manabu Yasumoto, Shekar Mekala, Jennifer S. Hirschi, and Daniel A. Singleton pp 12112–12113 DOI: 10.1021/ja065603a Supporting Info

Crystal Engineering of a Permanently Porous Network Sustained Exclusively by Charge-Assisted Hydrogen Bonds Sean A. Dalrymple and George K. H. Shimizu pp 12114–12116 DOI: 10.1021/ja076094v Supporting Info

Fluorescence Amplification by Electrochemically Deposited Silver Nanowires with Fractal Architecture Ewa M. Goldys, Krystyna Drozdowicz-Tomsia, Fang Xie, Tanya Shtoyko, Eva Matveeva, Ignacy Gryczynski, and Zygmunt Gryczynski pp 12117–12122 DOI: 10.1021/ja071981j

Stereospecific Synthesis and Characterization of Oligodeoxyribonucleotides Containing an N2-(1-Carboxyethyl)-2‘-deoxyguanosine Huachuan Cao, Yong Jiang, and Yinsheng Wang pp 12123–12130 DOI: 10.1021/ja072130e Supporting Info

Functionalization of Zeolitic Cavities:  Grafting NH2 Groups in Framework T Sites of B-SSZ-13 A Way to Obtain Basic Solids Catalysts? Laura Regli, Silvia Bordiga, Claudia Busco, Carmelo Prestipino, Piero Ugliengo, Adriano Zecchina, and Carlo Lamberti pp 12131–12140 DOI: 10.1021/ja0721770 Supporting Info

Synthetic Antimicrobial Oligomers Induce a Composition-Dependent Topological Transition in Membranes Lihua Yang, Vernita D. Gordon, Abhijit Mishra, Abhigyan Som, Kirstin R. Purdy, Matthew A. Davis, Gregory N. Tew, and Gerard C. L. Wong pp 12141–12147 DOI: 10.1021/ja072310o

On the Mechanism of Intramolecular Sensitization of Photocleavage of the 2-(2-Nitrophenyl)propoxycarbonyl (NPPOC) Protecting Group Dominik Wöll, Stefan Laimgruber, Marina Galetskaya, Julia Smirnova, Wolfgang Pfleiderer, Björn Heinz, Peter Gilch, and Ulrich E. Steiner pp 12148–12158 DOI: 10.1021/ja072355p Supporting Info

A Redox-Driven Multicomponent Molecular Shuttle Sourav Saha, Amar H. Flood, J. Fraser Stoddart, Stefania Impellizzeri, Serena Silvi, Margherita Venturi, and Alberto Credi pp 12159–12171 DOI: 10.1021/ja0724590 Supporting Info

Role of Surface Dimer Dynamics in Creating Ordered Organic−Semiconductor Interfaces Robin L. Hayes and Mark E. Tuckerman pp 12172–12180 DOI: 10.1021/ja0724994 Supporting Info

Synthesis and Reactivity of the Methoxozirconium Pentatungstate (nBu4N)6[{(μ-MeO)ZrW5O18}2]:  Insights into Proton-Transfer Reactions, Solution Dynamics, and Assembly of {ZrW5O18}2- Building Blocks R. John Errington, Sagar S. Petkar, Paul S. Middleton, William McFarlane, William Clegg, Robert A. Coxall, and Ross W. Harrington pp 12181–12196 DOI: 10.1021/ja0725495 Supporting Info

Proton-Bound Homodimers:  How Are the Binding Energies Related to Proton Affinities? Bun Chan, Janet E. Del Bene, and Leo Radom pp 12197–12199 DOI: 10.1021/ja072690d Supporting Info

Surface-Assisted Assembly of an Ionic-Complementary Peptide:  Controllable Growth of Nanofibers Hong Yang, Shan-Yu Fung, Mark Pritzker, and P. Chen pp 12200–12210 DOI: 10.1021/ja073168u

Arylamine-Substituted Oligo(ladder-type pentaphenylene)s:  Electronic Communication between Bridged Redox Centers Gang Zhou, Martin Baumgarten, and Klaus Müllen pp 12211–12221 DOI: 10.1021/ja073148s Supporting Info

Simultaneous Arming and Structure/Activity Studies of Natural Products Employing O−H Insertions:  An Expedient and Versatile Strategy for Natural Products-Based Chemical Genetics Satyamaheshwar Peddibhotla, Yongjun Dang, Jun O. Liu, and Daniel Romo pp 12222–12231 DOI: 10.1021/ja0733686 Supporting Info

Effects of Cation Charge-Site Identity and Position on Electron-Transfer Dissociation of Polypeptide Cations Yu Xia, Harsha P. Gunawardena, David E. Erickson, and Scott A. McLuckey pp 12232–12243 DOI: 10.1021/ja0736764 Supporting Info

Polyoxometalates with Internal Cavities:  Redox Activity, Basicity, and Cation Encapsulation in [Xn+P5W30O110](15-n)- Preyssler Complexes, with X = Na+, Ca2+, Y3+, La3+, Ce3+, and Th4+ Jorge A. Fernández, Xavier López, Carles Bo, Coen de Graaf, Evert J. Baerends, and Josep M. Poblet pp 12244–12253 DOI: 10.1021/ja0737321 Supporting Info

Solution-Based Growth and Structural Characterization of Homo- and Heterobranched Semiconductor Nanowires Angang Dong, Rui Tang, and William E. Buhro pp 12254–12262 DOI: 10.1021/ja0737772 Supporting Info

Borate Binding to Siderophores:  Structure and Stability Wesley R. Harris, Shady A. Amin, Frithjof C. Küpper, David H. Green, and Carl J. Carrano pp 12263–12271 DOI: 10.1021/ja073788v Supporting Info

Specific Ion Effects on Interfacial Water Structure near Macromolecules Xin Chen, Tinglu Yang, Sho Kataoka, and Paul S. Cremer pp 12272–12279 DOI: 10.1021/ja073869r Supporting Info

H-ras Protein in a Bilayer:  Interaction and Structure Perturbation Alemayehu A. Gorfe, Arneh Babakhani, and J. Andrew McCammon pp 12280–12286 DOI: 10.1021/ja073949v Supporting Info

Insertion of a Bulky Rhodium Complex into a DNA Cytosine−Cytosine Mismatch:  An NMR Solution Study Christine Cordier, Valérie C. Pierre, and Jacqueline K. Barton pp 12287–12295 DOI: 10.1021/ja0739436 Supporting Info

Monolayer-Based Selective Optical Recognition and Quantification of FeCl3 via Electron Transfer Tarkeshwar Gupta and Milko E. van der Boom pp 12296–12303 DOI: 10.1021/ja074134p

Selective Chain Reaction of Acetone Leading to the Successive Growth of Mutually Perpendicular Molecular Lines on the Si(100)-(2×1)-H Surface Md. Zakir Hossain, Hiroyuki S. Kato, and Maki Kawai pp 12304–12309 DOI: 10.1021/ja074464+

Quantitative Microarray Profiling of DNA-Binding Molecules James W. Puckett, Katy A. Muzikar, Josh Tietjen, Christopher L. Warren, Aseem Z. Ansari, and Peter B. Dervan pp 12310–12319 DOI: 10.1021/ja0744899 Supporting Info

An Expedient Formal Total Synthesis of (−)-Diazonamide A via a Powerful, Stereoselective O-Aryl to C-Aryl Migration To Form the C10 Quaternary Center Chi-Ming Cheung, Frederick W. Goldberg, Philip Magnus, Claire J. Russell, Rachel Turnbull, and Vince Lynch pp 12320–12327 DOI: 10.1021/ja0744448 Supporting Info

Synthesis, Characterization, and Electronic Structures of a Series of Two-Dimensional Trimetallic Cluster Complexes, Ru3(CO)9(μ-SnPh2)3[Pt(PBut3)]x, x = 0−3 Richard D. Adams, Burjor Captain, Michael B. Hall, Eszter Trufan, and Xinzheng Yang pp 12328–12340 DOI: 10.1021/ja074527o Supporting Info

Issue 41

Unraveling the Wacker Oxidation Mechanisms John A. Keith, Robert J. Nielsen, Jonas Oxgaard, and William A. Goddard, III pp 12342–12343 DOI: 10.1021/ja072400t Supporting Info

Silicon Nanowire Array Photoelectrochemical Cells Adrian P. Goodey, Sarah M. Eichfeld, Kok-Keong Lew, Joan M. Redwing, and Thomas E. Mallouk pp 12344–12345 DOI: 10.1021/ja073125d Supporting Info

High Aspect Ratio Silicon Wire Array Photoelectrochemical Cells James R. Maiolo III, Brendan M. Kayes, Michael A. Filler, Morgan C. Putnam, Michael D. Kelzenberg, Harry A. Atwater, and Nathan S. Lewis pp 12346–12347 DOI: 10.1021/ja074897c Supporting Info

Label Transfer Chemistry for the Characterization of Protein−Protein Interactions Bo Liu, Chase T. Archer, Lyle Burdine, Thomas G. Gillette, and Thomas Kodadek pp 12348–12349 DOI: 10.1021/ja072904r Supporting Info

Spectroscopic Insights into Lead(II) Coordination by the Selective Lead(II)-Binding Protein PbrR691 Peng R. Chen, Erik C. Wasinger, Jing Zhao, Daniel van der Lelie, Lin X. Chen, and Chuan He pp 12350–12351 DOI: 10.1021/ja0733890 Supporting Info

Photovoltaic Activity of Photosystem I-Based Self-Assembled Monolayer Itai Carmeli, Ludmila Frolov, Chanoch Carmeli, and Shachar Richter pp 12352–12353 DOI: 10.1021/ja073040c Supporting Info

A Highly Sensitive Fluorescent Sensor for Palladium Based on the Allylic Oxidative Insertion Mechanism Fengling Song, Amanda L. Garner, and Kazunori Koide pp 12354–12355 DOI: 10.1021/ja073910q Supporting Info

γ-Methylidene-δ-valerolactones as a Coupling Partner for Cycloaddition:  Palladium-Catalyzed [4 + 3] Cycloaddition with Nitrones Ryo Shintani, Masataka Murakami, and Tamio Hayashi pp 12356–12357 DOI: 10.1021/ja073997f Supporting Info

Directed Ortho Insertion (DoI):  A New Approach to Functionalized Aryl and Heteroaryl Zinc Reagents Nadège Boudet, Shohei Sase, Pradipta Sinha, Ching-Yuan Liu, Arkady Krasovskiy, and Paul Knochel pp 12358–12359 DOI: 10.1021/ja074060h Supporting Info

Direct Observation of the Ground-Spin Alignment of Fe(II)−Fe(III) Single-Chain Magnet by Muon-Spin Relaxation Takashi Kajiwara, Isao Watanabe, Yukihiro Kaneko, Shinya Takaishi, Masaya Enomoto, Norimichi Kojima, and Masahiro Yamashita pp 12360–12361 DOI: 10.1021/ja0741877 Supporting Info

Double−Step Gas Sorption of a Two−Dimensional Metal−Organic Framework Atsushi Kondo, Hiroshi Noguchi, Lucia Carlucci, Davide M. Proserpio, Gianfranco Ciani, Hiroshi Kajiro, Tomonori Ohba, Hirofumi Kanoh, and Katsumi Kaneko pp 12362–12363 DOI: 10.1021/ja073568h Supporting Info

Vibrational Circular Dichroism Shows Unusual Sensitivity to Protein Fibril Formation and Development in Solution Shengli Ma, Xiaolin Cao, Mimi Mak, Adeola Sadik, Christoph Walkner, Teresa B. Freedman, Igor K. Lednev, Rina K. Dukor, and Laurence A. Nafie pp 12364–12365 DOI: 10.1021/ja074188z Supporting Info

A New Use of Wittig-Type Reagents as 1,3-Dipolar Cycloaddition Precursors and in Pyrrole Synthesis Daniel J. St. Cyr and Bruce A. Arndtsen pp 12366–12367 DOI: 10.1021/ja074330w Supporting Info

Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework Zhenqiang Wang and Seth M. Cohen pp 12368–12369 DOI: 10.1021/ja074366o Supporting Info

A Pyrazolate-Based Metalorganic Tantalum Precursor That Exhibits High Thermal Stability and Its Use in the Atomic Layer Deposition of Ta2O5 Charles L. Dezelah IV, Monika K. Wiedmann, Kenichiro Mizohata, Ronald J. Baird, Lauri Niinistö, and Charles H. Winter pp 12370–12371 DOI: 10.1021/ja074043s Supporting Info

Facile Dehydrogenation of Ethers and Alkanes with a β-Diiminate Pt Fragment Nathan M. West, Peter S. White, and Joseph L. Templeton pp 12372–12373 DOI: 10.1021/ja074488g Supporting Info

A Facile Thermolysis Route to Monodisperse Ferrite Nanocrystals Ningzhong Bao, Liming Shen, Yuhsiang Wang, Prahallad Padhan, and Arunava Gupta pp 12374–12375 DOI: 10.1021/ja074458d Supporting Info

Oxidation Potentials Correlate with Conductivities of Aromatic Molecular Wires Jordan R. Quinn, Frank W. Foss Jr., Latha Venkataraman, and Ronald Breslow pp 12376–12377 DOI: 10.1021/ja0745097 Supporting Info

Single-Molecule Analysis of Nucleotide-Dependent Substrate Binding by the Protein Unfoldase ClpA Mary E. Farbman, Anne Gershenson, and Stuart Licht pp 12378–12379 DOI: 10.1021/ja074168x Supporting Info

The Relationship of Oxygen Binding and Peroxide Sites and the Fluorescent Properties of Zinc Oxide Semiconductor Nanocrystals D. Scott Bohle and Carla J. Spina pp 12380–12381 DOI: 10.1021/ja0747223 Supporting Info

Photoluminescence Recovery from Single-Walled Carbon Nanotubes on Substrates Liming Xie, Cui Liu, Jin Zhang, Yongyi Zhang, Liying Jiao, Lai Jiang, Lun Dai, and Zhongfan Liu pp 12382–12383 DOI: 10.1021/ja074927b Supporting Info

Radical Cation Stabilization in a Cucurbituril Oligoaniline Rotaxane Rienk Eelkema, Kiminori Maeda, Barbara Odell, and Harry L. Anderson pp 12384–12385 DOI: 10.1021/ja074997i Supporting Info

Single Microwire Transistors of Oligoarenes by Direct Solution Process Yan Zhou, Wen-Jun Liu, Yuguo Ma, Hailiang Wang, Limin Qi, Yong Cao, Jian Wang, and Jian Pei pp 12386–12387 DOI: 10.1021/ja075045f Supporting Info

Facile Synthesis of ZnS−AgInS2 Solid Solution Nanoparticles for a Color-Adjustable Luminophore Tsukasa Torimoto, Tomohiro Adachi, Ken-ichi Okazaki, Miwa Sakuraoka, Tamaki Shibayama, Bunsho Ohtani, Akihiko Kudo, and Susumu Kuwabata pp 12388–12389 DOI: 10.1021/ja0750470 Supporting Info

Targeting Peptides with an Iron-Based Oxidant:  Cleavage of the Amino Acid Backbone and Oxidation of Side Chains Anil R. Ekkati and Jeremy J. Kodanko pp 12390–12391 DOI: 10.1021/ja075075i Supporting Info

Chiral Tetraaminophosphonium Salt-Mediated Asymmetric Direct Henry Reaction Daisuke Uraguchi, Sawako Sakaki, and Takashi Ooi pp 12392–12393 DOI: 10.1021/ja075152+ Supporting Info

Nanoscale Templating of Close-Packed C60 Nanowires Min Feng, Junseok Lee, Jin Zhao, John T. Yates, Jr., and Hrvoje Petek pp 12394–12395 DOI: 10.1021/ja075239v

Enantioselective Construction of Spirocyclic Oxindolic Cyclopentanes by Palladium-Catalyzed Trimethylenemethane-[3+2]-Cycloaddition Barry M. Trost, Nicolai Cramer, and Steven M. Silverman pp 12396–12397 DOI: 10.1021/ja075335w Supporting Info

Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Imines Barry M. Trost, Steven M. Silverman, and James P. Stambuli pp 12398–12399 DOI: 10.1021/ja0753389 Supporting Info

Multi-electron Activation of Dioxygen on Zirconium(IV) to Give an Unprecedented Bisperoxo Complex Corneliu Stanciu, Mary E. Jones, Phillip E. Fanwick, and Mahdi M. Abu-Omar pp 12400–12401 DOI: 10.1021/ja075396u Supporting Info

Gold(I)-Catalyzed [2 + 2]-Cycloaddition of Allenenes Michael R. Luzung, Pablo Mauleón, and F. Dean Toste pp 12402–12403 DOI: 10.1021/ja075412n Supporting Info

Copper-Catalyzed Arylation of Heterocycle C−H Bonds Hien-Quang Do and Olafs Daugulis pp 12404–12405 DOI: 10.1021/ja075802+ Supporting Info

2H Solid-State NMR of Mobile Protons:  It Is Not Always the Simple Way Young Joo Lee, Tatiana Murakhtina, Daniel Sebastiani, and Hans Wolfgang Spiess pp 12406–12407 DOI: 10.1021/ja0754857 Supporting Info

Size-Controlled Synthesis of Magnetic CuCr2Se4 Nanocrystals Yu-Hsiang A. Wang, Ningzhong Bao, Liming Shen, Prahallad Padhan, and Arunava Gupta pp 12408–12409 DOI: 10.1021/ja075893a Supporting Info

Role of Trace Amounts of Water in Transfers of Hydrophilic and Hydrophobic Ions to Low-Polarity Organic Solvents Peng Sun, François O. Laforge, and Michael V. Mirkin pp 12410–12411 DOI: 10.1021/ja075774v Supporting Info

A Stable Neutral Diborene Containing a BB Double Bond Yuzhong Wang, Brandon Quillian, Pingrong Wei, Chaitanya S. Wannere, Yaoming Xie, R. Bruce King, Henry F. Schaefer, III, Paul v. R. Schleyer, and Gregory H. Robinson pp 12412–12413 DOI: 10.1021/ja075932i Supporting Info

Intramolecular Anodic Olefin Coupling Reactions:  The Effect of Polarization on Carbon−Carbon Bond Formation Feili Tang and Kevin D. Moeller pp 12414–12415 DOI: 10.1021/ja076172e Supporting Info

Trans-dioxo Manganese(V) Porphyrins Ning Jin, Mohammed Ibrahim, Thomas G. Spiro, and John T. Groves pp 12416–12417 DOI: 10.1021/ja0761737 Supporting Info

Sulfur K-Edge X-ray Absorption Spectroscopy and Density Functional Theory Calculations on Superoxide Reductase:  Role of the Axial Thiolate in Reactivity Abhishek Dey, Francis E. Jenney, Jr., Michael W. W. Adams, Michael K. Johnson, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 12418–12431 DOI: 10.1021/ja064167p Supporting Info

Regiospecific Chlorination of (S)-β-Tyrosyl-S-Carrier Protein Catalyzed by SgcC3 in the Biosynthesis of the Enediyne Antitumor Antibiotic C-1027 Shuangjun Lin, Steven G. Van Lanen, and Ben Shen pp 12432–12438 DOI: 10.1021/ja072311g Supporting Info

Biochemical Evaluation of a 108-Member Deglycobleomycin Library:  Viability of a Selection Strategy for Identifying Bleomycin Analogues with Altered Properties Qian Ma, Zhidong Xu, Benjamin R. Schroeder, Wenyue Sun, Fang Wei, Shigeki Hashimoto, Kazuhide Konishi, Christopher J. Leitheiser, and Sidney M. Hecht pp 12439–12452 DOI: 10.1021/ja0722729 Supporting Info

16-Aza-ent-beyerane and 16-Aza-ent-trachylobane:  Potent Mechanism-Based Inhibitors of Recombinant ent-Kaurene Synthase from Arabidopsis thaliana Arnab Roy, Frank G. Roberts, P. Ross Wilderman, Ke Zhou, Reuben J. Peters, and Robert M. Coates pp 12453–12460 DOI: 10.1021/ja072447e Supporting Info

Engineered Holliday Junctions as Single-Molecule Reporters for Protein−DNA Interactions with Application to a MerR-Family Regulator Susanta K. Sarkar, Nesha May Andoy, Jaime J. Benítez, Peng R. Chen, Jason S. Kong, Chuan He, and Peng Chen pp 12461–12467 DOI: 10.1021/ja072485y Supporting Info

Self-Assembly of Multidomain Peptides:  Balancing Molecular Frustration Controls Conformation and Nanostructure He Dong, Sergey E. Paramonov, Lorenzo Aulisa, Erica L. Bakota, and Jeffrey D. Hartgerink pp 12468–12472 DOI: 10.1021/ja072536r Supporting Info

Low-Temperature Rapid-Scan Detection of Reactive Intermediates in Epoxidation Reactions Catalyzed by a New Enzyme Mimic of Cytochrome P450 Natalya Hessenauer-Ilicheva, Alicja Franke, Dominik Meyer, Wolf-D. Woggon, and Rudi van Eldik pp 12473–12479 DOI: 10.1021/ja073266f

Unprecedented Head-to-Head Right-Handed Cross-Links between the Antitumor Bis(μ-N,N‘-di-p-tolylformamidinate) Dirhodium(II,II) Core and the Dinucleotide d(ApA) with the Adenine Bases in the Rare Imino Form Helen T. Chifotides and Kim R. Dunbar pp 12480–12490 DOI: 10.1021/ja073422i Supporting Info

Effect of Protons on the Optical Properties of Oxide Nanostructures Markus Müller, Slavica Stankic, Oliver Diwald, Erich Knözinger, Peter V. Sushko, Paolo E. Trevisanutto, and Alexander L. Shluger pp 12491–12496 DOI: 10.1021/ja0736055 Supporting Info

All-Electron Calculations of the Nucleation Structures in Metal-Induced Zinc-Finger Folding:  Role of the Peptide Backbone Todor Dudev and Carmay Lim pp 12497–12504 DOI: 10.1021/ja073322c Supporting Info

Toward a Magnetostructural Correlation for a Family of Mn6 SMMs Constantinos J. Milios, Ross Inglis, Alina Vinslava, Rashmi Bagai, Wolfgang Wernsdorfer, Simon Parsons, Spyros P. Perlepes, George Christou, and Euan K. Brechin pp 12505–12511 DOI: 10.1021/ja0736616 Supporting Info

Efficient and Selective Cleavage of RNA Oligonucleotides by Calix[4]arene-Based Synthetic Metallonucleases Roberta Cacciapaglia, Alessandro Casnati, Luigi Mandolini, Alessio Peracchi, David N. Reinhoudt, Riccardo Salvio, Andrea Sartori, and Rocco Ungaro pp 12512–12520 DOI: 10.1021/ja0737366 Supporting Info

Hydrogen Generation from Weak Acids:  Electrochemical and Computational Studies of a Diiron Hydrogenase Mimic Greg A. N. Felton, Aaron K. Vannucci, Jinzhu Chen, L. Tori Lockett, Noriko Okumura, Benjamin J. Petro, Uzma I. Zakai, Dennis H. Evans, Richard S. Glass, and Dennis L. Lichtenberger pp 12521–12530 DOI: 10.1021/ja073886g Supporting Info

Probing the Nature of Three-Centered Hydrogen Bonds in Minor-Groove Ligand−DNA Interactions:  The Contribution of Fluorine Hydrogen Bonds to Complex Stability Zhenhua Sun and Larry W. McLaughlin pp 12531–12536 DOI: 10.1021/ja073981p Supporting Info

Investigating Carbazole Jacketed Precursor Dendrimers:  Sonochemical Synthesis, Characterization, and Electrochemical Crosslinking Properties Prasad Taranekar, Timothy Fulghum, Derek Patton, Ramakrishna Ponnapati, Gabriel Clyde, and Rigoberto Advincula pp 12537–12548 DOI: 10.1021/ja074007t Supporting Info

Fullerene-Like (IF) NbxMo1-xS2 Nanoparticles Francis Leonard Deepak, Hagai Cohen, Sidney Cohen, Yishay Feldman, Ronit Popovitz-Biro, Doron Azulay, Oded Millo, and Reshef Tenne pp 12549–12562 DOI: 10.1021/ja074081b Supporting Info

Design and Synthesis of C5 Methylated l-Arginine Analogues as Active Site Probes for Nitric Oxide Synthase Nathaniel I. Martin, Joshua J. Woodward, Michael B. Winter, William T. Beeson, and Michael A. Marletta pp 12563–12570 DOI: 10.1021/ja0746159 Supporting Info

Kinetics of Monodisperse Iron Oxide Nanocrystal Formation by “Heating-Up” Process Soon Gu Kwon, Yuanzhe Piao, Jongnam Park, Subramanian Angappane, Younghun Jo, Nong-Moon Hwang, Je-Geun Park, and Taeghwan Hyeon pp 12571–12584 DOI: 10.1021/ja074633q Supporting Info

Antibiofouling Polymer-Coated Gold Nanoparticles as a Contrast Agent for in Vivo X-ray Computed Tomography Imaging [J. Am. Chem. Soc. 2007, 129, 7661−7665]. Dongkyu Kim, Sangjin Park, Jae Hyuk Lee, Yong Yeon Jeong, and Sangyong Jon p 12585 DOI: 10.1021/ja076341v

One-Electron Photooxidation and Site-Selective Strand Cleavage at 5-Methylcytosine in DNA by Sensitization with 2-Methyl-1,4-naphthoquinone-Tethered Oligonucleotides [J. Am. Chem. Soc. 2007, 129, 8034−8040]. Kazuhito Tanabe, Hisatsugu Yamada, and Sei-ichi Nishimoto p 12585 DOI: 10.1021/ja076508k

Molecule Evoluator CIDRUX BV, Park Oosterspaarn 6, 2036 MB Haarlem, The Netherlands. www. cidrux.com. See Web site for pricing information. Jeff Zablocki p 12586 DOI: 10.1021/ja0769604

Issue 42

Dramatic Differences between the Energy Landscapes of SiO2 and SiS2 Zeotype Materials Martijn A. Zwijnenburg, Furio Corà, and Robert G. Bell pp 12588–12589 DOI: 10.1021/ja0727666 Supporting Info

Reversible Switching in Molecular Electronic Devices Adam C. Whalley, Michael L. Steigerwald, Xuefeng Guo, and Colin Nuckolls pp 12590–12591 DOI: 10.1021/ja073127y Supporting Info

Counting the Number of Proteins Coupled to Single Nanoparticles Didier Casanova, Domitille Giaume, Mélanie Moreau, Jean-Louis Martin, Thierry Gacoin, Jean-Pierre Boilot, and Antigoni Alexandrou pp 12592–12593 DOI: 10.1021/ja0731975 Supporting Info

Combined Analysis of 15N Relaxation Data from Solid- and Solution-State NMR Spectroscopy Veniamin Chevelkov, Anastasia V. Zhuravleva, Yi Xue, Bernd Reif, and Nikolai R. Skrynnikov pp 12594–12595 DOI: 10.1021/ja073234s Supporting Info

Rhodium-Catalyzed Carbonylation of Spiropentanes Takanori Matsuda, Tomoya Tsuboi, and Masahiro Murakami pp 12596–12597 DOI: 10.1021/ja0732779 Supporting Info

Ultrafast Dynamics of Triplet Excitons in Alq3-Bridge-Pt(II)porphyrin Electroluminescent Materials Victor A. Montes, César Pérez-Bolívar, Leandro A. Estrada, Joseph Shinar, and Pavel Anzenbacher, Jr. pp 12598–12599 DOI: 10.1021/ja073491x Supporting Info

Electrophile-Directed Diastereoselective Alkylation of Prochiral Enediolates Stephen P. Marsden and Rebecca Newton pp 12600–12601 DOI: 10.1021/ja073624e Supporting Info

Metal-Catalyzed Silylene Insertions of Allylic Ethers:  Stereoselective Formation of Chiral Allylic Silanes Laura E. Bourque, Pamela A. Cleary, and K. A. Woerpel pp 12602–12603 DOI: 10.1021/ja073758s Supporting Info

Olefinic Ester and Diene Ring-Closing Metathesis Using a Reduced Titanium Alkylidene Karthik Iyer and Jon D. Rainier pp 12604–12605 DOI: 10.1021/ja073880r Supporting Info

Effect of Spin State on the Dihydrogen Binding Strength to Transition Metal Centers in Metal-Organic Frameworks Y. Y. Sun, Yong-Hyun Kim, and S. B. Zhang pp 12606–12607 DOI: 10.1021/ja0740061 Supporting Info

Formation of Giant Lipid Vesiclelike Compartments from a Planar Lipid Membrane by a Pulsed Jet Flow Kei Funakoshi, Hiroaki Suzuki, and Shoji Takeuchi pp 12608–12609 DOI: 10.1021/ja074029f Supporting Info

Organocatalytic Stereoselective Ring-Opening Polymerization of Lactide with Dimeric Phosphazene Bases Lei Zhang, Fredrik Nederberg, Jamie M. Messman, Russell C. Pratt, James L. Hedrick, and Charles G. Wade pp 12610–12611 DOI: 10.1021/ja074131c Supporting Info

Synthesis, Structure, and Isomerization of Decapentynylcorannulene:  Enediyne Cyclization/Interconversion of C40R10 Isomers Tomoharu Hayama, Yao-Ting Wu, Anthony Linden, Kim K. Baldridge, and Jay S. Siegel pp 12612–12613 DOI: 10.1021/ja074403b Supporting Info

An Illustration of the Limit of the Metal Organic Framework's Isoreticular Principle Using a Semirigid Tritopic Linker Obtained by “Click” Chemistry Thomas Devic, Olivier David, Marion Valls, Jérôme Marrot, François Couty, and Gérard Férey pp 12614–12615 DOI: 10.1021/ja0744091 Supporting Info

Highly Enantioselective Insertion of Carbenoids into O−H Bonds of Phenols:  An Efficient Approach to Chiral α-Aryloxycarboxylic Esters Chao Chen, Shou-Fei Zhu, Bin Liu, Li-Xin Wang, and Qi-Lin Zhou pp 12616–12617 DOI: 10.1021/ja074729k Supporting Info

An Antiferromagnetic Molecular Metal Based on a New Bent-Donor Molecule Xunwen Xiao, Toshiki Hayashi, Hideki Fujiwara, Toyonari Sugimoto, Satoru Noguchi, Yufeng Weng, Harukazu Yoshino, Keizo Murata, and Hiroko Aruga Katori pp 12618–12619 DOI: 10.1021/ja074840q Supporting Info

Nearly Isostructural Polymorphs of Ethynylbenzene:  Resolution of CH···π(arene) and Cooperative CH···π(CC) Interactions by Pressure Freezing Kamil Dziubek, Marcin Podsiadło, and Andrzej Katrusiak pp 12620–12621 DOI: 10.1021/ja074885r Supporting Info

Highly Selective Hydrocyanation of Butadiene toward 3-Pentenenitrile Laura Bini, Christian Müller, Jos Wilting, Lars von Chrzanowski, Anthony L. Spek, and Dieter Vogt pp 12622–12623 DOI: 10.1021/ja074922e Supporting Info

Electrocatalysis on Bimetallic Surfaces:  Modifying Catalytic Reactivity for Oxygen Reduction by Voltammetric Surface Dealloying Shirlaine Koh and Peter Strasser pp 12624–12625 DOI: 10.1021/ja0742784 Supporting Info

EPR, UV−Vis, IR, and X-ray Demonstration of the Anionic Dimeric Dinitrosyl Iron Complex [(NO)2Fe(μ-StBu)2Fe(NO)2]-:  Relevance to the Products of Nitrosylation of Cytosolic and Mitochondrial Aconitases, and High-Potential Iron Proteins Chih-Chin Tsou, Tsai-Te Lu, and Wen-Feng Liaw pp 12626–12627 DOI: 10.1021/ja0751375 Supporting Info

Three Minutes-Long Electrophoretically Assisted Zeptomolar Microfluidic Immunoassay with Magnetic-Beads Detection Victor N. Morozov, Stephanie Groves, Michael J. Turell, and Charles Bailey pp 12628–12629 DOI: 10.1021/ja075069m Supporting Info

External Stimulus-Responsive Supramolecular Structures Formed by a Stilbene Cyclodextrin Dimer Paul Kuad, Atsuhisa Miyawaki, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 12630–12631 DOI: 10.1021/ja075139p Supporting Info

Phosphine-Catalyzed [4 + 2] Annulation:  Synthesis of Cyclohexenes Yang S. Tran and Ohyun Kwon pp 12632–12633 DOI: 10.1021/ja0752181 Supporting Info

Zirconocene-Mediated Highly Regio- and Stereoselective Synthesis of Multisubstituted Olefins Starting from 1-Alkynylboronates Yasushi Nishihara, Mitsuru Miyasaka, Masanori Okamoto, Hideki Takahashi, Eiji Inoue, Kenki Tanemura, and Kentaro Takagi pp 12634–12635 DOI: 10.1021/ja075234y Supporting Info

Unexpected Coordination Chemistry of Bisphenanthroline Complexes within Hybrid Materials:  A Mild Way to Eu2+ Containing Materials with Bright Yellow Luminescence Laurence Raehm, Ahmad Mehdi, Claudia Wickleder, Catherine Reyé, and Robert J. P. Corriu pp 12636–12637 DOI: 10.1021/ja075277e Supporting Info

Au(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of Münchnones with Electron-Deficient Alkenes Asa D. Melhado, Marco Luparia, and F. Dean Toste pp 12638–12639 DOI: 10.1021/ja074824t Supporting Info

Cyclic Denitrogenation of N-Heterocycles Applying a Homogeneous Titanium Reagent Alison R. Fout, Brad C. Bailey, John Tomaszewski, and Daniel J. Mindiola pp 12640–12641 DOI: 10.1021/ja075326n Supporting Info

Stable Analogues of Aminoacyl-tRNA for Inhibition of an Essential Step of Bacterial Cell-Wall Synthesis Maryline Chemama, Matthieu Fonvielle, Régis Villet, Michel Arthur, Jean-Marc Valéry, and Mélanie Etheve-Quelquejeu pp 12642–12643 DOI: 10.1021/ja0749946 Supporting Info

Enantioselective Iridium-Catalyzed Imine Vinylation:  Optically Enriched Allylic Amines via Alkyne−Imine Reductive Coupling Mediated by Hydrogen Ming-Yu Ngai, Andriy Barchuk, and Michael J. Krische pp 12644–12645 DOI: 10.1021/ja075438e Supporting Info

Effect of Spin-Ladder Topology on 2D Charge Ordering:  Toward New Spin-Antiferroelectric Transitions Bangbo Yan, Marilyn M. Olmstead, and Paul A. Maggard pp 12646–12647 DOI: 10.1021/ja0754709 Supporting Info

Geminal Tandem C-Methylation in the Discoid Resistomycin Pathway Keishi Ishida, Kathrin Fritzsche, and Christian Hertweck pp 12648–12649 DOI: 10.1021/ja075524e Supporting Info

Synthesis of (Arylalkenyl)silanes by Palladium-Catalyzed Regiospecific and Stereoselective Allyl Transfer from Silyl-Substituted Homoallyl Alcohols to Aryl Halides Sayuri Hayashi, Koji Hirano, Hideki Yorimitsu, and Koichiro Oshima pp 12650–12651 DOI: 10.1021/ja0755111 Supporting Info

Noncoherent Low-Power Upconversion in Solid Polymer Films Radiy R. Islangulov, Joseph Lott, Christoph Weder, and Felix N. Castellano pp 12652–12653 DOI: 10.1021/ja075014k

Synthesis of Monoalkoxide Monopyrrolyl Complexes Mo(NR)(CHR‘)(OR‘ ‘)(pyrrolyl): Enyne Metathesis with High Oxidation State Catalysts Rojendra Singh, Richard R. Schrock, Peter Müller, and Amir H. Hoveyda pp 12654–12655 DOI: 10.1021/ja075569f Supporting Info

Iridium-Catalyzed Reduction of Alkyl Halides by Triethylsilane Jian Yang and Maurice Brookhart pp 12656–12657 DOI: 10.1021/ja075725i Supporting Info

In Situ Investigation of Heterotrimeric G Protein βγ Subunit Binding and Orientation on Membrane Bilayers Xiaoyun Chen, Andrew P. Boughton, John J. G. Tesmer, and Zhan Chen pp 12658–12659 DOI: 10.1021/ja075542w Supporting Info

Air-Stable Disilacyclopropene with a SiC Bond and Its Conversion to Disilacyclopropenylium Ion:  Silicon−Carbon Hybrid 2π-Electron Systems Masayasu Igarashi, Masaaki Ichinohe, and Akira Sekiguchi pp 12660–12661 DOI: 10.1021/ja075740n Supporting Info

Multicomponent Radical Processes:  Synthesis of Substituted Piperidinones Edouard Godineau and Yannick Landais pp 12662–12663 DOI: 10.1021/ja075755l Supporting Info

Origin of Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions of Polyhalogenated Heterocycles Claude Y. Legault, Yeimy Garcia, Craig A. Merlic, and K. N. Houk pp 12664–12665 DOI: 10.1021/ja075785o Supporting Info

How Small Variations in Crystal Interactions Affect Macroscopic Properties F. Albert Cotton, Santiago Herrero, Reyes Jiménez-Aparicio, Carlos A. Murillo, Francisco A. Urbanos, Dino Villagrán, and Xiaoping Wang pp 12666–12667 DOI: 10.1021/ja075808z Supporting Info

Probing Supramolecular Structure from Measurement of Methyl 1H−13C Residual Dipolar Couplings Remco Sprangers and Lewis E. Kay pp 12668–12669 DOI: 10.1021/ja075846i Supporting Info

Protein Prosthesis:  1,5-Disubstituted[1,2,3]triazoles as cis-Peptide Bond Surrogates Annie Tam, Ulrich Arnold, Matthew B. Soellner, and Ronald T. Raines pp 12670–12671 DOI: 10.1021/ja075865s Supporting Info

Hyperbranched Macromolecules via Olefin Metathesis Irina A. Gorodetskaya, Tae-Lim Choi, and Robert H. Grubbs pp 12672–12673 DOI: 10.1021/ja0759040 Supporting Info

The Direction of Glycan Chain Elongation by Peptidoglycan Glycosyltransferases Deborah L. Perlstein, Yi Zhang, Tsung-Shing Wang, Daniel E. Kahne, and Suzanne Walker pp 12674–12675 DOI: 10.1021/ja075965y Supporting Info

Effective Modulation of the Donor Properties of N-Heterocyclic Carbene Ligands by “Through-Space” Communication within a Planar Chiral Scaffold Alois Fürstner, Manuel Alcarazo, Helga Krause, and Christian W. Lehmann pp 12676–12677 DOI: 10.1021/ja076028t Supporting Info

Carbonyl Allylation in the Absence of Preformed Allyl Metal Reagents:  Reverse Prenylation via Iridium-Catalyzed Hydrogenative Coupling of Dimethylallene Eduardas Skucas, John F. Bower, and Michael J. Krische pp 12678–12679 DOI: 10.1021/ja075971u Supporting Info

Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials Omar K. Farha, Alexander M. Spokoyny, Karen L. Mulfort, M. Frederick Hawthorne, Chad A. Mirkin, and Joseph T. Hupp pp 12680–12681 DOI: 10.1021/ja076167a Supporting Info

Rapid Access to Polyprenylated Phloroglucinols via Alkylative Dearomatization−Annulation:  Total Synthesis of (±)-Clusianone1 Ji Qi and John A. Porco, Jr. pp 12682–12683 DOI: 10.1021/ja0762339 Supporting Info

Introducing a Metal−Metal Multiply Bonded Group as an “Axial Ligand” to Iron:  Synthetic Design of a Linear Cr−Cr···Fe Framework Michael Nippe and John F. Berry pp 12684–12685 DOI: 10.1021/ja076337j Supporting Info

Highly Enantioselective [2+2]-Cycloaddition Reactions Catalyzed by a Chiral Aluminum Bromide Complex Eda Canales and E. J. Corey pp 12686–12687 DOI: 10.1021/ja0765262 Supporting Info

Ferromagnetism in a Heavy Atom Heterocyclic Radical Conductor Craig M. Robertson, Daniel J. T. Myles, Alicea A. Leitch, Robert W. Reed, Brynn M. Dooley, Natia L. Frank, Paul A. Dube, Laurence K. Thompson, and Richard T. Oakley pp 12688–12689 DOI: 10.1021/ja076841o Supporting Info

Extreme NN Bond Elongation and Facile N-Atom Functionalization Reactions within Two Structurally Versatile New Families of Group 4 Bimetallic “Side-on-Bridged” Dinitrogen Complexes for Zirconium and Hafnium Masakazu Hirotsu, Philip P. Fontaine, Peter Y. Zavalij, and Lawrence R. Sita pp 12690–12692 DOI: 10.1021/ja0752989 Supporting Info

Hairpin Peptide Beacon:  Dual-Labeled PNA-Peptide-Hybrids for Protein Detection Stefanie Thurley, Lars Röglin, and Oliver Seitz pp 12693–12695 DOI: 10.1021/ja075487r Supporting Info

Benzimidazole and Related Ligands for Cu-Catalyzed Azide−Alkyne Cycloaddition Valentin O. Rodionov, Stanislav I. Presolski, Sean Gardinier, Yeon-Hee Lim, and M. G. Finn pp 12696–12704 DOI: 10.1021/ja072678l Supporting Info

Ligand-Accelerated Cu-Catalyzed Azide−Alkyne Cycloaddition:  A Mechanistic Report Valentin O. Rodionov, Stanislav I. Presolski, David Díaz Díaz, Valery V. Fokin, and M. G. Finn pp 12705–12712 DOI: 10.1021/ja072679d Supporting Info

Diverse Stereocontrol Effects Induced by Weakly Coordinating Anions. Stereospecific Olefin Polymerization Pathways at Archetypal Cs- and C1-Symmetric Metallocenium Catalysts Using Mono- and Polynuclear Halo-perfluoroarylmetalates as Cocatalysts John A. S. Roberts, Ming-Chou Chen, Afif M. Seyam, Liting Li, Cristiano Zuccaccia, Nicholas G. Stahl, and Tobin J. Marks pp 12713–12733 DOI: 10.1021/ja0680360 Supporting Info

On the Kinetic and Thermodynamic Reactivity of Lithium Di(alkyl)amidozincate Bases in Directed Ortho Metalation Yoshinori Kondo, James V. Morey, Jacqueline C. Morgan, Hiroshi Naka, Daisuke Nobuto, Paul R. Raithby, Masanobu Uchiyama, and Andrew E. H. Wheatley pp 12734–12738 DOI: 10.1021/ja072118m Supporting Info

Thermally Cross-Linked Superparamagnetic Iron Oxide Nanoparticles:  Synthesis and Application as a Dual Imaging Probe for Cancer in Vivo Haerim Lee, Mi Kyung Yu, Sangjin Park, Sungmin Moon, Jung Jun Min, Yong Yeon Jeong, Hae-Won Kang, and Sangyong Jon pp 12739–12745 DOI: 10.1021/ja072210i Supporting Info

Orientational and Dynamical Heterogeneity of Rhodamine 6G Terminally Attached to a DNA Helix Revealed by NMR and Single-Molecule Fluorescence Spectroscopy Heike Neubauer, Natalia Gaiko, Sylvia Berger, Jörg Schaffer, Christian Eggeling, Jennifer Tuma, Laurent Verdier, Claus A. M. Seidel, Christian Griesinger, and Andreas Volkmer pp 12746–12755 DOI: 10.1021/ja0722574 Supporting Info

Conformational Dependence of Hemoglobin Reactivity under High Viscosity Conditions:  The Role of Solvent Slaved Dynamics Uri Samuni, Camille J. Roche, David Dantsker, and Joel M. Friedman pp 12756–12764 DOI: 10.1021/ja072342b Supporting Info

Explanation of the Unusual Temperature Dependence of the Atmospherically Important OH + H2S → H2O + HS Reaction and Prediction of the Rate Constant at Combustion Temperatures Benjamin A. Ellingson and Donald G. Truhlar pp 12765–12771 DOI: 10.1021/ja072538b Supporting Info

Solvent Dynamical Control of Ultrafast Ground State Electron Transfer:  Implications for Class II−III Mixed Valency Benjamin J. Lear, Starla D. Glover, J. Catherine Salsman, Casey H. Londergan, and Clifford P. Kubiak pp 12772–12779 DOI: 10.1021/ja072653m Supporting Info

Non-carbohydrate Inhibitors of the Lectin DC-SIGN M. Jack Borrok and Laura L. Kiessling pp 12780–12785 DOI: 10.1021/ja072944v Supporting Info

Paramagnetism-Based NMR Restraints Provide Maximum Allowed Probabilities for the Different Conformations of Partially Independent Protein Domains Ivano Bertini, Yogesh K. Gupta, Claudio Luchinat, Giacomo Parigi, Massimiliano Peana, Luca Sgheri, and Jing Yuan pp 12786–12794 DOI: 10.1021/ja0726613 Supporting Info

Anomeric Reactivity-Based One-Pot Synthesis of Heparin-Like Oligosaccharides Tülay Polat and Chi-Huey Wong pp 12795–12800 DOI: 10.1021/ja073098r Supporting Info

Enthalpic and Entropic Stages in α-Helical Peptide Unfolding, from Laser T-Jump/UV Raman Spectroscopy Gurusamy Balakrishnan, Ying Hu, Gretchen M. Bender, Zelleka Getahun, William F. DeGrado, and Thomas G. Spiro pp 12801–12808 DOI: 10.1021/ja073366l

Small Molecule Inhibitors of the MDM2-p53 Interaction Discovered by Ensemble-Based Receptor Models Anna L. Bowman, Zaneta Nikolovska-Coleska, Haizhen Zhong, Shaomeng Wang, and Heather A. Carlson pp 12809–12814 DOI: 10.1021/ja073687x Supporting Info

Deducing the Energetic Cost of Protein Folding in Zinc Finger Proteins Using Designed Metallopeptides Amit R. Reddi, Tabitha R. Guzman, Robert M. Breece, David L. Tierney, and Brian R. Gibney pp 12815–12827 DOI: 10.1021/ja073902+ Supporting Info

Organic−Inorganic Nanocomposites via Directly Grafting Conjugated Polymers onto Quantum Dots Jun Xu, Jun Wang, Mike Mitchell, Prasun Mukherjee, Malika Jeffries-EL, Jacob W. Petrich, and Zhiqun Lin pp 12828–12833 DOI: 10.1021/ja074133x Supporting Info

Imidazolium Carboxylates as Versatile and Selective N-Heterocyclic Carbene Transfer Agents:  Synthesis, Mechanism, and Applications Adelina M. Voutchkova, Marta Feliz, Eric Clot, Odile Eisenstein, and Robert H. Crabtree pp 12834–12846 DOI: 10.1021/ja0742885 Supporting Info

Voltammetry of Quinones in Unbuffered Aqueous Solution:  Reassessing the Roles of Proton Transfer and Hydrogen Bonding in the Aqueous Electrochemistry of Quinones May Quan, Daniel Sanchez, Mark F. Wasylkiw, and Diane K. Smith pp 12847–12856 DOI: 10.1021/ja0743083 Supporting Info

Scope and Mechanism of Direct Indole and Pyrrole Couplings Adjacent to Carbonyl Compounds:  Total Synthesis of Acremoauxin A and Oxazinin 3 Jeremy M. Richter, Brandon W. Whitefield, Thomas J. Maimone, David W. Lin, M. Pilar Castroviejo, and Phil S. Baran pp 12857–12869 DOI: 10.1021/ja074392m Supporting Info

DNA Strand Damage Product Analysis Provides Evidence That the Tumor Cell-Specific Cytotoxin Tirapazamine Produces Hydroxyl Radical and Acts as a Surrogate for O2 Goutam Chowdhury, Venkatraman Junnotula, J. Scott Daniels, Marc M. Greenberg, and Kent S. Gates pp 12870–12877 DOI: 10.1021/ja074432m

Preparation and Controlled Self-Assembly of Janus Magnetic Nanoparticles Marco Lattuada and T. Alan Hatton pp 12878–12889 DOI: 10.1021/ja0740521

A Catalytic One-Step Process for the Chemo- and Regioselective Acylation of Monosaccharides Takeo Kawabata, Wataru Muramatsu, Tadashi Nishio, Takeshi Shibata, and Hartmut Schedel pp 12890–12895 DOI: 10.1021/ja074882e Supporting Info

On the Structure of Palau'amine:  Evidence for the Revised Relative Configuration from Chemical Synthesis Brian A. Lanman, Larry E. Overman, Ralph Paulini, and Nicole S. White pp 12896–12900 DOI: 10.1021/ja074939x Supporting Info

Issue 43

Carbon Dioxide-Mediated Catalytic Rearrangement of Propargyl Alcohols into α,β-Unsaturated Ketones Yudai Sugawara, Wataru Yamada, Shunsuke Yoshida, Taketo Ikeno, and Tohru Yamada pp 12902–12903 DOI: 10.1021/ja074350y Supporting Info

Conjugated Polymer Dots for Multiphoton Fluorescence Imaging Changfeng Wu, Craig Szymanski, Zachary Cain, and Jason McNeill pp 12904–12905 DOI: 10.1021/ja074590d Supporting Info

Porphyrinoid Chemistry in Hemoprotein Matrix:  Detection and Reactivities of Iron(IV)-Oxo Species of Porphycene Incorporated into Horseradish Peroxidase Takashi Matsuo, Dai Murata, Yoshio Hisaeda, Hiroshi Hori, and Takashi Hayashi pp 12906–12907 DOI: 10.1021/ja074685f Supporting Info

Reversible Photoswitchable Axially Chiral Dopants with High Helical Twisting Power Quan Li, Lisa Green, Nithya Venkataraman, Irina Shiyanovskaya, Asad Khan, Augustine Urbas, and J. William Doane pp 12908–12909 DOI: 10.1021/ja0747573 Supporting Info

At the Water's Edge:  Nitric Acid as a Weak Acid Eric S. Shamay, Victoria Buch, Michele Parrinello, and Geraldine L. Richmond pp 12910–12911 DOI: 10.1021/ja074811f Supporting Info

Reversible Formation and Dispersion of Chiral Assemblies Responding to Electron Transfer Junpei Yuasa and Shunichi Fukuzumi pp 12912–12913 DOI: 10.1021/ja075149q Supporting Info

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks Adrien P. Côté, Hani M. El-Kaderi, Hiroyasu Furukawa, Joseph R. Hunt, and Omar M. Yaghi pp 12914–12915 DOI: 10.1021/ja0751781 Supporting Info

Ruthenium-Catalyzed Decarbonylative Cyclization of 1,6-Diynes Carlos González-Rodríguez, Jesús A. Varela, Luis Castedo, and Carlos Saá pp 12916–12917 DOI: 10.1021/ja0752888 Supporting Info

Exchange-Biased Dimers of Single-Molecule Magnets in OFF and ON States Rashmi Bagai, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 12918–12919 DOI: 10.1021/ja075382o Supporting Info

Structural Assignment of Polarization in Hydrogen-Bonded Supramolecular Ferroelectrics Reiji Kumai, Sachio Horiuchi, Hajime Sagayama, Taka-hisa Arima, Masashi Watanabe, Yukio Noda, and Yoshinori Tokura pp 12920–12921 DOI: 10.1021/ja075406r Supporting Info

Catalytic Synthesis and Structural Characterizations of a Highly Crystalline Polyphenylacetylene Nanobelt Array Wei Liu, Zhi-Min Cui, Qiang Liu, Dong-Wei Yan, Jing-Yi Wu, Hui-Juan Yan, Yun-Long Guo, Chun-Ru Wang, Wei-Guo Song, Yun-Qi Liu, and Li-Jun Wan pp 12922–12923 DOI: 10.1021/ja075540b Supporting Info

Cylindrical Block Co-Micelles with Spatially Selective Functionalization by Nanoparticles Hai Wang, Wanjuan Lin, Karolina P. Fritz, Gregory D. Scholes, Mitchell A. Winnik, and Ian Manners pp 12924–12925 DOI: 10.1021/ja075587x Supporting Info

Trisubstituted Isoalloxazines as a New Class of G-Quadruplex Binding Ligands:  Small Molecule Regulation of c-kit Oncogene Expression Mallesham Bejugam, Sven Sewitz, Pravin S. Shirude, Raphaël Rodriguez, Ramla Shahid, and Shankar Balasubramanian pp 12926–12927 DOI: 10.1021/ja075881p Supporting Info

Bisphosphine-Catalyzed Mixed Double-Michael Reactions:  Asymmetric Synthesis of Oxazolidines, Thiazolidines, and Pyrrolidines Vardhineedi Sriramurthy, Gregg A. Barcan, and Ohyun Kwon pp 12928–12929 DOI: 10.1021/ja073754n Supporting Info

Design and Preparation of a Chiral Ligand Based on a Pseudorotaxane Skeleton:  Application to Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides Gaku Hattori, Tetsuharu Hori, Yoshihiro Miyake, and Yoshiaki Nishibayashi pp 12930–12931 DOI: 10.1021/ja075231l Supporting Info

Synthesis of ω-Hydroxy Hexathiolate-Protected Subnanometric Gold Clusters Jose M. Abad, Iuliana E. Sendroiu, Mhairi Gass, Andrew Bleloch, Allan J. Mills, and David J. Schiffrin pp 12932–12933 DOI: 10.1021/ja075434+ Supporting Info

Reaction of [σ:η5-(C9H6)C2B9H10]Zr(NMe2)(DME) with Guanidines:  Metallacarborane-Mediated C−N Bond Cleavage and 1,5-Sigmatropic Rearrangement Hao Shen, Hoi-Shan Chan, and Zuowei Xie pp 12934–12935 DOI: 10.1021/ja0754498 Supporting Info

Periodate-Triggered Cross-Linking Reveals Sug2/Rpt4 as the Molecular Target of a Peptoid Inhibitor of the 19S Proteasome Regulatory Particle Hyun-Suk Lim, Di Cai, Chase T. Archer, and Thomas Kodadek pp 12936–12937 DOI: 10.1021/ja075469+ Supporting Info

A New Type of Imido Group Donor:  Synthesis and Characterization of Sulfonylimino-λ3-bromane that Acts as a Nitrenoid in the Aziridination of Olefins at Room Temperature under Metal-Free Conditions Masahito Ochiai, Takao Kaneaki, Norihiro Tada, Kazunori Miyamoto, Hiroshi Chuman, Motoo Shiro, Satoko Hayashi, and Waro Nakanishi pp 12938–12939 DOI: 10.1021/ja075811i Supporting Info

Engineering and Analysis of a Self-Sufficient Biosynthetic Cytochrome P450 PikC Fused to the RhFRED Reductase Domain Shengying Li, Larissa M. Podust, and David H. Sherman pp 12940–12941 DOI: 10.1021/ja075842d Supporting Info

Hyperpolarized 89Y Offers the Potential of Direct Imaging of Metal Ions in Biological Systems by Magnetic Resonance Matthew E. Merritt, Crystal Harrison, Zoltan Kovacs, Preeti Kshirsagar, Craig R. Malloy, and A. Dean Sherry pp 12942–12943 DOI: 10.1021/ja075768z Supporting Info

Enantioselective Metallophosphite-Catalyzed C-Acylation of Nitrones Mary R. Garrett, James C. Tarr, and Jeffrey S. Johnson pp 12944–12945 DOI: 10.1021/ja076095n Supporting Info

Product Deuterium Isotope Effect for Orotidine 5‘-Monophosphate Decarboxylase:  Evidence for the Existence of a Short-Lived Carbanion Intermediate Krisztina Toth, Tina L. Amyes, Bryant M. Wood, Kui Chan, John A. Gerlt, and John P. Richard pp 12946–12947 DOI: 10.1021/ja076222f

Copper(II)-Catalyzed Enantioselective Intramolecular Carboamination of Alkenes Wei Zeng and Sherry R. Chemler pp 12948–12949 DOI: 10.1021/ja0762240 Supporting Info

Enantioselective Catalysis of Ketoester-ene Reaction of Silyl Enol Ether to Construct Quaternary Carbons by Chiral Dicationic Palladium(II) Complexes Koichi Mikami, Yuji Kawakami, Katsuhiro Akiyama, and Kohsuke Aikawa pp 12950–12951 DOI: 10.1021/ja076539f Supporting Info

Mechanism of Alkyne Insertion of a Cationic Zirconocene Aryl Complex Orson L. Sydora, Stefan M. Kilyanek, and Richard F. Jordan pp 12952–12953 DOI: 10.1021/ja0760067 Supporting Info

Role of Electrostatic Interactions in Transient Encounter Complexes in Protein−Protein Association Investigated by Paramagnetic Relaxation Enhancement Jeong-Yong Suh, Chun Tang, and G. Marius Clore pp 12954–12955 DOI: 10.1021/ja0760978 Supporting Info

Deuterium Exchange as an Indicator of Hydrogen Bond Donors and Acceptors Lauren R. Steffel, Timothy J. Cashman, Michael H. Reutershan, and Brian R. Linton pp 12956–12957 DOI: 10.1021/ja076185s Supporting Info

Enantioselective Chromatographic Resolution and One-Pot Synthesis of Enantiomerically Pure Sulfoxides over a Homochiral Zn−Organic Framework Alexey L. Nuzhdin, Danil N. Dybtsev, Konstantin P. Bryliakov, Evgenii P. Talsi, and Vladimir P. Fedin pp 12958–12959 DOI: 10.1021/ja076276p Supporting Info

The Sixteen CB11HnMe12-n- Anions with Fivefold Substitution Symmetry:  Anodic Oxidation and Electronic Structure Benjamin T. King, Stefanie Körbe, Peter J. Schreiber, Joshua Clayton, Adriana Němcová, Zdeněk Havlas, Kamesh Vyakaranam, Matthew G. Fete, Ilya Zharov, Jason Ceremuga, and Josef Michl pp 12960–12980 DOI: 10.1021/ja066247z Supporting Info

Notable Effect of an Electron-Withdrawing Group at C3 on the Selective Formation of Alkylidenecyclobutanes in the Thermal Denitrogenation of 4-Spirocyclopropane-1-pyrazolines. Nonstatistical Dynamics Effects in the Denitrogenation Reactions Masashi Hamaguchi, Masahiro Nakaishi, Toshikazu Nagai, Takeshi Nakamura, and Manabu Abe pp 12981–12988 DOI: 10.1021/ja068513e Supporting Info

Polarized X-ray Absorption Spectroscopy of Single-Crystal Mn(V) Complexes Relevant to the Oxygen-Evolving Complex of Photosystem II Junko Yano, John Robblee, Yulia Pushkar, Matthew A. Marcus, Jesper Bendix, José M. Workman, Terrence J. Collins, Edward I. Solomon, Serena DeBeer George, and Vittal K. Yachandra pp 12989–13000 DOI: 10.1021/ja071286b Supporting Info

Pd-Catalyzed Amidations of Aryl Chlorides Using Monodentate Biaryl Phosphine Ligands:  A Kinetic, Computational, and Synthetic Investigation Takashi Ikawa, Timothy E. Barder, Mark R. Biscoe, and Stephen L. Buchwald pp 13001–13007 DOI: 10.1021/ja0717414 Supporting Info

Synthetic Efficiency in Enzyme Mechanisms Involving Carbocations:  Aristolochene Synthase Rudolf K. Allemann, Neil J. Young, Shuhua Ma, Donald G. Truhlar, and Jiali Gao pp 13008–13013 DOI: 10.1021/ja0722067 Supporting Info

Pump-Shaped Dump Optimal Control Reveals the Nuclear Reaction Pathway of Isomerization of a Photoexcited Cyanine Dye Benjamin Dietzek, Ben Brüggemann, Torbjörn Pascher, and Arkady Yartsev pp 13014–13021 DOI: 10.1021/ja072639+ Supporting Info

Aromatic Molecules in Anion Recognition:  Electrostatics versus H-Bonding Holger Schneider, Kristen M. Vogelhuber, Florian Schinle, and J. Mathias Weber pp 13022–13026 DOI: 10.1021/ja073028k Supporting Info

Internuclear 31P−51V Distance Measurements in Polyoxoanionic Solids Using Rotational Echo Adiabatic Passage Double Resonance NMR Spectroscopy Wenlin Huang, Alexander J. Vega, Terry Gullion, and Tatyana Polenova pp 13027–13034 DOI: 10.1021/ja073170l Supporting Info

An Opsin Shift in Rhodopsin:  Retinal S0−S1 Excitation in Protein, in Solution, and in the Gas Phase Ksenia Bravaya, Anastasia Bochenkova, Alexander Granovsky, and Alexander Nemukhin pp 13035–13042 DOI: 10.1021/ja0732126 Supporting Info

An Artificial β-Sheet That Dimerizes through Parallel β-Sheet Interactions Sergiy Levin and James S. Nowick pp 13043–13048 DOI: 10.1021/ja073391r Supporting Info

Solid-State 63Cu and 65Cu NMR Spectroscopy of Inorganic and Organometallic Copper(I) Complexes Joel A. Tang, Bobby D. Ellis, Timothy H. Warren, John V. Hanna, Charles L. B. Macdonald, and Robert W. Schurko pp 13049–13065 DOI: 10.1021/ja073238x Supporting Info

Scaling Laws for Charge Transfer in Multiply Bridged Donor/Acceptor Molecules in a Dissipative Environment Randall H. Goldsmith, Michael R. Wasielewski, and Mark A. Ratner pp 13066–13071 DOI: 10.1021/ja073589b Supporting Info

Charge Transport Parameters of the Pentathienoacene Crystal Eung-Gun Kim, Veaceslav Coropceanu, Nadine E. Gruhn, Roel S. Sánchez-Carrera, Robert Snoeberger, Adam J. Matzger, and Jean-Luc Brédas pp 13072–13081 DOI: 10.1021/ja073587r Supporting Info

Characterization of the Maduropeptin Biosynthetic Gene Cluster from Actinomadura madurae ATCC 39144 Supporting a Unifying Paradigm for Enediyne Biosynthesis Steven G. Van Lanen, Tae-jin Oh, Wen Liu, Evelyn Wendt-Pienkowski, and Ben Shen pp 13082–13094 DOI: 10.1021/ja073275o

Conformational Manifold of α-Aminoisobutyric Acid (Aib) Containing Alanine-Based Tripeptides in Aqueous Solution Explored by Vibrational Spectroscopy, Electronic Circular Dichroism Spectroscopy, and Molecular Dynamics Simulations Reinhard Schweitzer-Stenner, Widalys Gonzales, Gregory T. Bourne, Jianwen A. Feng, and Garland R. Marshall pp 13095–13109 DOI: 10.1021/ja0738430 Supporting Info

Quantitative Inhibitor Fingerprinting of Metalloproteases Using Small Molecule Microarrays Mahesh Uttamchandani, Wei L. Lee, Jun Wang, and Shao Q. Yao pp 13110–13117 DOI: 10.1021/ja073914v Supporting Info

Spectroscopic and Kinetic Studies of Perturbed Trinuclear Copper Clusters:  The Role of Protons in Reductive Cleavage of the O−O Bond in the Multicopper Oxidase Fet3p Anthony J. Augustine, Liliana Quintanar, Christopher S. Stoj, Daniel J. Kosman, and Edward I. Solomon pp 13118–13126 DOI: 10.1021/ja073905m Supporting Info

Electronic Structure of the Peroxy Intermediate and Its Correlation to the Native Intermediate in the Multicopper Oxidases:  Insights into the Reductive Cleavage of the O−O Bond Jungjoo Yoon and Edward I. Solomon pp 13127–13136 DOI: 10.1021/ja073947a Supporting Info

Synthetic Ligands Discovered by in Vitro Selection S. Jarrett Wrenn, Rebecca M. Weisinger, David R. Halpin, and Pehr B. Harbury pp 13137–13143 DOI: 10.1021/ja073993a Supporting Info

Resistive-Pulse Studies of Proteins and Protein/Antibody Complexes Using a Conical Nanotube Sensor Lindsay T. Sexton, Lloyd P. Horne, Stefanie A. Sherrill, Gregory W. Bishop, Lane A. Baker, and Charles R. Martin pp 13144–13152 DOI: 10.1021/ja0739943

A Chemical Approach to the Pharmaceutical Optimization of an Anti-HIV Protein Les P. Miranda, Haiyan Shao, Jason Williams, Shiah-Yun Chen, Ting Kong, Rod Garcia, Yvonne Chinn, Nathalie Fraud, Bill O'Dwyer, Jay Ye, Jill Wilken, Donald E. Low, E. Neil Cagle, Maia Carnevali, Alexander Lee, Di Song, Ada Kung, James A. Bradburne, Xavier Paliard, and Gerd G. Kochendoerfer pp 13153–13159 DOI: 10.1021/ja073982h Supporting Info

Spatial and Intensity Modulation of Nanowire Emission Induced by Mobile Charges Vladimir Protasenko, Stanislav Gordeyev, and Masaru Kuno pp 13160–13171 DOI: 10.1021/ja073642w Supporting Info

Activation of Carbon−Hydrogen Bonds via 1,2-Addition across M−X (X = OH or NH2) Bonds of d6 Transition Metals as a Potential Key Step in Hydrocarbon Functionalization:  A Computational Study Thomas R. Cundari, Thomas V. Grimes, and T. Brent Gunnoe pp 13172–13182 DOI: 10.1021/ja074125g Supporting Info

Meta Conjugation Effect on the Torsional Motion of Aminostilbenes in the Photoinduced Intramolecular Charge-Transfer State Jye-Shane Yang, Kang-Ling Liau, Chun-Yi Li, and Mon-Yao Chen pp 13183–13192 DOI: 10.1021/ja0741022 Supporting Info

1,4,5,8,9,12-Hexamethyltriphenylene. A Molecule with a Flipping Twist Yi Wang, Andrew D Stretton, Mark C McConnell, Peter A. Wood, Simon Parsons, John B Henry, Andrew R Mount, and Trent H Galow pp 13193–13200 DOI: 10.1021/ja074120j Supporting Info

Structural Requirements and Reaction Pathways in Dimethyl Ether Combustion Catalyzed by Supported Pt Clusters Akio Ishikawa, Matthew Neurock, and Enrique Iglesia pp 13201–13212 DOI: 10.1021/ja073712z Supporting Info

17O and 29Si NMR Parameters of MgSiO3 Phases from High-Resolution Solid-State NMR Spectroscopy and First-Principles Calculations Sharon E. Ashbrook, Andrew J. Berry, Daniel J. Frost, Alan Gregorovic, Chris J. Pickard, Jennifer E. Readman, and Stephen Wimperis pp 13213–13224 DOI: 10.1021/ja074428a

Single Molecule Junctions Formed via Au−Thiol Contact:  Stability and Breakdown Mechanism Zhifeng Huang, Fang Chen, Peter A. Bennett, and Nongjian Tao pp 13225–13231 DOI: 10.1021/ja074456t Supporting Info

TROSY-Based z-Exchange Spectroscopy:  Application to the Determination of the Activation Energy for Intermolecular Protein Translocation between Specific Sites on Different DNA Molecules Debashish Sahu, G. Marius Clore, and Junji Iwahara pp 13232–13237 DOI: 10.1021/ja074604f

A Peptide Dendrimer Enzyme Model with a Single Catalytic Site at the Core Sacha Javor, Estelle Delort, Tamis Darbre, and Jean-Louis Reymond pp 13238–13246 DOI: 10.1021/ja074115f Supporting Info

Experimental Evidence for a Highly Reversible Excited State Equilibrium between s-Cis and s-Trans Rotational Isomers of 2-Methoxynaphthalene in Solution Ioanna Balomenou and George Pistolis pp 13247–13253 DOI: 10.1021/ja074638n

Dual-Mode Fluorophore-Doped Nickel Nitrilotriacetic Acid-Modified Silica Nanoparticles Combine Histidine-Tagged Protein Purification with Site-Specific Fluorophore Labeling Sung Hoon Kim, M. Jeyakumar, and John A. Katzenellenbogen pp 13254–13264 DOI: 10.1021/ja074443f Supporting Info

7,8-Dihydro Retinals Outperform the Native Retinals in Conferring Photosensitivity to Visual Opsin Willem J. DeGrip, Petra H.M. Bovee-Geurts, Ineke van der Hoef, and Johan Lugtenburg pp 13265–13269 DOI: 10.1021/ja074937c Supporting Info

Probing the Electronic Structure of Early Transition-Metal Oxide Clusters:  Polyhedral Cages of (V2O5)n- (n = 2−4) and (M2O5)2- (M = Nb, Ta) Hua-Jin Zhai, Jens Döbler, Joachim Sauer, and Lai-Sheng Wang pp 13270–13276 DOI: 10.1021/ja0750874

Diversification of Self-Organized Architectures in Supramolecular Dye Assemblies Shiki Yagai, Tetsuro Kinoshita, Masatsugu Higashi, Keiki Kishikawa, Takashi Nakanishi, Takashi Karatsu, and Akihide Kitamura pp 13277–13287 DOI: 10.1021/ja075257c Supporting Info

Conformational Preferences of Chondroitin Sulfate Oligomers Using Partially Oriented NMR Spectroscopy of 13C-Labeled Acetyl Groups Fei Yu, Jeremy J. Wolff, I. Jonathan Amster, and James H. Prestegard pp 13288–13297 DOI: 10.1021/ja075272h

Programmed Thermodynamic Formation and Structure Analysis of Star-like Nanogels with Core Cross-linked by Thermally Exchangeable Dynamic Covalent Bonds Yoshifumi Amamoto, Yuji Higaki, Yasuhiro Matsuda, Hideyuki Otsuka, and Atsushi Takahara pp 13298–13304 DOI: 10.1021/ja075447n Supporting Info

Self-Construction of Core−Shell and Hollow Zeolite Analcime Icositetrahedra:  A Reversed Crystal Growth Process via Oriented Aggregation of Nanocrystallites and Recrystallization from Surface to Core Xueying Chen, Minghua Qiao, Songhai Xie, Kangnian Fan, Wuzong Zhou, and Heyong He pp 13305–13312 DOI: 10.1021/ja074834u

Switching in Molecular Transport Junctions:  Polarization Response Sina Yeganeh, Michael Galperin, and Mark A. Ratner pp 13313–13320 DOI: 10.1021/ja0730967 Supporting Info

Palladium-Catalyzed Cross-Coupling Reactions in One-Pot Multicatalytic Processes Hélène Lebel, Chehla Ladjel, and Lise Bréthous pp 13321–13326 DOI: 10.1021/ja0733235 Supporting Info

Synchronicity of Mononuclear and Dinuclear Events in Homogeneous Catalysis. Hydroformylation of Cyclopentene Using Rh4(CO)12 and HRe(CO)5 as Precursors Chuanzhao Li, Li Chen, and Marc Garland pp 13327–13334 DOI: 10.1021/ja073339v Supporting Info

Direct Measurement of a pKa near Neutrality for the Catalytic Cytosine in the Genomic HDV Ribozyme Using Raman Crystallography Bo Gong, Jui-Hui Chen, Elaine Chase, Durga M. Chadalavada, Rieko Yajima, Barbara L. Golden, Philip C. Bevilacqua, and Paul R. Carey pp 13335–13342 DOI: 10.1021/ja0743893 Supporting Info

Effect of Xenon on Fullerene Reactions Michael Frunzi, R. James Cross, and Martin Saunders pp 13343–13346 DOI: 10.1021/ja075568n Supporting Info

Living Radical Polymerizations with Germanium, Tin, and Phosphorus Catalysts − Reversible Chain Transfer Catalyzed Polymerizations (RTCPs) Atsushi Goto, Hirokazu Zushi, Norihiro Hirai, Tsutomu Wakada, Yoshinobu Tsujii, and Takeshi Fukuda pp 13347–13354 DOI: 10.1021/ja0755820 Supporting Info

A New Class of Macrocyclic Receptors from iota-Peptides  [J. Am. Chem. Soc. 2007, 129, 1486−1487]. Sang-Woo Kang, Chris M. Gothard, Santanu Maitra, Atia-tul-Wahab, andJames S. Nowick p 13355 DOI: 10.1021/ja079950b

Cis−Trans Isomerization in Biochemistry Edited by Christophe Dugave (CEA/Saclay, Gif-sur-Yvette, France). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xvi + 354 pp. $190. ISBN 3-527-31304-4. Thomas P. Sakmar p 13356 DOI: 10.1021/ja076941u

The Quantum Theory of Atoms in Molecules:  From Solid State to DNA and Drug Design Edited by Chérif F. Matta (Mount Saint Vincent University, Halifax, Canada) and Russell J. Boyd (Dalhousie University, Halifax, Canada). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xxxviii + 528 pp. $200. ISBN 978-3-527-30748-7. Thomas L. Beck pp 13356–13357 DOI: 10.1021/ja076962o

Biochemistry and Molecular Biology Compendium By Roger L. Lundblad (Consultant, Chapel Hill, NC). CRC Press/Taylor & Francis Group:  Boca Raton, FL. 2007. x + 410 pp. $99.95. ISBN 1-4200-4347-1. p 13357 DOI: 10.1021/ja0769954

Reviews of Reactive Intermediate Chemistry Edited by Matthew S. Platz (The Ohio State University, Columbus, OH), Robert A. Moss (Rutgers University, New Brunswick, NJ), and Maitland Jones, Jr. (Princeton University, Princeton, NJ). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. x + 472 pp. $115. ISBN 978-0-471-73166-5. Robert E. Continetti pp 13357–13358 DOI: 10.1021/ja076957k

Fourier Transform Infrared Spectrometry, 2nd ed By Peter R. Griffiths (University of Idaho, Moscow) and James A. De Haseth (University of Georgia, Athens). J. Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xviii + 530 pp. $ 115. ISBN 978-0-471-19404-0. Richard Mendelsohn p 13358 DOI: 10.1021/ja076968d

Issue 44

Reaction Pathway of Conjugate Addition of Lithium Organozincates to s-trans-Enones Masanobu Uchiyama, Shinji Nakamura, Taniyuki Furuyama, Eiichi Nakamura, and Keiji Morokuma pp 13360–13361 DOI: 10.1021/ja070123k Supporting Info

Anthracenedicarboximides as Air-Stable N-Channel Semiconductors for Thin-Film Transistors with Remarkable Current On−Off Ratios Zhiming Wang, Choongik Kim, Antonio Facchetti, and Tobin J. Marks pp 13362–13363 DOI: 10.1021/ja073306f Supporting Info

Room-Temperature Discotic Nematic Liquid Crystals over a Wide Temperature Range:  Alkali-Metal-Ion-Induced Phase Transition from Discotic Nematic to Columnar Phases Shigeo Kohmoto, Emiko Mori, and Keiki Kishikawa pp 13364–13365 DOI: 10.1021/ja073962f Supporting Info

Total Synthesis of (±)-Phomactin B2 via an Intramolecular Cyclohexadienone Annulation of a Chromium Carbene Complex Jie Huang, Chunrui Wu, and William D. Wulff pp 13366–13367 DOI: 10.1021/ja074275r Supporting Info

Reductive Cleavage of Sulfones and Sulfonamides by a Neutral Organic Super-Electron-Donor (S.E.D.) Reagent Franziska Schoenebeck, John A. Murphy, Sheng-ze Zhou, Yoshitaka Uenoyama, Yves Miclo, and Tell Tuttle pp 13368–13369 DOI: 10.1021/ja074417h Supporting Info

Supramolecular Control of Charge Transport in Molecular Wires Ferdinand C. Grozema, Coralie Houarner-Rassin, Paulette Prins, Laurens D. A. Siebbeles, and Harry L. Anderson pp 13370–13371 DOI: 10.1021/ja0751274 Supporting Info

Simultaneous Monitoring of Discrete Binding Events Using Dual-Acceptor Terbium-Based LRET Kevin R. Kupcho, Deborah K. Stafslien, Therese DeRosier, Tina M. Hallis, Mary Szatkowski Ozers, and Kurt W. Vogel pp 13372–13373 DOI: 10.1021/ja074791h Supporting Info

Controlling Protein−Protein Interactions through Metal Coordination:  Assembly of a 16-Helix Bundle Protein Eric N. Salgado, Jasmin Faraone-Mennella, and F. Akif Tezcan pp 13374–13375 DOI: 10.1021/ja075261o Supporting Info

Modular Access to Structurally Switchable 3D Discrete DNA Assemblies Faisal A. Aldaye and Hanadi F. Sleiman pp 13376–13377 DOI: 10.1021/ja075966q Supporting Info

A Simple Molecular Machine Operated by Photoinduced Proton Transfer Serena Silvi, Arturo Arduini, Andrea Pochini, Andrea Secchi, Massimiliano Tomasulo, Françisco M. Raymo, Massimo Baroncini, and Alberto Credi pp 13378–13379 DOI: 10.1021/ja0753851 Supporting Info

Gallepins. Neutral Gallium Analogues of the Tropylium Ion:  Synthesis, Structure, and Aromaticity Brandon Quillian, Yuzhong Wang, Pingrong Wei, Chaitanya S. Wannere, Paul v. R. Schleyer, and Gregory H. Robinson pp 13380–13381 DOI: 10.1021/ja075428d Supporting Info

A Methyl Group Controls Conformational Equilibrium in Human Mitochondrial tRNALys Felix Voigts-Hoffmann, Martin Hengesbach, Andrei Yu. Kobitski, Arthur van Aerschot, Piet Herdewijn, G. Ulrich Nienhaus, and Mark Helm pp 13382–13383 DOI: 10.1021/ja075520+ Supporting Info

A Unique Flavin Mononucleotide-Linked Primary Alcohol Oxidase for Glycopeptide A40926 Maturation Yi-Shan Li, Jin-Yuan Ho, Chia-Chi Huang, Syue-Yi Lyu, Chun-Yen Lee, Yu-Ting Huang, Chang-Jer Wu, Hsiu-Chien Chan, Chuan-Jiuan Huang, Ning-Shian Hsu, Ming-Daw Tsai, and Tsung-Lin Li pp 13384–13385 DOI: 10.1021/ja075748x Supporting Info

Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule Manfred Scheer, Andrea Schindler, Roger Merkle, Brian P. Johnson, Michael Linseis, Rainer Winter, Christopher E. Anson, and Alexander V. Virovets pp 13386–13387 DOI: 10.1021/ja075926m Supporting Info

Direct Fabrication of Well-Aligned Free-Standing Mesoporous Carbon Nanofiber Arrays on Silicon Substrates Kaixue Wang, Wenhua Zhang, Richard Phelan, Michael A. Morris, and Justin D. Holmes pp 13388–13389 DOI: 10.1021/ja0752843 Supporting Info

Ordering of Binary Polymeric Nanoparticles on Hydrophobic Surfaces Assembled from Low Volume Fraction Dispersions Rupa Mukhopadhyay, Othman Al-Hanbali, Saju Pillai, Anne Gry Hemmersam, Rikke Louise Meyer, Alan Christy Hunter, Kenneth John Rutt, Flemming Besenbacher, Seyed Moein Moghimi, and Peter Kingshott pp 13390–13391 DOI: 10.1021/ja075988c Supporting Info

Magnetic Glyco-nanoparticles:  A Unique Tool for Rapid Pathogen Detection, Decontamination, and Strain Differentiation Kheireddine El-Boubbou, Cyndee Gruden, and Xuefei Huang pp 13392–13393 DOI: 10.1021/ja076086e Supporting Info

Structural Characterization of the Fleeting Ferric Peroxo Species in Myoglobin:  Experiment and Theory Masaki Unno, Hui Chen, Shusuke Kusama, Sason Shaik, and Masao Ikeda-Saito pp 13394–13395 DOI: 10.1021/ja076108x Supporting Info

Characterization of Chemical Exchange Using Residual Dipolar Coupling Tatyana I. Igumenova, Ulrika Brath, Mikael Akke, and Arthur G. Palmer, III pp 13396–13397 DOI: 10.1021/ja0761636 Supporting Info

Kinetic Trapping of Large Amount of Long Polymers in Nanopores Andrzej Żywociński, Anna Korda, Joanna Gosk, Stefan A. Wieczorek, Agnieszka Wilk, and Robert Hołyst pp 13398–13399 DOI: 10.1021/ja0762590 Supporting Info

Elemental Tomography of Cancer-Cell Spheroids Reveals Incomplete Uptake of Both Platinum(II) and Platinum(IV) Complexes Rebecca A. Alderden, Howard R. Mellor, Szabolcs Modok, Matthew D. Hall, Stephen R. Sutton, Matthew G. Newville, Richard Callaghan, and Trevor W. Hambley pp 13400–13401 DOI: 10.1021/ja076281t Supporting Info

Nickel(0)-Catalyzed [2 + 2 + 2 + 2] Cycloadditions of Terminal Diynes for the Synthesis of Substituted Cyclooctatetraenes Paul A. Wender and Justin P. Christy pp 13402–13403 DOI: 10.1021/ja0763044 Supporting Info

Enantioselective Pictet−Spengler-Type Cyclizations of Hydroxylactams:  H-Bond Donor Catalysis by Anion Binding Izzat T. Raheem, Parvinder S. Thiara, Emily A. Peterson, and Eric N. Jacobsen pp 13404–13405 DOI: 10.1021/ja076179w Supporting Info

Tailoring Relaxation Dispersion Experiments for Fast-Associating Protein Complexes Kenji Sugase, Jonathan C. Lansing, H. Jane Dyson, and Peter E. Wright pp 13406–13407 DOI: 10.1021/ja0762238 Supporting Info

Spectroscopic Evidence for a High-Spin Br-Fe(IV)-Oxo Intermediate in the α-Ketoglutarate-Dependent Halogenase CytC3 from Streptomyces Danica Galonić Fujimori, Eric W. Barr, Megan L. Matthews, Gretchen M. Koch, J. Ryan Yonce, Christopher T. Walsh, J. Martin Bollinger, Jr., Carsten Krebs, and Pamela J. Riggs-Gelasco pp 13408–13409 DOI: 10.1021/ja076454e Supporting Info

Catalytic Asymmetric Cyclopropanation of Enones with Dimethyloxosulfonium Methylide Promoted by a La−Li3−(Biphenyldiolate)3 + NaI Complex Hiroyuki Kakei, Toshihiko Sone, Yoshihiro Sohtome, Shigeki Matsunaga, and Masakatsu Shibasaki pp 13410–13411 DOI: 10.1021/ja076797c Supporting Info

On the Role of Water in Intermolecular Proton-Transfer Reactions Bradley J. Siwick and Huib J. Bakker pp 13412–13420 DOI: 10.1021/ja069265p

Electronic Structure of the Mn4OxCa Cluster in the S0 and S2 States of the Oxygen-Evolving Complex of Photosystem II Based on Pulse 55Mn-ENDOR and EPR Spectroscopy Leonid V. Kulik, Boris Epel, Wolfgang Lubitz, and Johannes Messinger pp 13421–13435 DOI: 10.1021/ja071487f Supporting Info

Versatility of the Electronic Structure of Compound I in Catalase-Peroxidases Pietro Vidossich, Mercedes Alfonso-Prieto, Xavi Carpena, Peter C. Loewen, Ignacio Fita, and Carme Rovira pp 13436–13446 DOI: 10.1021/ja072245i Supporting Info

Development of an Iminocoumarin-Based Zinc Sensor Suitable for Ratiometric Fluorescence Imaging of Neuronal Zinc Kensuke Komatsu, Yasuteru Urano, Hirotatsu Kojima, and Tetsuo Nagano pp 13447–13454 DOI: 10.1021/ja072432g

Oxygen Donor-Mediated Equilibration of Diastereomeric Alkene−Palladium(II) Intermediates in Enantioselective Desymmetrizing Heck Cyclizations Axel B. Machotta, Bernd F. Straub, and Martin Oestreich pp 13455–13463 DOI: 10.1021/ja072571y Supporting Info

Extraction of Hydrophobic Species into a Water-Soluble Synthetic Receptor Richard J. Hooley, Hillary J. Van Anda, and Julius Rebek, Jr. pp 13464–13473 DOI: 10.1021/ja0727058 Supporting Info

Small-Angle Neutron and X-ray Scattering from Amphiphilic Stimuli-Responsive Diamond-Type Bicontinuous Cubic Phase Borislav Angelov, Angelina Angelova, Vasil M. Garamus, Geneviève Lebas, Sylviane Lesieur, Michel Ollivon, Sérgio S. Funari, Regine Willumeit, and Patrick Couvreur pp 13474–13479 DOI: 10.1021/ja072725+ Supporting Info

Small Multivalent Architectures Mimicking Homotrimers of the TNF Superfamily Member CD40L:  Delineating the Relationship between Structure and Effector Function Nathalie Trouche, Sébastien Wieckowski, Weimin Sun, Olivier Chaloin, Johan Hoebeke, Sylvie Fournel, and Gilles Guichard pp 13480–13492 DOI: 10.1021/ja073169m Supporting Info

Electron Transfer between a Tyrosyl Radical and a Cysteine Residue in Hemoproteins:  Spin Trapping Analysis Suchandra Bhattacharjee, Leesa J. Deterding, JinJie Jiang, Marcelo G. Bonini, Kenneth B. Tomer, Dario C. Ramirez, and Ronald P. Mason pp 13493–13501 DOI: 10.1021/ja073349w

Time-Resolved Long-Lived Luminescence Imaging Method Employing Luminescent Lanthanide Probes with a New Microscopy System Kenjiro Hanaoka, Kazuya Kikuchi, Shigeru Kobayashi, and Tetsuo Nagano pp 13502–13509 DOI: 10.1021/ja073392j Supporting Info

First-Principle Calculation of Equilibrium Cesium Ion-Pair Acidities in Tetrahydrofuran Yao Fu, Kuang Shen, Lei Liu, and Qing-Xiang Guo pp 13510–13519 DOI: 10.1021/ja073548f Supporting Info

How Does a Transient Amorphous Precursor Template Crystallization Tian Hui Zhang and Xiang Yang Liu pp 13520–13526 DOI: 10.1021/ja073598k

Extended Sugar-Assisted Glycopeptide Ligations:  Development, Scope, and Applications Richard J. Payne, Simon Ficht, Sishi Tang, Ashraf Brik, Yu-Ying Yang, David A. Case, and Chi-Huey Wong pp 13527–13536 DOI: 10.1021/ja073653p Supporting Info

Free Energy Perturbation (FEP) Simulation on the Transition States of Cocaine Hydrolysis Catalyzed by Human Butyrylcholinesterase and Its Mutants Yongmei Pan, Daquan Gao, Wenchao Yang, Hoon Cho, and Chang-Guo Zhan pp 13537–13543 DOI: 10.1021/ja073724k Supporting Info

One Water Molecule Stabilizes the Cationized Arginine Zwitterion Matthew F. Bush, James S. Prell, Richard J. Saykally, and Evan R. Williams pp 13544–13553 DOI: 10.1021/ja073796b Supporting Info

Photochemical Grafting of n-Alkenes onto Carbon Surfaces:  the Role of Photoelectron Ejection Paula E. Colavita, Bin Sun, Kiu-Yuen Tse, and Robert J. Hamers pp 13554–13565 DOI: 10.1021/ja073944y Supporting Info

Molecular Structures and Dynamics of the Stepwise Activation Mechanism of a Matrix Metalloproteinase Zymogen:  Challenging the Cysteine Switch Dogma Gabriel Rosenblum, Samy Meroueh, Marta Toth, Jed F. Fisher, Rafael Fridman, Shahriar Mobashery, and Irit Sagi pp 13566–13574 DOI: 10.1021/ja073941l Supporting Info

Boronic Acid Based Peptidic Receptors for Pattern-Based Saccharide Sensing in Neutral Aqueous Media, an Application in Real-Life Samples Nicola Y. Edwards, Thomas W. Sager, John T. McDevitt, and Eric V. Anslyn pp 13575–13583 DOI: 10.1021/ja073939u Supporting Info

Photochemical Reaction Pathways of Carbon Tetrabromide in Solution Probed by Picosecond X-ray Diffraction Qingyu Kong, Michael Wulff, Jae Hyuk Lee, Savo Bratos, and Hyotcherl Ihee pp 13584–13591 DOI: 10.1021/ja073503e Supporting Info

Cross-Strand Coupling of a β-Hairpin Peptide Stabilized with an Aib-Gly Turn Studied Using Isotope-Edited IR Spectroscopy Rong Huang, Vladimir Setnika, Marcus A. Etienne, Joohyun Kim, Jan Kubelka, Robert P. Hammer, and Timothy A. Keiderling pp 13592–13603 DOI: 10.1021/ja0736414 Supporting Info

Anatase-TiO2 Nanomaterials:  Analysis of Key Parameters Controlling Crystallization Marcos Fernández-García, Carolina Belver, Jonathan C. Hanson, Xianqin Wang, and José A. Rodriguez pp 13604–13612 DOI: 10.1021/ja074064m

Modulation of Bacterial Quorum Sensing with Synthetic Ligands:  Systematic Evaluation of N-Acylated Homoserine Lactones in Multiple Species and New Insights into Their Mechanisms of Action Grant D. Geske, Jennifer C. O'Neill, David M. Miller, Margrith E. Mattmann, and Helen E. Blackwell pp 13613–13625 DOI: 10.1021/ja074135h Supporting Info

Simple and Effective 3D Recognition of Domoic Acid Using a Molecularly Imprinted Polymer Koji Nemoto, Takuya Kubo, Makoto Nomachi, Tomoharu Sano, Takatoshi Matsumoto, Ken Hosoya, Tetsutaro Hattori, and Kunimitsu Kaya pp 13626–13632 DOI: 10.1021/ja0741426 Supporting Info

Molecular Dynamics Simulations of the Catalytic Pathway of a Cysteine Protease:  A Combined QM/MM Study of Human Cathepsin K Shuhua Ma, Lakshmi S. Devi-Kesavan, and Jiali Gao pp 13633–13645 DOI: 10.1021/ja074222+ Supporting Info

Solvent Effects on the Oxidation of RuIVO to ORuVIO by MnO4-. Hydrogen-Atom versus Oxygen-Atom Transfer William W. Y. Lam, Wai-Lun Man, Chi-Fai Leung, Chun-Yuen Wong, and Tai-Chu Lau pp 13646–13652 DOI: 10.1021/ja074282f Supporting Info

Lanthanide-Containing Polymer Nanoparticles for Biological Tagging Applications:  Nonspecific Endocytosis and Cell Adhesion Cédric Vancaeyzeele, Olga Ornatsky, Vladimir Baranov, Lei Shen, Ahmed Abdelrahman, and Mitchell A. Winnik pp 13653–13660 DOI: 10.1021/ja073970w

Aryl-Substituted C3-Bridged Oligopyrroles as Anion Receptors for Formation of Supramolecular Organogels Hiromitsu Maeda, Yohei Haketa, and Takashi Nakanishi pp 13661–13674 DOI: 10.1021/ja074435z Supporting Info

Assembly of a Homochiral, Body-Centered Cubic Network Composed of Vertex-Shared Mg12 Cages:  Use of Electrospray Ionization Mass Spectrometry to Monitor Metal Carboxylate Nucleation Jeffrey A. Rood, William C. Boggess, Bruce C. Noll, and Kenneth W. Henderson pp 13675–13682 DOI: 10.1021/ja074558j Supporting Info

Ultrafast Study of 9-Diazofluorene:  Direct Observation of the First Two Singlet States of Fluorenylidene Jin Wang, Jacek Kubicki, Edwin F. Hilinski, Sandra L. Mecklenburg, Terry L. Gustafson, and Matthew S. Platz pp 13683–13690 DOI: 10.1021/ja074612w Supporting Info

Organized Surface Functional Groups:  Cooperative Catalysis via Thiol/Sulfonic Acid Pairing Eric L. Margelefsky, Ryan K. Zeidan, Véronique Dufaud, and Mark E. Davis pp 13691–13697 DOI: 10.1021/ja074761e Supporting Info

Surface Recognition and Fluorescence Sensing of Histone by Dansyl-Appended Cyclophane-Based Resorcinarene Trimer Osamu Hayashida, Naoyuki Ogawa, and Masaki Uchiyama pp 13698–13705 DOI: 10.1021/ja074906h Supporting Info

A Flexible Coordination Polymer Crystal Providing Reversible Structural and Magnetic Conversions Wakako Kaneko, Masaaki Ohba, and Susumu Kitagawa pp 13706–13712 DOI: 10.1021/ja074915q Supporting Info

Structure Prediction of Protein−Solid Surface Interactions Reveals a Molecular Recognition Motif of Statherin for Hydroxyapatite Kosta Makrodimitris, David L. Masica, Eric T. Kim, and Jeffrey J. Gray pp 13713–13722 DOI: 10.1021/ja074602v Supporting Info

Petasis Borono-Mannich Reaction and Allylation of Carbonyl Compounds via Transient Allyl Boronates Generated by Palladium-Catalyzed Substitution of Allyl Alcohols. An Efficient One-Pot Route to Stereodefined α-Amino Acids and Homoallyl Alcohols Nicklas Selander, Andreas Kipke, Sara Sebelius, and Kálmán J. Szabó pp 13723–13731 DOI: 10.1021/ja074917a Supporting Info

Design of DNA Minor Groove Binding Diamidines That Recognize GC Base Pair Sequences:  A Dimeric-Hinge Interaction Motif Manoj Munde, Mohamed A. Ismail, Reem Arafa, Paul Peixoto, Catharine J. Collar, Yang Liu, Laixing Hu, Marie-Hélène David-Cordonnier, Amélie Lansiaux, Christian Bailly, David W. Boykin, and W. David Wilson pp 13732–13743 DOI: 10.1021/ja074560a

Dehydration-Induced Water Disordering in a Synthetic Potassium Gallosilicate Natrolite Yongjae Lee, Sun Jin Kim, Ivor Bull, Aaron J. Celestian, John B. Parise, Chi-Chang Kao, and Thomas Vogt pp 13744–13748 DOI: 10.1021/ja075037z Supporting Info

Sequence-Specific and Stereospecific Assignment of Methyl Groups Using Paramagnetic Lanthanides Michael John, Christophe Schmitz, Ah Young Park, Nicholas E. Dixon, Thomas Huber, and Gottfried Otting pp 13749–13757 DOI: 10.1021/ja0744753 Supporting Info

Stereospecificity of Ketoreductase Domains of the 6-Deoxyerythronolide B Synthase Roselyne Castonguay, Weiguo He, Alice Y. Chen, Chaitan Khosla, and David E. Cane pp 13758–13769 DOI: 10.1021/ja0753290 Supporting Info

Different Dynamics of Chiral and Racemic (l- and dl-) Serine Crystals:  Evidenced by Incoherent Inelastic Neutron and Raman Scattering [J. Am. Chem. Soc. 2007, 129, 10984−10985]. Heloisa N. Bordallo, Boris A. Kolesov, Elena V. Boldyreva, and Fanni Juranyi p 13770 DOI: 10.1021/ja076393k

Issue 45

Structural Competition between Hydrogen Bonds and Halogen Bonds Christer B. Aakeröy, Meg Fasulo, Nate Schultheiss, John Desper, and Curtis Moore pp 13772–13773 DOI: 10.1021/ja073201c Supporting Info

Frustrated 2D Molecular Crystallization Hui Zhou, Hung Dang, Ji-Hyun Yi, Antonio Nanci, Alain Rochefort, and James D. Wuest pp 13774–13775 DOI: 10.1021/ja0742535 Supporting Info

Biomimetic Assembly of Zinc Oxide Nanorods onto Flexible Polymers Stephen A. Morin, Fairland F. Amos, and Song Jin pp 13776–13777 DOI: 10.1021/ja074856g Supporting Info

Redox Potential Control by Drug Binding to Cytochrome P450 3A4 Aditi Das, Yelena V. Grinkova, and Stephen G. Sligar pp 13778–13779 DOI: 10.1021/ja074864x Supporting Info

Crystallographic Characterization of the α/β-Peptide 14/15-Helix Soo Hyuk Choi, Ilia A. Guzei, and Samuel H. Gellman pp 13780–13781 DOI: 10.1021/ja0753344 Supporting Info

Infrared Spectroscopy of the tert-Butyl Cation in the Gas Phase Gary E. Douberly, Allen M. Ricks, Brian W. Ticknor, Paul v. R. Schleyer, and Michael A. Duncan pp 13782–13783 DOI: 10.1021/ja0753593 Supporting Info

Catalytic Oxidation of Hydrazo Derivatives Promoted by a TiCl3/HBr System Eyal Drug and Michael Gozin pp 13784–13785 DOI: 10.1021/ja074413c Supporting Info

Robust Nanoporous Membranes Templated by a Doubly Reactive Block Copolymer Liang Chen, William A. Phillip, E. L. Cussler, and Marc A. Hillmyer pp 13786–13787 DOI: 10.1021/ja0753041 Supporting Info

Manganese- or Iron-Catalyzed Homocoupling of Grignard Reagents Using Atmospheric Oxygen as an Oxidant Gérard Cahiez, Alban Moyeux, Julien Buendia, and Christophe Duplais pp 13788–13789 DOI: 10.1021/ja075417k Supporting Info

Effective Visible Light-Activated B-Doped and B,N-Codoped TiO2 Photocatalysts Suil In, Alexander Orlov, Regina Berg, Felipe García, Sergio Pedrosa-Jimenez, Mintcho S. Tikhov, Dominic S. Wright, and Richard M. Lambert pp 13790–13791 DOI: 10.1021/ja0749237 Supporting Info

Anti-Markovnikov Addition of Both Primary and Secondary Amines to Terminal Alkynes Catalyzed by the TpRh(C2H4)2/PPh3 System Yoshiya Fukumoto, Harumi Asai, Masaki Shimizu, and Naoto Chatani pp 13792–13793 DOI: 10.1021/ja075484e Supporting Info

Total Synthesis of (±)-Communesin F Jun Yang, Haoxing Wu, Liqun Shen, and Yong Qin pp 13794–13795 DOI: 10.1021/ja075705g Supporting Info

Nucleophilic Carbene and HOAt Relay Catalysis in an Amide Bond Coupling:  An Orthogonal Peptide Bond Forming Reaction Harit U. Vora and Tomislav Rovis pp 13796–13797 DOI: 10.1021/ja0764052 Supporting Info

N-Heterocyclic Carbene-Catalyzed Redox Amidations of α-Functionalized Aldehydes with Amines Jeffrey W. Bode and Stephanie S. Sohn pp 13798–13799 DOI: 10.1021/ja0768136 Supporting Info

Fulvene Dialdehyde Strategy for adj-Dicarbaporphyrinoid Synthesis:  Preparation of a 22-Carbaazuliporphyrin Timothy D. Lash, Denise A. Colby, Aparna S. Idate, and Randall N. Davis pp 13800–13801 DOI: 10.1021/ja076414a Supporting Info

Generation of a Doubly Bridging CO2 Ligand and Deoxygenation of CO2 by an (NHC)Ni(0) Complex Chang Hoon Lee, David S. Laitar, Peter Mueller, and Joseph P. Sadighi pp 13802–13803 DOI: 10.1021/ja075630g Supporting Info

A Post-PKS Oxidation of the Amphotericin B Skeleton Predicted to be Critical for Channel Formation Is Not Required for Potent Antifungal Activity Daniel S. Palacios, Thomas M. Anderson, and Martin D. Burke pp 13804–13805 DOI: 10.1021/ja075739o Supporting Info

Probing Spatially-Resolved Pt Distribution in PtRu Nanoparticles with 195Pt EC-NMR Aaron L. Danberry, Bingchen Du, In-Su Park, Yung-Eun Sung, and YuYe Tong pp 13806–13807 DOI: 10.1021/ja076048v Supporting Info

Mechanophore-Linked Addition Polymers Stephanie L. Potisek, Douglas A. Davis, Nancy R. Sottos, Scott R. White, and Jeffrey S. Moore pp 13808–13809 DOI: 10.1021/ja076189x Supporting Info

Fluorescently Labeled Cellulose Nanocrystals for Bioimaging Applications Shuping Dong and Maren Roman pp 13810–13811 DOI: 10.1021/ja076196l

Tethering Small Molecules to a Phage Display Library:  Discovery of a Selective Bivalent Inhibitor of Protein Kinase A Scott C. Meyer, Carolyn D. Shomin, Thomas Gaj, and Indraneel Ghosh pp 13812–13813 DOI: 10.1021/ja076197d Supporting Info

Reengineering a Natural Riboswitch by Dual Genetic Selection Yoko Nomura and Yohei Yokobayashi pp 13814–13815 DOI: 10.1021/ja076298b Supporting Info

Size-Tunable Hexagonal Fullerene (C60) Nanosheets at the Liquid−Liquid Interface Marappan Sathish and Kun'ichi Miyazawa pp 13816–13817 DOI: 10.1021/ja076251q Supporting Info

Inkless Microcontact Printing on Self-Assembled Monolayers of Fmoc-Protected Aminothiols Alexander A. Shestopalov, Robert L. Clark, and Eric J. Toone pp 13818–13819 DOI: 10.1021/ja076226k Supporting Info

Spectroscopic Signatures of Gas-Phase Helices:  Ac-Phe-(Ala)5-Lys-H+ and Ac-Phe-(Ala)10-Lys-H+ Jaime A. Stearns, Oleg V. Boyarkin, and Thomas R. Rizzo pp 13820–13821 DOI: 10.1021/ja076507s Supporting Info

Watching Nanoparticles Grow:  The Mechanism and Kinetics for the Formation of TiO2-Supported Platinum Nanoparticles Peter J. Chupas, Karena W. Chapman, Guy Jennings, Peter L. Lee, and Clare P. Grey pp 13822–13824 DOI: 10.1021/ja076437p Supporting Info

The Relationship between the Manganese(II) Zero-Field Interaction and Mn(II)/Mn(III) Redox Potential of Mn(4‘-X-terpy)2 Complexes Jessica Gätjens, Martin Sjödin, Vincent L. Pecoraro, and Sun Un pp 13825–13827 DOI: 10.1021/ja076024o Supporting Info

Direct Observation of a Transient Tyrosine Radical Competent for Initiating Turnover in a Photochemical Ribonucleotide Reductase Steven Y. Reece, Mohammad R. Seyedsayamdost, JoAnne Stubbe, and Daniel G. Nocera pp 13828–13830 DOI: 10.1021/ja074452o Supporting Info

Transition-State Structure of Neisseria meningitides 5‘-Methylthioadenosine/S-Adenosylhomocysteine Nucleosidase Vipender Singh, Minkui Luo, Rosemary L. Brown, Gillian E. Norris, and Vern L. Schramm pp 13831–13833 DOI: 10.1021/ja0754204 Supporting Info

An Effect of Bulk on the Ratio of Fragmentation to Stereomutation in Three Cyclobutane Dimers of 3-Methylenecholest-4-ene William von E. Doering and Edmund J. Keliher pp 13834–13839 DOI: 10.1021/ja068971n Supporting Info

Mapping Electron Paramagnetic Resonance Spin Label Conformations by the Simulated Scaling Method Mikolai I. Fajer, Hongzhi Li, Wei Yang, and Piotr G. Fajer pp 13840–13846 DOI: 10.1021/ja071404v Supporting Info

The Effects of Dissolved Halide Anions on Hydrogen Bonding in Liquid Water Jared D. Smith, Richard J. Saykally, and Phillip L. Geissler pp 13847–13856 DOI: 10.1021/ja071933z Supporting Info

Hydrogen Encapsulation in a Silicon Clathrate Type I Structure:  Na5.5(H2)2.15Si46:  Synthesis and Characterization Doinita Neiner, Norihiko L. Okamoto, Cathie L. Condron, Quentin M. Ramasse, Ping Yu, Nigel D. Browning, and Susan M. Kauzlarich pp 13857–13862 DOI: 10.1021/ja0724700

Carbonic Acid:  From Polyamorphism to Polymorphism Katrin Winkel, Wolfgang Hage, Thomas Loerting, Sarah L. Price, and Erwin Mayer pp 13863–13871 DOI: 10.1021/ja073594f

Nanoporous Magnets of Chiral and Racemic [{Mn(HL)}2Mn{Mo(CN)7}2] with Switchable Ordering Temperatures (TC = 85 K ↔ 106 K) Driven by H2O Sorption (L = N,N-Dimethylalaninol) Julie Milon, Marie-Christine Daniel, Abdellah Kaiba, Philippe Guionneau, Stéphane Brandès, and Jean-Pascal Sutter pp 13872–13878 DOI: 10.1021/ja073612t Supporting Info

A Concept of Supported Amino Acid Ionic Liquids and Their Application in Metal Scavenging and Heterogeneous Catalysis Wen Chen, Yuanyuan Zhang, Liangbo Zhu, Jingbo Lan, Rugang Xie, and Jingsong You pp 13879–13886 DOI: 10.1021/ja073633n Supporting Info

Structure and Bonding in β-HMX-Characterization of a Trans-Annular N···N Interaction Elizabeth A. Zhurova, Vladimir V. Zhurov, and A. Alan Pinkerton pp 13887–13893 DOI: 10.1021/ja073801b Supporting Info

Controllable and Repeatable Synthesis of Thermally Stable Anatase Nanocrystal−Silica Composites with Highly Ordered Hexagonal Mesostructures Weiyang Dong, Yaojun Sun, Chul Wee Lee, Weiming Hua, Xinchun Lu, Yifeng Shi, Shicheng Zhang, Jianmin Chen, and Dongyuan Zhao pp 13894–13904 DOI: 10.1021/ja073804o Supporting Info

Unraveling the Origin of the Peculiar Reaction Field of Triruthenium Ring Core Structures Athanassios C. Tsipis, Christos E. Kefalidis, and Constantinos A. Tsipis pp 13905–13922 DOI: 10.1021/ja074094p Supporting Info

Pressure-Induced Splitting and Buckling of Cu−O Chains in the Low-Dimensional Structure of SrCuO2 Fuxiang Zhang, Jianwei Wang, Udo Becker, Jie Lian, Jingzhu Hu, Surendra Saxena, and Rodney C. Ewing pp 13923–13926 DOI: 10.1021/ja074290w

Highly Enantioselective Oxidative Couplings of 2-Naphthols Catalyzed by Chiral Bimetallic Oxovanadium Complexes with Either Oxygen or Air as Oxidant Qi-Xiang Guo, Zhi-Jun Wu, Zhi-Bin Luo, Quan-Zhong Liu, Jian-Liang Ye, Shi-Wei Luo, Lin-Feng Cun, and Liu-Zhu Gong pp 13927–13938 DOI: 10.1021/ja074322f Supporting Info

Size Control of Gold Nanocrystals in Citrate Reduction:  The Third Role of Citrate Xiaohui Ji, Xiangning Song, Jun Li, Yubai Bai, Wensheng Yang, and Xiaogang Peng pp 13939–13948 DOI: 10.1021/ja074447k Supporting Info

Mutagenesis of Morphinone Reductase Induces Multiple Reactive Configurations and Identifies Potential Ambiguity in Kinetic Analysis of Enzyme Tunneling Mechanisms Christopher R. Pudney, Sam Hay, Jiayun Pang, Claire Costello, David Leys, Michael J. Sutcliffe, and Nigel S. Scrutton pp 13949–13956 DOI: 10.1021/ja074463h Supporting Info

Organic Zeolites from a Diolefinic Monomer Ozge Guney-Altay, Dmitry Pestov, and Gary Tepper pp 13957–13962 DOI: 10.1021/ja0745658

Cation−Anion Interactions and Polar Structures in the Solid State Michael R. Marvel, Julien Lesage, Jaewook Baek, P. Shiv Halasyamani, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 13963–13969 DOI: 10.1021/ja074659h Supporting Info

A Stroboscopic Approach for Fast Photoactivation−Localization Microscopy with Dronpa Mutants Cristina Flors, Jun-ichi Hotta, Hiroshi Uji-i, Peter Dedecker, Ryoko Ando, Hideaki Mizuno, Atsushi Miyawaki, and Johan Hofkens pp 13970–13977 DOI: 10.1021/ja074704l Supporting Info

Molecular Catenation via Metal-Directed Self-Assembly and π-Donor/π-Acceptor Interactions:  Efficient One-Pot Synthesis, Characterization, and Crystal Structures of [3]Catenanes Based on Pd or Pt Dinuclear Metallocycles Víctor Blanco, Marcos Chas, Dolores Abella, Carlos Peinador, and José M. Quintela pp 13978–13986 DOI: 10.1021/ja074721a Supporting Info

Enhancing the Stability and Biological Functionalities of Quantum Dots via Compact Multifunctional Ligands Kimihiro Susumu, H. Tetsuo Uyeda, Igor L. Medintz, Thomas Pons, James B. Delehanty, and Hedi Mattoussi pp 13987–13996 DOI: 10.1021/ja0749744 Supporting Info

Direct Observation of Atoms Entering and Exiting l-Alanyl-l-valine Nanotubes by Hyperpolarized Xenon-129 NMR Chi-Yuan Cheng and Clifford R. Bowers pp 13997–14002 DOI: 10.1021/ja074563n

NMR Identification of Transient Complexes Critical to Adenylate Kinase Catalysis Jörgen Ådén and Magnus Wolf-Watz pp 14003–14012 DOI: 10.1021/ja075055g Supporting Info

Biomolecular Interaction Monitoring of Autoantibodies by Scanning Surface Plasmon Resonance Microarray Imaging Angelique M. C. Lokate, J. Bianca Beusink, Geert A. J. Besselink, Ger J. M. Pruijn, and Richard B. M. Schasfoort pp 14013–14018 DOI: 10.1021/ja075103x Supporting Info

Photoionization of 1-Alkenylperoxy and Alkylperoxy Radicals and a General Rule for the Stability of Their Cations Giovanni Meloni, Talitha M. Selby, Fabien Goulay, Stephen R. Leone, David L. Osborn, and Craig A. Taatjes pp 14019–14025 DOI: 10.1021/ja075130n Supporting Info

The Reach of Linear Protein−DNA Dimerizers Ryan L. Stafford and Peter B. Dervan pp 14026–14033 DOI: 10.1021/ja075247b Supporting Info

Catalyzing the Translocation of Polypeptides through Attractive Interactions Aaron J. Wolfe, Mohammad M. Mohammad, Stephen Cheley, Hagan Bayley, and Liviu Movileanu pp 14034–14041 DOI: 10.1021/ja0749340 Supporting Info

Synthesis and Mesomorphic Properties of Rigid-Core Ionic Liquid Crystals Paul H. J. Kouwer and Timothy M. Swager pp 14042–14052 DOI: 10.1021/ja075651a Supporting Info

Dangling OD Confined in a Langmuir Monolayer Gang Ma, Xiangke Chen, and Heather C. Allen pp 14053–14057 DOI: 10.1021/ja075806e Supporting Info

Template Adaptability Is Key in the Oriented Crystallization of CaCO3 Daniela C. Popescu, Maarten M. J. Smulders, Benoît P. Pichon, Natalia Chebotareva, Seo-Young Kwak, Otto L. J. van Asselen, Rint P. Sijbesma, Elaine DiMasi, and Nico A. J. M. Sommerdijk pp 14058–14067 DOI: 10.1021/ja075875t Supporting Info

pH-Induced Protonation of Lysine in Aqueous Solution Causes Chemical Shifts in X-ray Photoelectron Spectroscopy Dirk Nolting, Emad F. Aziz, Niklas Ottosson, Manfred Faubel, Ingolf V. Hertel, and Bernd Winter pp 14068–14073 DOI: 10.1021/ja072971l Supporting Info

Self-Assembled Templates for Polypeptide Synthesis Maxim G. Ryadnov and Derek N. Woolfson pp 14074–14081 DOI: 10.1021/ja072960s Supporting Info

Reactive Sulfur Species:  Kinetics and Mechanisms of the Oxidation of Cysteine by Hypohalous Acid to Give Cysteine Sulfenic Acid Péter Nagy and Michael T. Ashby pp 14082–14091 DOI: 10.1021/ja0737218

Rational Design, Synthesis, and Evaluation of Key Analogues of CC-1065 and the Duocarmycins Mark S. Tichenor, Karen S. MacMillan, James S. Stover, Scott E. Wolkenberg, Maria G. Pavani, Lorenzo Zanella, Abdel N. Zaid, Gianpiero Spalluto, Thomas J. Rayl, Inkyu Hwang, Pier Giovanni Baraldi, and Dale L. Boger pp 14092–14099 DOI: 10.1021/ja073989z Supporting Info

Zinc−Zinc Bonded Zincocene Structures. Synthesis and Characterization of Zn2(η5-C5Me5)2 and Zn2(η5-C5Me4Et)2 [J. Am. Chem. Soc. 2007, 129, 693−703]. Abdessamad Grirrane, Irene Resa, Amor Rodríguez, Ernesto Carmona, Eleuterio Alvarez, Enrique Gutiérrez-Puebla, Angeles Monge, Agustín Galindo, Diego del Río, and Richard A. Andersen p 14100 DOI: 10.1021/ja075362m

Palladium-Catalyzed Direct Functionalization of Imidazolinone:  Synthesis of Dibromophakellstatin [J. Am. Chem. Soc. 2007, 129, 7768−7769]. Jianming Lu, Xianghui Tan, and Chuo Chen p 14100 DOI: 10.1021/ja077266r

Organic Reactions in Water:  Principles, Strategies and Applications Edited by U. Marcus Lindström (McGill University). Blackwell Publishing:  Oxford. 2007. xvi + 406 pp. $199.99. ISBN 978-1-4051-3890-1. Eric R. Marinez p 14101 DOI: 10.1021/ja076966t

Macromolecular Engineering:  Precise Synthesis, Materials Properties, Applications. Volumes 1−4 Edited by Krzysztof Matyjaszewski (Carnegie Mellon University, Pittsburgh, PA, USA), Yves Gnanou (Université Bordeaux I, Pessac, France), and Ludwik Leibler (Ecole Supérieure de Physique et Chimie Industrielles, Paris, France). Wiley-VCH Verlag GmbH & Co. KGa:  Weinheim. 2007. 2982 pp. $675. ISBN 978-3-527-31446-1. Joseph P. Kennedy pp 14101–14102 DOI: 10.1021/ja0769806

Discrimination of Chiral Compounds Using NMR Spectroscopy By Thomas J. Wenzel (Bates College, Lewiston, ME). J. Wiley & Sons, Inc.:  Hoboken, NJ. xxiv + 550 pp. $110. ISBN 978-0-471-76352-9. Guillermo Moyna pp 14102–14103 DOI: 10.1021/ja0769696

Springer Handbook of Enzymes, Volume 36:  Class 2, Transferases IX, EC 2.7.1.38−2.7.1.112, 2nd ed Edited by Dietmar Schomburg and Ida Schomburg and Coedited by Antje Chang (Technical University Braunschweig, Germany). Springer:  Berlin, Heidelberg, New York. 2007. xxii + 624 pp. $369.00. ISBN 978-3-540-47807-2. p 14103 DOI: 10.1021/ja0769907

In Situ NMR Methods in Catalysis Edited by Joachim Bargon (University of Bonn, Germany) and Lars T. Kuhn (Oxford University, U.K.). Springer:  Berlin, Heidelberg, New York. 2007. xii + 170 pp. $179.00. ISBN 978-3-540-71426-2. Tanja Pietrass pp 14103–14104 DOI: 10.1021/ja076998g

Peptide Characterization and Application Protocols. Methods in Molecular Biology, 386 Edited by Gregg B. Fields (Florida Atlantic University, Boca Raton, FL). Humana Press:  Totowa, NJ. 2007. xii + 342 pp. $99.50. ISBN:  978-1-58829-550-7. p 14104 DOI: 10.1021/ja077006+

Organic-Chemical Drugs and Their Synonyms, Extensively Enlarged 9th ed., Volumes 1−7 By Martin Negwer and Hans-Georg Scharnow (Berlin). Wiley-VCH Verlag GmbH and Co. KGaA:  Weinheim. 2007. xviii + 5656 pp. $2000. ISBN 978-3-527-31939-8. p 14104 DOI: 10.1021/ja077009m

Issue 46

Rh(II)-Catalyzed Intermolecular Oxidative Sulfamidation of Aldehydes:  A Mild Efficient Synthesis of N-Sulfonylcarboxamides Johann Chan, Kyle D. Baucom, and Jerry A. Murry pp 14106–14107 DOI: 10.1021/ja073872a Supporting Info

Vi -Value Analysis:  A Pressure-Based Method for Mapping the Folding Transition State Ensemble of Proteins Lally Mitra, Kazumi Hata, Ryohei Kono, Akihiro Maeno, Daniel Isom, Jean-Baptiste Rouget, Roland Winter, Kazuyuki Akasaka, Bertrand García-Moreno, and Catherine A. Royer pp 14108–14109 DOI: 10.1021/ja073576y Supporting Info

Biomimetic Design of Reversibly Unfolding Cross-Linker to Enhance Mechanical Properties of 3D Network Polymers Aaron M. Kushner, Vahe Gabuchian, Evan G. Johnson, and Zhibin Guan pp 14110–14111 DOI: 10.1021/ja0742176 Supporting Info

Enantioselective 1,4-Addition Reactions of Diphenyl Phosphite to Nitroalkenes Catalyzed by an Axially Chiral Guanidine Masahiro Terada, Takashi Ikehara, and Hitoshi Ube pp 14112–14113 DOI: 10.1021/ja0746619 Supporting Info

Hexamethyldisilazane-Mediated Controlled Polymerization of α-Amino Acid N-Carboxyanhydrides Hua Lu and Jianjun Cheng pp 14114–14115 DOI: 10.1021/ja074961q Supporting Info

From Helical to Staggered Stacking of Zigzag Nanographenes Xinliang Feng, Wojciech Pisula, and Klaus Müllen pp 14116–14117 DOI: 10.1021/ja075260w Supporting Info

Absence of Curie Relaxation in Paramagnetic Solids Yields Long 1H Coherence Lifetimes Gwendal Kervern, Stefan Steuernagel, Frank Engelke, Guido Pintacuda, and Lyndon Emsley pp 14118–14119 DOI: 10.1021/ja075319z Supporting Info

Water as Nucleophile in Palladium-Catalyzed Oxidative Carbohydroxylation of Allene-Substituted Conjugated Dienes Julio Piera, Andreas Persson, Xisco Caldentey, and Jan-E. Bäckvall pp 14120–14121 DOI: 10.1021/ja075488j Supporting Info

Blue Electroluminescence from InN@SiO2 Nanomaterials Mingqian Tan, Prabhakaran Munusamy, Venkataramanan Mahalingam, and Frank C. J. M. van Veggel pp 14122–14123 DOI: 10.1021/ja075490a Supporting Info

NMR Structures of Peptide−RuII(Porphyrin) Complexes Jiangyun Wang, Michael M. Rosenblatt, and Kenneth S. Suslick pp 14124–14125 DOI: 10.1021/ja075532v Supporting Info

Resolution-Enhanced 4D 15N/13C NOESY Protein NMR Spectroscopy by Application of the Covariance Transform David A. Snyder, Yingqi Xu, Daiwen Yang, and Rafael Brüschweiler pp 14126–14127 DOI: 10.1021/ja075533n Supporting Info

Battery-Inspired, Nonvolatile, and Rewritable Memory Architecture:  a Radical Polymer-Based Organic Device Yasunori Yonekuta, Kentaro Susuki, Kenichi Oyaizu, Kenji Honda, and Hiroyuki Nishide pp 14128–14129 DOI: 10.1021/ja075553p Supporting Info

Rearrangement of Pyridine to Its 2-Carbene Tautomer Mediated by Iridium Eleuterio Álvarez, Salvador Conejero, Patricia Lara, Jorge A. López, Margarita Paneque, Ana Petronilho, Manuel L. Poveda, Diego del Río, Oracio Serrano, and Ernesto Carmona pp 14130–14131 DOI: 10.1021/ja075685i Supporting Info

Self-Assembled Epitaxial Nanocomposite BaTiO3−NiFe2O4 Films Prepared by Polymer-Assisted Deposition Hongmei Luo, Hao Yang, Scott A. Baily, Ozan Ugurlu, Menka Jain, Marilyn E. Hawley, T. Mark McCleskey, Anthony K. Burrell, Eve Bauer, Leonardo Civale, Terry G. Holesinger, and Quanxi Jia pp 14132–14133 DOI: 10.1021/ja075764u Supporting Info

Aligning One-Dimensional DNA Duplexes into Two-Dimensional Crystals Chuan Zhang, Yu He, Yi Chen, Alexander E. Ribbe, and Chengde Mao pp 14134–14135 DOI: 10.1021/ja075791k Supporting Info

A Quantum Chemical and Molecular Dynamics Study of the Coordination of Cm(III) in Water Daniel Hagberg, Eugeniusz Bednarz, Norman M. Edelstein, and Laura Gagliardi pp 14136–14137 DOI: 10.1021/ja075489b Supporting Info

Gd3+ Complexes as Potential Spin Labels for High Field Pulsed EPR Distance Measurements Arnold M. Raitsimring, Chidambaram Gunanathan, Alexey Potapov, Irena Efremenko, Jan M. L. Martin, David Milstein, and Daniella Goldfarb pp 14138–14139 DOI: 10.1021/ja075544g Supporting Info

Nanostructured Crystals:  Unique Hybrid Semiconductors Exhibiting Nearly Zero and Tunable Uniaxial Thermal Expansion Behavior Jing Li, Wenhua Bi, Wooseok Ki, Xiaoying Huang, and Srihari Reddy pp 14140–14141 DOI: 10.1021/ja075901n Supporting Info

A Chiral Pentadecanuclear Metallamacrocycle with a Sextuple Twisted Möbius Topology Rohith P. John, Mira Park, Dohyun Moon, Kyungjin Lee, Seunghee Hong, Yang Zou, Chang Seop Hong, and Myoung Soo Lah pp 14142–14143 DOI: 10.1021/ja075945w Supporting Info

Regio- and Stereospecific Formation of Protected Allylic Alcohols via Zirconium-Mediated SN2‘ Substitution of Allylic Chlorides Richard J. Fox, Gojko Lalic, and Robert G. Bergman pp 14144–14145 DOI: 10.1021/ja075967i Supporting Info

Toward Quantitative Interpretation of Methyl Side-Chain Dynamics from NMR by Molecular Dynamics Simulations Scott A. Showalter, Eric Johnson, Mark Rance, and Rafael Brüschweiler pp 14146–14147 DOI: 10.1021/ja075976r Supporting Info

Gold(I)-Catalyzed Dynamic Kinetic Enantioselective Intramolecular Hydroamination of Allenes Zhibin Zhang, Christopher F. Bender, and Ross A. Widenhoefer pp 14148–14149 DOI: 10.1021/ja0760731 Supporting Info

Dynamics of the Dissociation of a Disulfide Biradical on a CdSe Nanoparticle Surface Paul S. Billone, Luca Maretti, Vincent Maurel, and Juan C. Scaiano pp 14150–14151 DOI: 10.1021/ja076118y Supporting Info

Epimerization- and Protecting-Group-Free Synthesis of Peptidomimetic Conjugates from Amphoteric Amino Aldehydes Xinghan Li and Andrei K. Yudin pp 14152–14153 DOI: 10.1021/ja076155p Supporting Info

Stabilization of Folded Peptide and Protein Structures via Distance Matching with a Long, Rigid Cross-Linker Fuzhong Zhang, Oleg Sadovski, Steven J. Xin, and G. Andrew Woolley pp 14154–14155 DOI: 10.1021/ja075829t Supporting Info

Time-Dependent Density Functional Theory Investigations on the Excited States of Ru(II)-Dye-Sensitized TiO2 Nanoparticles:  The Role of Sensitizer Protonation Filippo De Angelis, Simona Fantacci, Annabella Selloni, Mohammad K. Nazeeruddin, and Michael Grätzel pp 14156–14157 DOI: 10.1021/ja076293e Supporting Info

Rhodium-Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols:  Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones Takahiro Nishimura, Taisuke Katoh, Keishi Takatsu, Ryo Shintani, and Tamio Hayashi pp 14158–14159 DOI: 10.1021/ja076346s Supporting Info

Reversible N−N Coupling of NO Ligands on Dinuclear Ruthenium Complexes and Subsequent N2O Evolution:  Relevance to Nitric Oxide Reductase Yasuhiro Arikawa, Taiki Asayama, Yusuke Moriguchi, Shoko Agari, and Masayoshi Onishi pp 14160–14161 DOI: 10.1021/ja0763504 Supporting Info

The Shortest Metal−Metal Bond Yet:  Molecular and Electronic Structure of a Dinuclear Chromium Diazadiene Complex Kevin A. Kreisel, Glenn P. A. Yap, Olga Dmitrenko, Clark R. Landis, and Klaus H. Theopold pp 14162–14163 DOI: 10.1021/ja076356t Supporting Info

Coplanar Oligo(p-phenylenedisilenylene)s Based on the Octaethyl-Substituted s-Hydrindacenyl Groups Aiko Fukazawa, Yongming Li, Shigehiro Yamaguchi, Hayato Tsuji, and Kohei Tamao pp 14164–14165 DOI: 10.1021/ja0764207 Supporting Info

Supercrystalline Colloidal Particles from Artificial Atoms Jiaqi Zhuang, Huimeng Wu, Yongan Yang, and Y. Charles Cao pp 14166–14167 DOI: 10.1021/ja076494i Supporting Info

Manganese and Magnesium Homochiral Materials:  Decoration of Honeycomb Channels with Homochiral Chains Jian Zhang, Shumei Chen, Henry Valle, Matthew Wong, Cristina Austria, Maria Cruz, and Xianhui Bu pp 14168–14169 DOI: 10.1021/ja076532y Supporting Info

Facile, Efficient Functionalization of Polyolefins via Controlled Incorporation of Terminal Olefins by Repeated 1,7-Octadiene Insertion Kotohiro Nomura, Jingyu Liu, Michiya Fujiki, and Arimitsu Takemoto pp 14170–14171 DOI: 10.1021/ja076633w Supporting Info

Chasing the Proton Culprit from Palladium-Catalyzed Allylic Amination Igor Dubovyk, Iain D. G. Watson, and Andrei K. Yudin pp 14172–14173 DOI: 10.1021/ja076659n Supporting Info

Generation, Identification, and Reactivity of Paramagnetic VO2 Centers in Zeolite BEA for Model Studies of Processes Involving Spin Pairing, Electron Transfer, and Oxygen Transfer Piotr Pietrzyk, Zbigniew Sojka, Stanislaw Dzwigaj, and Michel Che pp 14174–14175 DOI: 10.1021/ja076689q Supporting Info

Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) Steven S. Kaye, Anne Dailly, Omar M. Yaghi, and Jeffrey R. Long pp 14176–14177 DOI: 10.1021/ja076877g Supporting Info

Highly Efficient Near-IR Emitting Yb/Yb and Yb/Al Helicates Markus Albrecht, Olga Osetska, Roland Fröhlich, Jean-Claude G. Bünzli, Annina Aebischer, Frédéric Gumy, and Josef Hamacek pp 14178–14179 DOI: 10.1021/ja0768688 Supporting Info

NHC-Mediated Aggregation of P4:  Isolation of a P12 Cluster Jason D. Masuda, Wolfgang W. Schoeller, Bruno Donnadieu, and Guy Bertrand pp 14180–14181 DOI: 10.1021/ja077296u Supporting Info

Allosteric Regulation of Phosphate Diester Transesterification Based upon a Dinuclear Zinc Catalyst Assembled via the Weak-Link Approach Hyo Jae Yoon, Jungseok Heo, and Chad A. Mirkin pp 14182–14183 DOI: 10.1021/ja077467v Supporting Info

Total Synthesis of the Maduropeptin Chromophore Aglycon Kazuo Komano, Satoshi Shimamura, Masayuki Inoue, and Masahiro Hirama pp 14184–14186 DOI: 10.1021/ja076671f Supporting Info

A Highly Efficient Approach to the Self-Assembly of Hexagonal Cavity-Cored Tris[2]pseudorotaxanes from Several Components via Multiple Noncovalent Interactions Hai-Bo Yang, Koushik Ghosh, Brian H. Northrop, Yao-Rong Zheng, Matthew M. Lyndon, David C. Muddiman, and Peter J. Stang pp 14187–14189 DOI: 10.1021/ja073744m Supporting Info

Copper(I)−α-Ketocarboxylate Complexes:  Characterization and O2 Reactions That Yield Copper−Oxygen Intermediates Capable of Hydroxylating Arenes Sungjun Hong, Stefan M. Huber, Laura Gagliardi, Christopher C. Cramer, and William B. Tolman pp 14190–14192 DOI: 10.1021/ja0760426 Supporting Info

Palladium-Catalyzed Reductive Coupling of Styrenes and Organostannanes under Aerobic Conditions Keith M. Gligorich, Sarah A. Cummings, and Matthew S. Sigman pp 14193–14195 DOI: 10.1021/ja076746f Supporting Info

Nanoencapsulation of Calix[4]arene Inclusion Complexes Alexander Shivanyuk pp 14196–14199 DOI: 10.1021/ja067402c Supporting Info

Reversible Inhibition/Activation of Olefin Metathesis:  A Kinetic Investigation of ROMP and RCM Reactions with Grubbs' Catalyst Steven J. P'Pool and Hans-Jörg Schanz pp 14200–14212 DOI: 10.1021/ja071938w Supporting Info

Thermally Reduced Ruthenium Nanoparticles as a Highly Active Heterogeneous Catalyst for Hydrogenation of Monoaromatics Fabing Su, Lu Lv, Fang Yin Lee, Tao Liu, Andrew I. Cooper, and Xiu Song Zhao pp 14213–14223 DOI: 10.1021/ja072697v Supporting Info

CD and MCD of CytC3 and Taurine Dioxygenase:  Role of the Facial Triad in α-KG-Dependent Oxygenases Michael L. Neidig, Christina D. Brown, Kenneth M. Light, Danica Galonić Fujimori, Elizabeth M. Nolan, John C. Price, Eric W. Barr, J. Martin Bollinger, Jr., Carsten Krebs, Christopher T. Walsh, and Edward I. Solomon pp 14224–14231 DOI: 10.1021/ja074557r Supporting Info

Fabrication of Monodisperse Asymmetric Colloidal Clusters by Using Contact Area Lithography (CAL) Changdeuck Bae, Jooho Moon, Hyunjung Shin, Jiyoung Kim, and Myung M. Sung pp 14232–14239 DOI: 10.1021/ja073043p

Exciton Fission and Fusion in Bis(tetracene) Molecules with Different Covalent Linker Structures Astrid M. Müller, Yuri S. Avlasevich, Wolfgang W. Schoeller, Klaus Müllen, and Christopher J. Bardeen pp 14240–14250 DOI: 10.1021/ja073173y Supporting Info

Self-Organizing Core−Shell Nanostructures:  Spontaneous Accumulation of Dye in the Core of Doped Silica Nanoparticles Enrico Rampazzo, Sara Bonacchi, Marco Montalti, Luca Prodi, and Nelsi Zaccheroni pp 14251–14256 DOI: 10.1021/ja073150j

Theoretical Studies on Conjugated Phenyl-Cored Thiophene Dendrimers for Photovoltaic Applications Muhammet E. Köse, William J. Mitchell, Nikos Kopidakis, Christopher H. Chang, Sean E. Shaheen, Kwiseon Kim, and Garry Rumbles pp 14257–14270 DOI: 10.1021/ja073455y Supporting Info

Control of Stripelike and Hexagonal Self-Assembly of Gold Nanoparticles by the Tuning of Interactions between Triphenylene Ligands Zhongrong Shen, Mami Yamada, and Mikio Miyake pp 14271–14280 DOI: 10.1021/ja073518c

Mechanistic Studies of Olefin and Alkyne Trimerization with Chromium Catalysts:  Deuterium Labeling and Studies of Regiochemistry Using a Model Chromacyclopentane Complex Theodor Agapie, Jay A. Labinger, and John E. Bercaw pp 14281–14295 DOI: 10.1021/ja073493h Supporting Info

Photodetector Arrays Directly Assembled onto Polymer Substrates from Aqueous Solution Fairland F. Amos, Stephen A. Morin, Jeremy A. Streifer, Robert J. Hamers, and Song Jin pp 14296–14302 DOI: 10.1021/ja073675b Supporting Info

Homogeneous Catalytic Reduction of Dioxygen Using Transfer Hydrogenation Catalysts Zachariah M. Heiden and Thomas B. Rauchfuss pp 14303–14310 DOI: 10.1021/ja073774p Supporting Info

Confinement or the Nature of the Interface? Dynamics of Nanoscopic Water David E. Moilanen, Nancy E. Levinger, D. B. Spry, and M. D. Fayer pp 14311–14318 DOI: 10.1021/ja073977d

Effects of Bay Substituents on the Racemization Barriers of Perylene Bisimides:  Resolution of Atropo-Enantiomers Peter Osswald and Frank Würthner pp 14319–14326 DOI: 10.1021/ja074508e Supporting Info

Spectroscopic Properties of Colloidal Indium Phosphide Quantum Wires Fudong Wang, Heng Yu, Jingbo Li, Qingling Hang, Dmitry Zemlyanov, Patrick C. Gibbons, Lin-Wang Wang, David B. Janes, and William E. Buhro pp 14327–14335 DOI: 10.1021/ja074049h Supporting Info

Biosynthetic Tailoring of Microcin E492m:  Post-translational Modification Affords an Antibacterial Siderophore−Peptide Conjugate Elizabeth M. Nolan, Michael A. Fischbach, Alexander Koglin, and Christopher T. Walsh pp 14336–14347 DOI: 10.1021/ja074650f Supporting Info

Different Apolipoproteins Impact Nanolipoprotein Particle Formation Brett A. Chromy, Erin Arroyo, Craig D. Blanchette, Graham Bench, Henry Benner, Jenny A. Cappuccio, Matthew A. Coleman, Paul T. Henderson, Angie K. Hinz, Edward A. Kuhn, Joseph B. Pesavento, Brent W. Segelke, Todd A. Sulchek, Ted Tarasow, Vicki L. Walsworth, and Paul D. Hoeprich pp 14348–14354 DOI: 10.1021/ja074753y Supporting Info

Atomic-Scale Assembly of a Heterogeneous Catalytic Site Patrick Han, Stephanus Axnanda, Igor Lyubinetsky, and D. Wayne Goodman pp 14355–14361 DOI: 10.1021/ja074891n Supporting Info

Single-Molecule Magnets:  A New Approach To Investigate the Electronic Structure of Mn12 Molecules by Scanning Tunneling Spectroscopy Michael Burgert, Sönke Voss, Simon Herr, Mikhail Fonin, Ulrich Groth, and Ulrich Rüdiger pp 14362–14366 DOI: 10.1021/ja074884z Supporting Info

Electrochemical Doping in Electrolyte-Gated Polymer Transistors Jonathan D. Yuen, Anoop S. Dhoot, Ebinazar B. Namdas, Nelson E. Coates, Martin Heeney, Iain McCulloch, Daniel Moses, and Alan J. Heeger pp 14367–14371 DOI: 10.1021/ja0749845

Tuning the Absorption, Charge Transport Properties, and Solar Cell Efficiency with the Number of Thienyl Rings in Platinum-Containing Poly(aryleneethynylene)s Wai-Yeung Wong, Xing-Zhu Wang, Ze He, Kwok-Kwan Chan, Aleksandra B. Djurišić, Kai-Yin Cheung, Cho-Tung Yip, Alan Man-Ching Ng, Yan Yan Xi, Chris S. K. Mak, and Wai-Kin Chan pp 14372–14380 DOI: 10.1021/ja074959z Supporting Info

Determination of the Rod−Wire Transition Length in Colloidal Indium Phosphide Quantum Rods Fudong Wang and William E. Buhro pp 14381–14387 DOI: 10.1021/ja075015c Supporting Info

Spectroscopic Detection and Theoretical Confirmation of the Role of Cr2(CO)5(C5R5)2 and ·Cr(CO)2(ketene)(C5R5) as Intermediates in Carbonylation of NNCHSiMe3 to OCCHSiMe3 by ·Cr(CO)3(C5R5) (R = H, CH3) George C. Fortman, Tamás Kégl, Qian-Shu Li, Xiuhui Zhang, Henry F. Schaefer III, Yaoming Xie, R. Bruce King, Joshua Telser, and Carl D. Hoff pp 14388–14400 DOI: 10.1021/ja075008o Supporting Info

Remarkable Co-catalyst Effect of Gold Nanoclusters on Olefin Oxidation Catalyzed by a Manganese−Porphyrin Complex Yoshitaka Murakami and Katsuaki Konishi pp 14401–14407 DOI: 10.1021/ja075051b Supporting Info

Reaction of Ta(NMe2)5 with O2:  Formation of Aminoxy and Unusual (Aminomethyl)amide Oxo Complexes and Theoretical Studies of the Mechanistic Pathways Shu-Jian Chen, Xin-Hao Zhang, Xianghua Yu, He Qiu, Glenn P. A. Yap, Ilia A. Guzei, Zhenyang Lin, Yun-Dong Wu, and Zi-Ling Xue pp 14408–14421 DOI: 10.1021/ja075076a Supporting Info

A General and Regioselective Synthesis of Cyclopentenone Derivatives through Nickel(0)-Mediated [3 + 2] Cyclization of Alkenyl Fischer Carbene Complexes and Internal Alkynes José Barluenga, Pablo Barrio, Lorena Riesgo, Luis. A. López, and Miguel Tomás pp 14422–14426 DOI: 10.1021/ja075106+ Supporting Info

DNA Sensing by Field-Effect Transistors Based on Networks of Carbon Nanotubes Ee Ling Gui, Lain-Jong Li, Keke Zhang, Yangping Xu, Xiaochen Dong, Xinning Ho, Pooi See Lee, Johnson Kasim, Z. X. Shen, John. A. Rogers, and S.G. Mhaisalkar pp 14427–14432 DOI: 10.1021/ja075176g

Pressure-Induced Intermetallic Valence Transition in BiNiO3 Masaki Azuma, Sandra Carlsson, Jennifer Rodgers, Matthew G. Tucker, Masahiko Tsujimoto, Shintaro Ishiwata, Seiji Isoda, Yuichi Shimakawa, Mikio Takano, and J. Paul Attfield pp 14433–14436 DOI: 10.1021/ja074880u Supporting Info

Nanostructured Silica Thin Films Self-Assembled with Electron Donors and Acceptors to Measure Electron Tunneling Erik Johansson and Jeffrey I. Zink pp 14437–14443 DOI: 10.1021/ja075323a

The Natural Product Avrainvillamide Binds to the Oncoprotein Nucleophosmin Jeremy E. Wulff, Romain Siegrist, and Andrew G. Myers pp 14444–14451 DOI: 10.1021/ja075327f Supporting Info

An Artificial Molecular Chaperone:  Poly-pseudo-rotaxane with an Extensible Axle Motofumi Osaki, Yoshinori Takashima, Hiroyasu Yamaguchi, and Akira Harada pp 14452–14457 DOI: 10.1021/ja075140o Supporting Info

Elongation Factor Tu Mutants Expand Amino Acid Tolerance of Protein Biosynthesis System Yoshio Doi, Takashi Ohtsuki, Yoshihiro Shimizu, Takuya Ueda, and Masahiko Sisido pp 14458–14462 DOI: 10.1021/ja075557u Supporting Info

A Regio- and Stereoselective Approach to Quaternary Centers from Chiral Trisubstituted Aziridines Erin M. Forbeck, Cory D. Evans, John A. Gilleran, Pixu Li, and Madeleine M. Joullié pp 14463–14469 DOI: 10.1021/ja0758077 Supporting Info

Origin of the Humidity Sensitivity of Al/AlOx/MHA/Au Molecular Tunnel Junctions Xiaohang Zhang, Stephen A. McGill, and Peng Xiong pp 14470–14474 DOI: 10.1021/ja0758988

Rolling Circle Enzymatic Replication of a Complex Multi-Crossover DNA Nanostructure Chenxiang Lin, Xing Wang, Yan Liu, Nadrian C. Seeman, and Hao Yan pp 14475–14481 DOI: 10.1021/ja0760980 Supporting Info

Understanding cAMP-Dependent Allostery by NMR Spectroscopy:  Comparative Analysis of the EPAC1 cAMP-Binding Domain in Its Apo and cAMP-Bound States Mohammad T. Mazhab-Jafari, Rahul Das, Steven A. Fotheringham, Soumita SilDas, Somenath Chowdhury, and Giuseppe Melacini pp 14482–14492 DOI: 10.1021/ja0753703 Supporting Info

Facile RAFT Precipitation Polymerization for the Microwave-Assisted Synthesis of Well-Defined, Double Hydrophilic Block Copolymers and Nanostructured Hydrogels Zesheng An, Qihui Shi, Wei Tang, Chia-Kuang Tsung, Craig J. Hawker, and Galen D. Stucky pp 14493–14499 DOI: 10.1021/ja0756974 Supporting Info

Characterization of the Arene-Oxidizing Intermediate in ToMOH as a Diiron(III) Species Leslie J. Murray, Sunil G. Naik, Danilo O. Ortillo, Ricardo García-Serres, Jessica K. Lee, Boi Hanh Huynh, and Stephen J. Lippard pp 14500–14510 DOI: 10.1021/ja076121h Supporting Info

An Osmium−DNA Interstrand Complex:  Application to Facile DNA Methylation Analysis Kazuo Tanaka, Kazuki Tainaka, Tadashi Umemoto, Akiko Nomura, and Akimitsu Okamoto pp 14511–14517 DOI: 10.1021/ja076140r

Harnessing Functional Plasticity of Enzymes:  A Fluorogenic Probe for Imaging 17β-HSD10 Dehydrogenase, an Enzyme Involved in Alzheimer's and Parkinson's Diseases Mary K. Froemming and Dalibor Sames pp 14518–14522 DOI: 10.1021/ja072601x Supporting Info

Octamethyl-octaundecylcyclo[8]pyrrole:  A Promising Sulfate Anion Extractant [J. Am. Chem. Soc. 2007, 129, 11020−11021]. Leah R. Eller, Marcin Stpień, Christopher J. Fowler, Jeong Tae Lee, Jonathan L. Sessler, and Bruce A. Moyer p 14523 DOI: 10.1021/ja077858+ Supporting Info

Mechanistic Study of Competitive sp3-sp3 and sp2-sp3 Carbon−Carbon Reductive Elimination from a Platinum (IV) Center and the Isolation of a C−C Agostic Complex [J. Am. Chem. Soc. 2007, 129, 9538−9539]. Brian L. Madison, Summer B. Thyme, Sarra Keene, and B. Scott Williams p 14523 DOI: 10.1021/ja0799514

Core Concepts in Supramolecular Chemistry and Nanochemistry By Jonathan W. Steed (Durham University, U.K.), David R. Turner (Monash University, Australia), and Karl J. Wallace (University of Southern Mississippi). John Wiley & Sons, Ltd:  Chichester. 2007. xii + 308 pp. $50. ISBN 978-0-470-85867-7. Vincent M. Rotello p 14524 DOI: 10.1021/ja0769853

Thin Layer Chromatography in Chiral Separation and Analysis. Chromatographic Science Series, Volume 98 Edited by Terasa Kowalska (University of Silesia, Katowice, Poland) and Joseph Sherma (Lafayette College, Easton, PA). CRC Press/Taylor and Francis Group:  Boca Raton, FL, 2007. xvi + 420 pp. $169.95. ISBN 0-8493-4369-0. Colin F. Poole p 14524 DOI: 10.1021/ja0770025

Functional Organic Materials:  Syntheses, Strategies and Applications Edited by Thomas J. J. Müller (Heinrich-Heine-Universität Düsseldorf, Germany) and Uwe H. F. Bunz (Georgia Institute of Technology, Atlanta, GA, USA). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xx + 592 pp. $335. ISBN 978-3-527-31302-0. Vance E. Williams pp 14524–14525 DOI: 10.1021/ja076982q

Laser Chemistry:  Spectroscopy, Dynamics and Applications Edited by Helmut H. Telle (Swansea University, U.K.), Angel González Ureña (Universidad Complutense de Madrid, Spain), and Robert J. Donovan (Edinburg University, U.K.). John Wiley & Sons, Ltd.:  Chichester. 2007. xiv + 502 pp. $90.00. ISBN 978-0-471-48571-1. Joseph Chaiken pp 14525–14526 DOI: 10.1021/ja076987n

Atomic and Nuclear Analytical Methods:  XRF, Mössbauer, XPS, NAA and Ion-Beam Spectroscopic Techniques By H. R. Verma (Punjabi University, Patiala, India). Springer:  Berlin, Heidelberg, New York. 2007. xiv + 376 pp. $169.00. ISBN 978-3-540-30277-3. Martina Schmeling p 14526 DOI: 10.1021/ja076996w

Polymers and Light:  Fundamentals and Technical Applications By Wolfram Schnabel (Hahn-Meitner-Institut, Berlin, Germany). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2007. xiv + 382 pp. $190. ISBN 978-3-527-31866-7. James E. Hanson pp 14526–14527 DOI: 10.1021/ja076983i

Computational Organic Chemistry By Steven M. Bachrach (Trinity University, San Antonio, TX). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xviii + 478 pp. $110. ISBN 978-0-471-71342-5. Donald E. Elmore pp 14527–14528 DOI: 10.1021/ja077005h

Macromolecules Containing Metal and Metal-Like Elements, Volume 8:  Boron-Containing Polymers Edited by Alaa S. Abd-El-Aziz (University of British Columbia, Okanagan, BC), Charles E. Carraher, Jr. (Florida Atlantic University, Boca Raton, FL) and (Florida Center for Environmental Studies, Palm Beach Gardens, FL), Charles U. Pittman, Jr. (Mississippi State University, Mississippi State, MS), and Martel Zeldin (University of Richmond, Richmond, VA). John Wiley & Sons, Inc.:  Hoboken, NJ, 2007. xiv + 206 pp. $150. ISBN 978-0-471-73012-5. Robert H. Neilson p 14528 DOI: 10.1021/ja076993j

Issue 47

Compact Cysteine-Coated CdSe(ZnCdS) Quantum Dots for in Vivo Applications Wenhao Liu, Hak Soo Choi, John P. Zimmer, Eiichi Tanaka, John V. Frangioni, and Moungi Bawendi pp 14530–14531 DOI: 10.1021/ja073790m Supporting Info

Formation of Gold−Methanethiyl Self-Assembled Monolayers Yun Wang, Noel S. Hush, and Jeffrey R. Reimers pp 14532–14533 DOI: 10.1021/ja0743442

Supramolecular Star Polymers. Increased Molecular Weight with Decreased Polydispersity through Self-Assembly Eric M. Todd and Steven C. Zimmerman pp 14534–14535 DOI: 10.1021/ja075453j

Molecular Simulations Reveal a Common Binding Mode for Glycosylase Binding of Oxidatively Damaged DNA Lesions Kun Song, Catherine Kelso, Carlos de los Santos, Arthur P. Grollman, and Carlos Simmerling pp 14536–14537 DOI: 10.1021/ja075128w Supporting Info

Tuning the Thermoresponsiveness of Weak Polyelectrolytes by pH and Light:  Lower and Upper Critical-Solution Temperature of Poly(N,N-dimethylaminoethyl methacrylate) Felix A. Plamper, Alexander Schmalz, Matthias Ballauff, and Axel H. E. Müller pp 14538–14539 DOI: 10.1021/ja074720i Supporting Info

Modeling Thymine Photodimerizations in DNA:  Mechanism and Correlation Diagrams Lluís Blancafort and Annapaola Migani pp 14540–14541 DOI: 10.1021/ja074734o Supporting Info

Advancing Palladium-Catalyzed C−N Bond Formation:  Bisindoline Construction from Successive Amide Transfer to Internal Alkenes Kilian Muñiz pp 14542–14543 DOI: 10.1021/ja075655f Supporting Info

Activation of sp3 C−H Bonds with Cobalt(I):  Catalytic Synthesis of Enamines Andrew D. Bolig and Maurice Brookhart pp 14544–14545 DOI: 10.1021/ja075694r Supporting Info

Iron-Catalyzed Highly Regio- and Stereoselective Conjugate Addition of 2,3-Allenoates with Grignard Reagents Zhan Lu, Guobi Chai, and Shengming Ma pp 14546–14547 DOI: 10.1021/ja075750o Supporting Info

Mo-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of 3-Aryloxindoles Barry M. Trost and Yong Zhang pp 14548–14549 DOI: 10.1021/ja0755717 Supporting Info

Phase-Tunable Fluorophores Based upon Benzobis(imidazolium) Salts Andrew J. Boydston, Cory S. Pecinovsky, Steven T. Chao, and Christopher W. Bielawski pp 14550–14551 DOI: 10.1021/ja075963d Supporting Info

Highly Enantioselective Imine Cinnamylation with a Remarkable Diastereochemical Switch John D. Huber and James L. Leighton pp 14552–14553 DOI: 10.1021/ja076035h Supporting Info

Can H2 Inside C60 Communicate with the Outside World? Juan López-Gejo, Angel A. Martí, Marco Ruzzi, Steffen Jockusch, Koichi Komatsu, Fumiyuki Tanabe, Yasujiro Murata, and Nicholas J. Turro pp 14554–14555 DOI: 10.1021/ja076104s Supporting Info

Total Synthesis of (−)-Pseudolaric Acid B Barry M. Trost, Jerome Waser, and Arndt Meyer pp 14556–14557 DOI: 10.1021/ja076165q Supporting Info

Synthesis of Uniform Goethite Nanotubes with Parallelogram Cross Section Taekyung Yu, Jinkyung Park, Jaewon Moon, Kwangjin An, Yuanzhe Piao, and Taeghwan Hyeon pp 14558–14559 DOI: 10.1021/ja076176j Supporting Info

Photo-Leucine Incorporation Reveals the Target of a Cyclodepsipeptide Inhibitor of Cotranslational Translocation Andrew L. MacKinnon, Jennifer L. Garrison, Ramanujan S. Hegde, and Jack Taunton pp 14560–14561 DOI: 10.1021/ja076250y Supporting Info

Gas-Phase Zwitterion Stabilization by a Metal Dication Robert C. Dunbar, Nick C. Polfer, and Jos Oomens pp 14562–14563 DOI: 10.1021/ja076131i Supporting Info

Relaxation Rate for an Ultrafast Folding Protein Is Independent of Chemical Denaturant Concentration Troy Cellmer, Eric R. Henry, Jan Kubelka, James Hofrichter, and William A. Eaton pp 14564–14565 DOI: 10.1021/ja0761939 Supporting Info

Direct Detection of a Transient Oxenium Ion in Water Generated by Laser Flash Photolysis Yue-Ting Wang, Jin Wang, Matthew S. Platz, and Michael Novak pp 14566–14567 DOI: 10.1021/ja0764456 Supporting Info

In Vitro Selection of Histone H4 Aptamers for Recognition Imaging Microscopy Liyun Lin, Doris Hom, Stuart M. Lindsay, and John C. Chaput pp 14568–14569 DOI: 10.1021/ja076488m Supporting Info

High-Yielding Palladium-Catalyzed Intramolecular Alkane Arylation:  Reaction Development and Mechanistic Studies Marc Lafrance, Serge I. Gorelsky, and Keith Fagnou pp 14570–14571 DOI: 10.1021/ja076588s Supporting Info

Detection of Sequence-Specific Protein-DNA Interactions via Surface Enhanced Resonance Raman Scattering Andrew J. Bonham, Gary Braun, Ioana Pavel, Martin Moskovits, and Norbert O. Reich pp 14572–14573 DOI: 10.1021/ja0767837 Supporting Info

Ultrafast Excited-State Deactivation and Energy Transfer in Guanine−Cytosine DNA Double Helices François-Alexandre Miannay, Ákos Bányász, Thomas Gustavsson, and Dimitra Markovitsi pp 14574–14575 DOI: 10.1021/ja077100q Supporting Info

One Template Synthesis of Raspberry-like Hierarchical Siliceous Hollow Spheres Meihua Yu, Hongning Wang, Xufeng Zhou, Pei Yuan, and Chengzhong Yu pp 14576–14577 DOI: 10.1021/ja077110r

Intrinsically Cell-Permeable Miniature Proteins Based on a Minimal Cationic PPII Motif Douglas S. Daniels and Alanna Schepartz pp 14578–14579 DOI: 10.1021/ja0772445 Supporting Info

Reversible Microwave-Assisted Cycloaddition of Aziridines to Carbon Nanotubes Fulvio G. Brunetti, M. Antonia Herrero, Juan de M. Muñoz, Silvia Giordani, Angel Díaz-Ortiz, Salvatore Filippone, Giorgio Ruaro, Moreno Meneghetti, Maurizio Prato, and Ester Vázquez pp 14580–14581 DOI: 10.1021/ja077927k Supporting Info

The Biosynthesis of Spinosyn in Saccharopolyspora spinosa:  Synthesis of the Cross-Bridging Precursor and Identification of the Function of SpnJ Hak Joong Kim, Rongson Pongdee, Qingquan Wu, Lin Hong, and Hung-wen Liu pp 14582–14584 DOI: 10.1021/ja076580i Supporting Info

Structure of the Monoclinic-Form Misfit-Layer Compound, (Ca0.85OH)2αCoO2 (α ≈ 0.57822) Masaaki Isobe, Mitsuko Onoda, Mitsuyuki Shizuya, Masahiko Tanaka, and Eiji Takayama-Muromachi pp 14585–14596 DOI: 10.1021/ja072052v

Mechanism of Enzymatic Fluorination in Streptomyces cattleya Xiaofeng Zhu, David A. Robinson, Andrew R. McEwan, David O'Hagan, and James H. Naismith pp 14597–14604 DOI: 10.1021/ja0731569 Supporting Info

Probing Variable Axial Ligation in Nickel Superoxide Dismutase Utilizing Metallopeptide-Based Models:  Insight into the Superoxide Disproportionation Mechanism Kosh P. Neupane, Kristie Gearty, Ashish Francis, and Jason Shearer pp 14605–14618 DOI: 10.1021/ja0731625 Supporting Info

Real-Time Observation of Polyelectrolyte-Induced Binding of Charged Bilayers Yuxia Luan and Laurence Ramos pp 14619–14624 DOI: 10.1021/ja073412h Supporting Info

Directed Formation of Micro- and Nanoscale Patterns of Functional Light-Harvesting LH2 Complexes Nicholas P. Reynolds, Stefan Janusz, Maryana Escalante-Marun, John Timney, Robert E. Ducker, John D. Olsen, Cees Otto, Vinod Subramaniam, Graham J. Leggett, and C. Neil Hunter pp 14625–14631 DOI: 10.1021/ja073658m

Asymmetric Sulfur Ylide Reactions with Boranes:  Scope and Limitations, Mechanism and Understanding Guang Y. Fang, Olov A. Wallner, Nadia Di Blasio, Xavier Ginesta, Jeremy N. Harvey, and Varinder K. Aggarwal pp 14632–14639 DOI: 10.1021/ja074110i Supporting Info

Architectural Diversity and Elastic Networks in Hydrogen-Bonded Host Frameworks:  From Molecular Jaws to Cylinders Matthew J. Horner, K. Travis Holman, and Michael D. Ward pp 14640–14660 DOI: 10.1021/ja0741574 Supporting Info

β-Strand Flipping and Slipping Triggered by Turn Replacement Reveal the Opportunistic Nature of β-Strand Pairing Koki Makabe, Shude Yan, Valentina Tereshko, Grzegorz Gawlak, and Shohei Koide pp 14661–14669 DOI: 10.1021/ja074252c Supporting Info

Elucidation of the Kijanimicin Gene Cluster:  Insights into the Biosynthesis of Spirotetronate Antibiotics and Nitrosugars Hua Zhang, Jess A. White-Phillip, Charles E. Melançon, III, Hyung-jin Kwon, Wei-luen Yu, and Hung-wen Liu pp 14670–14683 DOI: 10.1021/ja0744854

Analysis of an Unprecedented Mechanism for the Catalytic Hydrosilylation of Carbonyl Compounds Kristine A. Nolin, Jennifer R. Krumper, Michael D. Pluth, Robert G. Bergman, and F. Dean Toste pp 14684–14696 DOI: 10.1021/ja074477n Supporting Info

Isotopic Probing of Molecular Oxygen Activation at Copper(I) Sites Michael P. Lanci, Valeriy V. Smirnov, Christopher J. Cramer, Ekaterina V. Gauchenova, Jörg Sundermeyer, and Justine P. Roth pp 14697–14709 DOI: 10.1021/ja074620c Supporting Info

Double-Stranded DNA Dissociates into Single Strands When Dragged into a Poor Solvent Shuxun Cui, Jin Yu, Ferdinand Kühner, Klaus Schulten, and Hermann E. Gaub pp 14710–14716 DOI: 10.1021/ja074776c Supporting Info

Membrane-Bound Conformation of Peptaibols with Methyl-Deuterated α-Amino Isobutyric Acids by 2H Magic Angle Spinning Solid-State NMR Spectroscopy Kresten Bertelsen, Jan M. Pedersen, Brian S. Rasmussen, Troels Skrydstrup, Niels Chr. Nielsen, and Thomas Vosegaard pp 14717–14723 DOI: 10.1021/ja0749690

Effect of Electron-Donating and Electron-Withdrawing Groups on Peptide/Single-Walled Carbon Nanotube Interactions Vasiliki Z. Poenitzsch, David C. Winters, Hui Xie, Gregg R. Dieckmann, Alan B. Dalton, and Inga H. Musselman pp 14724–14732 DOI: 10.1021/ja0750827 Supporting Info

Long-Range Electron and Hole Transport through DNA with Tethered Cyclometalated Iridium(III) Complexes Fangwei Shao and Jacqueline K. Barton pp 14733–14738 DOI: 10.1021/ja0752437

Dynamics of B-DNA on the Microsecond Time Scale Alberto Pérez, F. Javier Luque, and Modesto Orozco pp 14739–14745 DOI: 10.1021/ja0753546 Supporting Info

Biophysical and Structural Characterization of a Robust Octameric β-Peptide Bundle Jessica L. Goodman, E. James Petersson, Douglas S. Daniels, Jade X. Qiu, and Alanna Schepartz pp 14746–14751 DOI: 10.1021/ja0754002 Supporting Info

Catalysis of the Cleavage of Uridine 3‘-2,2,2-Trichloroethylphosphate by a Designed Helix−Loop−Helix Motif Peptide Jesus Razkin, Helena Nilsson, and Lars Baltzer pp 14752–14758 DOI: 10.1021/ja075478i Supporting Info

Imaging and Tracking of Tat Peptide-Conjugated Quantum Dots in Living Cells:  New Insights into Nanoparticle Uptake, Intracellular Transport, and Vesicle Shedding Gang Ruan, Amit Agrawal, Adam I. Marcus, and Shuming Nie pp 14759–14766 DOI: 10.1021/ja074936k Supporting Info

Boron Rings Enclosing Planar Hypercoordinate Group 14 Elements Rafael Islas, Thomas Heine, Keigo Ito, Paul v. R. Schleyer, and Gabriel Merino pp 14767–14774 DOI: 10.1021/ja074956m Supporting Info

Widely Useful DMAP-Catalyzed Esterification under Auxiliary Base- and Solvent-Free Conditions Akira Sakakura, Kimio Kawajiri, Takuro Ohkubo, Yuji Kosugi, and Kazuaki Ishihara pp 14775–14779 DOI: 10.1021/ja075824w Supporting Info

D-Periodic Collagen-Mimetic Microfibers Shyam Rele, Yuhua Song, Robert P. Apkarian, Zheng Qu, Vincent P. Conticello, and Elliot L. Chaikof pp 14780–14787 DOI: 10.1021/ja0758990 Supporting Info

Highly Stereo- and Regioselective Synthesis of (Z)-Trisubstituted Alkenes via 1-Bromo-1-alkyne Hydroboration−Migratory Insertion−Zn-Promoted Iodinolysis and Pd-Catalyzed Organozinc Cross-Coupling Zhihong Huang and Ei-ichi Negishi pp 14788–14792 DOI: 10.1021/ja0772039 Supporting Info

Inherent Antibacterial Activity of a Peptide-Based β-Hairpin Hydrogel Daphne A. Salick, Juliana K. Kretsinger, Darrin J. Pochan, and Joel P. Schneider pp 14793–14799 DOI: 10.1021/ja076300z Supporting Info

Direct Demonstration of the Presence of Coordinated Sulfate in the Reaction Pathway of Arabidopsis thaliana Sulfite Oxidase Using 33S Labeling and ESEEM Spectroscopy Andrei V. Astashkin, Kayunta Johnson-Winters, Eric L. Klein, Robert S. Byrne, Russ Hille, Arnold M. Raitsimring, and John H. Enemark pp 14800–14810 DOI: 10.1021/ja0704885

d-Fructose-6-Phosphate Aldolase-Catalyzed One-Pot Synthesis of Iminocyclitols Masakazu Sugiyama, Zhangyong Hong, Pi-Hui Liang, Stephen M. Dean, Lisa J. Whalen, William A. Greenberg, and Chi-Huey Wong pp 14811–14817 DOI: 10.1021/ja073911i Supporting Info

Lithium Diisopropylamide-Mediated Reactions of Imines, Unsaturated Esters, Epoxides, and Aryl Carbamates:  Influence of Hexamethylphosphoramide and Ethereal Cosolvents on Reaction Mechanisms Yun Ma and David B. Collum pp 14818–14825 DOI: 10.1021/ja074554e Supporting Info

Gd3N@C2n (n = 40, 42, and 44):  Remarkably Low HOMO−LUMO Gap and Unusual Electrochemical Reversibility of Gd3N@C88 Manuel N. Chaur, Frederic Melin, Bevan Elliott, Andreas J. Athans, Kenneth Walker, Brian C. Holloway, and Luis Echegoyen pp 14826–14829 DOI: 10.1021/ja075930y Supporting Info

Structural Studies on the Radical Cations of Benzene, Naphthalene, Biphenylene, and Anthracene Fully Annelated with Bicyclo[2.2.2]octene Frameworks [J. Am. Chem. Soc. 2000, 122, 10007−10016]. Akira Matsuura, Tohru Nishinaga, and Koichi Komatsu p 14830 DOI: 10.1021/ja077519g Supporting Info

Reviews in Computational Chemistry, Volume 24 Edited by Kenny B. Lipkowitz (Howard University, Washington, D.C.), Thomas R. Cundari (University of North Texas, Denton), and Editor Emeritus, Donald B. Boyd (Indiana University-Purdue University, Indianapolis). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xxxiv + 518 pp. $175. ISBN 978-0-470-11281-6. Richard K. Bowles p 14831 DOI: 10.1021/ja076992r

A Practical Guide to Magnetic Circular Dichroism Spectroscopy By W. Roy Mason (Northern Illinois University). John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xii + 224 pp. $125.00. ISBN:  978-0-470-06978-3. Patricia Ann Snyder pp 14831–14832 DOI: 10.1021/ja077004p

Issue 48

A Strategy to Protect and Sensitize Near-Infrared Luminescent Nd3+ and Yb3+:  Organic Tropolonate Ligands for the Sensitization of Ln3+-Doped NaYF4 Nanocrystals Jian Zhang, Chad M. Shade, Demetra A. Chengelis, and Stéphane Petoud pp 14834–14835 DOI: 10.1021/ja074564f Supporting Info

A Rhodium-Catalyzed C−H Activation/Cycloisomerization Tandem Christophe Aïssa and Alois Fürstner pp 14836–14837 DOI: 10.1021/ja0746316 Supporting Info

Caldariomyces fumago Chloroperoxidase Catalyzes the Oxidative Dehalogenation of Chlorophenols by a Mechanism Involving Two One-Electron Steps Robert L. Osborne, Michael K. Coggins, James Terner, and John H. Dawson pp 14838–14839 DOI: 10.1021/ja0746969 Supporting Info

Protonation States of Buried Histidine Residues in Human Deoxyhemoglobin Revealed by Neutron Crystallography Toshiyuki Chatake, Naoya Shibayama, Sam-Yong Park, Kazuo Kurihara, Taro Tamada, Ichiro Tanaka, Nobuo Niimura, Ryota Kuroki, and Yukio Morimoto pp 14840–14841 DOI: 10.1021/ja0749441 Supporting Info

One-Step Photochemical Introduction of Nanopatterned Protein-Binding Functionalities to Oligo(ethylene glycol)-Terminated Self-Assembled Monolayers Robert E. Ducker, Stefan Janusz, Shuqing Sun, and Graham J. Leggett pp 14842–14843 DOI: 10.1021/ja0749800 Supporting Info

Synthetic Hydrogenases:  Incorporation of an Iron Carbonyl Thiolate into a Designed Peptide Anne K. Jones, Bruce R. Lichtenstein, Arnab Dutta, Gwyneth Gordon, and P. Leslie Dutton pp 14844–14845 DOI: 10.1021/ja075116a Supporting Info

The Mechanism of Cysteine Oxygenation by Cysteine Dioxygenase Enzymes Swathi Aluri and Sam P. de Visser pp 14846–14847 DOI: 10.1021/ja0758178 Supporting Info

Misfolding of Amyloidogenic Proteins at Membrane Surfaces:  The Impact of Macromolecular Crowding Marcus Bokvist and Gerhard Gröbner pp 14848–14849 DOI: 10.1021/ja076059o Supporting Info

Total Synthesis and Antibacterial Properties of Carbaplatensimycin K. C. Nicolaou, Yefeng Tang, Jianhua Wang, Antonia F. Stepan, Ang Li, and Ana Montero pp 14850–14851 DOI: 10.1021/ja076126e Supporting Info

Ultrafast Plasmon-Induced Electron Transfer from Gold Nanodots into TiO2 Nanoparticles Akihiro Furube, Luchao Du, Kohjiro Hara, Ryuzi Katoh, and Masanori Tachiya pp 14852–14853 DOI: 10.1021/ja076134v

Distinctive Inhibition of O-GlcNAcase Isoforms by an α-GlcNAc Thiolsulfonate Eun J. Kim, Benjamin Amorelli, Mohannad Abdo, Craig J. Thomas, Dona C. Love, Spencer Knapp, and John A. Hanover pp 14854–14855 DOI: 10.1021/ja076038u Supporting Info

Copper-Catalyzed Enantioselective Substitution of Allylic Carbonates with Diboron:  An Efficient Route to Optically Active α-Chiral Allylboronates Hajime Ito, Shinichiro Ito, Yusuke Sasaki, Kou Matsuura, and Masaya Sawamura pp 14856–14857 DOI: 10.1021/ja076634o Supporting Info

Essential Role of an Active-Site Guanine in glmS Ribozyme Catalysis Daniel J. Klein, Michael D. Been, and Adrian R. Ferré-D'Amaré pp 14858–14859 DOI: 10.1021/ja0768441 Supporting Info

Palladium-Catalyzed Decarboxylative sp3−sp3 Coupling of Nitrobenzene Acetic Esters Shelli R. Waetzig and Jon A. Tunge pp 14860–14861 DOI: 10.1021/ja077070r Supporting Info

Reversible Photoregulation of Binding of α-Chymotrypsin to a Gold Surface David Pearson, Alison J. Downard, Andrew Muscroft-Taylor, and Andrew D. Abell pp 14862–14863 DOI: 10.1021/ja0766674 Supporting Info

Enantioselective Construction of Quaternary Stereogenic Carbons by the Lewis Base Catalyzed Additions of Silyl Ketene Imines to Aldehydes Scott E. Denmark, Tyler W. Wilson, Matthew T. Burk, and John R. Heemstra, Jr. pp 14864–14865 DOI: 10.1021/ja077134y Supporting Info

Palladium-Catalyzed Synthesis of Spiro[2.4]heptanes:  Ligand-Dependent Position Control in the Nucleophilic Attack to a π-Allylpalladium Intermediate Ryo Shintani, Soyoung Park, and Tamio Hayashi pp 14866–14867 DOI: 10.1021/ja077236o Supporting Info

Sila Morita−Baylis−Hillman Reaction of Cyclopropenes Stepan Chuprakov, Denis A. Malyshev, Alexander Trofimov, and Vladimir Gevorgyan pp 14868–14869 DOI: 10.1021/ja077437s Supporting Info

Rational Design and Synthesis of Catalytically Driven Nanorotors Lidong Qin, Matthew J. Banholzer, Xiaoyang Xu, Ling Huang, and Chad A. Mirkin pp 14870–14871 DOI: 10.1021/ja0772391 Supporting Info

Total Synthesis of (−)-Okilactomycin Amos B. Smith, III, Kallol Basu, and Todd Bosanac pp 14872–14874 DOI: 10.1021/ja077569l Supporting Info

Modular Multi-Level Circuits from Immobilized DNA-Based Logic Gates Brian M. Frezza, Scott L. Cockroft, and M. Reza Ghadiri pp 14875–14879 DOI: 10.1021/ja0710149 Supporting Info

Highly Luminescent CdTe/CdSe Colloidal Heteronanocrystals with Temperature-Dependent Emission Color Patrick T. K. Chin, Celso de Mello Donegá, Svetlana S. van Bavel, Stefan C. J. Meskers, Nico A. J. M. Sommerdijk, and René A. J. Janssen pp 14880–14886 DOI: 10.1021/ja0738071 Supporting Info

Molecular Dynamics Simulations of Hydrophobic Associations in Aqueous Salt Solutions Indicate a Connection between Water Hydrogen Bonding and the Hofmeister Effect Andrew S. Thomas and Adrian H. Elcock pp 14887–14898 DOI: 10.1021/ja073097z Supporting Info

Structures, Rugged Energetic Landscapes, and Nanothermodynamics of Aln (2 ≤ n ≤ 65) Particles Zhen Hua Li, Ahren W. Jasper, and Donald G. Truhlar pp 14899–14910 DOI: 10.1021/ja073129i Supporting Info

Synthesis of 5-Fluoropyrimidine Nucleotides as Sensitive NMR Probes of RNA Structure Mirko Hennig, Lincoln G. Scott, Edit Sperling, Wolfgang Bermel, and James R. Williamson pp 14911–14921 DOI: 10.1021/ja073825i Supporting Info

Redesign of Protein Domains Using One-Bead-One-Compound Combinatorial Chemistry Jose J. Pastor, Giovanna Granados, Natàlia Carulla, Francesc Rabanal, and Ernest Giralt pp 14922–14932 DOI: 10.1021/ja073969x Supporting Info

Development and Initial Application of a Hybridization-Independent, DNA-Encoded Reaction Discovery System Compatible with Organic Solvents Mary M. Rozenman, Matthew W. Kanan, and David R. Liu pp 14933–14938 DOI: 10.1021/ja074155j Supporting Info

Exciton−Plasmon Interaction in a Composite Metal−Insulator−Semiconductor Nanowire System Yuri Fedutik, Vasily Temnov, Ulrike Woggon, Elena Ustinovich, and Mikhail Artemyev pp 14939–14945 DOI: 10.1021/ja074705d

Control of Calcium Oxalate Crystal Growth by Face-Specific Adsorption of an Osteopontin Phosphopeptide Bernd Grohe, Jason O'Young, D. Andrei Ionescu, Gilles Lajoie, Kem A. Rogers, Mikko Karttunen, Harvey A. Goldberg, and Graeme K. Hunter pp 14946–14951 DOI: 10.1021/ja0745613 Supporting Info

Fourier Transform Infrared Characterization of a CuB−Nitrosyl Complex in Cytochrome ba3 from Thermus thermophilus:  Relevance to NO Reductase Activity in Heme−Copper Terminal Oxidases Takahiro Hayashi, I-Jin Lin, Ying Chen, James A. Fee, and Pierre Moënne-Loccoz pp 14952–14958 DOI: 10.1021/ja074600a Supporting Info

Dead-End Street of Protein Folding: Thermodynamic Rationale of Amyloid Fibril Formation András Perczel, Péter Hudáky, and Villö K. Pálfi pp 14959–14965 DOI: 10.1021/ja0747122 Supporting Info

Measurement of the Effect of Monovalent Cations on RNA Hairpin Stability Jeffrey Vieregg, Wei Cheng, Carlos Bustamante, and Ignacio Tinoco, Jr. pp 14966–14973 DOI: 10.1021/ja074809o Supporting Info

Intramolecular Cyclization of Ruthenium Vinylidene Complexes with a Tethering Vinyl Group:  Facile Cleavage and Reconstruction of the C−C Double Bond Cheng-Wei Cheng, Yi-Chun Kuo, Shu-Hao Chang, Ying-Chih Lin, Yi-Hong Liu, and Yu Wang pp 14974–14980 DOI: 10.1021/ja074951p Supporting Info

Quantitative and Comprehensive Decomposition of the Ion Atmosphere around Nucleic Acids Yu Bai, Max Greenfeld, Kevin J. Travers, Vincent B. Chu, Jan Lipfert, Sebastian Doniach, and Daniel Herschlag pp 14981–14988 DOI: 10.1021/ja075020g Supporting Info

Conformation and Location of Membrane-Bound Salinomycin−Sodium Complex Deduced from NMR in Isotropic Bicelles Nobuaki Matsumori, Atsushi Morooka, and Michio Murata pp 14989–14995 DOI: 10.1021/ja075024l Supporting Info

Helical Polymer 1/∞[P2Se62-]:  Strong Second Harmonic Generation Response and Phase-Change Properties of Its K and Rb Salts In Chung, Christos D. Malliakas, Joon I. Jang, Christian G. Canlas, David P. Weliky, and Mercouri G. Kanatzidis pp 14996–15006 DOI: 10.1021/ja075096c Supporting Info

Substrate-Dependent Stereochemical Course of the (Z)-13-Desaturation Catalyzed by the Processionary Moth Multifunctional Desaturase José-Luis Abad, Francisco Camps, and Gemma Fabriàs pp 15007–15012 DOI: 10.1021/ja0751936 Supporting Info

Binding of Genistein to the Estrogen Receptor Based on an Experimental Electron Density Study Eric J. Yearley, Elizabeth A. Zhurova, Vladimir V. Zhurov, and A. Alan Pinkerton pp 15013–15021 DOI: 10.1021/ja075211j Supporting Info

Growth of First Generation Dendrons on SiO2:  Controlling Chemisorption of Transition Metal Coordination Complexes Manish Sharma, Abhishek Dube, and James R. Engstrom pp 15022–15033 DOI: 10.1021/ja0752944 Supporting Info

Surprisingly High Stability of Collagen ABC Heterotrimer:  Evaluation of Side Chain Charge Pairs Varun Gauba and Jeffrey D. Hartgerink pp 15034–15041 DOI: 10.1021/ja075854z Supporting Info

Anticancer and Antimicrobial Metallopharmaceutical Agents Based on Palladium, Gold, and Silver N-Heterocyclic Carbene Complexes Sriparna Ray, Renu Mohan, Jay K. Singh, Manoja K. Samantaray, Mobin M. Shaikh, Dulal Panda, and Prasenjit Ghosh pp 15042–15053 DOI: 10.1021/ja075889z Supporting Info

Self-Assembly of Fluorescent Inclusion Complexes in Competitive Media Including the Interior of Living Cells Jeremiah J. Gassensmith, Easwaran Arunkumar, Lorna Barr, Jeffrey M. Baumes, Kristy M. DiVittorio, James R. Johnson, Bruce C. Noll, and Bradley D. Smith pp 15054–15059 DOI: 10.1021/ja075567v Supporting Info

Site-Specific Insertion of 3-Aminotyrosine into Subunit α2 of E. coli Ribonucleotide Reductase:  Direct Evidence for Involvement of Y730 and Y731 in Radical Propagation Mohammad R. Seyedsayamdost, Jianming Xie, Clement T. Y. Chan, Peter G. Schultz, and JoAnne Stubbe pp 15060–15071 DOI: 10.1021/ja076043y Supporting Info

Side Chain Disorder and Phase Transitions in Alkyl-Substituted, Conjugated Oligomers. Relation to Side-Chain Melting in P3ATs M. David Curtis, John I. Nanos, Hyunsik Moon, and Woong Sang Jahng pp 15072–15084 DOI: 10.1021/ja076235t Supporting Info

A Switchable Palladium-Complexed Molecular Shuttle and Its Metastable Positional Isomers James D. Crowley, David A. Leigh, Paul J. Lusby, Roy T. McBurney, Laure-Emmanuelle Perret-Aebi, Christiane Petzold, Alexandra M. Z. Slawin, and Mark D. Symes pp 15085–15090 DOI: 10.1021/ja076570h Supporting Info

Issue 49

Porous Crystalline Ruthenium Complexes Are Oxygen Sensors Kari A. McGee, David J. Veltkamp, Brian J. Marquardt, and Kent R. Mann pp 15092–15093 DOI: 10.1021/ja0681772 Supporting Info

A Coordination Network That Catalyzes O2-Based Oxidations Jong Woo Han and Craig L. Hill pp 15094–15095 DOI: 10.1021/ja069319v Supporting Info

Polymer-Caged Lipsomes:  A pH-Responsive Delivery System with High Stability Sang-Min Lee, Haimei Chen, Christine M. Dettmer, Thomas V. O'Halloran, and SonBinh T. Nguyen pp 15096–15097 DOI: 10.1021/ja070748i Supporting Info

The Role of Free Energy Change in Coupled Electron−Proton Transfer Christine J. Fecenko, H. Holden Thorp, and Thomas J. Meyer pp 15098–15099 DOI: 10.1021/ja072558d Supporting Info

Clarification of the Role of Water in Proline-Mediated Aldol Reactions Natalia Zotova, Axel Franzke, Alan Armstrong, and Donna G. Blackmond pp 15100–15101 DOI: 10.1021/ja0738881 Supporting Info

Direct ortho Cupration:  A New Route to Regioselectively Functionalized Aromatics Shinya Usui, Yuichi Hashimoto, James V. Morey, Andrew E. H. Wheatley, and Masanobu Uchiyama pp 15102–15103 DOI: 10.1021/ja074669i Supporting Info

Urea Orientation at Protein Surfaces Xin Chen, Laura B. Sagle, and Paul S. Cremer pp 15104–15105 DOI: 10.1021/ja075034m Supporting Info

Considerations of Macromolecular Structure in the Design of Proton Conducting Polymer Membranes:  Graft versus Diblock Polyelectrolytes Emily M. W. Tsang, Zhaobin Zhang, Zhiqing Shi, Tatyana Soboleva, and Steven Holdcroft pp 15106–15107 DOI: 10.1021/ja074765j Supporting Info

Dumbbell-Shaped Nanocircular RNAs for RNA Interference Naoko Abe, Hiroshi Abe, and Yoshihiro Ito pp 15108–15109 DOI: 10.1021/ja0754453 Supporting Info

Enantioselective Aza-Henry Reaction with an N-Sulfinyl Urea Organocatalyst MaryAnn T. Robak, Monica Trincado, and Jonathan A. Ellman pp 15110–15111 DOI: 10.1021/ja075653v Supporting Info

Synthesis of Substituted 1,4-Dienes by Direct Alkylation of Allylic Alcohols Filip Kolundzic and Glenn C. Micalizio pp 15112–15113 DOI: 10.1021/ja075678u Supporting Info

Stereochemistry of Sagittamide A from Residual Dipolar Coupling Enhanced NMR Anne Schuetz, Jochen Junker, Andrei Leonov, Oliver F. Lange, Tadeusz F. Molinski, and Christian Griesinger pp 15114–15115 DOI: 10.1021/ja075876l Supporting Info

Synthesis of Sulfur-Rich Polymers:  Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System Koji Nakano, Go Tatsumi, and Kyoko Nozaki pp 15116–15117 DOI: 10.1021/ja076056b Supporting Info

Step-by-Step Route for the Synthesis of Metal−Organic Frameworks Osama Shekhah, Hui Wang, Stefan Kowarik, Frank Schreiber, Michael Paulus, Metin Tolan, Christian Sternemann, Florian Evers, Denise Zacher, Roland A. Fischer, and Christof Wöll pp 15118–15119 DOI: 10.1021/ja076210u Supporting Info

Electrochemical Biomineralization:  The Deposition of Calcite with Chiral Morphologies Elizabeth A. Kulp and Jay A. Switzer pp 15120–15121 DOI: 10.1021/ja076303b Supporting Info

Pd-Catalyzed Dynamic Kinetic Enantioselective Arylation of Silylphosphines Vincent S. Chan, Robert G. Bergman, and F. Dean Toste pp 15122–15123 DOI: 10.1021/ja076457r Supporting Info

Interfacial Trapping of Single-Walled Carbon Nanotube Bundles Randy K. Wang, Ryan D. Reeves, and Kirk J. Ziegler pp 15124–15125 DOI: 10.1021/ja076700m Supporting Info

Ion Pair-Driven Heterodimeric Capsule Based on Boronate Esterification:  Construction and the Dynamic Behavior Kenichi Kataoka, Tony D. James, and Yuji Kubo pp 15126–15127 DOI: 10.1021/ja076792f Supporting Info

N2O Activation and Oxidation Reactivity from a Non-Heme Iron Pyrrole Platform W. Hill Harman and Christopher J. Chang pp 15128–15129 DOI: 10.1021/ja076842g Supporting Info

Dynamics and Efficiency of DNA Hole Transport via Alternating AT versus Poly(A) Sequences Frederick D. Lewis, Pierre Daublain, Boiko Cohen, Josh Vura-Weis, Vladimir Shafirovich, and Michael R. Wasielewski pp 15130–15131 DOI: 10.1021/ja076876o Supporting Info

Ultrafast Charge Separation at CdS Quantum Dot/Rhodamine B Molecule Interface Abdelaziz Boulesbaa, Abey Issac, Dave Stockwell, Zhuangqun Huang, Jier Huang, Jianchang Guo, and Tianquan Lian pp 15132–15133 DOI: 10.1021/ja0773406 Supporting Info

Catalytic C−C Coupling via Transfer Hydrogenation:  Reverse Prenylation, Crotylation, and Allylation from the Alcohol or Aldehyde Oxidation Level John F. Bower, Eduardas Skucas, Ryan L. Patman, and Michael J. Krische pp 15134–15135 DOI: 10.1021/ja077389b Supporting Info

Doping the Golden Cage Au16- with Si, Ge, and Sn Lei-Ming Wang, Satya Bulusu, Wei Huang, Rhitankar Pal, Lai-Sheng Wang, and Xiao Cheng Zeng pp 15136–15137 DOI: 10.1021/ja077465a Supporting Info

A Germanium(II)-Centered Dication Paul A. Rupar, Viktor N. Staroverov, Paul J. Ragogna, and Kim M. Baines pp 15138–15139 DOI: 10.1021/ja0775725 Supporting Info

Selenium Becomes Metallic in Ru−Se Fuel Cell Catalysts:  An EC-NMR and XPS Investigation Panakkattu K. Babu, Adam Lewera, Jong Ho Chung, Ralf Hunger, Wolfram Jaegermann, Nicolas Alonso-Vante, Andrzej Wieckowski, and Eric Oldfield pp 15140–15141 DOI: 10.1021/ja077498q Supporting Info

Reactivity of Pd(II) Complexes with Electrophilic Chlorinating Reagents:  Isolation of Pd(IV) Products and Observation of C−Cl Bond-Forming Reductive Elimination Salena R. Whitfield and Melanie S. Sanford pp 15142–15143 DOI: 10.1021/ja077866q Supporting Info

A Fan-Shaped Polynuclear Gd6Cu12 Amino Acid Cluster:  A “Hollow” and Ferromagnetic [Gd6(μ3-OH)8] Octahedral Core Encapsulated by Six [Cu2] Glycinato Blade Fragments Shengchang Xiang, Shengmin Hu, Tianlu Sheng, Ruibiao Fu, Xintao Wu, and Xudong Zhang pp 15144–15146 DOI: 10.1021/ja0760832 Supporting Info

Characterization and Mechanistic Study of a Radical SAM Dehydrogenase in the Biosynthesis of Butirosin Kenichi Yokoyama, Mario Numakura, Fumitaka Kudo, Daijiro Ohmori, and Tadashi Eguchi pp 15147–15155 DOI: 10.1021/ja072481t Supporting Info

Site-Directed Conjugation of “Clicked” Glycopolymers To Form Glycoprotein Mimics:  Binding to Mammalian Lectin and Induction of Immunological Function Jin Geng, Giuseppe Mantovani, Lei Tao, Julien Nicolas, Gaojian Chen, Russell Wallis, Daniel A. Mitchell, Benjamin R. G. Johnson, Stephen D. Evans, and David M. Haddleton pp 15156–15163 DOI: 10.1021/ja072999x Supporting Info

Paramagnetic NMR Relaxation in Polymeric Matrixes:  Sensitivity Enhancement and Selective Suppression of Embedded Species (1H and 13C PSR Filter) Eduardo Fernandez-Megia, Juan Correa, Ramon Novoa-Carballal, and Ricardo Riguera pp 15164–15173 DOI: 10.1021/ja0737117

On the Orientation of a Designed Transmembrane Peptide:  Toward the Right Tilt Angle? Suat Özdirekcan, Catherine Etchebest, J. Antoinette Killian, and Patrick F. J. Fuchs pp 15174–15181 DOI: 10.1021/ja073784q Supporting Info

Engineered Biosynthesis of Nonribosomal Lipopeptides with Modified Fatty Acid Side Chains Amanda Powell, Mathew Borg, Bagher Amir-Heidari, Joanne M. Neary, Jenny Thirlway, Barrie Wilkinson, Colin P. Smith, and Jason Micklefield pp 15182–15191 DOI: 10.1021/ja074331o Supporting Info

Controlling Relative Fundamental Crystal Growth Rates in Silicalite:  AFM Observation L. Itzel Meza, Michael W. Anderson, Jonathan R. Agger, Colin S. Cundy, Chin B. Chong, and Richard J. Plaisted pp 15192–15201 DOI: 10.1021/ja0739887 Supporting Info

On the Mechanism of Hydrogen Storage in a Metal−Organic Framework Material Jonathan L. Belof, Abraham C. Stern, Mohamed Eddaoudi, and Brian Space pp 15202–15210 DOI: 10.1021/ja0737164 Supporting Info

Contrasting Two- and Three-Dimensional Crystal Properties of Isomeric Dialkyl Phthalates Katherine E. Plass, Keary M. Engle, and Adam J. Matzger pp 15211–15217 DOI: 10.1021/ja0744798 Supporting Info

Isostable DNA Carolin Ahlborn, Karsten Siegmund, and Clemens Richert pp 15218–15232 DOI: 10.1021/ja074209p Supporting Info

Determination of Global Structure from Distance and Orientation Constraints in Biological Solids Using Solid-State NMR Spectroscopy Loren B. Andreas, Anil K. Mehta, and Manish A. Mehta pp 15233–15239 DOI: 10.1021/ja074789q Supporting Info

Enantioselective Chemisorption of Propylene Oxide on a 2-Butanol Modified Pd(111) Surface:  The Role of Hydrogen-Bonding Interactions Feng Gao, Yilin Wang, Luke Burkholder, and Wilfred. T. Tysoe pp 15240–15249 DOI: 10.1021/ja074482r

Mechanistic Studies of Copper(I)-Catalyzed Allylic Amination Radhey S. Srivastava, Nathan R. Tarver, and Kenneth M. Nicholas pp 15250–15258 DOI: 10.1021/ja0751072 Supporting Info

Tuning Orbital Energetics in Arylene Diimide Semiconductors. Materials Design for Ambient Stability of n-Type Charge Transport Brooks A. Jones, Antonio Facchetti, Michael R. Wasielewski, and Tobin J. Marks pp 15259–15278 DOI: 10.1021/ja075242e Supporting Info

Design, Synthesis, and Characterization of a Potent, Nonpeptide, Cell-Permeable, Bivalent Smac Mimetic That Concurrently Targets Both the BIR2 and BIR3 Domains in XIAP Haiying Sun, Zaneta Nikolovska-Coleska, Jianfeng Lu, Jennifer L. Meagher, Chao-Yie Yang, Su Qiu, York Tomita, Yumi Ueda, Sheng Jiang, Krzysztof Krajewski, Peter P. Roller, Jeanne A. Stuckey, and Shaomeng Wang pp 15279–15294 DOI: 10.1021/ja074725f Supporting Info

The Many Ways To Have a Quintuple Bond Gabriel Merino, Kelling J. Donald, Jason S. D'Acchioli, and Roald Hoffmann pp 15295–15302 DOI: 10.1021/ja075454b Supporting Info

Inelastic Electron Tunneling Spectroscopy of Alkane Monolayers with Dissimilar Attachment Chemistry to Gold David P. Long and Alessandro Troisi pp 15303–15310 DOI: 10.1021/ja074970z Supporting Info

Gas-Phase Models for Catalysis:  Alkane Activation and Olefin Epoxidation by the Triatomic Cation Ag2O+ Jana Roithová and Detlef Schröder pp 15311–15318 DOI: 10.1021/ja075628p Supporting Info

DNA as Supramolecular Scaffold for Porphyrin Arrays on the Nanometer Scale Leslie-Anne Fendt, Imenne Bouamaied, Sandra Thöni, Nicolas Amiot, and Eugen Stulz pp 15319–15329 DOI: 10.1021/ja075711c Supporting Info

Detection of Reactive Tetrahedral Intermediates in a Deep Cavitand with an Introverted Functionality Richard J. Hooley, Tetsuo Iwasawa, and Julius Rebek, Jr. pp 15330–15339 DOI: 10.1021/ja0759343 Supporting Info

The Role of Selection Pressure in RNA-Mediated Evolutionary Materials Synthesis Stefan Franzen, Marta Cerruti, Donovan N. Leonard, and Gerd Duscher pp 15340–15346 DOI: 10.1021/ja076054r Supporting Info

The Oxidation Potential of Adenosine and Adenosine-Thymidine Base Pair in Chloroform Solution Tonino Caruso, Amedeo Capobianco, and Andrea Peluso pp 15347–15353 DOI: 10.1021/ja076181n Supporting Info

Resolution of Chiral, Tetrahedral M4L6 Metal−Ligand Hosts1 Anna V. Davis, Dorothea Fiedler, Marco Ziegler, Andreas Terpin, and Kenneth N. Raymond pp 15354–15363 DOI: 10.1021/ja0764815 Supporting Info

Quantitative Single Molecule Measurements on the Interaction Forces of Poly(l-glutamic acid) with Calcite Crystals Lars Sonnenberg, Yufei Luo, Helmut Schlaad, Markus Seitz, Helmut Cölfen, and Hermann E. Gaub pp 15364–15371 DOI: 10.1021/ja074070i Supporting Info

A Convergent Synthesis of Polysubstituted Aromatic Nitriles via Palladium-Catalyzed C−H Functionalization Brian Mariampillai, Julien Alliot, Mengzhou Li, and Mark Lautens pp 15372–15379 DOI: 10.1021/ja075599i Supporting Info

Unraveling the Role of Stereo-electronic, Dynamical, and Environmental Effects in Tuning the Structure and Magnetic Properties of Glycine Radical in Aqueous Solution at Different pH Values Giuseppe Brancato, Nadia Rega, and Vincenzo Barone pp 15380–15390 DOI: 10.1021/ja074910t Supporting Info

A Unique Class of Duocarmycin and CC-1065 Analogues Subject to Reductive Activation Wei Jin, John D. Trzupek, Thomas J. Rayl, Melinda A. Broward, George A. Vielhauer, Scott J. Weir, Inkyu Hwang, and Dale L. Boger pp 15391–15397 DOI: 10.1021/ja075398e Supporting Info

Asymmetric Allylboration of Acyl Imines Catalyzed by Chiral Diols Sha Lou, Philip N. Moquist, and Scott E. Schaus pp 15398–15404 DOI: 10.1021/ja075204v Supporting Info

Intramolecular Carbozincation of Unactivated Alkenes Occurs through a Zinc Radical Transfer Mechanism Theodore Cohen, Heather Gibney, Roman Ivanov, Edmund A.-H. Yeh, Ilan Marek, and Dennis P. Curran pp 15405–15409 DOI: 10.1021/ja076554k Supporting Info

New Frontiers in Asymmetric Catalysis Edited by Koichi Mikami (Tokyo Institute of Technology) and Mark Lautens (University of Toronto). J. Wiley and Sons, Inc.:  Hoboken, NJ. 2007. xvi + 418 pp. $100. ISBN 978-0-471-68026-0. Brian T. Connell p 15410 DOI: 10.1021/ja076967l

Issue 50

(R)-β,γ-Fluoromethylene-dGTP-DNA Ternary Complex with DNA Polymerase β Charles E. McKenna, Boris A. Kashemirov, Thomas G. Upton, Vinod K. Batra, Myron F. Goodman, Lars C. Pedersen, William A. Beard, and Samuel H. Wilson pp 15412–15413 DOI: 10.1021/ja072127v Supporting Info

Molecular Simulation of Silica/Surfactant Self-Assembly in the Synthesis of Periodic Mesoporous Silicas Miguel Jorge, José R. B. Gomes, M. Natália D. S. Cordeiro, and Nigel A. Seaton pp 15414–15415 DOI: 10.1021/ja075070l Supporting Info

Direct Probing Molecular Twist and Tilt in Aromatic Self-Assembled Monolayers Nirmalya Ballav, Björn Schüpbach, Ole Dethloff, Peter Feulner, Andreas Terfort, and Michael Zharnikov pp 15416–15417 DOI: 10.1021/ja0751882 Supporting Info

The Modular Synthesis of Functional Porous Coordination Networks Masaki Kawano, Takehide Kawamichi, Tsuyoshi Haneda, Takahiro Kojima, and Makoto Fujita pp 15418–15419 DOI: 10.1021/ja0752540 Supporting Info

Stereocontrolled and Convergent Entry to CF2-Sialosides:  Synthesis of CF2-Linked Ganglioside GM4 Go Hirai, Toru Watanabe, Kazunori Yamaguchi, Taeko Miyagi, and Mikiko Sodeoka pp 15420–15421 DOI: 10.1021/ja075738w Supporting Info

Biosynthetic Studies of Platensimycin Kithsiri B. Herath, Athula B. Attygalle, and Sheo B. Singh pp 15422–15423 DOI: 10.1021/ja0758943 Supporting Info

Amplification of 4‘-ThioDNA in the Presence of 4‘-Thio-dTTP and 4‘-Thio-dCTP, and 4‘-ThioDNA-Directed Transcription in Vitro and in Mammalian Cells Naonori Inoue, Aki Shionoya, Noriaki Minakawa, Akiko Kawakami, Naoki Ogawa, and Akira Matsuda pp 15424–15425 DOI: 10.1021/ja075953c Supporting Info

Efficient Quenching of Oligomeric Fluorophores on a DNA Backbone James N. Wilson, Yin Nah Teo, and Eric T. Kool pp 15426–15427 DOI: 10.1021/ja075968a Supporting Info

A New Labeling Method for Methyl Transverse Relaxation-Optimized Spectroscopy NMR Spectra of Alanine Residues Rivka L. Isaacson, Peter J. Simpson, Minhao Liu, Ernesto Cota, Xiaodong Zhang, Paul Freemont, and Stephen Matthews pp 15428–15429 DOI: 10.1021/ja0761784 Supporting Info

Metal-Dependent Reactivity Differences for Transients Formed By Flash Photolysis of (PNP)M(CO), M = Co and Rh R. Dale Rimmer, David C. Grills, Hongjun Fan, Peter C. Ford, and Kenneth G. Caulton pp 15430–15431 DOI: 10.1021/ja076357l Supporting Info

Colloidal InP Nanocrystals as Efficient Emitters Covering Blue to Near-Infrared Renguo Xie, David Battaglia, and Xiaogang Peng pp 15432–15433 DOI: 10.1021/ja076363h Supporting Info

Meta Halogenation of 1,3-Disubstituted Arenes via Iridium-Catalyzed Arene Borylation Jaclyn M. Murphy, Xuebin Liao, and John F. Hartwig pp 15434–15435 DOI: 10.1021/ja076498n Supporting Info

Thiophene-Derivatized Pybox and Its Highly Luminescent Lanthanide Ion Complexes Ana de Bettencourt-Dias, Subha Viswanathan, and Alexandra Rollett pp 15436–15437 DOI: 10.1021/ja076485+ Supporting Info

Organocatalytic Vinyl and Friedel−Crafts Alkylations with Trifluoroborate Salts Sandra Lee and David W. C. MacMillan pp 15438–15439 DOI: 10.1021/ja0767480 Supporting Info

The Prion Protein is a Combined Zinc and Copper Binding Protein:  Zn2+ Alters the Distribution of Cu2+ Coordination Modes Eric D. Walter, Daniel J. Stevens, Micah P. Visconte, and Glenn L. Millhauser pp 15440–15441 DOI: 10.1021/ja077146j Supporting Info

Spin-Density Distribution of the Carotenoid Triplet State in the Peridinin-Chlorophyll-Protein Antenna. A Q-Band Pulse Electron-Nuclear Double Resonance and Density Functional Theory Study Jens Niklas, Tim Schulte, Shipra Prakash, Maurice van Gastel, Eckhard Hofmann, and Wolfgang Lubitz pp 15442–15443 DOI: 10.1021/ja077225v Supporting Info

Synthesis of Single-Crystalline Niobate Nanorods via Ion-Exchange Based on Molten-Salt Reaction Cheng-Yan Xu, Liang Zhen, Rusen Yang, and Zhong Lin Wang pp 15444–15445 DOI: 10.1021/ja077251t Supporting Info

Sub-10 nm Thick Microporous Membranes Made by Plasma-Defined Atomic Layer Deposition of a Bridged Silsesquioxane Precursor Ying-Bing Jiang, George Xomeritakis, Zhu Chen, Darren Dunphy, David J. Kissel, Joseph L. Cecchi, and C. Jeffrey Brinker pp 15446–15447 DOI: 10.1021/ja0773756 Supporting Info

Electrochemical Aptasensor Based on Proximity-Dependent Surface Hybridization Assay for Single-Step, Reusable, Sensitive Protein Detection Yan-Li Zhang, Yong Huang, Jian-Hui Jiang, Guo-Li Shen, and Ru-Qin Yu pp 15448–15449 DOI: 10.1021/ja0773047 Supporting Info

Copolymerization of Ethylene and Vinyl Fluoride by (Phosphine-Sulfonate)Pd(Me)(py) Catalysts Wei Weng, Zhongliang Shen, and Richard F. Jordan pp 15450–15451 DOI: 10.1021/ja0774717 Supporting Info

Facile Synthesis of Tadpole-like Nanostructures Consisting of Au Heads and Pd Tails Pedro H. C. Camargo, Yujie Xiong, Li Ji, Jian M. Zuo, and Younan Xia pp 15452–15453 DOI: 10.1021/ja077505a Supporting Info

Fluorous Metal−Organic Frameworks for High-Density Gas Adsorption Chi Yang, Xiaoping Wang, and Mohammad A. Omary pp 15454–15455 DOI: 10.1021/ja0775265 Supporting Info

Microcontact Printing Using the Spontaneous Reduction of Aryldiazonium Salts David J. Garrett, Joshua Lehr, Gordon M. Miskelly, and Alison J. Downard pp 15456–15457 DOI: 10.1021/ja0775321 Supporting Info

Dynamic Disorder and Stepwise Deactivation in a Chymotrypsin Catalyzed Hydrolysis Reaction Gert De Cremer, Maarten B. J. Roeffaers, Mukulesh Baruah, Michel Sliwa, Bert F. Sels, Johan Hofkens, and Dirk E. De Vos pp 15458–15459 DOI: 10.1021/ja077621d Supporting Info

An Efficient Synthetic Approach to Cyanocycline A and Bioxalomycin β2 via [C+NC+CC] Coupling H. Ümit Kaniskan and Philip Garner pp 15460–15461 DOI: 10.1021/ja077853c Supporting Info

Proton-Coupled Electron Transfer of Tyrosine Oxidation:  Buffer Dependence and Parallel Mechanisms Tania Irebo, Steven Y. Reece, Martin Sjödin, Daniel G. Nocera, and Leif Hammarström pp 15462–15464 DOI: 10.1021/ja073012u Supporting Info

Collapse in Crystalline Structure and Decline in Catalytic Activity of Pt Nanoparticles on Reducing Particle Size to 1 nm Yubao Sun, Lin Zhuang, Juntao Lu, Xinlin Hong, and Peifang Liu pp 15465–15467 DOI: 10.1021/ja076177b Supporting Info

Enantiopure, Octadentate Ligands as Sensitizers for Europium and Terbium Circularly Polarized Luminescence in Aqueous Solution Michael Seitz, Evan G. Moore, Andrew J. Ingram, Gilles Muller, and Kenneth N. Raymond pp 15468–15470 DOI: 10.1021/ja076005e Supporting Info

Peptide α/310-Helix Dimorphism in the Crystal State Marco Crisma, Michele Saviano, Alessandro Moretto, Quirinus B. Broxterman, Bernard Kaptein, and Claudio Toniolo pp 15471–15473 DOI: 10.1021/ja076656a Supporting Info

Mimicry of Antimicrobial Host-Defense Peptides by Random Copolymers Brendan P. Mowery, Sarah E. Lee, Denis A. Kissounko, Raquel F. Epand, Richard M. Epand, Bernard Weisblum, Shannon S. Stahl, and Samuel H. Gellman pp 15474–15476 DOI: 10.1021/ja077288d Supporting Info

Nano-Flares:  Probes for Transfection and mRNA Detection in Living Cells Dwight S. Seferos, David A. Giljohann, Haley D. Hill, Andrew E. Prigodich, and Chad A. Mirkin pp 15477–15479 DOI: 10.1021/ja0776529 Supporting Info

Structure-Guided Design of AMP Mimics That Inhibit Fructose-1,6-bisphosphatase with High Affinity and Specificity Mark D. Erion, Qun Dang, M. Rami Reddy, Srinivas Rao Kasibhatla, Jingwei Huang, William N. Lipscomb, and Paul D. van Poelje pp 15480–15490 DOI: 10.1021/ja074869u Supporting Info

Discovery of Potent and Specific Fructose-1,6-Bisphosphatase Inhibitors and a Series of Orally-Bioavailable Phosphoramidase-Sensitive Prodrugs for the Treatment of Type 2 Diabetes Qun Dang, Srinivas Rao Kasibhatla, K. Raja Reddy, Tao Jiang, M. Rami Reddy, Scott C. Potter, James M. Fujitaki, Paul D. van Poelje, Jingwei Huang, William N. Lipscomb, and Mark D. Erion pp 15491–15502 DOI: 10.1021/ja074871l Supporting Info

DFT Study of the Mechanisms of In Water Au(I)-Catalyzed Tandem [3,3]-Rearrangement/Nazarov Reaction/[1,2]-Hydrogen Shift of Enynyl Acetates:  A Proton-Transport Catalysis Strategy in the Water-Catalyzed [1,2]-Hydrogen Shift Fu-Qiang Shi, Xin Li, Yuanzhi Xia, Liming Zhang, and Zhi-Xiang Yu pp 15503–15512 DOI: 10.1021/ja071070+ Supporting Info

Mechanism of the Morita−Baylis−Hillman Reaction:  A Computational Investigation Raphaël Robiette, Varinder K Aggarwal, and Jeremy N. Harvey pp 15513–15525 DOI: 10.1021/ja0717865 Supporting Info

Folding of 8-17 Deoxyribozyme Studied by Three-Color Alternating-Laser Excitation of Single Molecules Nam Ki Lee, Hye Ran Koh, Kyu Young Han, and Seong Keun Kim pp 15526–15534 DOI: 10.1021/ja0725145 Supporting Info

Sharp Melting Transitions in DNA Hybrids without Aggregate Dissolution:  Proof of Neighboring-Duplex Cooperativity Julianne M. Gibbs-Davis, George C. Schatz, and SonBinh T. Nguyen pp 15535–15540 DOI: 10.1021/ja073034g Supporting Info

The Use of Combinatorial Chemical Vapor Deposition in the Synthesis of Ti3-δO4N with 0.06 < δ < 0.25:  A Titanium Oxynitride Phase Isostructural to Anosovite Geoffrey Hyett, Mark A. Green, and Ivan P. Parkin pp 15541–15548 DOI: 10.1021/ja073355s Supporting Info

An Efficient Unnatural Base Pair for PCR Amplification Ichiro Hirao, Tsuneo Mitsui, Michiko Kimoto, and Shigeyuki Yokoyama pp 15549–15555 DOI: 10.1021/ja073830m Supporting Info

Ultrafast Structural Dynamics in BLUF Domains:  Transient Infrared Spectroscopy of AppA and Its Mutants Allison L. Stelling, Kate L. Ronayne, Jérôme Nappa, Peter J. Tonge, and Stephen R. Meech pp 15556–15564 DOI: 10.1021/ja074074n

H2O Nucleation around Au+ J. Ulises Reveles, Patrizia Calaminici, Marcela R. Beltrán, Andres M. Köster, and Shiv N. Khanna pp 15565–15571 DOI: 10.1021/ja074336l Supporting Info

Steric Effects in Electron Transfer from Potassium to π-Bonded Oriented Molecules CH3CN, CH3NC, and CCl3CN Philip R. Brooks, Peter W. Harland, Sean A. Harris, Terry Kennair, Crystal Redden, and Jack F. Tate pp 15572–15580 DOI: 10.1021/ja074302d

Networking Particles over Distance Using Oligonucleotide-Based Devices Ruslan Yashin, Sergei Rudchenko, and Milan N. Stojanovic pp 15581–15584 DOI: 10.1021/ja074335t Supporting Info

The Role of Outer-Sphere Surface Acidity in Alkene Epoxidation Catalyzed by Calixarene−Ti(IV) Complexes Justin M. Notestein, Andrew Solovyov, Leandro R. Andrini, Felix G. Requejo, Alexander Katz, and Enrique Iglesia pp 15585–15595 DOI: 10.1021/ja074614g Supporting Info

Strand Invasion of Mixed-Sequence B-DNA by Acridine-Linked, γ-Peptide Nucleic Acid (γ-PNA) Srinivas Rapireddy, Gaofei He, Subhadeep Roy, Bruce A. Armitage, and Danith H. Ly pp 15596–15600 DOI: 10.1021/ja074886j Supporting Info

Both Water- and Organo-Soluble Supramolecular Polymer Stabilized by Hydrogen-Bonding and Hydrophobic Interactions Edouard Obert, Mathilde Bellot, Laurent Bouteiller, Florence Andrioletti, Catherine Lehen-Ferrenbach, and François Boué pp 15601–15605 DOI: 10.1021/ja074296l Supporting Info

Reversible Gas Uptake by a Nonporous Crystalline Solid Involving Multiple Changes in Covalent Bonding Guillermo Mínguez Espallargas, Michael Hippler, Alastair J. Florence, Philippe Fernandes, Jacco van de Streek, Michela Brunelli, William I. F. David, Kenneth Shankland, and Lee Brammer pp 15606–15614 DOI: 10.1021/ja075265t Supporting Info

Antimicrobial Activity and Protease Stability of Peptides Containing Fluorinated Amino Acids He Meng and Krishna Kumar pp 15615–15622 DOI: 10.1021/ja075373f Supporting Info

Electrostatically “Patchy” Coatings via Cooperative Adsorption of Charged Nanoparticles Stoyan K. Smoukov, Kyle J. M. Bishop, Bartlomiej Kowalczyk, Alexander M. Kalsin, and Bartosz A. Grzybowski pp 15623–15630 DOI: 10.1021/ja075456w

Stepwise Noncovalent Synthesis Leading to Dendrimer-Based Assemblies in Water Thomas M. Hermans, Maarten A. C Broeren, Nikos Gomopoulos, A. F. Smeijers, Brahim Mezari, Ellen N. M. Van Leeuwen, Matthijn R. J. Vos, Pieter C. M. M. Magusin, Peter A. J. Hilbers, Marcel H. P. Van Genderen, Nico A. J. M. Sommerdijk, George Fytas, and E.W. Meijer pp 15631–15638 DOI: 10.1021/ja074991t Supporting Info

Cavitands with Introverted Functionality Stabilize Tetrahedral Intermediates Richard J. Hooley, Per Restorp, Tetsuo Iwasawa, and Julius Rebek, Jr. pp 15639–15643 DOI: 10.1021/ja0756366 Supporting Info

C60−PMO: Periodic Mesoporous Buckyballsilica Wesley Whitnall, Ludovico Cademartiri, and Geoffrey A. Ozin pp 15644–15649 DOI: 10.1021/ja075729n Supporting Info

Metallic and Carbon Nanotube-Catalyzed Coupling of Hydrogenation in Magnesium Xiangdong Yao, Chengzhang Wu, Aijun Du, Jin Zou, Zhonghua Zhu, Ping Wang, Huiming Cheng, Sean Smith, and Gaoqing Lu pp 15650–15654 DOI: 10.1021/ja0751431 Supporting Info

Structured Polymer Grafts on Diamond Marin Steenackers, Simon Q. Lud, Martin Niedermeier, Paola Bruno, Dieter M. Gruen, Peter Feulner, Martin Stutzmann, Jose A. Garrido, and Rainer Jordan pp 15655–15661 DOI: 10.1021/ja075378c

Toward Mechanical Switching of Surface-Adsorbed [2]Catenane by in Situ Copper Complexation Dietmar Payer, Stephan Rauschenbach, Nicola Malinowski, Mitsuharu Konuma, Chariya Virojanadara, Ulrich Starke, Christiane Dietrich-Buchecker, Jean-Paul Collin, Jean-Pierre Sauvage, Nian Lin, and Klaus Kern pp 15662–15667 DOI: 10.1021/ja075886m Supporting Info

A Computational Investigation of Allostery in the Catabolite Activator Protein Liwei Li, Vladimir N. Uversky, A. Keith Dunker, and Samy O. Meroueh pp 15668–15676 DOI: 10.1021/ja076046a Supporting Info

The Skeletal Rearrangement of Gold- and Platinum-Catalyzed Cycloisomerization of cis-4,6-Dien-1-yn-3-ols:  Pinacol Rearrangement and Formation of Bicyclo[4.1.0]heptenone and Reorganized Styrene Derivatives Jhih-Meng Tang, Sabyasachi Bhunia, Shariar Md. Abu Sohel, Ming-Yuan Lin, Hsin-Yi Liao, Swarup Datta, Arindam Das, and Rai-Shung Liu pp 15677–15683 DOI: 10.1021/ja076175r Supporting Info

Using Ferroelectric Poling to Change Adsorption on Oxide Surfaces Yang Yun and Eric I. Altman pp 15684–15689 DOI: 10.1021/ja0762644

Human Tryptophan Dioxygenase:  A Comparison to Indoleamine 2,3-Dioxygenase Dipanwita Batabyal and Syun-Ru Yeh pp 15690–15701 DOI: 10.1021/ja076186k Supporting Info

Binary Nanoparticle Superlattices in the Semiconductor−Semiconductor System:  CdTe and CdSe Zhuoying Chen, Jenny Moore, Guillaume Radtke, Henning Sirringhaus, and Stephen O'Brien pp 15702–15709 DOI: 10.1021/ja076698z Supporting Info

Manganese(III)-Catalyzed Free Radical Reactions on Trimetallic Nitride Endohedral Metallofullerenes Chunying Shu, Ting Cai, Liaosa Xu, Tianming Zuo, Jonathan Reid, Kim Harich, Harry C. Dorn, and Harry W. Gibson pp 15710–15717 DOI: 10.1021/ja0768439 Supporting Info

Magnetic Field Effect Studies Indicate Reduced Geminate Recombination of the Radical Pair in Substrate-Bound Adenosylcobalamin-Dependent Ethanolamine Ammonia Lyase Alex R. Jones, Sam Hay, Jonathan R. Woodward, and Nigel S. Scrutton pp 15718–15727 DOI: 10.1021/ja077124x Supporting Info

Multi-Emissive Difluoroboron Dibenzoylmethane Polylactide Exhibiting Intense Fluorescence and Oxygen-Sensitive Room-Temperature Phosphorescence [J. Am. Chem. Soc. 2007, 129, 8942−8943]. Guoqing Zhang, Jianbin Chen, Sarah J. Payne, Steven E. Kooi, J. N. Demas, and Cassandra L. Fraser p 15728 DOI: 10.1021/ja079953o

Issue 51

Sphingomyelin/Phosphatidylcholine and Cholesterol Interactions Studied by Imaging Mass Spectrometry Leiliang Zheng, Carolyn M. McQuaw, Andrew G. Ewing, and Nicholas Winograd pp 15730–15731 DOI: 10.1021/ja0741675 Supporting Info

Highly Soluble [1]Benzothieno[3,2-b]benzothiophene (BTBT) Derivatives for High-Performance, Solution-Processed Organic Field-Effect Transistors Hideaki Ebata, Takafumi Izawa, Eigo Miyazaki, Kazuo Takimiya, Masaaki Ikeda, Hirokazu Kuwabara, and Tatsuto Yui pp 15732–15733 DOI: 10.1021/ja074841i Supporting Info

A New Paradigm for Carbon−Carbon Bond Formation:  Aerobic, Copper-Templated Cross-Coupling Janette M. Villalobos, Jiri Srogl, and Lanny S. Liebeskind pp 15734–15735 DOI: 10.1021/ja074931n Supporting Info

A Single Residue Switch Converts Abietadiene Synthase into a Pimaradiene Specific Cyclase P. Ross Wilderman and Reuben J. Peters pp 15736–15737 DOI: 10.1021/ja074977g Supporting Info

Single Crystal-to-Single Crystal Transformation from Ferromagnetic Discrete Molecules to a Spin-Canting Antiferromagnetic Layer Xiao-Ning Cheng, Wei-Xiong Zhang, and Xiao-Ming Chen pp 15738–15739 DOI: 10.1021/ja074962i Supporting Info

Porous Crystal Derived from a Tricarboxylate Linker with Two Distinct Binding Motifs Antek G. Wong-Foy, Olivier Lebel, and Adam J. Matzger pp 15740–15741 DOI: 10.1021/ja0753952 Supporting Info

Ordering of Dipeptide Chains on Cu Surfaces through 2D Cocrystallization Yeliang Wang, Magalí Lingenfelder, Thomas Classen, Giovanni Costantini, and Klaus Kern pp 15742–15743 DOI: 10.1021/ja075118v Supporting Info

The Mechanism of MIO-Based Aminomutases in β-Amino Acid Biosynthesis Carl V. Christianson, Timothy J. Montavon, Grace M. Festin, Heather A. Cooke, Ben Shen, and Steven D. Bruner pp 15744–15745 DOI: 10.1021/ja0762689 Supporting Info

S,C-Sulfonium Ylides from Thiophenes:  Potential Carbene Precursors Stacey A. Stoffregen, Melanie Heying, and William S. Jenks pp 15746–15747 DOI: 10.1021/ja076351w Supporting Info

PELDOR Spectroscopy with DOPA-β2 and NH2Y-α2s:  Distance Measurements between Residues Involved in the Radical Propagation Pathway of E. coli Ribonucleotide Reductase Mohammad R. Seyedsayamdost, Clement T. Y. Chan, Veronica Mugnaini, JoAnne Stubbe, and Marina Bennati pp 15748–15749 DOI: 10.1021/ja076459b

Observation of an Acryloyl−Thiamin Diphosphate Adduct in the First Step of Clavulanic Acid Biosynthesis Matthew Merski and Craig A. Townsend pp 15750–15751 DOI: 10.1021/ja076704r Supporting Info

Isolation of 6,13-Dipropylpentacene and Its Tautomerization Tamotsu Takahashi, Ken Kashima, Shi Li, Kiyohiko Nakajima, and Ken-ichiro Kanno pp 15752–15753 DOI: 10.1021/ja076819v Supporting Info

Unbiased Selectivity Coefficients Obtained for the Pulsed Chronopotentiometric Polymeric Membrane Ion Sensors Hasini Perera and Alexey Shvarev pp 15754–15755 DOI: 10.1021/ja076821m Supporting Info

Reactive Sulfur Species:  Hydrolysis of Hypothiocyanite To Give Thiocarbamate-S-oxide Péter Nagy, Xiaoguang Wang, Kelemu Lemma, and Michael T. Ashby pp 15756–15757 DOI: 10.1021/ja0770532 Supporting Info

Zipper Assembly of Photoactive Rigid-Rod Naphthalenediimide π-Stack Architectures on Gold Nanoparticles and Gold Electrodes Naomi Sakai, Adam L. Sisson, Thomas Bürgi, and Stefan Matile pp 15758–15759 DOI: 10.1021/ja077099v Supporting Info

DNA−TiO2 Nanoconjugates Labeled with Magnetic Resonance Contrast Agents Paul J. Endres, Tatjana Paunesku, Stefan Vogt, Thomas J. Meade, and Gayle E. Woloschak pp 15760–15761 DOI: 10.1021/ja0772389 Supporting Info

The Lyngbyatoxin Biosynthetic Assembly Line:  Chain Release by Four-Electron Reduction of a Dipeptidyl Thioester to the Corresponding Alcohol Jay A. Read and Christopher T. Walsh pp 15762–15763 DOI: 10.1021/ja077374d Supporting Info

Kinetically Favored Platination of Adenine in the G-Rich Human Telomeric Repeat Lu Rao and Ulrich Bierbach pp 15764–15765 DOI: 10.1021/ja077390a Supporting Info

Alkane Hydroxylation by a Nonheme Iron Catalyst that Challenges the Heme Paradigm for Oxygenase Action Anna Company, Laura Gómez, Mireia Güell, Xavi Ribas, Josep M. Luis, Lawrence Que, Jr., and Miquel Costas pp 15766–15767 DOI: 10.1021/ja077761n Supporting Info

Contact Chemistry and Single-Molecule Conductance:  A Comparison of Phosphines, Methyl Sulfides, and Amines Young S. Park, Adam C. Whalley, Maria Kamenetska, Michael L. Steigerwald, Mark S. Hybertsen, Colin Nuckolls, and Latha Venkataraman pp 15768–15769 DOI: 10.1021/ja0773857 Supporting Info

Selective Synthesis Combined with Chemical Separation of Single-Walled Carbon Nanotubes for Chirality Selection Xiaolin Li, Xiaomin Tu, Sasa Zaric, Kevin Welsher, Won Seok Seo, Wei Zhao, and Hongjie Dai pp 15770–15771 DOI: 10.1021/ja077886s Supporting Info

Oxide-Driven Carbon Nanotube Growth in Supported Catalyst CVD Mark H. Rümmeli, Franziska Schäffel, Christian Kramberger, Thomas Gemming, Alicja Bachmatiuk, Ryszard J. Kalenczuk, Bernd Rellinghaus, Bernd Büchner, and Thomas Pichler pp 15772–15773 DOI: 10.1021/ja0779405

An Electronic Rationale for Observed Initiation Rates in Ruthenium-Mediated Olefin Metathesis:  Charge Donation in Phosphine and N-Heterocyclic Carbene Ligands Kendra Getty, Mario Ulises Delgado-Jaime, and Pierre Kennepohl pp 15774–15776 DOI: 10.1021/ja0747674 Supporting Info

Non-enzymatic Covalent Protein Labeling Using a Reactive Tag Hiroshi Nonaka, Shinya Tsukiji, Akio Ojida, and Itaru Hamachi pp 15777–15779 DOI: 10.1021/ja074176d Supporting Info

Enrichment Tags for Enhanced-Resolution Profiling of the Polar Metabolome Erin E. Carlson and Benjamin F. Cravatt pp 15780–15782 DOI: 10.1021/ja0779506 Supporting Info

Mössbauer Studies of the Membrane-Associated Methane Monooxygenase from Methylococcus capsulatus Bath:  Evidence for a Diiron Center Marlène Martinho, Dong W. Choi, Alan A. DiSpirito, William E. Antholine, Jeremy D. Semrau, and Eckard Münck pp 15783–15785 DOI: 10.1021/ja077682b Supporting Info

Secondary Nucleation and Growth of ZnO Thomas L. Sounart, Jun Liu, James A. Voigt, Mae Huo, Erik D. Spoerke, and Bonnie McKenzie pp 15786–15793 DOI: 10.1021/ja071209g Supporting Info

Methylrhenium Trioxide Revisited:  Mechanisms for Nonredox Oxygen Insertion in an M−CH3 Bond Jason M. Gonzales, Robert DistasioJr., Roy A. Periana, William A. Goddard III, and Jonas Oxgaard pp 15794–15804 DOI: 10.1021/ja0714742 Supporting Info

Residue-Specific pKa Determination of Lysine and Arginine Side Chains by Indirect 15N and 13C NMR Spectroscopy:  Application to apo Calmodulin Ingemar André, Sara Linse, and Frans A. A. Mulder pp 15805–15813 DOI: 10.1021/ja0721824 Supporting Info

13C-Detection in RNA Bases:  Revealing Structure−Chemical Shift Relationships Christophe Farès, Irene Amata, and Teresa Carlomagno pp 15814–15823 DOI: 10.1021/ja0727417 Supporting Info

Immunomagnetic Diffractometry for Detection of Diagnostic Serum Markers Ghanashyam Acharya, Chun-Li Chang, Derek D. Doorneweerd, Erina Vlashi, Walter A. Henne, Lynn C Hartmann, Philip S. Low, and Cagri A. Savran pp 15824–15829 DOI: 10.1021/ja073094m Supporting Info

Structural and Initial Biological Analysis of Synthetic Arylomycin A2 Tucker C. Roberts, Peter A. Smith, Ryan T. Cirz, and Floyd E. Romesberg pp 15830–15838 DOI: 10.1021/ja073340u Supporting Info

Hollowing Sn-Doped TiO2 Nanospheres via Ostwald Ripening Jing Li and Hua Chun Zeng pp 15839–15847 DOI: 10.1021/ja073521w Supporting Info

Biomimetic Aminoacylation of Ribonucleotides and RNA with Aminoacyl Phosphate Esters and Lanthanum Salts Svetlana Tzvetkova and Ronald Kluger pp 15848–15854 DOI: 10.1021/ja073976l

Silylene Extrusion from Organosilanes via Double Geminal Si−H Bond Activation by a Cp*Ru(κ2-P,N)+ Complex:  Observation of a Key Stoichiometric Step in the Glaser−Tilley Alkene Hydrosilylation Mechanism Matthew A. Rankin, Darren F. MacLean, Gabriele Schatte, Robert McDonald, and Mark Stradiotto pp 15855–15864 DOI: 10.1021/ja0768800 Supporting Info

Supramolecular Carbon Nanotube-Fullerene Donor−Acceptor Hybrids for Photoinduced Electron Transfer Francis D'Souza, Raghu Chitta, Atula S. D. Sandanayaka, Navaneetha K. Subbaiyan, Lawrence D'Souza, Yasuyuki Araki, and Osamu Ito pp 15865–15871 DOI: 10.1021/ja073773x Supporting Info

Cooperative Catalysis by Tertiary Amino-Thioureas:  Mechanism and Basis for Enantioselectivity of Ketone Cyanosilylation Stephan J. Zuend and Eric N. Jacobsen pp 15872–15883 DOI: 10.1021/ja0735352 Supporting Info

Watching Electrons Move in Real Time:  Ultrafast Infrared Spectroscopy of a Polymer Blend Photovoltaic Material Larry W. Barbour, Maureen Hegadorn, and John B. Asbury pp 15884–15894 DOI: 10.1021/ja074657x

The Reversal by Sulfate of the Denaturant Activity of Guanidinium Christopher E. Dempsey, Philip E. Mason, John W. Brady, and George W. Neilson pp 15895–15902 DOI: 10.1021/ja074719j

Scanning Kelvin Probe Imaging of the Potential Profiles in Fixed and Dynamic Planar LECs Liam S. C. Pingree, Deanna B. Rodovsky, David C. Coffey, Glenn P. Bartholomew, and David S. Ginger pp 15903–15910 DOI: 10.1021/ja074760m Supporting Info

Chemosensory Performance of Molecularly Imprinted Fluorescent Conjugated Polymer Materials Jiahui Li, Claire E. Kendig, and Evgueni E. Nesterov pp 15911–15918 DOI: 10.1021/ja0748027 Supporting Info

The β Effect of Silicon in Phenyl Cations Valentina Dichiarante, Andrea Salvaneschi, Stefano Protti, Daniele Dondi, Maurizio Fagnoni, and Angelo Albini pp 15919–15926 DOI: 10.1021/ja074778x Supporting Info

Single-Label Kinase and Phosphatase Assays for Tyrosine Phosphorylation Using Nanosecond Time-Resolved Fluorescence Detection Harekrushna Sahoo, Andreas Hennig, Mara Florea, Doris Roth, Thilo Enderle, and Werner M. Nau pp 15927–15934 DOI: 10.1021/ja074975w

Structure of the Charge Separated State in the Photosynthetic Reaction Centers of Rhodobacter sphaeroides by Quantum Beat Oscillations and High-Field Electron Paramagnetic Resonance:  Evidence for Light-Induced Reorientation Ulrich Heinen, Lisa M. Utschig, Oleg G. Poluektov, Gerhard Link, Ernst Ohmes, and Gerd Kothe pp 15935–15946 DOI: 10.1021/ja075065h

Improved Optical Enrichment of SWNTs through Extraction with Chiral Nanotweezers of 2,6-Pyridylene-Bridged Diporphyrins Xiaobin Peng, Naoki Komatsu, Takahide Kimura, and Atsuhiro Osuka pp 15947–15953 DOI: 10.1021/ja075094s Supporting Info

Two [Fe(IV)O Trp•] Intermediates in M. tuberculosis Catalase-Peroxidase Discriminated by Multifrequency (9−285 GHz) EPR Spectroscopy:  Reactivity toward Isoniazid Rahul Singh, Jack Switala, Peter C. Loewen, and Anabella Ivancich pp 15954–15963 DOI: 10.1021/ja075108u Supporting Info

Iron-Catalyzed Olefin Epoxidation in the Presence of Acetic Acid:  Insights into the Nature of the Metal-Based Oxidant Rubén Mas-Ballesté and Lawrence Que Jr. pp 15964–15972 DOI: 10.1021/ja075115i Supporting Info

Azobenzene-Linked Porphyrin−Fullerene Dyads David I. Schuster, Ke Li, Dirk M. Guldi, Amit Palkar, Luis Echegoyen, Christopher Stanisky, R. James Cross, Marja Niemi, Nikolai V. Tkachenko, and Helge Lemmetyinen pp 15973–15982 DOI: 10.1021/ja074684n Supporting Info

Spectroscopic and Quantum Chemical Studies on Low-Spin FeIVO Complexes:  Fe−O Bonding and Its Contributions to Reactivity Andrea Decker, Jan-Uwe Rohde, Eric J. Klinker, Shaun D. Wong, Lawrence Que, Jr., and Edward I. Solomon pp 15983–15996 DOI: 10.1021/ja074900s Supporting Info

Characterization of Pore Structure in Metal−Organic Framework by Small-Angle X-ray Scattering Cheng-Si Tsao, Ming-Sheng Yu, Tsui-Yun Chung, Hsiu-Chu Wu, Cheng-Yu Wang, Kuei-Sen Chang, and Hsin-Lung Chen pp 15997–16004 DOI: 10.1021/ja0752336

Thermodynamics and Kinetics of Aggregation for the GNNQQNY Peptide Birgit Strodel, Chris S. Whittleston, and David J. Wales pp 16005–16014 DOI: 10.1021/ja075346p Supporting Info

A Noncovalent Switch for Lysozyme Kirstin Wenck, Sebastian Koch, Christian Renner, Wei Sun, and Thomas Schrader pp 16015–16019 DOI: 10.1021/ja075507p Supporting Info

Anthryl-Doped Conjugated Polyelectrolytes as Aggregation-Based Sensors for Nonquenching Multicationic Analytes Andrew Satrijo and Timothy M. Swager pp 16020–16028 DOI: 10.1021/ja075573r

Stable Aqueous Dispersion of ZnO Quantum Dots with Strong Blue Emission via Simple Solution Route Ying-Song Fu, Xi-Wen Du, Sergei A. Kulinich, Jian-Sheng Qiu, Wen-Jing Qin, Rui Li, Jing Sun, and Jim Liu pp 16029–16033 DOI: 10.1021/ja075604i Supporting Info

Rapid Vapor-Phase Fabrication of Organic−Inorganic Hybrid Superlattices with Monolayer Precision Byoung H. Lee, Min Ki Ryu, Sung-Yool Choi, Kwang-H. Lee, Seongil Im, and Myung M. Sung pp 16034–16041 DOI: 10.1021/ja075664o

Direct Detection of Membrane Channels from Gels Using Water-in-Oil Droplet Bilayers Andrew J. Heron, James R. Thompson, Amy E. Mason, and Mark I. Wallace pp 16042–16047 DOI: 10.1021/ja075715h Supporting Info

Structural and Thermodynamic Studies of the Interaction of Distamycin A with the Parallel Quadruplex Structure [d(TGGGGT)]4 Luigi Martino, Ada Virno, Bruno Pagano, Antonella Virgilio, Simone Di Micco, Aldo Galeone, Concetta Giancola, Giuseppe Bifulco, Luciano Mayol, and Antonio Randazzo pp 16048–16056 DOI: 10.1021/ja075710k Supporting Info

Implementation of a Hamiliton-Receptor-Based Hydrogen-Bonding Motif toward a New Electron Donor−Acceptor Prototype:  Electron versus Energy Transfer Florian Wessendorf, Jan-Frederik Gnichwitz, Ginka H. Sarova, Kristine Hager, Uwe Hartnagel, Dirk M. Guldi, and Andreas Hirsch pp 16057–16071 DOI: 10.1021/ja075751g Supporting Info

Dynamics of Large Elongated RNA by NMR Carbon Relaxation Alexandar L. Hansen and Hashim M. Al-Hashimi pp 16072–16082 DOI: 10.1021/ja0757982 Supporting Info

Factors Controlling Adsorption Equilibria from Solution onto Solid Surfaces:  The Uptake of Cinchona Alkaloids on Platinum Surfaces Zhen Ma, Ilkeun Lee, and Francisco Zaera pp 16083–16090 DOI: 10.1021/ja076011a Supporting Info

Characterization of the Covalently Bound Anionic Flavin Radical in Monoamine Oxidase A by Electron Paramagnetic Resonance Christopher W. M. Kay, Hassane El Mkami, Gianluca Molla, Loredano Pollegioni, and Rona R. Ramsay pp 16091–16097 DOI: 10.1021/ja076090q

Spin Accommodation and Reactivity of Aluminum Based Clusters with O2 Arthur C. Reber, Shiv N. Khanna, Patrick J. Roach, William H. Woodward, and A. Welford Castleman, Jr. pp 16098–16101 DOI: 10.1021/ja075998d

Common and Divergent Structural Features of a Series of Corticotropin Releasing Factor-Related Peptides Christy Rani R. Grace, Marilyn H. Perrin, Jeffrey P. Cantle, Wylie W. Vale, Jean E. Rivier, and Roland Riek pp 16102–16114 DOI: 10.1021/ja0760933 Supporting Info

Calculations of the Effect of Tunneling on the Swain−Schaad Exponents (SSEs) for the 1,5-Hydrogen Shift in 5-Methyl-1,3-cyclopentadiene. Can SSEs Be Used to Diagnose the Occurrence of Tunneling? G. Robert Shelton, David A. Hrovat, and Weston Thatcher Borden pp 16115–16118 DOI: 10.1021/ja076132a Supporting Info

Catalytic Asymmetric Generation of (Z)-Disubstituted Allylic Alcohols Luca Salvi, Sang-Jin Jeon, Ethan L. Fisher, Patrick J. Carroll, and Patrick J. Walsh pp 16119–16125 DOI: 10.1021/ja0762285 Supporting Info

Interaction of Urea with Amino Acids:  Implications for Urea-Induced Protein Denaturation Martin C. Stumpe and Helmut Grubmüller pp 16126–16131 DOI: 10.1021/ja076216j Supporting Info

Subdiffraction Imaging through the Selective Donut-Mode Depletion of Thermally Stable Photoswitchable Fluorophores:  Numerical Analysis and Application to the Fluorescent Protein Dronpa Peter Dedecker, Jun-ichi Hotta, Cristina Flors, Michel Sliwa, Hiroshi Uji-i, Maarten B. J. Roeffaers, Ryoko Ando, Hideaki Mizuno, Atsushi Miyawaki, and Johan Hofkens pp 16132–16141 DOI: 10.1021/ja076128z Supporting Info

Protein Nanopores with Covalently Attached Molecular Adapters Hai-Chen Wu, Yann Astier, Giovanni Maglia, Ellina Mikhailova, and Hagan Bayley pp 16142–16148 DOI: 10.1021/ja0761840 Supporting Info

Synthesis of [59]Fullerenones through Peroxide-Mediated Stepwise Cleavage of Fullerene Skeleton Bonds and X-ray Structures of Their Water-Encapsulated Open-Cage Complexes Zuo Xiao, Jiayao Yao, Dazhi Yang, Fudong Wang, Shaohua Huang, Liangbing Gan, Zhenshan Jia, Zhongping Jiang, Xiaobing Yang, Bo Zheng, Gu Yuan, Shiwei Zhang, and Zheming Wang pp 16149–16162 DOI: 10.1021/ja0763798 Supporting Info

Sterically Controlled Recognition of Macromolecular Sequence Information by Molecular Tweezers Howard M. Colquhoun, Zhixue Zhu, Christine J. Cardin, Yu Gan, and Michael G. B. Drew pp 16163–16174 DOI: 10.1021/ja0759996 Supporting Info

Routes to Covalent Catalysis by Reactive Selection for Nascent Protein Nucleophiles Andrey V. Reshetnyak, Maria Francesca Armentano, Natalia A. Ponomarenko, Domenica Vizzuso, Oxana M. Durova, Rustam Ziganshin, Marina Serebryakova, Vadim Govorun, Gennady Gololobov, Herbert C. Morse III, Alain Friboulet, Sudesh P. Makker, Alexander G. Gabibov, and Alfonso Tramontano pp 16175–16182 DOI: 10.1021/ja076528m Supporting Info

Root-Growth Mechanism for Single-Walled Boron Nitride Nanotubes in Laser Vaporization Technique Raul Arenal, Odile Stephan, Jean-Lou Cochon, and Annick Loiseau pp 16183–16189 DOI: 10.1021/ja076135n

Star-Shaped Oligo(p-phenylenevinylene) Substituted Hexaarylbenzene:  Purity, Stability, and Chiral Self-assembly† Željko Tomović, Joost van Dongen, Subi J. George, Hong Xu, Wojciech Pisula, Philippe Leclère, Maarten M. J. Smulders, Steven De Feyter, E. W. Meijer, and Albertus P. H. J. Schenning pp 16190–16196 DOI: 10.1021/ja0765417 Supporting Info

Isomeric Forms of Heavier Main Group Hydrides:  Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar = Terphenyl) System Eric Rivard, Roland C. Fischer, Robert Wolf, Yang Peng, W. Alexander Merrill, Nathan D. Schley, Zhongliang Zhu, Lihung Pu, James C. Fettinger, Simon J. Teat, Isreal Nowik, Rolfe H. Herber, Nozomi Takagi, Shigeru Nagase, and Philip P. Power pp 16197–16208 DOI: 10.1021/ja076453m Supporting Info

Electrospray Ionization Mass Spectrometry of Uniform and Mixed Monolayer Nanoparticles:  Au25[S(CH2)2Ph]18 and Au25[S(CH2)2Ph]18-x(SR)x Joseph B. Tracy, Matthew C. Crowe, Joseph F. Parker, Oliver Hampe, Christina A. Fields-Zinna, Amala Dass, and Royce W. Murray pp 16209–16215 DOI: 10.1021/ja076621a Supporting Info

Crucial Role of Fluorescence in the Solid-State Thermochromism of Salicylideneanilines Jun Harada, Toshikatsu Fujiwara, and Keiichiro Ogawa pp 16216–16221 DOI: 10.1021/ja076635g Supporting Info

Conformational Dynamics of Bistable RNAs Studied by Time-Resolved NMR Spectroscopy Boris Fürtig, Philipp Wenter, Luc Reymond, Christian Richter, Stefan Pitsch, and Harald Schwalbe pp 16222–16229 DOI: 10.1021/ja076739r Supporting Info

A Molecular Mechanism for the Chemoselective Hydrogenation of Substituted Nitroaromatics with Nanoparticles of Gold on TiO2 Catalysts:  A Cooperative Effect between Gold and the Support Mercè Boronat, Patricia Concepción, Avelino Corma, Silvia González, Francesc Illas, and Pedro Serna pp 16230–16237 DOI: 10.1021/ja076721g

The Dinuclear Zn(II) Complex Catalyzed Cyclization of a Series of 2-Hydroxypropyl Aryl Phosphate RNA Models:  Progressive Change in Mechanism from Rate-Limiting P−O Bond Cleavage to Substrate Binding Shannon E. Bunn, C. Tony Liu, Zhong-Lin Lu, Alexei A. Neverov, and R. Stan Brown pp 16238–16248 DOI: 10.1021/ja076847d Supporting Info

A Frequency Domain Existence Proof of Single-Molecule Surface-Enhanced Raman Spectroscopy Jon A. Dieringer, Robert B. Lettan II, Karl A. Scheidt, and Richard P. Van Duyne pp 16249–16256 DOI: 10.1021/ja077243c

Chemically Adjusting Plasma Temperature, Energy, and Reactivity (CAPTEAR) Method Using NOx and Combustion for Selective Synthesis of Sc3N@C80 Metallic Nitride Fullerenes Steven Stevenson, M. Corey Thompson, H. Louie Coumbe, Mary A. Mackey, Curtis E. Coumbe, and J. Paige Phillips pp 16257–16262 DOI: 10.1021/ja077305z

Selective Formation of Triplet Alkyl Nitrenes from Photolysis of β-Azido-Propiophenone and Their Reactivity Pradeep N. D. Singh, Sarah M. Mandel, Jagadis Sankaranarayanan, Sivaramakrishnan Muthukrishnan, Mingxin Chang, Rachel M. Robinson, Paul M. Lahti, Bruce S. Ault, and Anna D. Gudmundsdóttir pp 16263–16272 DOI: 10.1021/ja077523s Supporting Info

A Two-Directional Approach to a (−)-Dictyostatin C11−C23 Segment:  Development of a Highly Diastereoselective, Kinetically-Controlled Meerwein−Ponndorf−Verley Reduction Andrew K. Dilger, Vijay Gopalsamuthiram, and Steven D. Burke pp 16273–16277 DOI: 10.1021/ja077336u Supporting Info

Probing Excitation Delocalization in Supramolecular Chiral Stacks by Means of Circularly Polarized Light:  Experiment and Modeling [J. Am. Chem. Soc. 2007, 129, 7044−7054]. Frank C. Spano, Stefan C. J. Meskers, Emanuelle Hennebicq, David Beljonne p 16278 DOI: 10.1021/ja0780838

Synthesis of Monoalkoxide Monopyrrolyl Complexes Mo(NR)(CHR‘)(OR‘ ‘)(pyrrolyl):  Enyne Metathesis with High Oxidation State Catalysts [J. Am. Chem. Soc. 2007, 129, 12654−12655] Rojendra Singh, Richard R. Schrock, Peter Müller, and Amir H. Hoveyda p 16278 DOI: 10.1021/ja078211s

Advances in Electrochemical Science and Engineering, Volume 9:  Diffraction and Spectroscopic Methods in Electrochemistry Edited by Richard C. Alkire (University of Illinois, Urbana, USA), Dieter M. Kolb (University of Ulm, Germany), Jacek Lipkowski (University of Guelph, Canada), and Philip N. Ross (Lawrence Berkeley National Laboratory, Berkeley, CA, USA). Wiley-VCH Verlag GmbH & Co. KGaA:  Weinheim. 2006. xviii + 428 pp. $190.00. ISBN 3-527-31317-6. Sanjeev Mukerjee p 16279 DOI: 10.1021/ja069824s

Metal Ions in Life Sciences, Volume 3:  The Ubiquitous Roles of Cytochrome P450 Proteins Edited by Astrid Sigel, Helmut Sigel (University of Basel, Switzerland), and Roland K. O. Sigel (University of Zürich, Switzerland). John Wiley & Sons, Ltd:  Chichester. 2007. xxvi + 652 pp. $360. ISBN 978-0-470-01672-5. James TernerAvram Gold pp 16279–16280 DOI: 10.1021/ja076984a

Comprehensive Organic Reactions in Aqueous Media, 2nd ed By Chao-Jun Li (McGill University, Canada) and Tak-Hang Chan (McGill University and Hong Kong Polytechnic University)John Wiley & Sons, Inc.:  Hoboken, NJ. 2007. xvi + 418 pp. $125. ISBN 978-0-471-76129-7. David Edwards and Robert Stanley Brown p 16280 DOI: 10.1021/ja076994b